top

  Info

  • Utilizzare la checkbox di selezione a fianco di ciascun documento per attivare le funzionalità di stampa, invio email, download nei formati disponibili del (i) record.

  Info

  • Utilizzare questo link per rimuovere la selezione effettuata.

Biblioteca

MARC Lista (tabellare)
Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl
Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl
Autore Kühl Olaf
Pubbl/distr/stampa Chichester, West Sussex, : Wiley, 2010
Descrizione fisica 1 online resource (365 p.)
Disciplina 541.2242
547.05
Soggetto topico Ligands
Heterocyclic compounds
Transition metal complexes
ISBN 1-282-48220-3
9786612482205
0-470-68583-2
0-470-68584-0
Classificazione CHE 330f
CHE 612f
CHE 670f
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; 1.1 Synthesis; 1.1.1 Synthesis of the Imidazolium Salts; 1.1.2 Closing the Ring; 1.1.3 Synthesis of the Free Carbenes; 1.1.4 Synthesis of Transition Metal Complexes of NHC; 1.2 Properties of NHC; 1.2.1 The Internal Electronic Structure; 1.2.2 Basicity of NHC; 1.2.3 Steric Properties; 1.2.4 The Carbene-Metal Bond; 1.2.5 Decomposition Pathways; References; Chapter 2 Why Functionalisation?; 2.1 Phosphane Mimic; 2.2 Hemilability; 2.3 Chirality; 2.3.1 Planar Chirality; 2.3.2 Axial Chirality
2.4 Ligand Geometry2.5 Catalysis; 2.5.1 Allylic Alkylation; 2.5.2 Coupling Reactions; 2.5.3 Olefin Metathesis; 2.5.4 Polymerisations; 2.5.5 Organocatalysis; References; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; 3.1 Amine Functionalities; 3.1.1 Heteroaromatic Functional Groups; 3.1.2 Oxazolines; 3.1.3 Imino Functional Groups; 3.1.4 Amino Functionalised NHC; 3.2 Oxygen-Containing Groups; 3.3 Phosphane Functionalities; 3.4 Bis-Carbene Ligands; 3.5 Tris-N-Heterocyclic Carbene Ligands; 3.6 Pincer Carbenes; References; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups
4.1 Oxygen-Containing Groups4.2 Nitrogen-Containing Groups; 4.3 NHC Ligands Incorporating Cp Moieties; 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds; 4.5 Immobilisation of the Catalyst; 4.6 Sulfur-Containing Functional Groups; References; Chapter 5 Chiral N-Heterocyclic Carbenes; References; Chapter 6 Natural Products; 6.1 Thiazole; 6.1.1 Isolation and Stability of Thiazolylidene; 6.1.2 Benzothiazoles; 6.1.3 Metal Complexes; 6.2 Amino Acids; 6.3 Purines and Xanthines; 6.4 Carbohydrates; 6.5 Miscellaneous; References; Index; A; B; C; D; E; F; G; H; I; J; K; L; M; N
OP; Q; R; S; T; U; V; W; X; Z
Record Nr. UNINA-9910139504603321
Kühl Olaf  
Chichester, West Sussex, : Wiley, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl
Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl
Autore Kühl Olaf
Pubbl/distr/stampa Chichester, West Sussex, : Wiley, 2010
Descrizione fisica 1 online resource (365 p.)
Disciplina 541.2242
547.05
Soggetto topico Ligands
Heterocyclic compounds
Transition metal complexes
ISBN 1-282-48220-3
9786612482205
0-470-68583-2
0-470-68584-0
Classificazione CHE 330f
CHE 612f
CHE 670f
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; 1.1 Synthesis; 1.1.1 Synthesis of the Imidazolium Salts; 1.1.2 Closing the Ring; 1.1.3 Synthesis of the Free Carbenes; 1.1.4 Synthesis of Transition Metal Complexes of NHC; 1.2 Properties of NHC; 1.2.1 The Internal Electronic Structure; 1.2.2 Basicity of NHC; 1.2.3 Steric Properties; 1.2.4 The Carbene-Metal Bond; 1.2.5 Decomposition Pathways; References; Chapter 2 Why Functionalisation?; 2.1 Phosphane Mimic; 2.2 Hemilability; 2.3 Chirality; 2.3.1 Planar Chirality; 2.3.2 Axial Chirality
2.4 Ligand Geometry2.5 Catalysis; 2.5.1 Allylic Alkylation; 2.5.2 Coupling Reactions; 2.5.3 Olefin Metathesis; 2.5.4 Polymerisations; 2.5.5 Organocatalysis; References; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; 3.1 Amine Functionalities; 3.1.1 Heteroaromatic Functional Groups; 3.1.2 Oxazolines; 3.1.3 Imino Functional Groups; 3.1.4 Amino Functionalised NHC; 3.2 Oxygen-Containing Groups; 3.3 Phosphane Functionalities; 3.4 Bis-Carbene Ligands; 3.5 Tris-N-Heterocyclic Carbene Ligands; 3.6 Pincer Carbenes; References; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups
4.1 Oxygen-Containing Groups4.2 Nitrogen-Containing Groups; 4.3 NHC Ligands Incorporating Cp Moieties; 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds; 4.5 Immobilisation of the Catalyst; 4.6 Sulfur-Containing Functional Groups; References; Chapter 5 Chiral N-Heterocyclic Carbenes; References; Chapter 6 Natural Products; 6.1 Thiazole; 6.1.1 Isolation and Stability of Thiazolylidene; 6.1.2 Benzothiazoles; 6.1.3 Metal Complexes; 6.2 Amino Acids; 6.3 Purines and Xanthines; 6.4 Carbohydrates; 6.5 Miscellaneous; References; Index; A; B; C; D; E; F; G; H; I; J; K; L; M; N
OP; Q; R; S; T; U; V; W; X; Z
Record Nr. UNINA-9910830352403321
Kühl Olaf  
Chichester, West Sussex, : Wiley, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui