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Surface chemistry of surfactants and polymers / / Bengt Kronberg, Krister Holmberg, Björn Lindman
Surface chemistry of surfactants and polymers / / Bengt Kronberg, Krister Holmberg, Björn Lindman
Autore Kronberg Bengt
Pubbl/distr/stampa West Sussex, England : , : Wiley, , 2014
Descrizione fisica 1 online resource (499 p.)
Disciplina 668/.1
Soggetto topico Surface chemistry
Surface active agents
Polymer solutions
Suspensions (Chemistry)
ISBN 1-118-69598-4
1-118-69596-8
1-118-69600-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Surface Chemistry of Surfactants and Polymers; Copyright; Contents; Preface; Acronyms; Chapter 1 Types of Surfactants, their Synthesis, and Applications; Definition of a Surfactant; Surfactants Adsorb at Interfaces; Surfactants Aggregate in Solution and at Interfaces; All Surfactants Contain at Least One Polar Head Group and at Least One Hydrophobic Tail; Surface Active Compounds are Plentiful in Nature; Surfactant Raw Materials may be Based on Petrochemicals or Oleochemicals; Surfactants are Classified by the Polar Head Group; Anionics; Nonionics; Cationics; Zwitterionics
Hydrotropes and SolubilizationGemini Surfactants have Special Features; Synthesis; Gemini Surfactants are More Efficient; Cleavable Surfactants are Attractive from an Environmental Point of View; Background; Alkali-Labile Surfactants; Normal Ester Quats; Betaine Esters; Acid-Labile Surfactants; Acetals; Ortho Esters; Overview; Self-Aggregation of a Surfactant may Increase or Decrease the Hydrolysis Rate of Surfactants Containing a Labile Bond; Increased Hydrolysis Rate-Micellar Catalysis; Decreased Hydrolysis Rate-Micellar Inhibition
Use of Polymerizable Surfactants is a Way to Immobilize the SurfactantMode of Surfactant Polymerization; Position of the Polymerizable Group; Applications of Polymerizable Surfactants; Emulsion Polymerization; Alkyd Emulsions; Surface Modification; Surfactant Self-Assemblies; Special Surfactants Give Extreme Surface Tension Reduction; Bibliography; Chapter 2 Environmental and Health Aspects of Surfactants; Environmental Concern is a Strong Driving Force for Surfactant Development; The Polar Head Group; Polyol Surfactants; Amino Acid-Based Surfactants; The Hydrocarbon Tail; Biodegradability
The Rate of Biodegradation Depends on the Surfactant StructureAquatic Toxicity; Bioaccumulation; Other Regulatory Concerns; Dermatological Aspects of Surfactants; REACH; Bibliography; Chapter 3 Two Fundamental Forces in Surface and Colloid Chemistry; Counterion Binding Affects Self-Assembly and Adsorption of Surfactants and Polymers; Micelle Formation and Interaction of Micelles; Adsorption of Surfactants at Nonpolar Surfaces; Polymer Systems; Colloidal Stability; The Hydrophobic Effect is due to the High Energy Density of Water; Ordering of the Water Leads to an Enthalpy-Entropy Compensation
The Solubility of Hydrocarbons Increases due to Water StructuringBibliography; Chapter 4 Surfactant Self-Assembly: General Aspects and Spherical Micelles; Amphiphilic Molecules Self-Assemble; Surfactants Start to Form Micelles at the CMC; CMC Depends on Chemical Structure; Temperature and Cosolutes Affect CMC; The Solubility of Surfactants may be Strongly Temperature Dependent; Driving Forces of Micelle Formation and Thermodynamic Models; Hydrophobic Interactions; Phase Separation Model; Mass Action Law Model; The Association Process and Counterion Binding can be Monitored by NMR Spectroscopy
Hydrophobic Compounds can be Solubilized in Micelles
Record Nr. UNINA-9910140508903321
Kronberg Bengt  
West Sussex, England : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Surface chemistry of surfactants and polymers / / Bengt Kronberg, Krister Holmberg, Björn Lindman
Surface chemistry of surfactants and polymers / / Bengt Kronberg, Krister Holmberg, Björn Lindman
Autore Kronberg Bengt
Pubbl/distr/stampa West Sussex, England : , : Wiley, , 2014
Descrizione fisica 1 online resource (499 p.)
Disciplina 668/.1
Soggetto topico Surface chemistry
Surface active agents
Polymer solutions
Suspensions (Chemistry)
ISBN 1-118-69598-4
1-118-69596-8
1-118-69600-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Surface Chemistry of Surfactants and Polymers; Copyright; Contents; Preface; Acronyms; Chapter 1 Types of Surfactants, their Synthesis, and Applications; Definition of a Surfactant; Surfactants Adsorb at Interfaces; Surfactants Aggregate in Solution and at Interfaces; All Surfactants Contain at Least One Polar Head Group and at Least One Hydrophobic Tail; Surface Active Compounds are Plentiful in Nature; Surfactant Raw Materials may be Based on Petrochemicals or Oleochemicals; Surfactants are Classified by the Polar Head Group; Anionics; Nonionics; Cationics; Zwitterionics
Hydrotropes and SolubilizationGemini Surfactants have Special Features; Synthesis; Gemini Surfactants are More Efficient; Cleavable Surfactants are Attractive from an Environmental Point of View; Background; Alkali-Labile Surfactants; Normal Ester Quats; Betaine Esters; Acid-Labile Surfactants; Acetals; Ortho Esters; Overview; Self-Aggregation of a Surfactant may Increase or Decrease the Hydrolysis Rate of Surfactants Containing a Labile Bond; Increased Hydrolysis Rate-Micellar Catalysis; Decreased Hydrolysis Rate-Micellar Inhibition
Use of Polymerizable Surfactants is a Way to Immobilize the SurfactantMode of Surfactant Polymerization; Position of the Polymerizable Group; Applications of Polymerizable Surfactants; Emulsion Polymerization; Alkyd Emulsions; Surface Modification; Surfactant Self-Assemblies; Special Surfactants Give Extreme Surface Tension Reduction; Bibliography; Chapter 2 Environmental and Health Aspects of Surfactants; Environmental Concern is a Strong Driving Force for Surfactant Development; The Polar Head Group; Polyol Surfactants; Amino Acid-Based Surfactants; The Hydrocarbon Tail; Biodegradability
The Rate of Biodegradation Depends on the Surfactant StructureAquatic Toxicity; Bioaccumulation; Other Regulatory Concerns; Dermatological Aspects of Surfactants; REACH; Bibliography; Chapter 3 Two Fundamental Forces in Surface and Colloid Chemistry; Counterion Binding Affects Self-Assembly and Adsorption of Surfactants and Polymers; Micelle Formation and Interaction of Micelles; Adsorption of Surfactants at Nonpolar Surfaces; Polymer Systems; Colloidal Stability; The Hydrophobic Effect is due to the High Energy Density of Water; Ordering of the Water Leads to an Enthalpy-Entropy Compensation
The Solubility of Hydrocarbons Increases due to Water StructuringBibliography; Chapter 4 Surfactant Self-Assembly: General Aspects and Spherical Micelles; Amphiphilic Molecules Self-Assemble; Surfactants Start to Form Micelles at the CMC; CMC Depends on Chemical Structure; Temperature and Cosolutes Affect CMC; The Solubility of Surfactants may be Strongly Temperature Dependent; Driving Forces of Micelle Formation and Thermodynamic Models; Hydrophobic Interactions; Phase Separation Model; Mass Action Law Model; The Association Process and Counterion Binding can be Monitored by NMR Spectroscopy
Hydrophobic Compounds can be Solubilized in Micelles
Record Nr. UNINA-9910815550203321
Kronberg Bengt  
West Sussex, England : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui