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Copper-catalyzed asymmetric synthesis / / edited by Alexandre Alexakis, Norbert Krause, and Simon Woodward ; Shinya Adachi [and thirty-one others] ; contributors
| Copper-catalyzed asymmetric synthesis / / edited by Alexandre Alexakis, Norbert Krause, and Simon Woodward ; Shinya Adachi [and thirty-one others] ; contributors |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 |
| Descrizione fisica | 1 online resource (472 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) |
AlexakisAlexandre
KrauseNorbert WoodwardSimon AdachiShinya |
| Soggetto topico |
Asymmetric synthesis
Copper catalysts Organocopper compounds Organic compounds - Synthesis |
| ISBN |
3-527-66457-2
3-527-66459-9 3-527-66460-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Copper-Catalyzed Asymmetric Synthesis; Contents; List of Contributors; Introduction; Chapter 1 The Primary Organometallic in Copper-Catalyzed Reactions; 1.1 Scope and Introduction; 1.2 Terminal Organometallics Sources Available; 1.3 Coordination Motifs in Asymmetric Copper Chemistry; 1.3.1 Classical Cuprate Structure and Accepted Modes of Reaction; 1.3.1.1 Conjugate Addition; 1.3.1.2 SN2 Allylation Reactions; 1.3.2 Motifs in Copper-Main Group Bimetallics and Substrate Binding; 1.4 Asymmetric Organolithium-Copper Reagents; 1.5 Asymmetric Grignard-Copper Reagents
1.6 Asymmetric Organozinc-Copper Reagents1.7 Asymmetric Organoboron-Copper Reagents; 1.8 Asymmetric Organoaluminium-Copper Reagents; 1.9 Asymmetric Silane and Stannane Copper-Promoted Reagents; 1.10 Conclusions; References; Chapter 2 Copper-Catalyzed Asymmetric Conjugate Addition; 2.1 Introduction; 2.2 Conjugate Addition; 2.2.1 The Nucleophile; 2.2.2 The Copper Salt; 2.2.3 The Ligand; 2.2.4 Scope of Michael Acceptors; 2.2.4.1 Enones; 2.2.4.2 Enals; 2.2.4.3 Nitroalkenes; 2.2.4.4 α,β-Unsaturated Amide and Ester Derivatives; 2.2.4.5 Other Michael Acceptors 2.2.5 Formation of All-Carbon Quaternary Stereocenters2.3 Trapping of Enolates; References; Chapter 3 Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond Systems; 3.1 Introduction; 3.2 Copper-Catalyzed Asymmetric Conjugate Addition (ACA) to Polyconjugated Michael Acceptors; 3.2.1 Background; 3.2.2 1,6 Selectivity in ACA to Polyconjugated Systems; 3.2.3 1,4 Selectivity in ACA to Polyconjugated Systems; 3.3 Copper-Catalyzed Asymmetric Allylic Substitution on Extended Multiple-Bond Systems; 3.3.1 Background 3.3.2 Copper-Catalyzed Enantioselective Allylic Substitution on Extended Multiple-Bond Systems3.4 Conclusion; References; Chapter 4 Asymmetric Allylic Alkylation; 4.1 Introduction; 4.2 Nucleophiles in Enantioselective Process Development; 4.2.1 Grignard Nucleophiles; 4.2.2 Diorganozinc Nucleophiles; 4.2.3 Triorganoaluminium Nucleophiles; 4.2.4 Organoboranes Nucleophiles; 4.2.5 Organolithium Nucleophiles; 4.3 Functionalized Substrates; 4.3.1 Trisubstituted Substrates; 4.3.2 Ester Derivatives; 4.3.3 Heterofunctionalized Substrates; 4.3.4 Vinylic Boronates and Silanes 4.3.5 Substrates Bearing Two Leaving Groups (1,4 or 1,1')4.3.6 Enyne-Type Substrates; 4.4 Desymmetrization of meso-Allylic Substrates; 4.4.1 Polycyclic Hydrazines, Symmetric Allylic Epoxides, Oxabicyclic Alkenes; 4.4.2 Cyclic Allylic Bis(Diethyl phosphates); 4.4.3 Miscellaneous Desymmetrization; 4.5 Kinetic Resolution Processes; 4.5.1 Allylic Epoxides and Aziridines, Oxabicyclic Alkenes, Bicyclic Oxazines; 4.5.2 Stereodivergent Kinetic Resolution on Acyclic Allylic Halides; 4.6 Direct Enantioconvergent Transformation; 4.7 Conclusion and Perspectives; References Chapter 5 Ring Opening of Epoxides and Related Systems |
| Record Nr. | UNINA-9910138966103321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Copper-catalyzed asymmetric synthesis / / edited by Alexandre Alexakis, Norbert Krause, and Simon Woodward ; Shinya Adachi [and thirty-one others] ; contributors
| Copper-catalyzed asymmetric synthesis / / edited by Alexandre Alexakis, Norbert Krause, and Simon Woodward ; Shinya Adachi [and thirty-one others] ; contributors |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 |
| Descrizione fisica | 1 online resource (472 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) |
AlexakisAlexandre
KrauseNorbert WoodwardSimon AdachiShinya |
| Soggetto topico |
Asymmetric synthesis
Copper catalysts Organocopper compounds Organic compounds - Synthesis |
| ISBN |
3-527-66457-2
3-527-66459-9 3-527-66460-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Copper-Catalyzed Asymmetric Synthesis; Contents; List of Contributors; Introduction; Chapter 1 The Primary Organometallic in Copper-Catalyzed Reactions; 1.1 Scope and Introduction; 1.2 Terminal Organometallics Sources Available; 1.3 Coordination Motifs in Asymmetric Copper Chemistry; 1.3.1 Classical Cuprate Structure and Accepted Modes of Reaction; 1.3.1.1 Conjugate Addition; 1.3.1.2 SN2 Allylation Reactions; 1.3.2 Motifs in Copper-Main Group Bimetallics and Substrate Binding; 1.4 Asymmetric Organolithium-Copper Reagents; 1.5 Asymmetric Grignard-Copper Reagents
1.6 Asymmetric Organozinc-Copper Reagents1.7 Asymmetric Organoboron-Copper Reagents; 1.8 Asymmetric Organoaluminium-Copper Reagents; 1.9 Asymmetric Silane and Stannane Copper-Promoted Reagents; 1.10 Conclusions; References; Chapter 2 Copper-Catalyzed Asymmetric Conjugate Addition; 2.1 Introduction; 2.2 Conjugate Addition; 2.2.1 The Nucleophile; 2.2.2 The Copper Salt; 2.2.3 The Ligand; 2.2.4 Scope of Michael Acceptors; 2.2.4.1 Enones; 2.2.4.2 Enals; 2.2.4.3 Nitroalkenes; 2.2.4.4 α,β-Unsaturated Amide and Ester Derivatives; 2.2.4.5 Other Michael Acceptors 2.2.5 Formation of All-Carbon Quaternary Stereocenters2.3 Trapping of Enolates; References; Chapter 3 Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond Systems; 3.1 Introduction; 3.2 Copper-Catalyzed Asymmetric Conjugate Addition (ACA) to Polyconjugated Michael Acceptors; 3.2.1 Background; 3.2.2 1,6 Selectivity in ACA to Polyconjugated Systems; 3.2.3 1,4 Selectivity in ACA to Polyconjugated Systems; 3.3 Copper-Catalyzed Asymmetric Allylic Substitution on Extended Multiple-Bond Systems; 3.3.1 Background 3.3.2 Copper-Catalyzed Enantioselective Allylic Substitution on Extended Multiple-Bond Systems3.4 Conclusion; References; Chapter 4 Asymmetric Allylic Alkylation; 4.1 Introduction; 4.2 Nucleophiles in Enantioselective Process Development; 4.2.1 Grignard Nucleophiles; 4.2.2 Diorganozinc Nucleophiles; 4.2.3 Triorganoaluminium Nucleophiles; 4.2.4 Organoboranes Nucleophiles; 4.2.5 Organolithium Nucleophiles; 4.3 Functionalized Substrates; 4.3.1 Trisubstituted Substrates; 4.3.2 Ester Derivatives; 4.3.3 Heterofunctionalized Substrates; 4.3.4 Vinylic Boronates and Silanes 4.3.5 Substrates Bearing Two Leaving Groups (1,4 or 1,1')4.3.6 Enyne-Type Substrates; 4.4 Desymmetrization of meso-Allylic Substrates; 4.4.1 Polycyclic Hydrazines, Symmetric Allylic Epoxides, Oxabicyclic Alkenes; 4.4.2 Cyclic Allylic Bis(Diethyl phosphates); 4.4.3 Miscellaneous Desymmetrization; 4.5 Kinetic Resolution Processes; 4.5.1 Allylic Epoxides and Aziridines, Oxabicyclic Alkenes, Bicyclic Oxazines; 4.5.2 Stereodivergent Kinetic Resolution on Acyclic Allylic Halides; 4.6 Direct Enantioconvergent Transformation; 4.7 Conclusion and Perspectives; References Chapter 5 Ring Opening of Epoxides and Related Systems |
| Record Nr. | UNINA-9910824691103321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fundiert forschen : Wissenschaftliche Bildung für Promovierende und Postdocs / / herausgegeben von Hanna Kauhaus, Norbert Krause
| Fundiert forschen : Wissenschaftliche Bildung für Promovierende und Postdocs / / herausgegeben von Hanna Kauhaus, Norbert Krause |
| Edizione | [1st ed. 2017.] |
| Pubbl/distr/stampa | Wiesbaden : , : Springer Fachmedien Wiesbaden : , : Imprint : Springer VS, , 2017 |
| Descrizione fisica | 1 online resource (X, 221 S.) |
| Disciplina | 378 |
| Soggetto topico |
Higher education
Philosophy and science Philosophy and social sciences Higher Education Philosophy of Science Philosophy of Education |
| ISBN | 3-658-15575-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto | Grundlagen und Ziele wissenschaftlicher Bildung -- Inhalte wissenschaftlicher Bildung -- Praxisbeispiele -- Interdisziplinarität. |
| Record Nr. | UNINA-9910483911203321 |
| Wiesbaden : , : Springer Fachmedien Wiesbaden : , : Imprint : Springer VS, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern organocopper chemistry
| Modern organocopper chemistry |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (391 pages) |
| Disciplina | 547/.05652 |
| Soggetto topico |
Organocopper compounds
Organic Chemistry Chemistry Physical Sciences & Mathematics |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-55752-4
9786610557523 3-527-60008-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910146055203321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern organocopper chemistry
| Modern organocopper chemistry |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (391 pages) |
| Disciplina | 547/.05652 |
| Soggetto topico |
Organocopper compounds
Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN |
1-280-55752-4
9786610557523 3-527-60008-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830154803321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern organocopper chemistry
| Modern organocopper chemistry |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (391 pages) |
| Disciplina | 547/.05652 |
| Soggetto topico |
Organocopper compounds
Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN |
1-280-55752-4
9786610557523 3-527-60008-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910876857503321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||