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Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen
| Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen |
| Autore | Kamer Paul |
| Pubbl/distr/stampa | Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 |
| Descrizione fisica | 1 online resource (567 p.) |
| Disciplina |
541.2242
546.712595 546/.712595 |
| Altri autori (Persone) | LeeuwenP. W. N. M. van (Piet W. N. M.) |
| Soggetto topico |
Phosphorus compounds
Ligands Catalysis TECHNOLOGY & ENGINEERING / Material Science |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-78471-7
9786613695109 1-118-29970-1 1-118-29971-X 1-118-29973-6 |
| Classificazione | TEC021000 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus( III ) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References
2 Chiral Phosphines and Diphosphines2.1 Introduction; 2.1.1 Early developments; 2.2 Chiral chelating diphosphines with a linking scaffold; 2.2.1 Building chiral backbones from naturally available materials; 2.2.2 Design and synthesis of chiral backbones; 2.2.3 Synthesis from optical resolution of phosphine precursors or intermediates; 2.3 Chiral atropisomeric biaryl diphosphines; 2.3.1 Synthesis of BINAP and its derivatives; 2.3.2 Synthesis of atropisomeric biaryl ligands; 2.3.3 General strategies of synthesizing of atropisomeric biaryl ligands; 2.4 Chiral phosphacyclic diphosphines 2.4.1 Fundamental discovery and syntheses of BPE and DuPhos2.4.2 Design and synthesis of bisphosphetanes; 2.4.3 Design and synthesis of bisphospholanes; 2.4.4 Design and synthesis of bisphospholes; 2.4.5 Design and synthesis of bisphosphinanes; 2.4.6 Design and synthesis of bisphosphepines; 2.4.7 Summary of synthetic strategies of phosphacycles; 2.5 P-stereogenic diphosphine ligands; 2.6 Experimental procedures for the syntheses of selected diphosphine ligands; 2.6.1 Synthesis procedure for DIOP* ligand; 2.6.2 Synthesis procedure of SDP ligands; 2.6.3 Synthesis procedure of (R,R)-BICP 2.6.4 Synthesis procedure of SEGPHOS2.6.5 Synthesis procedure of Ph-BPE; 2.6.6 Synthesis procedure of TangPhos; 2.6.7 Synthesis procedure of Binaphane; 2.7 Concluding remarks; References; 3 Design and Synthesis of Phosphite Ligands for Homogeneous Catalysis; 3.1 Introduction; 3.2 Synthesis of phosphites; 3.2.1 Monophosphites; 3.2.2 Diphosphite ligands; 3.2.3 Triphosphites; 3.3 Highlights of catalytic applications of phosphite ligands; 3.3.1 Hydrogenation reactions; 3.3.2 Functionalization of alkenes: hydroformylation and hydrocyanation 3.3.3 Addition of nucleophiles to carbonyl compounds and derivatives3.3.4 Allylic substitution reactions; 3.3.5 Miscellaneous reactions; 3.4 General synthetic procedures; 3.4.1 Symmetrically substituted phosphites; 3.4.2 Nonsymmetrically substituted phosphites; 3.4.3 Phosphites bearing dioxaphospho-cyclic units; References; 4 Phosphoramidite Ligands; 4.1 Introduction; 4.1.1 History; 4.2 Synthesis of phosphoramidites; 4.3 Reactivity of the phosphoramidites; 4.4 Types of phosphoramidite ligands; 4.4.1 Acyclic monodentate phosphoramidites; 4.4.2 Cyclic monodentate phosphoramidites based on diols 4.4.3 Cyclic phosphoramidites based on amino alcohols |
| Record Nr. | UNINA-9910141261103321 |
Kamer Paul
|
||
| Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen
| Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen |
| Autore | Kamer Paul |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 |
| Descrizione fisica | 1 online resource (567 p.) |
| Disciplina |
541.2242
546.712595 546/.712595 |
| Altri autori (Persone) | LeeuwenP. W. N. M. van (Piet W. N. M.) |
| Soggetto topico |
Phosphorus compounds
Ligands Catalysis TECHNOLOGY & ENGINEERING / Material Science |
| ISBN |
1-280-78471-7
9786613695109 1-118-29970-1 1-118-29971-X 1-118-29973-6 |
| Classificazione | TEC021000 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus( III ) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References
2 Chiral Phosphines and Diphosphines2.1 Introduction; 2.1.1 Early developments; 2.2 Chiral chelating diphosphines with a linking scaffold; 2.2.1 Building chiral backbones from naturally available materials; 2.2.2 Design and synthesis of chiral backbones; 2.2.3 Synthesis from optical resolution of phosphine precursors or intermediates; 2.3 Chiral atropisomeric biaryl diphosphines; 2.3.1 Synthesis of BINAP and its derivatives; 2.3.2 Synthesis of atropisomeric biaryl ligands; 2.3.3 General strategies of synthesizing of atropisomeric biaryl ligands; 2.4 Chiral phosphacyclic diphosphines 2.4.1 Fundamental discovery and syntheses of BPE and DuPhos2.4.2 Design and synthesis of bisphosphetanes; 2.4.3 Design and synthesis of bisphospholanes; 2.4.4 Design and synthesis of bisphospholes; 2.4.5 Design and synthesis of bisphosphinanes; 2.4.6 Design and synthesis of bisphosphepines; 2.4.7 Summary of synthetic strategies of phosphacycles; 2.5 P-stereogenic diphosphine ligands; 2.6 Experimental procedures for the syntheses of selected diphosphine ligands; 2.6.1 Synthesis procedure for DIOP* ligand; 2.6.2 Synthesis procedure of SDP ligands; 2.6.3 Synthesis procedure of (R,R)-BICP 2.6.4 Synthesis procedure of SEGPHOS2.6.5 Synthesis procedure of Ph-BPE; 2.6.6 Synthesis procedure of TangPhos; 2.6.7 Synthesis procedure of Binaphane; 2.7 Concluding remarks; References; 3 Design and Synthesis of Phosphite Ligands for Homogeneous Catalysis; 3.1 Introduction; 3.2 Synthesis of phosphites; 3.2.1 Monophosphites; 3.2.2 Diphosphite ligands; 3.2.3 Triphosphites; 3.3 Highlights of catalytic applications of phosphite ligands; 3.3.1 Hydrogenation reactions; 3.3.2 Functionalization of alkenes: hydroformylation and hydrocyanation 3.3.3 Addition of nucleophiles to carbonyl compounds and derivatives3.3.4 Allylic substitution reactions; 3.3.5 Miscellaneous reactions; 3.4 General synthetic procedures; 3.4.1 Symmetrically substituted phosphites; 3.4.2 Nonsymmetrically substituted phosphites; 3.4.3 Phosphites bearing dioxaphospho-cyclic units; References; 4 Phosphoramidite Ligands; 4.1 Introduction; 4.1.1 History; 4.2 Synthesis of phosphoramidites; 4.3 Reactivity of the phosphoramidites; 4.4 Types of phosphoramidite ligands; 4.4.1 Acyclic monodentate phosphoramidites; 4.4.2 Cyclic monodentate phosphoramidites based on diols 4.4.3 Cyclic phosphoramidites based on amino alcohols |
| Record Nr. | UNINA-9910810261803321 |
|
Kamer Paul
|
||
| Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||