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Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs
| Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (342 p.) |
| Disciplina |
541.395
547.1395 |
| Altri autori (Persone) |
VosD. E. de (Dirk E.)
VankelecomI. F. J (Ivo F. J.) JacobsPeter A |
| Soggetto topico |
Enantioselective catalysis
Catalysts |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-76408-6
9786611764081 3-527-61314-5 3-527-61315-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chiral Catalvst Immobilization and Recycling; Contents; 1 Enantioselective Heterogeneous Catalysis: Academic and Industrial Challenges; 1.1 Introduction; 1.2 The Industrial Process in General and the Specific Prerequisites for Chiral Catalysts; 1. 2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of (Heterogeneous) Enantioselective Catalysts; 1. 2.3 Important Criteria for Enantioselective Catalysts; 1.3 The General Challenges; 1.3.1 For Academia; 1.3.2 For Industry
1.4 Chiral Heterogeneous Catalysts: State of the Art and Future Challenges1.4.1 Heterogeneous Catalysts Modified with a Chiral Auxiliary; 1.4.1.1 Metallic Catalysts on Chiral Supports; 1.4.1.2 Metallic Catalysts Modified with a Low Molecular Weight Chiral Auxiliary; 1.4.1.3 Metal Oxide Catalysts Modified with a Chiral Auxiliary having Low Molecular Weight; 1.4.2 Immobilized and Functionalized Homogeneous Catalysts; 1.4.2.1 lmmobilized Homogeneous Catalysts; 1.4.2.2 Alternative Methods Using Functionalized Ligands; 1.4.3 Catalysts with No Known Heterogeneous or Homogeneous Precedent 1.4.3.1 Insoluble Polypeptides and Gels1.4.3.2 Artificial Catalytic Antibodies; 1.5 Conclusions; References; 2 Catalyst Immobilization on Inorganic Supports; 2.1 Introduction; 2.2 General Considerations; 2.3 Supports; 2.4 Improved Activity of Heterogeneous Complexes; 2.5 Practical Examples; 2.5.1 Covalent Attachment; 2.5.2 Adsorption or Ion-Pair Formation; 2.5.3 Encapsutation; 2.5.4 Entrapment; 2.5.5 Supported Liquid Phase (SLP); 2.5.6 Modification of an Achiral Heterogeneous Catalyst with a Chiral Auxiliary; 2.5.7 Achiral Metal Catalysts on Chiral Supports; References 3 Organic Polymers as a Catalyst Recovery Vehicle3.1 General Introduction; 3.2 Alkene Hydrogenation; 3.3 Carbonyl and Imine Reduction; 3.4 Carbon-Carbon Bond Formation; 3.5 Carbonyl Alkylation; 3.6 Diels-Alder Reactions; 3.7 Enolate Chemistry; 3.8 Strecker Chemistry; 3.9 Asymmetric Dihydroxylation; 3.10 Epoxidation and Epoxide Ring Opening; 3.11 Acylation Catalysts; 3.12 Conclusion; References; 4 Liquid Biphasic Enantioselective Catalysis; 4.1 Introduction; 4.2 Hydrogenation; 4.3 Hydroformylation; 4.4 Oxidation; 4.5 Lewis Acid-Catalyzed Reactions; 4.6 Enzymatic Reactions; 4.7 Summary References5 Immobilized Enzymes in Enantioselective Organic Synthesis; 5.1 Introduction; 5.2 Immobilization; 5.2.1 Methods of Immobilization; 5.2.1.1 Enzymes; 5.2.1.2 Carriers; 5.2.1.3 Binding Enzymes to Carriers; 5.2.1.4 Cross-Linked Enzyme Crystals; 5.2.2 Activity Assay; 5.2.3 Activity Balance; 5.2.4 Cost of Immobilization; 5.3 Operation; 5.3.1 Reactors; 5.3.2 Operational Stability; 5.4 Summary; References; 6 Enantioselective Hydrogenation Catalyzed by Platinum Group Metals Modified by Natural Alkaloids; 6.1 Historical Perspective 6.2 Enantioselective Hydrogenation of Activated Ketones over Platinum |
| Record Nr. | UNINA-9910144279303321 |
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs
| Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (342 p.) |
| Disciplina |
541.395
547.1395 |
| Altri autori (Persone) |
VosD. E. de (Dirk E.)
VankelecomI. F. J (Ivo F. J.) JacobsPeter A |
| Soggetto topico |
Enantioselective catalysis
Catalysts |
| ISBN |
1-281-76408-6
9786611764081 3-527-61314-5 3-527-61315-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chiral Catalvst Immobilization and Recycling; Contents; 1 Enantioselective Heterogeneous Catalysis: Academic and Industrial Challenges; 1.1 Introduction; 1.2 The Industrial Process in General and the Specific Prerequisites for Chiral Catalysts; 1. 2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of (Heterogeneous) Enantioselective Catalysts; 1. 2.3 Important Criteria for Enantioselective Catalysts; 1.3 The General Challenges; 1.3.1 For Academia; 1.3.2 For Industry
1.4 Chiral Heterogeneous Catalysts: State of the Art and Future Challenges1.4.1 Heterogeneous Catalysts Modified with a Chiral Auxiliary; 1.4.1.1 Metallic Catalysts on Chiral Supports; 1.4.1.2 Metallic Catalysts Modified with a Low Molecular Weight Chiral Auxiliary; 1.4.1.3 Metal Oxide Catalysts Modified with a Chiral Auxiliary having Low Molecular Weight; 1.4.2 Immobilized and Functionalized Homogeneous Catalysts; 1.4.2.1 lmmobilized Homogeneous Catalysts; 1.4.2.2 Alternative Methods Using Functionalized Ligands; 1.4.3 Catalysts with No Known Heterogeneous or Homogeneous Precedent 1.4.3.1 Insoluble Polypeptides and Gels1.4.3.2 Artificial Catalytic Antibodies; 1.5 Conclusions; References; 2 Catalyst Immobilization on Inorganic Supports; 2.1 Introduction; 2.2 General Considerations; 2.3 Supports; 2.4 Improved Activity of Heterogeneous Complexes; 2.5 Practical Examples; 2.5.1 Covalent Attachment; 2.5.2 Adsorption or Ion-Pair Formation; 2.5.3 Encapsutation; 2.5.4 Entrapment; 2.5.5 Supported Liquid Phase (SLP); 2.5.6 Modification of an Achiral Heterogeneous Catalyst with a Chiral Auxiliary; 2.5.7 Achiral Metal Catalysts on Chiral Supports; References 3 Organic Polymers as a Catalyst Recovery Vehicle3.1 General Introduction; 3.2 Alkene Hydrogenation; 3.3 Carbonyl and Imine Reduction; 3.4 Carbon-Carbon Bond Formation; 3.5 Carbonyl Alkylation; 3.6 Diels-Alder Reactions; 3.7 Enolate Chemistry; 3.8 Strecker Chemistry; 3.9 Asymmetric Dihydroxylation; 3.10 Epoxidation and Epoxide Ring Opening; 3.11 Acylation Catalysts; 3.12 Conclusion; References; 4 Liquid Biphasic Enantioselective Catalysis; 4.1 Introduction; 4.2 Hydrogenation; 4.3 Hydroformylation; 4.4 Oxidation; 4.5 Lewis Acid-Catalyzed Reactions; 4.6 Enzymatic Reactions; 4.7 Summary References5 Immobilized Enzymes in Enantioselective Organic Synthesis; 5.1 Introduction; 5.2 Immobilization; 5.2.1 Methods of Immobilization; 5.2.1.1 Enzymes; 5.2.1.2 Carriers; 5.2.1.3 Binding Enzymes to Carriers; 5.2.1.4 Cross-Linked Enzyme Crystals; 5.2.2 Activity Assay; 5.2.3 Activity Balance; 5.2.4 Cost of Immobilization; 5.3 Operation; 5.3.1 Reactors; 5.3.2 Operational Stability; 5.4 Summary; References; 6 Enantioselective Hydrogenation Catalyzed by Platinum Group Metals Modified by Natural Alkaloids; 6.1 Historical Perspective 6.2 Enantioselective Hydrogenation of Activated Ketones over Platinum |
| Record Nr. | UNINA-9910830973703321 |
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral catalyst immobilization and recycling / / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs
| Chiral catalyst immobilization and recycling / / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (342 p.) |
| Disciplina |
541.395
547.1395 |
| Altri autori (Persone) |
VosD. E. de (Dirk E.)
VankelecomI. F. J (Ivo F. J.) JacobsPeter A |
| Soggetto topico |
Enantioselective catalysis
Catalysts |
| ISBN |
1-281-76408-6
9786611764081 3-527-61314-5 3-527-61315-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chiral Catalvst Immobilization and Recycling; Contents; 1 Enantioselective Heterogeneous Catalysis: Academic and Industrial Challenges; 1.1 Introduction; 1.2 The Industrial Process in General and the Specific Prerequisites for Chiral Catalysts; 1. 2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of (Heterogeneous) Enantioselective Catalysts; 1. 2.3 Important Criteria for Enantioselective Catalysts; 1.3 The General Challenges; 1.3.1 For Academia; 1.3.2 For Industry
1.4 Chiral Heterogeneous Catalysts: State of the Art and Future Challenges1.4.1 Heterogeneous Catalysts Modified with a Chiral Auxiliary; 1.4.1.1 Metallic Catalysts on Chiral Supports; 1.4.1.2 Metallic Catalysts Modified with a Low Molecular Weight Chiral Auxiliary; 1.4.1.3 Metal Oxide Catalysts Modified with a Chiral Auxiliary having Low Molecular Weight; 1.4.2 Immobilized and Functionalized Homogeneous Catalysts; 1.4.2.1 lmmobilized Homogeneous Catalysts; 1.4.2.2 Alternative Methods Using Functionalized Ligands; 1.4.3 Catalysts with No Known Heterogeneous or Homogeneous Precedent 1.4.3.1 Insoluble Polypeptides and Gels1.4.3.2 Artificial Catalytic Antibodies; 1.5 Conclusions; References; 2 Catalyst Immobilization on Inorganic Supports; 2.1 Introduction; 2.2 General Considerations; 2.3 Supports; 2.4 Improved Activity of Heterogeneous Complexes; 2.5 Practical Examples; 2.5.1 Covalent Attachment; 2.5.2 Adsorption or Ion-Pair Formation; 2.5.3 Encapsutation; 2.5.4 Entrapment; 2.5.5 Supported Liquid Phase (SLP); 2.5.6 Modification of an Achiral Heterogeneous Catalyst with a Chiral Auxiliary; 2.5.7 Achiral Metal Catalysts on Chiral Supports; References 3 Organic Polymers as a Catalyst Recovery Vehicle3.1 General Introduction; 3.2 Alkene Hydrogenation; 3.3 Carbonyl and Imine Reduction; 3.4 Carbon-Carbon Bond Formation; 3.5 Carbonyl Alkylation; 3.6 Diels-Alder Reactions; 3.7 Enolate Chemistry; 3.8 Strecker Chemistry; 3.9 Asymmetric Dihydroxylation; 3.10 Epoxidation and Epoxide Ring Opening; 3.11 Acylation Catalysts; 3.12 Conclusion; References; 4 Liquid Biphasic Enantioselective Catalysis; 4.1 Introduction; 4.2 Hydrogenation; 4.3 Hydroformylation; 4.4 Oxidation; 4.5 Lewis Acid-Catalyzed Reactions; 4.6 Enzymatic Reactions; 4.7 Summary References5 Immobilized Enzymes in Enantioselective Organic Synthesis; 5.1 Introduction; 5.2 Immobilization; 5.2.1 Methods of Immobilization; 5.2.1.1 Enzymes; 5.2.1.2 Carriers; 5.2.1.3 Binding Enzymes to Carriers; 5.2.1.4 Cross-Linked Enzyme Crystals; 5.2.2 Activity Assay; 5.2.3 Activity Balance; 5.2.4 Cost of Immobilization; 5.3 Operation; 5.3.1 Reactors; 5.3.2 Operational Stability; 5.4 Summary; References; 6 Enantioselective Hydrogenation Catalyzed by Platinum Group Metals Modified by Natural Alkaloids; 6.1 Historical Perspective 6.2 Enantioselective Hydrogenation of Activated Ketones over Platinum |
| Record Nr. | UNINA-9910877635903321 |
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||