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Principles of chemical kinetics [[electronic resource] /] / James E. House
| Principles of chemical kinetics [[electronic resource] /] / James E. House |
| Autore | House J. E |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Amsterdam ; ; Boston, : Elsevier/Academic Press, c2007 |
| Descrizione fisica | 1 online resource (337 p.) |
| Disciplina | 541/.394 |
| Soggetto topico |
Chemical kinetics
Chemistry, Physical and theoretical |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-54031-9
9786612540318 0-08-055050-9 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Principles of Chemical Kinetics; Copyright Page; Preface; Contents; Chapter 1: Fundamental Concepts of Kinetics; 1.1 Rates of Reactions; 1.2.1 First-Order; 1.2.3 Zero-Order; 1.2.4 Nth-Order Reactions; 1.3 Cautions on Treating Kinetic Data; 1.5 Some Common Reaction Mechanisms; 1.5.3 Substitution Reactions; References for Further Reading; Problems; Chapter 2: Kinetics of More Complex Systems; 2.1 Second-Order Reaction, First-Order in Two Components; 2.3 Parallel Reactions; 2.7 Autocatalysis; References for Further Reading; Problems; Chapter 3: Techniques and Methods
3.1 Calculating Rate Constants 3.2 The Method of Half-Lives; 3.4 Using Large Excess of a Reactant (Flooding); 3.5 The Logarithmic Method; 3.6 Effects of Pressure; 3.9 Tracer Methods; References for Further Reading; Problems; Chapter 4: Reactions in the Gas Phase; 4.1 Collision Theory; 4.2 The Potential Energy Surface; 4.3 Transition State Theory; 4.4 Unimolecular Decomposition of Gases; 4.5 Free Radical or Chain Mechanisms; 4.6 Adsorption of Gases on Solids; 4.6.2 B-E-T Isotherm; References for Further Reading; Problems; Chapter 5: Reactions in Solutions; 5.1 The Nature of Liquids 5.1.1 Intermolecular Forces 5.1.2 The Solubility Parameter; 5.1.3 Solvation of Ions and Molecules; 5.1.4 The Hard-Soft Interaction Principle (HSIP); 5.2 Effects of Solvent Polarity on Rates; 5.3 Ideal Solutions; 5.5 Effects of Solvent Cohesion Energy on Rates; 5.6 Solvation and Its Effects on Rates; 5.7 Effects of Ionic Strength; 5.8 Linear Free Energy Relationships; 5.9 The Compensation Effect; 5.10 Some Correlations of Rates with Solubility Parameter; References for Further Reading; Problems; Chapter 6: Enzyme Catalysis; 6.1 Enzyme Action; 6.2.2 Lineweaver-Burk and Eadie Analyses 6.3.1 Competitive Inhibition References for Further Reading; Problems; Chapter 7: Kinetics of Reactions in the Solid State; 7.1 Some General Considerations; 7.2 Factors Affecting Reactions in Solids; 7.3 Rate Laws for Reactions in Solids; 7.3.1 The Parabolic Rate Law; 7.3.2 The First-Order Rate Law; 7.3.3 The Contracting Sphere Rate Law; 7.4 The Prout-Tompkins Equation; 7.5 Rate Laws Based on Nucleation; 7.6 Applying Rate Laws; 7.7 Results of Some Kinetic Studies; 7.7.1 The Deaquation-Anation of [Co(NH3)5H2O]Cl3; 7.7.3 The Dehydration of Trans-[Co(NH3)4Cl2]IO3bull 2H2O 7.7.4 Two Reacting Solids Problems; Chapter 8: Nonisothermal Methods in Kinetics; 8.1 TGA and DSC Methods; 8.3 The Reich and Stivala Method; 8.4 A Method Based on Three (alpha,T) Data Pairs; 8.5 A Method Based on Four (alpha,T) Data Pairs; 8.6 A Differential Method; 8.7 A Comprehensive Nonisothermal Kinetic Method; 8.8 The General Rate Law and a Comprehensive Method; References for Further Reading; Problems; Chapter 9: Additional Applications of Kinetics; 9.1 Radioactive Decay; 9.1.1 Independent Isotopes; 9.1.2 Parent-Daughter Cases; 9.3 A Further Look at Solvent Properties and Rates References for Further Reading |
| Record Nr. | UNINA-9910459098003321 |
House J. E
|
||
| Amsterdam ; ; Boston, : Elsevier/Academic Press, c2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Principles of chemical kinetics [[electronic resource] /] / James E. House
| Principles of chemical kinetics [[electronic resource] /] / James E. House |
| Autore | House J. E |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Amsterdam ; ; Boston, : Elsevier/Academic Press, c2007 |
| Descrizione fisica | 1 online resource (337 p.) |
| Disciplina | 541/.394 |
| Soggetto topico |
Chemical kinetics
Chemistry, Physical and theoretical |
| ISBN |
1-282-54031-9
9786612540318 0-08-055050-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Principles of Chemical Kinetics; Copyright Page; Preface; Contents; Chapter 1: Fundamental Concepts of Kinetics; 1.1 Rates of Reactions; 1.2.1 First-Order; 1.2.3 Zero-Order; 1.2.4 Nth-Order Reactions; 1.3 Cautions on Treating Kinetic Data; 1.5 Some Common Reaction Mechanisms; 1.5.3 Substitution Reactions; References for Further Reading; Problems; Chapter 2: Kinetics of More Complex Systems; 2.1 Second-Order Reaction, First-Order in Two Components; 2.3 Parallel Reactions; 2.7 Autocatalysis; References for Further Reading; Problems; Chapter 3: Techniques and Methods
3.1 Calculating Rate Constants 3.2 The Method of Half-Lives; 3.4 Using Large Excess of a Reactant (Flooding); 3.5 The Logarithmic Method; 3.6 Effects of Pressure; 3.9 Tracer Methods; References for Further Reading; Problems; Chapter 4: Reactions in the Gas Phase; 4.1 Collision Theory; 4.2 The Potential Energy Surface; 4.3 Transition State Theory; 4.4 Unimolecular Decomposition of Gases; 4.5 Free Radical or Chain Mechanisms; 4.6 Adsorption of Gases on Solids; 4.6.2 B-E-T Isotherm; References for Further Reading; Problems; Chapter 5: Reactions in Solutions; 5.1 The Nature of Liquids 5.1.1 Intermolecular Forces 5.1.2 The Solubility Parameter; 5.1.3 Solvation of Ions and Molecules; 5.1.4 The Hard-Soft Interaction Principle (HSIP); 5.2 Effects of Solvent Polarity on Rates; 5.3 Ideal Solutions; 5.5 Effects of Solvent Cohesion Energy on Rates; 5.6 Solvation and Its Effects on Rates; 5.7 Effects of Ionic Strength; 5.8 Linear Free Energy Relationships; 5.9 The Compensation Effect; 5.10 Some Correlations of Rates with Solubility Parameter; References for Further Reading; Problems; Chapter 6: Enzyme Catalysis; 6.1 Enzyme Action; 6.2.2 Lineweaver-Burk and Eadie Analyses 6.3.1 Competitive Inhibition References for Further Reading; Problems; Chapter 7: Kinetics of Reactions in the Solid State; 7.1 Some General Considerations; 7.2 Factors Affecting Reactions in Solids; 7.3 Rate Laws for Reactions in Solids; 7.3.1 The Parabolic Rate Law; 7.3.2 The First-Order Rate Law; 7.3.3 The Contracting Sphere Rate Law; 7.4 The Prout-Tompkins Equation; 7.5 Rate Laws Based on Nucleation; 7.6 Applying Rate Laws; 7.7 Results of Some Kinetic Studies; 7.7.1 The Deaquation-Anation of [Co(NH3)5H2O]Cl3; 7.7.3 The Dehydration of Trans-[Co(NH3)4Cl2]IO3bull 2H2O 7.7.4 Two Reacting Solids Problems; Chapter 8: Nonisothermal Methods in Kinetics; 8.1 TGA and DSC Methods; 8.3 The Reich and Stivala Method; 8.4 A Method Based on Three (alpha,T) Data Pairs; 8.5 A Method Based on Four (alpha,T) Data Pairs; 8.6 A Differential Method; 8.7 A Comprehensive Nonisothermal Kinetic Method; 8.8 The General Rate Law and a Comprehensive Method; References for Further Reading; Problems; Chapter 9: Additional Applications of Kinetics; 9.1 Radioactive Decay; 9.1.1 Independent Isotopes; 9.1.2 Parent-Daughter Cases; 9.3 A Further Look at Solvent Properties and Rates References for Further Reading |
| Record Nr. | UNINA-9910792587203321 |
|
House J. E
|
||
| Amsterdam ; ; Boston, : Elsevier/Academic Press, c2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Principles of chemical kinetics / / James E. House
| Principles of chemical kinetics / / James E. House |
| Autore | House J. E |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Amsterdam ; ; Boston, : Elsevier/Academic Press, c2007 |
| Descrizione fisica | 1 online resource (337 p.) |
| Disciplina | 541/.394 |
| Soggetto topico |
Chemical kinetics
Chemistry, Physical and theoretical |
| ISBN |
1-282-54031-9
9786612540318 0-08-055050-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Principles of Chemical Kinetics; Copyright Page; Preface; Contents; Chapter 1: Fundamental Concepts of Kinetics; 1.1 Rates of Reactions; 1.2.1 First-Order; 1.2.3 Zero-Order; 1.2.4 Nth-Order Reactions; 1.3 Cautions on Treating Kinetic Data; 1.5 Some Common Reaction Mechanisms; 1.5.3 Substitution Reactions; References for Further Reading; Problems; Chapter 2: Kinetics of More Complex Systems; 2.1 Second-Order Reaction, First-Order in Two Components; 2.3 Parallel Reactions; 2.7 Autocatalysis; References for Further Reading; Problems; Chapter 3: Techniques and Methods
3.1 Calculating Rate Constants 3.2 The Method of Half-Lives; 3.4 Using Large Excess of a Reactant (Flooding); 3.5 The Logarithmic Method; 3.6 Effects of Pressure; 3.9 Tracer Methods; References for Further Reading; Problems; Chapter 4: Reactions in the Gas Phase; 4.1 Collision Theory; 4.2 The Potential Energy Surface; 4.3 Transition State Theory; 4.4 Unimolecular Decomposition of Gases; 4.5 Free Radical or Chain Mechanisms; 4.6 Adsorption of Gases on Solids; 4.6.2 B-E-T Isotherm; References for Further Reading; Problems; Chapter 5: Reactions in Solutions; 5.1 The Nature of Liquids 5.1.1 Intermolecular Forces 5.1.2 The Solubility Parameter; 5.1.3 Solvation of Ions and Molecules; 5.1.4 The Hard-Soft Interaction Principle (HSIP); 5.2 Effects of Solvent Polarity on Rates; 5.3 Ideal Solutions; 5.5 Effects of Solvent Cohesion Energy on Rates; 5.6 Solvation and Its Effects on Rates; 5.7 Effects of Ionic Strength; 5.8 Linear Free Energy Relationships; 5.9 The Compensation Effect; 5.10 Some Correlations of Rates with Solubility Parameter; References for Further Reading; Problems; Chapter 6: Enzyme Catalysis; 6.1 Enzyme Action; 6.2.2 Lineweaver-Burk and Eadie Analyses 6.3.1 Competitive Inhibition References for Further Reading; Problems; Chapter 7: Kinetics of Reactions in the Solid State; 7.1 Some General Considerations; 7.2 Factors Affecting Reactions in Solids; 7.3 Rate Laws for Reactions in Solids; 7.3.1 The Parabolic Rate Law; 7.3.2 The First-Order Rate Law; 7.3.3 The Contracting Sphere Rate Law; 7.4 The Prout-Tompkins Equation; 7.5 Rate Laws Based on Nucleation; 7.6 Applying Rate Laws; 7.7 Results of Some Kinetic Studies; 7.7.1 The Deaquation-Anation of [Co(NH3)5H2O]Cl3; 7.7.3 The Dehydration of Trans-[Co(NH3)4Cl2]IO3bull 2H2O 7.7.4 Two Reacting Solids Problems; Chapter 8: Nonisothermal Methods in Kinetics; 8.1 TGA and DSC Methods; 8.3 The Reich and Stivala Method; 8.4 A Method Based on Three (alpha,T) Data Pairs; 8.5 A Method Based on Four (alpha,T) Data Pairs; 8.6 A Differential Method; 8.7 A Comprehensive Nonisothermal Kinetic Method; 8.8 The General Rate Law and a Comprehensive Method; References for Further Reading; Problems; Chapter 9: Additional Applications of Kinetics; 9.1 Radioactive Decay; 9.1.1 Independent Isotopes; 9.1.2 Parent-Daughter Cases; 9.3 A Further Look at Solvent Properties and Rates References for Further Reading |
| Record Nr. | UNINA-9910828161103321 |
|
House J. E
|
||
| Amsterdam ; ; Boston, : Elsevier/Academic Press, c2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||