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The chemistry of the fullerenes [[electronic resource] /] / Andreas Hirsch
| The chemistry of the fullerenes [[electronic resource] /] / Andreas Hirsch |
| Autore | Hirsch Andreas, Dr. rer. nat. |
| Pubbl/distr/stampa | Stuttgart ; ; New York, : G. Thieme Verlag, 1994 |
| Descrizione fisica | 1 online resource (218 p.) |
| Disciplina |
543.0894
546.681 |
| Collana | Thieme organic chemistry monograph series |
| Soggetto topico | Fullerenes |
| ISBN |
1-281-84341-5
9786611843410 3-527-61921-6 3-527-61922-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Chemistry of the Fullerenes; Contents; Chapter 1. The Parent Fullerenes; 1.1 The Fullerenes: Molecular Allotropes of Carbon; 1.2 The Discovery of the Fullerenes; 1.3 Fullerene Production; 1.3.1 Fullerene Generation by Vaporization of Graphite; 1.3.1.1 Resitive Heating of Graphite; 1.3.1.2 Arc heating of Graphite; 1.3.1.3 Solar Generators; 1.3.1.4 Inductive Heating of Graphite; 1.3.2 Fullerene Synthesis in Combustion; 1.3.3 Formation of Fullerenes by Pyrolysis of Naphthalene; 1.3.4 Endohedrals; 1.3.5 The Formation Process; 1.4 Separation and Purification; 1.5 Properties; 1.5.1 Structures
1.5.2 Physical and Spectroscopic PropertiesReferences; Chapter 2. Reduction; 2.1 Introduction; 2.2 Fulleride Anions; 2.3 Reductive Electrosynthesis; 2.3.1 Electrocrystallization; 2.3.2 Electrophilic Additions to Fulleride Anions; 2.4 Reduction with Metals; 2.4.1 Alkali Metal Fullerides; 2.4.1.1 Generation in Solution and Quenching Experiments; 2.4.1.2 Synthesis and Properties of Alkali Metal Fulleride Solids; 2.4.2 Alkaline Earth Metal Fullerides; 2.4.3 Reduction with Mercury; 2.5 Reduction with Organic Donor Molecules; References; Chapter 3. Nucleophilic Additions; 3.1 Introduction 3.2 Addition of Carbon Nucleophiles3.2.1 Hydroalkylation and Hydroarylation of C60 and C70; 3.2.2 Langmuir - Blodgett Films of C60Ht-Bu; 3.2.3 Addition of Macromolecular Carbanions - Fullerene Polymers; 3.2.4 Cyclopropanation of C60 and C70; 3.3 Addition of Amines; 3.4 Addition of Hydroxide; References; Chapter 4. Cycloadditions; 4.1 Introduction; 4.2 [4+2] Cycloadditions; 4.3 [3+2] Cycloadditions; 4.3.1 Addition of Diazomethanes. Diazoacetates and Diazoamides; 4.3.2 Addition of Azides; 4.3.3 Addition of Trimethylenemethanes; 4.3.4 Addition of Azomethine Ylides 4.3.5 Addition of Nitrile Oxides4.3.6 Addition of Sulfinimides; 4.3.7 Addition of Disiliranes; 4.4 [2+2] Cycloadditions; 4.4.1 Addition of Benzyne; 4.4.2 Addition of Enones; 4.4.3 Addition of Quadricyclane; 4.4.4 Addition of Electron Rich Alkynes; 4.4.5 Photopolymerization of C60; 4.5 [2+1] Cycloadditions; 4.5.1 Addition of Carbenes; 4.5.2 Addition of Silylenes; References; Chapter 5. Hydrogenation; 5.1 Introduction; 5.2 Oligohydrofullerenes C60Hzn and C70H2n (n = 1 - 6); 5.2.1 Hydrogenation via Hydroboration, Hydrozirconation and Zinc/Acid Reduction; 5.2.2 Theoretical Investigations 5.3 Polyhydrofullerenes C60H2n and C70H2n (n = 7 - 70)5.3.1 Birch - Huckel Reduction; 5.3.2 Transfer Hydrogenation of C60 and C70; 5.3.3 Catalytic Hydrogenation; 5.3.4 Theoretical Investigations; References; Chapter 6. Radical Additions; 6.1 Introduction; 6.2 ESR Investigations of Radical Additions; 6.2.1 Addition of Single Radicals; 6.2.2 Multiple Radical Additions; 6.3 Metalation of C60 with Pentacarbonylrhenium Radicals; 6.4 Hydrostannylation of C60; 6.5 Addition of Bis(trifluoromethyl)nitroxide; 6.6 Radical Copolymerization of C60 and Paracyclophane; References Chapter 7. Transition Metal Complex Formation |
| Record Nr. | UNINA-9910144098003321 |
Hirsch Andreas, Dr. rer. nat.
|
||
| Stuttgart ; ; New York, : G. Thieme Verlag, 1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The chemistry of the fullerenes [[electronic resource] /] / Andreas Hirsch
| The chemistry of the fullerenes [[electronic resource] /] / Andreas Hirsch |
| Autore | Hirsch Andreas, Dr. rer. nat. |
| Pubbl/distr/stampa | Stuttgart ; ; New York, : G. Thieme Verlag, 1994 |
| Descrizione fisica | 1 online resource (218 p.) |
| Disciplina |
543.0894
546.681 |
| Collana | Thieme organic chemistry monograph series |
| Soggetto topico | Fullerenes |
| ISBN |
1-281-84341-5
9786611843410 3-527-61921-6 3-527-61922-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Chemistry of the Fullerenes; Contents; Chapter 1. The Parent Fullerenes; 1.1 The Fullerenes: Molecular Allotropes of Carbon; 1.2 The Discovery of the Fullerenes; 1.3 Fullerene Production; 1.3.1 Fullerene Generation by Vaporization of Graphite; 1.3.1.1 Resitive Heating of Graphite; 1.3.1.2 Arc heating of Graphite; 1.3.1.3 Solar Generators; 1.3.1.4 Inductive Heating of Graphite; 1.3.2 Fullerene Synthesis in Combustion; 1.3.3 Formation of Fullerenes by Pyrolysis of Naphthalene; 1.3.4 Endohedrals; 1.3.5 The Formation Process; 1.4 Separation and Purification; 1.5 Properties; 1.5.1 Structures
1.5.2 Physical and Spectroscopic PropertiesReferences; Chapter 2. Reduction; 2.1 Introduction; 2.2 Fulleride Anions; 2.3 Reductive Electrosynthesis; 2.3.1 Electrocrystallization; 2.3.2 Electrophilic Additions to Fulleride Anions; 2.4 Reduction with Metals; 2.4.1 Alkali Metal Fullerides; 2.4.1.1 Generation in Solution and Quenching Experiments; 2.4.1.2 Synthesis and Properties of Alkali Metal Fulleride Solids; 2.4.2 Alkaline Earth Metal Fullerides; 2.4.3 Reduction with Mercury; 2.5 Reduction with Organic Donor Molecules; References; Chapter 3. Nucleophilic Additions; 3.1 Introduction 3.2 Addition of Carbon Nucleophiles3.2.1 Hydroalkylation and Hydroarylation of C60 and C70; 3.2.2 Langmuir - Blodgett Films of C60Ht-Bu; 3.2.3 Addition of Macromolecular Carbanions - Fullerene Polymers; 3.2.4 Cyclopropanation of C60 and C70; 3.3 Addition of Amines; 3.4 Addition of Hydroxide; References; Chapter 4. Cycloadditions; 4.1 Introduction; 4.2 [4+2] Cycloadditions; 4.3 [3+2] Cycloadditions; 4.3.1 Addition of Diazomethanes. Diazoacetates and Diazoamides; 4.3.2 Addition of Azides; 4.3.3 Addition of Trimethylenemethanes; 4.3.4 Addition of Azomethine Ylides 4.3.5 Addition of Nitrile Oxides4.3.6 Addition of Sulfinimides; 4.3.7 Addition of Disiliranes; 4.4 [2+2] Cycloadditions; 4.4.1 Addition of Benzyne; 4.4.2 Addition of Enones; 4.4.3 Addition of Quadricyclane; 4.4.4 Addition of Electron Rich Alkynes; 4.4.5 Photopolymerization of C60; 4.5 [2+1] Cycloadditions; 4.5.1 Addition of Carbenes; 4.5.2 Addition of Silylenes; References; Chapter 5. Hydrogenation; 5.1 Introduction; 5.2 Oligohydrofullerenes C60Hzn and C70H2n (n = 1 - 6); 5.2.1 Hydrogenation via Hydroboration, Hydrozirconation and Zinc/Acid Reduction; 5.2.2 Theoretical Investigations 5.3 Polyhydrofullerenes C60H2n and C70H2n (n = 7 - 70)5.3.1 Birch - Huckel Reduction; 5.3.2 Transfer Hydrogenation of C60 and C70; 5.3.3 Catalytic Hydrogenation; 5.3.4 Theoretical Investigations; References; Chapter 6. Radical Additions; 6.1 Introduction; 6.2 ESR Investigations of Radical Additions; 6.2.1 Addition of Single Radicals; 6.2.2 Multiple Radical Additions; 6.3 Metalation of C60 with Pentacarbonylrhenium Radicals; 6.4 Hydrostannylation of C60; 6.5 Addition of Bis(trifluoromethyl)nitroxide; 6.6 Radical Copolymerization of C60 and Paracyclophane; References Chapter 7. Transition Metal Complex Formation |
| Record Nr. | UNISA-996203742303316 |
|
Hirsch Andreas, Dr. rer. nat.
|
||
| Stuttgart ; ; New York, : G. Thieme Verlag, 1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
The chemistry of the fullerenes [[electronic resource] /] / Andreas Hirsch
| The chemistry of the fullerenes [[electronic resource] /] / Andreas Hirsch |
| Autore | Hirsch Andreas, Dr. rer. nat. |
| Pubbl/distr/stampa | Stuttgart ; ; New York, : G. Thieme Verlag, 1994 |
| Descrizione fisica | 1 online resource (218 p.) |
| Disciplina |
543.0894
546.681 |
| Collana | Thieme organic chemistry monograph series |
| Soggetto topico | Fullerenes |
| ISBN |
1-281-84341-5
9786611843410 3-527-61921-6 3-527-61922-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Chemistry of the Fullerenes; Contents; Chapter 1. The Parent Fullerenes; 1.1 The Fullerenes: Molecular Allotropes of Carbon; 1.2 The Discovery of the Fullerenes; 1.3 Fullerene Production; 1.3.1 Fullerene Generation by Vaporization of Graphite; 1.3.1.1 Resitive Heating of Graphite; 1.3.1.2 Arc heating of Graphite; 1.3.1.3 Solar Generators; 1.3.1.4 Inductive Heating of Graphite; 1.3.2 Fullerene Synthesis in Combustion; 1.3.3 Formation of Fullerenes by Pyrolysis of Naphthalene; 1.3.4 Endohedrals; 1.3.5 The Formation Process; 1.4 Separation and Purification; 1.5 Properties; 1.5.1 Structures
1.5.2 Physical and Spectroscopic PropertiesReferences; Chapter 2. Reduction; 2.1 Introduction; 2.2 Fulleride Anions; 2.3 Reductive Electrosynthesis; 2.3.1 Electrocrystallization; 2.3.2 Electrophilic Additions to Fulleride Anions; 2.4 Reduction with Metals; 2.4.1 Alkali Metal Fullerides; 2.4.1.1 Generation in Solution and Quenching Experiments; 2.4.1.2 Synthesis and Properties of Alkali Metal Fulleride Solids; 2.4.2 Alkaline Earth Metal Fullerides; 2.4.3 Reduction with Mercury; 2.5 Reduction with Organic Donor Molecules; References; Chapter 3. Nucleophilic Additions; 3.1 Introduction 3.2 Addition of Carbon Nucleophiles3.2.1 Hydroalkylation and Hydroarylation of C60 and C70; 3.2.2 Langmuir - Blodgett Films of C60Ht-Bu; 3.2.3 Addition of Macromolecular Carbanions - Fullerene Polymers; 3.2.4 Cyclopropanation of C60 and C70; 3.3 Addition of Amines; 3.4 Addition of Hydroxide; References; Chapter 4. Cycloadditions; 4.1 Introduction; 4.2 [4+2] Cycloadditions; 4.3 [3+2] Cycloadditions; 4.3.1 Addition of Diazomethanes. Diazoacetates and Diazoamides; 4.3.2 Addition of Azides; 4.3.3 Addition of Trimethylenemethanes; 4.3.4 Addition of Azomethine Ylides 4.3.5 Addition of Nitrile Oxides4.3.6 Addition of Sulfinimides; 4.3.7 Addition of Disiliranes; 4.4 [2+2] Cycloadditions; 4.4.1 Addition of Benzyne; 4.4.2 Addition of Enones; 4.4.3 Addition of Quadricyclane; 4.4.4 Addition of Electron Rich Alkynes; 4.4.5 Photopolymerization of C60; 4.5 [2+1] Cycloadditions; 4.5.1 Addition of Carbenes; 4.5.2 Addition of Silylenes; References; Chapter 5. Hydrogenation; 5.1 Introduction; 5.2 Oligohydrofullerenes C60Hzn and C70H2n (n = 1 - 6); 5.2.1 Hydrogenation via Hydroboration, Hydrozirconation and Zinc/Acid Reduction; 5.2.2 Theoretical Investigations 5.3 Polyhydrofullerenes C60H2n and C70H2n (n = 7 - 70)5.3.1 Birch - Huckel Reduction; 5.3.2 Transfer Hydrogenation of C60 and C70; 5.3.3 Catalytic Hydrogenation; 5.3.4 Theoretical Investigations; References; Chapter 6. Radical Additions; 6.1 Introduction; 6.2 ESR Investigations of Radical Additions; 6.2.1 Addition of Single Radicals; 6.2.2 Multiple Radical Additions; 6.3 Metalation of C60 with Pentacarbonylrhenium Radicals; 6.4 Hydrostannylation of C60; 6.5 Addition of Bis(trifluoromethyl)nitroxide; 6.6 Radical Copolymerization of C60 and Paracyclophane; References Chapter 7. Transition Metal Complex Formation |
| Record Nr. | UNINA-9910831094603321 |
|
Hirsch Andreas, Dr. rer. nat.
|
||
| Stuttgart ; ; New York, : G. Thieme Verlag, 1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The chemistry of the fullerenes / / Andreas Hirsch
| The chemistry of the fullerenes / / Andreas Hirsch |
| Autore | Hirsch Andreas, Dr. rer. nat. |
| Pubbl/distr/stampa | Stuttgart ; ; New York, : G. Thieme Verlag, 1994 |
| Descrizione fisica | 1 online resource (218 p.) |
| Disciplina |
543.0894
546.681 |
| Collana | Thieme organic chemistry monograph series |
| Soggetto topico | Fullerenes |
| ISBN |
1-281-84341-5
9786611843410 3-527-61921-6 3-527-61922-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Chemistry of the Fullerenes; Contents; Chapter 1. The Parent Fullerenes; 1.1 The Fullerenes: Molecular Allotropes of Carbon; 1.2 The Discovery of the Fullerenes; 1.3 Fullerene Production; 1.3.1 Fullerene Generation by Vaporization of Graphite; 1.3.1.1 Resitive Heating of Graphite; 1.3.1.2 Arc heating of Graphite; 1.3.1.3 Solar Generators; 1.3.1.4 Inductive Heating of Graphite; 1.3.2 Fullerene Synthesis in Combustion; 1.3.3 Formation of Fullerenes by Pyrolysis of Naphthalene; 1.3.4 Endohedrals; 1.3.5 The Formation Process; 1.4 Separation and Purification; 1.5 Properties; 1.5.1 Structures
1.5.2 Physical and Spectroscopic PropertiesReferences; Chapter 2. Reduction; 2.1 Introduction; 2.2 Fulleride Anions; 2.3 Reductive Electrosynthesis; 2.3.1 Electrocrystallization; 2.3.2 Electrophilic Additions to Fulleride Anions; 2.4 Reduction with Metals; 2.4.1 Alkali Metal Fullerides; 2.4.1.1 Generation in Solution and Quenching Experiments; 2.4.1.2 Synthesis and Properties of Alkali Metal Fulleride Solids; 2.4.2 Alkaline Earth Metal Fullerides; 2.4.3 Reduction with Mercury; 2.5 Reduction with Organic Donor Molecules; References; Chapter 3. Nucleophilic Additions; 3.1 Introduction 3.2 Addition of Carbon Nucleophiles3.2.1 Hydroalkylation and Hydroarylation of C60 and C70; 3.2.2 Langmuir - Blodgett Films of C60Ht-Bu; 3.2.3 Addition of Macromolecular Carbanions - Fullerene Polymers; 3.2.4 Cyclopropanation of C60 and C70; 3.3 Addition of Amines; 3.4 Addition of Hydroxide; References; Chapter 4. Cycloadditions; 4.1 Introduction; 4.2 [4+2] Cycloadditions; 4.3 [3+2] Cycloadditions; 4.3.1 Addition of Diazomethanes. Diazoacetates and Diazoamides; 4.3.2 Addition of Azides; 4.3.3 Addition of Trimethylenemethanes; 4.3.4 Addition of Azomethine Ylides 4.3.5 Addition of Nitrile Oxides4.3.6 Addition of Sulfinimides; 4.3.7 Addition of Disiliranes; 4.4 [2+2] Cycloadditions; 4.4.1 Addition of Benzyne; 4.4.2 Addition of Enones; 4.4.3 Addition of Quadricyclane; 4.4.4 Addition of Electron Rich Alkynes; 4.4.5 Photopolymerization of C60; 4.5 [2+1] Cycloadditions; 4.5.1 Addition of Carbenes; 4.5.2 Addition of Silylenes; References; Chapter 5. Hydrogenation; 5.1 Introduction; 5.2 Oligohydrofullerenes C60Hzn and C70H2n (n = 1 - 6); 5.2.1 Hydrogenation via Hydroboration, Hydrozirconation and Zinc/Acid Reduction; 5.2.2 Theoretical Investigations 5.3 Polyhydrofullerenes C60H2n and C70H2n (n = 7 - 70)5.3.1 Birch - Huckel Reduction; 5.3.2 Transfer Hydrogenation of C60 and C70; 5.3.3 Catalytic Hydrogenation; 5.3.4 Theoretical Investigations; References; Chapter 6. Radical Additions; 6.1 Introduction; 6.2 ESR Investigations of Radical Additions; 6.2.1 Addition of Single Radicals; 6.2.2 Multiple Radical Additions; 6.3 Metalation of C60 with Pentacarbonylrhenium Radicals; 6.4 Hydrostannylation of C60; 6.5 Addition of Bis(trifluoromethyl)nitroxide; 6.6 Radical Copolymerization of C60 and Paracyclophane; References Chapter 7. Transition Metal Complex Formation |
| Record Nr. | UNINA-9910877823703321 |
|
Hirsch Andreas, Dr. rer. nat.
|
||
| Stuttgart ; ; New York, : G. Thieme Verlag, 1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fullerenes [[electronic resource] ] : chemistry and reactions / / Andreas Hirsch, Michael Brettreich
| Fullerenes [[electronic resource] ] : chemistry and reactions / / Andreas Hirsch, Michael Brettreich |
| Autore | Hirsch Andreas, Dr. rer. nat. |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (445 p.) |
| Disciplina | 546.681 |
| Altri autori (Persone) | BrettreichMichael |
| Soggetto topico |
Fullerenes
Carbon - Metabolism |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-52082-5
9786610520824 3-527-60349-2 1-61583-457-5 3-527-60594-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fullerenes; Foreword; Preface; Preface of "The Chemistry of the Fullerenes" by Andreas Hirsch (1994); Contents; Abbreviations; 1 Parent Fullerenes; 1.1 Fullerenes: Molecular Allotropes of Carbon; 1.2 Discovery of the Fullerenes; 1.3 Fullerene Production; 1.3.1 Fullerene Generation by Vaporization of Graphite; 1.3.1.1 Resistive Heating of Graphite; 1.3.1.2 Arc Heating of Graphite; 1.3.1.3 Solar Generators; 1.3.1.4 Inductive Heating of Graphite and Other Carbon Sources; 1.3.2 Fullerene Synthesis in Combustion; 1.3.3 Formation of Fullerenes by Pyrolysis of Hydrocarbons
1.3.4 Generation of Endohedral Fullerenes1.3.5 Total Synthesis Approaches; 1.3.6 Formation Process; 1.4 Separation and Purification; 1.5 Properties; 1.5.1 Structures; 1.5.2 Physical and Spectroscopic Properties; References; 2 Reduction; 2.1 Introduction; 2.2 Fulleride Anions; 2.3 Reductive Electrosynthesis; 2.3.1 Electrocrystallization; 2.3.2 Electrophilic Additions to Fulleride Anions; 2.4 Reduction with Metals; 2.4.1 Alkali Metal Fullerides; 2.4.1.1 Generation in Solution and Quenching Experiments; 2.4.1.2 Synthesis and Properties of Alkali Metal Fulleride Solids 2.4.2 Alkaline Earth Metal Fullerides2.4.3 Reduction with Mercury; 2.5 Reduction with Organic Donor Molecules; References; 3 Nucleophilic Additions; 3.1 Introduction; 3.2 Addition of Carbon Nucleophiles; 3.2.1 Hydroalkylation and Hydroarylation of C(60) and C(70); 3.2.2 Cyclopropanation of C(60) and C(70); 3.2.3 Addition of Cyanide; 3.3 Addition of Amines; 3.4 Addition of Hydroxide and Alkoxides; 3.5 Addition of Phosphorus Nucleophiles; 3.6 Addition of Silicon and Germanium Nucleophiles; 3.7 Addition of Macromolecular Nucleophiles - Fullerene Polymers; References; 4 Cycloadditions 4.1 Introduction4.2 [4+2] Cycloadditions; 4.3 [3+2] Cycloadditions; 4.3.1 Addition of Diazomethanes, Diazoacetates and Diazoamides; 4.3.2 Addition of Azides; 4.3.3 Addition of Trimethylenemethanes; 4.3.4 Addition of Azomethine Ylides; 4.3.5 Addition of Nitrile Oxides and Nitrile Imines; 4.3.6 Addition of Sulfinimides and Thiocarbonyl Ylides; 4.3.7 Addition of Carbonyl Ylides; 4.3.8 Addition of Nitrile Ylides and Isonitriles; 4.3.9 Addition of Disiliranes; 4.4 [2+2] Cycloadditions; 4.4.1 Addition of Benzyne; 4.4.2 Addition of Enones; 4.4.3 Addition of Electron-rich Alkynes and Alkenes 4.4.4 Addition of Ketenes and Ketene Acetals4.4.5 Addition of Quadricyclane; 4.4.6 Photodimerization of C(60); 4.5 [2+1] Cycloadditions; 4.5.1 Addition of Carbenes; 4.5.2 Addition of Nitrenes; 4.5.3 Addition of Silylenes; References; 5 Hydrogenation; 5.1 Introduction; 5.2 Oligohydrofullerenes C(60)H(n) and C(70)H(n) (n = 2-12); 5.2.1 Hydrogenation via Hydroboration and Hydrozirconation; 5.2.2 Reduction with Reducing Metals (Zn/Cu); 5.2.3 Hydrogenation with Hydrazine and with Organic Reducing Agents; 5.2.4 Theoretical Investigations; 5.3 Polyhydrofullerenes C(60)H(n) and C(70)H(n) (n = 14-60) 5.3.1 Birch-Hückel Reduction |
| Record Nr. | UNINA-9910144299203321 |
|
Hirsch Andreas, Dr. rer. nat.
|
||
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fullerenes : chemistry and reactions / / Andreas Hirsch, Michael Brettreich
| Fullerenes : chemistry and reactions / / Andreas Hirsch, Michael Brettreich |
| Autore | Hirsch Andreas, Dr. rer. nat. |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (445 p.) |
| Disciplina | 546.681 |
| Altri autori (Persone) | BrettreichMichael |
| Soggetto topico |
Fullerenes
Carbon - Metabolism |
| ISBN |
1-280-52082-5
9786610520824 3-527-60349-2 1-61583-457-5 3-527-60594-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fullerenes; Foreword; Preface; Preface of "The Chemistry of the Fullerenes" by Andreas Hirsch (1994); Contents; Abbreviations; 1 Parent Fullerenes; 1.1 Fullerenes: Molecular Allotropes of Carbon; 1.2 Discovery of the Fullerenes; 1.3 Fullerene Production; 1.3.1 Fullerene Generation by Vaporization of Graphite; 1.3.1.1 Resistive Heating of Graphite; 1.3.1.2 Arc Heating of Graphite; 1.3.1.3 Solar Generators; 1.3.1.4 Inductive Heating of Graphite and Other Carbon Sources; 1.3.2 Fullerene Synthesis in Combustion; 1.3.3 Formation of Fullerenes by Pyrolysis of Hydrocarbons
1.3.4 Generation of Endohedral Fullerenes1.3.5 Total Synthesis Approaches; 1.3.6 Formation Process; 1.4 Separation and Purification; 1.5 Properties; 1.5.1 Structures; 1.5.2 Physical and Spectroscopic Properties; References; 2 Reduction; 2.1 Introduction; 2.2 Fulleride Anions; 2.3 Reductive Electrosynthesis; 2.3.1 Electrocrystallization; 2.3.2 Electrophilic Additions to Fulleride Anions; 2.4 Reduction with Metals; 2.4.1 Alkali Metal Fullerides; 2.4.1.1 Generation in Solution and Quenching Experiments; 2.4.1.2 Synthesis and Properties of Alkali Metal Fulleride Solids 2.4.2 Alkaline Earth Metal Fullerides2.4.3 Reduction with Mercury; 2.5 Reduction with Organic Donor Molecules; References; 3 Nucleophilic Additions; 3.1 Introduction; 3.2 Addition of Carbon Nucleophiles; 3.2.1 Hydroalkylation and Hydroarylation of C(60) and C(70); 3.2.2 Cyclopropanation of C(60) and C(70); 3.2.3 Addition of Cyanide; 3.3 Addition of Amines; 3.4 Addition of Hydroxide and Alkoxides; 3.5 Addition of Phosphorus Nucleophiles; 3.6 Addition of Silicon and Germanium Nucleophiles; 3.7 Addition of Macromolecular Nucleophiles - Fullerene Polymers; References; 4 Cycloadditions 4.1 Introduction4.2 [4+2] Cycloadditions; 4.3 [3+2] Cycloadditions; 4.3.1 Addition of Diazomethanes, Diazoacetates and Diazoamides; 4.3.2 Addition of Azides; 4.3.3 Addition of Trimethylenemethanes; 4.3.4 Addition of Azomethine Ylides; 4.3.5 Addition of Nitrile Oxides and Nitrile Imines; 4.3.6 Addition of Sulfinimides and Thiocarbonyl Ylides; 4.3.7 Addition of Carbonyl Ylides; 4.3.8 Addition of Nitrile Ylides and Isonitriles; 4.3.9 Addition of Disiliranes; 4.4 [2+2] Cycloadditions; 4.4.1 Addition of Benzyne; 4.4.2 Addition of Enones; 4.4.3 Addition of Electron-rich Alkynes and Alkenes 4.4.4 Addition of Ketenes and Ketene Acetals4.4.5 Addition of Quadricyclane; 4.4.6 Photodimerization of C(60); 4.5 [2+1] Cycloadditions; 4.5.1 Addition of Carbenes; 4.5.2 Addition of Nitrenes; 4.5.3 Addition of Silylenes; References; 5 Hydrogenation; 5.1 Introduction; 5.2 Oligohydrofullerenes C(60)H(n) and C(70)H(n) (n = 2-12); 5.2.1 Hydrogenation via Hydroboration and Hydrozirconation; 5.2.2 Reduction with Reducing Metals (Zn/Cu); 5.2.3 Hydrogenation with Hydrazine and with Organic Reducing Agents; 5.2.4 Theoretical Investigations; 5.3 Polyhydrofullerenes C(60)H(n) and C(70)H(n) (n = 14-60) 5.3.1 Birch-Hückel Reduction |
| Record Nr. | UNINA-9910877784203321 |
|
Hirsch Andreas, Dr. rer. nat.
|
||
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||