| Edizione | [1st ed.] |
| Pubbl/distr/stampa |
Cambridge, : Royal Society of Chemistry, 2013
|
| Descrizione fisica |
1 online resource (167 p.)
|
| Disciplina |
620.192
|
| Altri autori (Persone) |
HayesWayne
GreenlandBarnaby W
|
| Collana |
RSC Polymer Chemistry Series
|
| Soggetto topico |
Polymers - Deterioration
Polymers - Biodegradation
|
| ISBN |
1-84973-747-9
|
| Formato |
Materiale a stampa  |
| Livello bibliografico |
Monografia |
| Lingua di pubblicazione |
eng
|
| Nota di contenuto |
Intro -- Contents -- Chapter 1 Healable Polymeric Materials -- 1.1 Introduction -- 1.2 Healable Polymers - Potential Applications -- 1.3 Categorisation of Healable Materials -- 1.4 Healing - Definitions -- 1.5 Measuring Healing -- 1.5.1 Cantilever Beam Tests to Determine Healing -- 1.5.2 Impact Testing -- 1.5.3 Rheological Healing Methods -- 1.5.4 Rheology - Background -- 1.6 Summary -- References -- Chapter 2 Encapsulation-Based Self-Healing Polymers and Composites -- 2.1 Introduction -- 2.2 Microencapsulation -- 2.2.1 In situ Poly(urea-formaldehyde) Encapsulation -- 2.2.2 Interfacial Polymerization -- 2.2.3 Hollow Fiber Encapsulation -- 2.2.4 Microcapsule Characterization -- 2.3 Chemistry of Encapsulated Self-Healing Materials -- 2.3.1 Ring-Opening Metathesis Polymerization -- 2.3.2 Siloxane-Based Healing Systems -- 2.3.3 Radical-Initiated Healing Chemistries -- 2.3.4 Isocyanate-Based Healing Systems -- 2.3.5 Epoxy-Based Healing Systems -- 2.3.6 ''Click-Chemistry''-Based Healing Agents -- 2.3.7 Solvent or Plasticizer-Based Healing Chemistries -- 2.3.8 Summary of Encapsulation-Based Self-Healing Materials -- 2.4 Performance and Testing of Microcapsule-Based Self-Healing Materials -- 2.4.1 Fracture Testing -- 2.4.2 Impact/Ballistic Testing -- 2.4.3 Tear Testing -- 2.4.4 Barrier Properties -- 2.4.5 Interfacial Strength -- 2.4.6 Conductivity -- 2.5 Summary and Outlook -- References -- Chapter 3 Reversible Covalent Bond Formation as a Strategy for Healable Polymer Networks -- 3.1 Introduction -- 3.2 A Brief Historical Account -- 3.3 Covalent Adaptable Network (CAN) Design -- 3.3.1 Network Architecture -- 3.3.2 Reversible Covalent Cross-link Type -- 3.4 Reversible Covalent Cross-link Chemistries -- 3.4.1 Trans-X Reactions -- 3.4.2 Radical-Mediated Addition-Fragmentation Reactions -- 3.4.3 Disulfides -- 3.4.4 The Diels-Alder Reaction.
3.4.5 Other Reversible Chemistries -- 3.5 Kinetics and Mechanical Properties -- 3.6 Conclusion and Outlook -- References -- Chapter 4 Healable Supramolecular Polymeric Materials -- 4.1 Introduction -- 4.1.1 Supramolecular Polymer Chemistry: A Concise History -- 4.2 Healable Supramolecular Polymers Utilizing Hydrogen Bonding -- 4.2.1 Supramolecular Polymers Containing Hydrogen Bonding Motifs with Low Association Constants -- 4.2.2 Healable Supramolecular Polymers Utilizing Hydrogen Bonding Interactions -- 4.3 Healable Supramolecular Polymers Utilizing π-π Stacking Interactions -- 4.4 Healable Supramolecular Nano-composite Materials -- 4.5 Healable Supramolecular Polymers Utilizing Metal-Ligand Interactions -- 4.6 Introduction to Healable Supramolecular Gels -- 4.6.1 Healable Supramolecular Polymeric Gels -- 4.6.2 Healable Nano-composite Gels -- 4.6.3 Healable Molecular Gels -- 4.7 Conclusions and Future Perspectives -- References -- Chapter 5 Thermodynamics of Self-Healing in Polymeric Materials -- 5.1 Introduction -- 5.2 Thermodynamics of Self-Healing -- 5.3 Self-Healing Reactions in Thermoplastic and Thermosetting Polymers -- 5.3.1 Bond Cleavage Reactions in Thermoplastic and Thermosetting Polymers -- 5.3.2 Supramolecular Approaches to Healable Thermoplastic and Thermosetting Polymers -- 5.4 Summary -- References -- Subject Index.
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| Record Nr. | UNINA-9910821119903321 |
Info
Healable polymer systems [[electronic resource] /] / edited by Wayne Hayes and Barnaby W. Greenland