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Electron paramagnetic resonance [[electronic resource] ] : a practitioner's toolkit / / edited by Marina Brustolon, Elio Giamello
| Electron paramagnetic resonance [[electronic resource] ] : a practitioner's toolkit / / edited by Marina Brustolon, Elio Giamello |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2009 |
| Descrizione fisica | 1 online resource (568 p.) |
| Disciplina | 543/.67 |
| Altri autori (Persone) |
BrustolonMarina
GiamelloGiacomo |
| Soggetto topico | Electron paramagnetic resonance |
| ISBN |
1-282-36816-8
9786612368165 0-470-43223-3 0-470-43222-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRON PARAMAGNETIC RESONANCE; CONTENTS; FOREWORD; PREFACE; CONTRIBUTORS; I PRINCIPLES; 1 Introduction to Electron Paramagnetic Resonance; 1.1 Chapter Summary; 1.2 EPR Spectrum: What Is It?; 1.3 The Electron Spin; 1.4 Electron Spin in a Magnetic Field (Zeeman Effect); 1.5 Effect of Electromagnetic Fields; 1.6 Macroscopic Collection of Electron Spins; 1.7 Observation of Magnetic Resonance; 1.8 Electron Spin in Atoms and Molecules; 1.9 Macroscopic Magnetization; 1.10 Spin Relaxation and Bloch Equations; 1.11 Nuclear Spins; 1.12 Anisotropy of the Hyperfine Interaction; 1.13 ENDOR
1.14 Two Interacting Electron Spins1.15 Quantum Machinery; 1.16 Electron Spin in a Static Magnetic Field; 1.17 Electron Spin Coupled to a Nuclear Spin; 1.18 Electron Spin in a Zeeman Magnetic Field in the Presence of a Microwave Field; 2 Basic Experimental Methods in Continuous Wave Electron Paramagnetic Resonance; 2.1 Instrumental Components of a Continuous Wave Electron Paramagnetic Resonance (CW-EPR) Spectrometer; 2.2 Experimental Techniques; Acknowledgment; References; Bibliography; 3 What Can Be Studied with Electron Paramagnetic Resonance?; 3.1 Introduction; 3.2 Organic Radicals 3.3 Organic Molecules with More than One Unpaired Electron3.4 Inorganic Radicals, Small Paramagnetic Molecules, and Isolated Atoms; 3.5 Transition Metal Ions; 3.6 Natural Systems and Processes; 3.7 Tailoring and Assembling PS for Magnetic Materials; 3.8 Industrial Applications of EPR; References; Bibliography; 4 Electron Paramagnetic Resonance Spectroscopy in the Liquid Phase; 4.1 General Considerations; 4.2 Generation of Radicals and Radical Ions; 4.3 Basic Interactions and Principles; 4.4 Patterns and Line Shapes of Fluid-Solution EPR Spectra; 4.5 Transition-Metal Ions; 4.6 Biradicals 4.7 Simulation Software4.8 How Fluid-Solution Spectra are Analyzed; 4.9 Calculation of EPR Parameters; 4.10 Molecular Properties Mirrored by EPR Spectra in Fluid Solution; 4.11 Chemically Induced Dynamic Electron Polarization (CIDEP) and CID Nuclear Polarization (CIDNP): Methods to Study Short-Lived Radicals; Acknowledgments; References; Further Reading; 5 Pulsed Electron Paramagnetic Resonance; 5.1 Introduction; 5.2 Vector Model for Pulsed EPR; 5.3 Pulse Sequences; 5.4 Data Analysis; 5.5 Spectrometer; References; 6 Electron Paramagnetic Resonance Spectra in the Solid State; 6.1 Introduction 6.2 Anisotropy of the Zeeman Interaction: The g Tensor6.3 The Hyperfine Interaction in the Solid State; 6.4 TMIs; 6.5 EPR Spectra for S > 1/2: ZFS; References; Appendix A.6.1 Simple Matrix Manipulations; Appendix A.6.2 Pauli Matrices; Appendix A.6.3 Transformation of Tensor Coordinates Via Matrices; Appendix A.6.4 Euler Angles; Appendix A.6.5 Matrix Elements of Spin-Orbit Coupling; Appendix A.6.6 Origin of the g and A Values for simple TMIs; Appendix References; 7 The Virtual Electron Paramagnetic Resonance Laboratory: A User Guide to ab initio Modeling; 7.1 Introduction; 7.2 Modeling Tools 7.3 Tutorial and Case Studies |
| Record Nr. | UNINA-9910146098803321 |
| Hoboken, N.J., : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron paramagnetic resonance [[electronic resource] ] : a practitioner's toolkit / / edited by Marina Brustolon, Elio Giamello
| Electron paramagnetic resonance [[electronic resource] ] : a practitioner's toolkit / / edited by Marina Brustolon, Elio Giamello |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2009 |
| Descrizione fisica | 1 online resource (568 p.) |
| Disciplina | 543/.67 |
| Altri autori (Persone) |
BrustolonMarina
GiamelloGiacomo |
| Soggetto topico | Electron paramagnetic resonance |
| ISBN |
1-282-36816-8
9786612368165 0-470-43223-3 0-470-43222-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRON PARAMAGNETIC RESONANCE; CONTENTS; FOREWORD; PREFACE; CONTRIBUTORS; I PRINCIPLES; 1 Introduction to Electron Paramagnetic Resonance; 1.1 Chapter Summary; 1.2 EPR Spectrum: What Is It?; 1.3 The Electron Spin; 1.4 Electron Spin in a Magnetic Field (Zeeman Effect); 1.5 Effect of Electromagnetic Fields; 1.6 Macroscopic Collection of Electron Spins; 1.7 Observation of Magnetic Resonance; 1.8 Electron Spin in Atoms and Molecules; 1.9 Macroscopic Magnetization; 1.10 Spin Relaxation and Bloch Equations; 1.11 Nuclear Spins; 1.12 Anisotropy of the Hyperfine Interaction; 1.13 ENDOR
1.14 Two Interacting Electron Spins1.15 Quantum Machinery; 1.16 Electron Spin in a Static Magnetic Field; 1.17 Electron Spin Coupled to a Nuclear Spin; 1.18 Electron Spin in a Zeeman Magnetic Field in the Presence of a Microwave Field; 2 Basic Experimental Methods in Continuous Wave Electron Paramagnetic Resonance; 2.1 Instrumental Components of a Continuous Wave Electron Paramagnetic Resonance (CW-EPR) Spectrometer; 2.2 Experimental Techniques; Acknowledgment; References; Bibliography; 3 What Can Be Studied with Electron Paramagnetic Resonance?; 3.1 Introduction; 3.2 Organic Radicals 3.3 Organic Molecules with More than One Unpaired Electron3.4 Inorganic Radicals, Small Paramagnetic Molecules, and Isolated Atoms; 3.5 Transition Metal Ions; 3.6 Natural Systems and Processes; 3.7 Tailoring and Assembling PS for Magnetic Materials; 3.8 Industrial Applications of EPR; References; Bibliography; 4 Electron Paramagnetic Resonance Spectroscopy in the Liquid Phase; 4.1 General Considerations; 4.2 Generation of Radicals and Radical Ions; 4.3 Basic Interactions and Principles; 4.4 Patterns and Line Shapes of Fluid-Solution EPR Spectra; 4.5 Transition-Metal Ions; 4.6 Biradicals 4.7 Simulation Software4.8 How Fluid-Solution Spectra are Analyzed; 4.9 Calculation of EPR Parameters; 4.10 Molecular Properties Mirrored by EPR Spectra in Fluid Solution; 4.11 Chemically Induced Dynamic Electron Polarization (CIDEP) and CID Nuclear Polarization (CIDNP): Methods to Study Short-Lived Radicals; Acknowledgments; References; Further Reading; 5 Pulsed Electron Paramagnetic Resonance; 5.1 Introduction; 5.2 Vector Model for Pulsed EPR; 5.3 Pulse Sequences; 5.4 Data Analysis; 5.5 Spectrometer; References; 6 Electron Paramagnetic Resonance Spectra in the Solid State; 6.1 Introduction 6.2 Anisotropy of the Zeeman Interaction: The g Tensor6.3 The Hyperfine Interaction in the Solid State; 6.4 TMIs; 6.5 EPR Spectra for S > 1/2: ZFS; References; Appendix A.6.1 Simple Matrix Manipulations; Appendix A.6.2 Pauli Matrices; Appendix A.6.3 Transformation of Tensor Coordinates Via Matrices; Appendix A.6.4 Euler Angles; Appendix A.6.5 Matrix Elements of Spin-Orbit Coupling; Appendix A.6.6 Origin of the g and A Values for simple TMIs; Appendix References; 7 The Virtual Electron Paramagnetic Resonance Laboratory: A User Guide to ab initio Modeling; 7.1 Introduction; 7.2 Modeling Tools 7.3 Tutorial and Case Studies |
| Record Nr. | UNINA-9910810907303321 |
| Hoboken, N.J., : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||