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Electron spin resonance spectroscopy of organic radicals [[electronic resource] /] / Fabian Gerson, Walter Huber
| Electron spin resonance spectroscopy of organic radicals [[electronic resource] /] / Fabian Gerson, Walter Huber |
| Autore | Gerson Fabian |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2003 |
| Descrizione fisica | 1 online resource (482 p.) |
| Disciplina |
538.346
543.67 |
| Altri autori (Persone) | HuberWalter <1949-> |
| Soggetto topico |
Electron paramagnetic resonance spectroscopy
Magnetic resonance |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-52033-7
3-527-60524-X 9786610520336 3-527-60162-7 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Electron Spin Resonance Spectroscopy of Organic Radicals; Contents; Preface; Abbreviations and Symbols; A General Part; 1 Physical Fundamentals of Electron Spin Resonance; 1.1 Spin and Magnetic Moment of Electron; 1.2 Zeeman Splitting and Resonance Condition; 1.3 Spin-lattice Relaxation; 1.4 Line-width and Line-form; 2 Paramagnetic Organic Species and Their Generation; 2.1 Spin Multiplicity; 2.2 Neutral Radicals; 2.3 Radical Ions; 2.4 Triplets: Electron-Electron Magnetic Interaction; 3 Electron-Nuclear Magnetic Interaction; 3.1 Nuclear Magnetism; 3.2 Hyperfine Splitting of ESR Signal
4 Spin Density, Spin Population, Spin Polarization, and Spin Delocalization4.1 Concepts; 4.2 π Radicals; 4.3 σ Radicals; 4.4 Triplet States; 4.5 Calculations of Spin Populations; 5 Multiresonance; 5.1 Historical Note; 5.2 ENDOR; 5.3 TRIPLE Resonance; 5.4 ELDOR; 6 Taking and Analyzing ESR Spectra; 6.1 Instrumentation; 6.2 g(e) Factor; 6.3 Optimal Conditions; 6.4 Unravelling Hyperfine Pattern; 6.5 Assignment and Sign of Coupling Constants; 6.6 Ion Pairing; 6.7 Intramolecular Dynamic Processes; B Special Part; 7 Organic Radicals Centered on One, Two, or Three Atoms 7.1 C-, N-, and O-centered Radicals7.2 Si-, P-, and S-centered Radicals; 7.3 CC-, NN-, and OO-centered Radicals; 7.4 NO- and NO(2)-centered Radicals; 7.5 PO-, PP-, SO-, SS-, and SO(2)-centered Radicals; 8 Conjugated Hydrocarbon Radicals; 8.1 Theoretical Introduction; 8.2 Odd Alternant Radicals; 8.3 Odd Nonalternant Radicals and Radical Dianions; 8.4 Even Alternant Radical Ions; 8.5 Even Nonalternant Radical Ions; 8.6 Radicals and Radical Ions with a Perturbed π Perimeter; 8.7 Radical Ions of Phanes; 8.8 Radical Ions of Radialenes; 9 Conjugated Radicals with Heteroatoms; 9.1 Neutral Radicals 9.2 Radical Anions of Electron Acceptors9.3 Radical Cations of Electron Donors; 9.4 Radical Cations with Special Structures; 9.5 Radical Ions of Multi-redox Systems; 10 Saturated Hydrocarbon Radicals; 10.1 Radical Cations of Alkanes; 10.2 Structurally Modified Radical Cations; 11 Biradicals and Triplet-state Molecules; 11.1 Biradicals; 11.2 Molecules in Photoexcited Triplet State; 11.3 Molecules in Ground or Thermally Accessible Triplet State; Appendices; A.1 Nitroxyls as Spin Labels and Spin Adducts; A.2 Hyperfine Splitting by Alkali-Metal Nuclei in Counterions of Radical Anions; References Index |
| Record Nr. | UNINA-9910146246803321 |
Gerson Fabian
|
||
| Weinheim, : Wiley-VCH, c2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron spin resonance spectroscopy of organic radicals / / Fabian Gerson, Walter Huber
| Electron spin resonance spectroscopy of organic radicals / / Fabian Gerson, Walter Huber |
| Autore | Gerson Fabian |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH GmbH, , [2003] |
| Descrizione fisica | 1 online resource (482 p.) |
| Disciplina | 543.67 |
| Soggetto topico | Electron paramagnetic resonance spectroscopy |
| ISBN |
1-280-52033-7
3-527-60524-X 9786610520336 3-527-60162-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Electron Spin Resonance Spectroscopy of Organic Radicals; Contents; Preface; Abbreviations and Symbols; A General Part; 1 Physical Fundamentals of Electron Spin Resonance; 1.1 Spin and Magnetic Moment of Electron; 1.2 Zeeman Splitting and Resonance Condition; 1.3 Spin-lattice Relaxation; 1.4 Line-width and Line-form; 2 Paramagnetic Organic Species and Their Generation; 2.1 Spin Multiplicity; 2.2 Neutral Radicals; 2.3 Radical Ions; 2.4 Triplets: Electron-Electron Magnetic Interaction; 3 Electron-Nuclear Magnetic Interaction; 3.1 Nuclear Magnetism; 3.2 Hyperfine Splitting of ESR Signal
4 Spin Density, Spin Population, Spin Polarization, and Spin Delocalization4.1 Concepts; 4.2 π Radicals; 4.3 σ Radicals; 4.4 Triplet States; 4.5 Calculations of Spin Populations; 5 Multiresonance; 5.1 Historical Note; 5.2 ENDOR; 5.3 TRIPLE Resonance; 5.4 ELDOR; 6 Taking and Analyzing ESR Spectra; 6.1 Instrumentation; 6.2 g(e) Factor; 6.3 Optimal Conditions; 6.4 Unravelling Hyperfine Pattern; 6.5 Assignment and Sign of Coupling Constants; 6.6 Ion Pairing; 6.7 Intramolecular Dynamic Processes; B Special Part; 7 Organic Radicals Centered on One, Two, or Three Atoms 7.1 C-, N-, and O-centered Radicals7.2 Si-, P-, and S-centered Radicals; 7.3 CC-, NN-, and OO-centered Radicals; 7.4 NO- and NO(2)-centered Radicals; 7.5 PO-, PP-, SO-, SS-, and SO(2)-centered Radicals; 8 Conjugated Hydrocarbon Radicals; 8.1 Theoretical Introduction; 8.2 Odd Alternant Radicals; 8.3 Odd Nonalternant Radicals and Radical Dianions; 8.4 Even Alternant Radical Ions; 8.5 Even Nonalternant Radical Ions; 8.6 Radicals and Radical Ions with a Perturbed π Perimeter; 8.7 Radical Ions of Phanes; 8.8 Radical Ions of Radialenes; 9 Conjugated Radicals with Heteroatoms; 9.1 Neutral Radicals 9.2 Radical Anions of Electron Acceptors9.3 Radical Cations of Electron Donors; 9.4 Radical Cations with Special Structures; 9.5 Radical Ions of Multi-redox Systems; 10 Saturated Hydrocarbon Radicals; 10.1 Radical Cations of Alkanes; 10.2 Structurally Modified Radical Cations; 11 Biradicals and Triplet-state Molecules; 11.1 Biradicals; 11.2 Molecules in Photoexcited Triplet State; 11.3 Molecules in Ground or Thermally Accessible Triplet State; Appendices; A.1 Nitroxyls as Spin Labels and Spin Adducts; A.2 Hyperfine Splitting by Alkali-Metal Nuclei in Counterions of Radical Anions; References Index |
| Record Nr. | UNINA-9910830498103321 |
|
Gerson Fabian
|
||
| Weinheim, Germany : , : Wiley-VCH GmbH, , [2003] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||