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Molten salts and ionic liquids [[electronic resource] ] : never the twain? / / edited by Marcelle Gaune-Escard, Kenneth R. Seddon
Molten salts and ionic liquids [[electronic resource] ] : never the twain? / / edited by Marcelle Gaune-Escard, Kenneth R. Seddon
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2010
Descrizione fisica 1 online resource (466 p.)
Disciplina 546.34
546/.34
Altri autori (Persone) Gaune-EscardMarcelle
SeddonKenneth R. <1950->
Soggetto topico Fused salts
Ionic solutions
Coulomb potential
Soggetto genere / forma Electronic books.
ISBN 1-280-88139-9
9786613722706
0-470-94777-2
0-470-94776-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Molten Salts and Ionic Liquids: Never the Twain?; CONTENTS; Acknowledgements; Preface; Editorial; Contributors; 1 Ionic Liquids in the Temperature Range 150-1500 K: Patterns and Problems; 2 Conductivities of Ionic Liquid Mixtures with Organic Electrolyte Solutions; 3 How Hydrophilic Ionic Liquids Behave in Aqueous Solutions; 4 Mass Spectrometric Studies on Ionic Liquid Aggregates; 5 Study of Sm-Al Alloy Formation in the Molten LiCl-KCl Eutectic; 6 Alumina Solubility and Electrical Conductivity in Potassium Cryolites with Low Cryolite Ratio
7 Ionic Liquids as Solvents for the Variable Temperature Electrodeposition of Metals and Semiconductors: A Short Introduction8 Predicting the Thermodynamic Behaviour of Water + Ionic Liquids Systems Using COSMO-RS; 9 Metallic Inert Anodes for Aluminium Electrolysis; 10 The Behaviour of Phosphorus and Sulfur in Cryolite-Alumina Melts: Thermodynamic Considerations; 11 Ionic Liquid-Ionic Liquid Biphasic Systems; 12 Recent Developments in the Reprocessing of Spent Fuel by Catalyst Enhanced Molten Salt Oxidation (CEMSO); 13 Plasma-Induced Molten Salt Electrolysis to Form Functional Fine Particles
14 Liquid Electrolytes: Their Characterisation, Investigation, and Diverse Applications15 Protection of a Microstructured Molybdenum Reactor from High Temperature Oxidation by Electrochemical Deposition Coatings in Molten Salts; 16 Molten Salt Synthesis of LaAlO3 Powder at Low Temperatures; 17 Accurate Measurement of Physicochemical Properties on Ionic Liquids and Molten Salts; 18 Molten Salt Physics and Chemistry in the Current Development of Spent Nuclear Fuel Management; 19 An Organic Chemist's Perspective on High Temperature Molten Salts and Room Temperature Ionic Liquids
20 Raman Spectroscopy of High Temperature Melts21 Thermodynamic Properties of LnI3-MI Binary Systems (Ln = La or Nd; M = K, Rb, or Cs); 22 Materials Informatics for Molten Salts Chemistry; 23 A Novel Ionic Liquid-Polymer Electrolyte for the Advanced Lithium Ion Polymer Battery; 24 Solubility of Al2O3 in NaCl-KCl Based Molten Salt System; 25 Molten Salt Synthesis of Ceramic Materials; 26 Fuel Cell and Electrolysis Studies with Dual Phase Proton and Oxide Ion Conduction; Index
Record Nr. UNINA-9910141270503321
Hoboken, N.J., : Wiley, c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Molten salts and ionic liquids [[electronic resource] ] : never the twain? / / edited by Marcelle Gaune-Escard, Kenneth R. Seddon
Molten salts and ionic liquids [[electronic resource] ] : never the twain? / / edited by Marcelle Gaune-Escard, Kenneth R. Seddon
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2010
Descrizione fisica 1 online resource (466 p.)
Disciplina 546.34
546/.34
Altri autori (Persone) Gaune-EscardMarcelle
SeddonKenneth R. <1950->
Soggetto topico Fused salts
Ionic solutions
Coulomb potential
ISBN 1-280-88139-9
9786613722706
0-470-94777-2
0-470-94776-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Molten Salts and Ionic Liquids: Never the Twain?; CONTENTS; Acknowledgements; Preface; Editorial; Contributors; 1 Ionic Liquids in the Temperature Range 150-1500 K: Patterns and Problems; 2 Conductivities of Ionic Liquid Mixtures with Organic Electrolyte Solutions; 3 How Hydrophilic Ionic Liquids Behave in Aqueous Solutions; 4 Mass Spectrometric Studies on Ionic Liquid Aggregates; 5 Study of Sm-Al Alloy Formation in the Molten LiCl-KCl Eutectic; 6 Alumina Solubility and Electrical Conductivity in Potassium Cryolites with Low Cryolite Ratio
7 Ionic Liquids as Solvents for the Variable Temperature Electrodeposition of Metals and Semiconductors: A Short Introduction8 Predicting the Thermodynamic Behaviour of Water + Ionic Liquids Systems Using COSMO-RS; 9 Metallic Inert Anodes for Aluminium Electrolysis; 10 The Behaviour of Phosphorus and Sulfur in Cryolite-Alumina Melts: Thermodynamic Considerations; 11 Ionic Liquid-Ionic Liquid Biphasic Systems; 12 Recent Developments in the Reprocessing of Spent Fuel by Catalyst Enhanced Molten Salt Oxidation (CEMSO); 13 Plasma-Induced Molten Salt Electrolysis to Form Functional Fine Particles
14 Liquid Electrolytes: Their Characterisation, Investigation, and Diverse Applications15 Protection of a Microstructured Molybdenum Reactor from High Temperature Oxidation by Electrochemical Deposition Coatings in Molten Salts; 16 Molten Salt Synthesis of LaAlO3 Powder at Low Temperatures; 17 Accurate Measurement of Physicochemical Properties on Ionic Liquids and Molten Salts; 18 Molten Salt Physics and Chemistry in the Current Development of Spent Nuclear Fuel Management; 19 An Organic Chemist's Perspective on High Temperature Molten Salts and Room Temperature Ionic Liquids
20 Raman Spectroscopy of High Temperature Melts21 Thermodynamic Properties of LnI3-MI Binary Systems (Ln = La or Nd; M = K, Rb, or Cs); 22 Materials Informatics for Molten Salts Chemistry; 23 A Novel Ionic Liquid-Polymer Electrolyte for the Advanced Lithium Ion Polymer Battery; 24 Solubility of Al2O3 in NaCl-KCl Based Molten Salt System; 25 Molten Salt Synthesis of Ceramic Materials; 26 Fuel Cell and Electrolysis Studies with Dual Phase Proton and Oxide Ion Conduction; Index
Record Nr. UNINA-9910830395703321
Hoboken, N.J., : Wiley, c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Molten salts and ionic liquids [[electronic resource] ] : never the twain? / / edited by Marcelle Gaune-Escard, Kenneth R. Seddon
Molten salts and ionic liquids [[electronic resource] ] : never the twain? / / edited by Marcelle Gaune-Escard, Kenneth R. Seddon
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2010
Descrizione fisica 1 online resource (466 p.)
Disciplina 546.34
546/.34
Altri autori (Persone) Gaune-EscardMarcelle
SeddonKenneth R. <1950->
Soggetto topico Fused salts
Ionic solutions
Coulomb potential
ISBN 1-280-88139-9
9786613722706
0-470-94777-2
0-470-94776-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Molten Salts and Ionic Liquids: Never the Twain?; CONTENTS; Acknowledgements; Preface; Editorial; Contributors; 1 Ionic Liquids in the Temperature Range 150-1500 K: Patterns and Problems; 2 Conductivities of Ionic Liquid Mixtures with Organic Electrolyte Solutions; 3 How Hydrophilic Ionic Liquids Behave in Aqueous Solutions; 4 Mass Spectrometric Studies on Ionic Liquid Aggregates; 5 Study of Sm-Al Alloy Formation in the Molten LiCl-KCl Eutectic; 6 Alumina Solubility and Electrical Conductivity in Potassium Cryolites with Low Cryolite Ratio
7 Ionic Liquids as Solvents for the Variable Temperature Electrodeposition of Metals and Semiconductors: A Short Introduction8 Predicting the Thermodynamic Behaviour of Water + Ionic Liquids Systems Using COSMO-RS; 9 Metallic Inert Anodes for Aluminium Electrolysis; 10 The Behaviour of Phosphorus and Sulfur in Cryolite-Alumina Melts: Thermodynamic Considerations; 11 Ionic Liquid-Ionic Liquid Biphasic Systems; 12 Recent Developments in the Reprocessing of Spent Fuel by Catalyst Enhanced Molten Salt Oxidation (CEMSO); 13 Plasma-Induced Molten Salt Electrolysis to Form Functional Fine Particles
14 Liquid Electrolytes: Their Characterisation, Investigation, and Diverse Applications15 Protection of a Microstructured Molybdenum Reactor from High Temperature Oxidation by Electrochemical Deposition Coatings in Molten Salts; 16 Molten Salt Synthesis of LaAlO3 Powder at Low Temperatures; 17 Accurate Measurement of Physicochemical Properties on Ionic Liquids and Molten Salts; 18 Molten Salt Physics and Chemistry in the Current Development of Spent Nuclear Fuel Management; 19 An Organic Chemist's Perspective on High Temperature Molten Salts and Room Temperature Ionic Liquids
20 Raman Spectroscopy of High Temperature Melts21 Thermodynamic Properties of LnI3-MI Binary Systems (Ln = La or Nd; M = K, Rb, or Cs); 22 Materials Informatics for Molten Salts Chemistry; 23 A Novel Ionic Liquid-Polymer Electrolyte for the Advanced Lithium Ion Polymer Battery; 24 Solubility of Al2O3 in NaCl-KCl Based Molten Salt System; 25 Molten Salt Synthesis of Ceramic Materials; 26 Fuel Cell and Electrolysis Studies with Dual Phase Proton and Oxide Ion Conduction; Index
Record Nr. UNINA-9910841749003321
Hoboken, N.J., : Wiley, c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Molten salts chemistry and technology / / edited by Marcelle Gaune-Escard and Geir Martin Haarberg
Molten salts chemistry and technology / / edited by Marcelle Gaune-Escard and Geir Martin Haarberg
Pubbl/distr/stampa Chichester, [England] : , : Wiley, , 2014
Descrizione fisica 1 online resource (634 p.)
Disciplina 546/.34
Soggetto topico Fused salts
ISBN 1-118-44882-0
1-118-44884-7
1-118-44883-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Title Page; Copyright; Contents; List of Contributors; Foreword; Preface; Part 1 Aluminium Electrolysis; Chapter 1.1 Formation of CO2 and CO on Carbon Anodes in Molten Salts; 1.1.1 Introduction; 1.1.2 Results; 1.1.2.1 Fluoride melts; 1.1.2.2 Chloride melts; 1.1.3 Discussion; 1.1.4 Conclusion; References; Chapter 1.2 Interaction of Carbon with Molten Salts-Chloride-Carbonate Melts; 1.2.1 Introduction; 1.2.2 Carbon as an anode in molten salt cells; 1.2.2.1 Inert anodes; 1.2.2.2 Reactive anodes; 1.2.3 Carbon in the form of carbonate ions; 1.2.4 Carbon in the form of carbide ions
1.2.5 Carbon as a cathode1.2.6 Conclusions; References; Chapter 1.3 Anode Processes on Carbon in Chloride Melts with Dissolved Oxides; 1.3.1 Introduction; 1.3.2 Electrochemical processes in chloride-oxide melts; 1.3.2.1 Cl2, CO and CO2 formation; 1.3.2.2 Melt systems; 1.3.3 Experimental; 1.3.4 Results; 1.3.4.1 Cyclic voltammograms in the NaCl-Na2O and NaCl-Na2O and NaCl-Na2O+CaCl2-CaO systems; 1.3.4.2 Stationary polarisation curves and gaseous products; 1.3.4.3 Gas composition; 1.3.4.4 Previous investigations
1.3.4.5 Adsorption capacitance and diffusion impedance from electrochemical impedance spectroscopy1.3.5 Discussion and conclusions; References; Chapter 1.4 Aluminium Electrolysis with Inert Anodes and Wettable Cathodes and with Low Energy Consumption; 1.4.1 Introduction; 1.4.2 Cell designs with inert anodes and wettable cathodes; 1.4.3 Electrolytes with low melting temperature; 1.4.4 Energetic aspects; 1.4.5 Material problems; 1.4.6 Conclusion; Acknowledgments; References; Chapter 1.5 Influence of the Sulfur Content in the Carbon Anodes in Aluminum Electrolysis-a Laboratory Study
1.5.1 Introduction1.5.2 Experimental; 1.5.2.1 Experimental conditions; 1.5.3 Results; 1.5.4 Discussion; 1.5.5 Conclusions; Acknowledgments; References; Chapter 1.6 Aluminum Electrolysis in an Inert Anode Cell; 1.6.1 Introduction; 1.6.2 Experimental; 1.6.2.1 Set up; 1.6.2.2 Electrolyte; 1.6.3 Current efficiency; 1.6.4 Liquidus temperature; 1.6.5 Electrolysis; 1.6.5.1 Electrolyte KF-AlF3; 1.6.5.2 Sodium fluoride impact; 1.6.5.3 Voltage anomalies; 1.6.5.4 Anode; 1.6.6 Conclusions; Acknowledgments; References
Chapter 1.7 Effect of Phosphorus Impurities on the Current Efficiency for Aluminium Deposition from Cryolite-Alumina Melts in a Laboratory Cell1.7.1 Introduction; 1.7.2 Experimental method; 1.7.3 Results and discussion; 1.7.3.1 Effect of current density; 1.7.3.2 Effect of phosphorus; 1.7.4 Conclusions; Acknowledgments; References; Chapter 1.8 Influence of LOI on Alumina Dissolution in Molten Aluminum Electrolyte; 1.8.1 Introduction; 1.8.2 Experimental; 1.8.2.1 Chemicals; 1.8.2.2 Experimental method and apparatus for alumina dissolution rate measurement; 1.8.3 Results and discussion
1.8.3.1 LOI of aluminas prepared at different temperatures
Record Nr. UNINA-9910132207803321
Chichester, [England] : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Molten salts chemistry and technology / / edited by Marcelle Gaune-Escard and Geir Martin Haarberg
Molten salts chemistry and technology / / edited by Marcelle Gaune-Escard and Geir Martin Haarberg
Pubbl/distr/stampa Chichester, [England] : , : Wiley, , 2014
Descrizione fisica 1 online resource (634 p.)
Disciplina 546/.34
Soggetto topico Fused salts
ISBN 1-118-44882-0
1-118-44884-7
1-118-44883-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Title Page; Copyright; Contents; List of Contributors; Foreword; Preface; Part 1 Aluminium Electrolysis; Chapter 1.1 Formation of CO2 and CO on Carbon Anodes in Molten Salts; 1.1.1 Introduction; 1.1.2 Results; 1.1.2.1 Fluoride melts; 1.1.2.2 Chloride melts; 1.1.3 Discussion; 1.1.4 Conclusion; References; Chapter 1.2 Interaction of Carbon with Molten Salts-Chloride-Carbonate Melts; 1.2.1 Introduction; 1.2.2 Carbon as an anode in molten salt cells; 1.2.2.1 Inert anodes; 1.2.2.2 Reactive anodes; 1.2.3 Carbon in the form of carbonate ions; 1.2.4 Carbon in the form of carbide ions
1.2.5 Carbon as a cathode1.2.6 Conclusions; References; Chapter 1.3 Anode Processes on Carbon in Chloride Melts with Dissolved Oxides; 1.3.1 Introduction; 1.3.2 Electrochemical processes in chloride-oxide melts; 1.3.2.1 Cl2, CO and CO2 formation; 1.3.2.2 Melt systems; 1.3.3 Experimental; 1.3.4 Results; 1.3.4.1 Cyclic voltammograms in the NaCl-Na2O and NaCl-Na2O and NaCl-Na2O+CaCl2-CaO systems; 1.3.4.2 Stationary polarisation curves and gaseous products; 1.3.4.3 Gas composition; 1.3.4.4 Previous investigations
1.3.4.5 Adsorption capacitance and diffusion impedance from electrochemical impedance spectroscopy1.3.5 Discussion and conclusions; References; Chapter 1.4 Aluminium Electrolysis with Inert Anodes and Wettable Cathodes and with Low Energy Consumption; 1.4.1 Introduction; 1.4.2 Cell designs with inert anodes and wettable cathodes; 1.4.3 Electrolytes with low melting temperature; 1.4.4 Energetic aspects; 1.4.5 Material problems; 1.4.6 Conclusion; Acknowledgments; References; Chapter 1.5 Influence of the Sulfur Content in the Carbon Anodes in Aluminum Electrolysis-a Laboratory Study
1.5.1 Introduction1.5.2 Experimental; 1.5.2.1 Experimental conditions; 1.5.3 Results; 1.5.4 Discussion; 1.5.5 Conclusions; Acknowledgments; References; Chapter 1.6 Aluminum Electrolysis in an Inert Anode Cell; 1.6.1 Introduction; 1.6.2 Experimental; 1.6.2.1 Set up; 1.6.2.2 Electrolyte; 1.6.3 Current efficiency; 1.6.4 Liquidus temperature; 1.6.5 Electrolysis; 1.6.5.1 Electrolyte KF-AlF3; 1.6.5.2 Sodium fluoride impact; 1.6.5.3 Voltage anomalies; 1.6.5.4 Anode; 1.6.6 Conclusions; Acknowledgments; References
Chapter 1.7 Effect of Phosphorus Impurities on the Current Efficiency for Aluminium Deposition from Cryolite-Alumina Melts in a Laboratory Cell1.7.1 Introduction; 1.7.2 Experimental method; 1.7.3 Results and discussion; 1.7.3.1 Effect of current density; 1.7.3.2 Effect of phosphorus; 1.7.4 Conclusions; Acknowledgments; References; Chapter 1.8 Influence of LOI on Alumina Dissolution in Molten Aluminum Electrolyte; 1.8.1 Introduction; 1.8.2 Experimental; 1.8.2.1 Chemicals; 1.8.2.2 Experimental method and apparatus for alumina dissolution rate measurement; 1.8.3 Results and discussion
1.8.3.1 LOI of aluminas prepared at different temperatures
Record Nr. UNINA-9910824339803321
Chichester, [England] : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui