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Carbon monoxide in organic synthesis : carbonylation chemistry / / edited by Bartolo Gabriele
| Carbon monoxide in organic synthesis : carbonylation chemistry / / edited by Bartolo Gabriele |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2022] |
| Descrizione fisica | 1 online resource (431 pages) |
| Disciplina | 547.2 |
| Soggetto topico | Carbonyl compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-82935-0
3-527-82933-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Introduction: Carbon Monoxide as Synthon in Organic Synthesis -- References -- Part I Carbonylations Promoted by First Row Transition Metal Catalysts -- Chapter 2 Cobalt‐Catalyzed Carbonylations -- 2.1 Introduction -- 2.2 Carbon Monoxide and Its Surrogates -- 2.3 Hydroformylation of Alkenes -- 2.4 Carbonylation of Alkynes by the Pauson-Khand [2+2+1] Reaction -- 2.5 Carbonylation of Methanol -- 2.6 Carbonylation of Heterocycles -- 2.7 Carbonylation of Alkyl and Aryl Halides -- 2.8 C H Bond Carbonylations -- 2.9 Miscellaneous Co‐Catalyzed Carbonylations -- 2.10 Summary and Conclusions -- References -- Chapter 3 Nickel‐Catalyzed Carbonylations -- 3.1 Introduction -- 3.2 Nickel Halides in Carbonylation Reaction -- 3.3 Ni‐Chelates as Precatalysts -- 3.4 Nanoparticles as Active Catalysts -- 3.5 Dinickel Complexes as Catalysts -- 3.6 Ni/AC as a Promising Heterogeneous Catalyst -- 3.7 Use of CO Surrogates with Nickel Catalysts -- 3.7.1 Metal Carbonyls as CO Surrogates -- 3.7.2 Formates as CO Surrogates -- 3.7.3 Acid or Acid Chlorides as CO Surrogates -- 3.8 Other Prominent Roles of Nickel in Carbonylation -- 3.9 Conclusion and Future Outlook -- References -- Chapter 4 Carbonylations Catalyzed by Other First Row Transition‐Metal Catalysts (Manganese, Iron, Copper) -- 4.1 Introduction -- 4.2 Synthesis of Ketones -- 4.3 Synthesis of Esters -- 4.4 Synthesis of Amides -- 4.5 Synthesis of Other Products -- 4.6 Summary and Conclusions -- References -- Part II Carbonylations Promoted by Second Row Transition Metal Catalysts -- Chapter 5 Ruthenium‐Catalyzed Carbonylations -- 5.1 Introduction -- 5.2 CH Activation of Nitrogen‐Containing Arene Derivatives -- 5.3 Ruthenium‐Catalyzed Carbonylations of Olefins and Nitroarenes -- 5.3.1 Ruthenium‐Catalyzed Hydroformylations.
5.3.2 Ruthenium‐Catalyzed Alkoxycarbonylation of Olefins -- 5.3.3 Carbonylation of Nitroarenes -- 5.4 Ruthenium‐Catalyzed Carbonylation of Amines and Alcohols -- 5.5 Ruthenium‐Catalyzed Cyclocarbonylations -- 5.6 Ruthenium‐Catalyzed Reactions Using Syngas -- 5.6.1 Fischer-Tropsch Synthesis -- 5.6.2 Synthesis of Oxo Products from Syngas -- 5.7 Synthesis of Oxo Products from H2 and CO2 -- 5.8 Conclusions -- References -- Chapter 6 Rhodium‐Catalyzed Carbonylations -- 6.1 Introduction -- 6.2 Hydroformylation -- 6.2.1 Catalyst Recovery -- 6.2.2 Aqueous Biphase Hydroformylation -- 6.2.3 Enantioselective Hydroformylation -- 6.2.4 Tandem Hydroformylation -- 6.2.5 Syngas Surrogates -- 6.3 Carbonylation -- 6.4 Some Relevant Patents and Patent Applications (2015-2020) -- 6.4.1 Hydroformylation -- 6.4.2 Preparation of Acetic Acid and Similar Compounds and Derivatives -- 6.4.3 Alcohols -- 6.5 Summary and Conclusions -- References -- Chapter 7 Palladium(0)‐Catalyzed Carbonylations -- 7.1 Introduction -- 7.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives -- 7.2.1 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives from Aryl Halides -- 7.2.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives from Alkynes -- 7.2.3 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives Using Benzyl Amines -- 7.3 Palladium(0)‐Catalyzed Carbonylative Synthesis of Amide Derivatives -- 7.3.1 Palladium(0)‐Catalyzed Carbonylative Synthesis of β‐Lactams -- 7.3.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Five, Six, Seven‐Membered Cyclic Amides -- 7.3.3 Palladium(0)‐Catalyzed Carbonylative Synthesis of Benzamide Derivatives -- 7.4 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ketone Derivatives -- 7.4.1 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ketone Derivatives from Aryl Halides. 7.4.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ketone Derivatives from Other Substrates -- 7.5 Palladium(0)‐Catalyzed Carbonylative Synthesis of α,β‐Alkynyl Ketones Derivatives -- 7.6 Palladium(0)‐Catalyzed Carbonylative Synthesis of Other Carbonyl Compounds -- 7.7 Summary and Conclusions -- References -- Chapter 8 Palladium(II)‐Catalyzed Carbonylations -- 8.1 Introduction -- 8.2 Palladium(II)‐Catalyzed Carbonylation of Alkanes and Saturated C H Bonds -- 8.3 Palladium(II)‐Catalyzed Carbonylation of Arenes and Heteroarenes -- 8.4 Palladium(II)‐Catalyzed Carbonylation of Alkenes -- 8.4.1 Palladium(II)‐Catalyzed Carbonylation of Unfunctionalized Alkenes, Dienes, and Allenes -- 8.4.2 Palladium(II)‐Catalyzed Carbonylation of Functionalized Alkenes and Allenes -- 8.5 Palladium(II)‐Catalyzed Carbonylation of Alkynes -- 8.5.1 Palladium(II)‐Catalyzed Carbonylation of Unfunctionalized Alkynes -- 8.5.2 Palladium(II)‐Catalyzed Carbonylation of Functionalized Alkynes -- 8.6 Palladium(II)‐Catalyzed Carbonylation of Other Substrates -- 8.7 Summary and Conclusions -- References -- Chapter 9 Carbonylations Catalyzed by Other Second‐Row Transition Metal Catalysts -- 9.1 Introduction -- 9.2 Zirconium Compounds as Carbonylation Catalysts -- 9.2.1 Carbonylation with Carbon Monoxide on Sulfated‐Doped Zirconia as the Solid Acid Catalyst -- 9.2.2 Carbonylation of Zirconocene Complexes -- 9.3 Silver Compounds in Carbonylation Reactions -- 9.3.1 Koch‐Type Reactions in the Presence of Silver Carbonyl Ion Catalyst -- 9.3.2 Koch‐Type Reactions in the Presence of Silver Lewis Acids under CO Atmosphere -- 9.3.3 Carbonylative Coupling Reactions Promoted by Metal-Silver Bimetallic Catalysts -- 9.4 Molybdenum Compounds in Carbonylation Reactions -- 9.4.1 Formal Carbonylation Processes: Carbonylation of Ethylene and Methanol. 9.4.2 Molybdenum Carbonyl Complexes as Catalysts and CO Source in Intermolecular Carbonylation Coupling Reactions of Aryl or Alkenyl Halides -- 9.4.3 Molybdenum Carbonyl Complexes as Both Catalysts and CO Source in Intramolecular Carbonylation Coupling Reactions -- 9.4.4 Metal‐Catalyzed Coupling Procedures Using Molybdenum as the CO Source -- 9.4.4.1 Intermolecular Cross‐Coupling Procedures -- 9.4.4.2 Cascade and Intramolecular Cross‐Coupling Procedures -- 9.4.4.3 Carbonylative Cross‐Coupling in the Presence of Transmetalation Partners -- 9.5 Summary and Conclusions -- References -- Part III Miscellaneous Carbonylation Reactions -- Chapter 10 Carbonylations Promoted by Third‐Row Transition Metal Catalysts -- 10.1 Introduction -- 10.2 Methanol Carbonylation -- 10.2.1 Acetic Acid Production -- 10.2.2 Process Considerations and Mechanism for Rh Catalyst -- 10.2.3 Iridium Catalysts -- 10.2.3.1 Mechanism for Iridium Catalyst -- 10.2.3.2 Role of Promoters in Iridium‐Catalyzed Methanol Carbonylation -- 10.2.3.3 Recent Developments -- 10.3 Hydroformylation -- 10.3.1 Iridium Catalysts -- 10.3.2 Platinum Catalysts -- 10.3.3 Osmium Catalysts -- 10.4 Other Carbonylation Reactions -- 10.4.1 Alkoxycarbonylation of Alkenes -- 10.4.2 Carbonylation Reactions Involving Alkynes -- 10.4.3 Oxidative Carbonylations -- 10.5 Summary and Conclusions -- References -- Chapter 11 Transition Metal‐Free Carbonylation Processes -- 11.1 Introduction -- 11.2 Transition‐Metal‐Free Carbonylation for the Synthesis of Aldehydes and Ketones -- 11.3 Transition‐Metal‐Free Carbonylation for the Synthesis of Esters and Lactones -- 11.4 Transition‐Metal‐Free Carbonylation for the Synthesis of Amides -- 11.5 Transition‐Metal‐Free Carbonylation for the Synthesis of Acids and Anhydrides -- 11.6 Transition‐Metal‐Free Carbonylation for the Synthesis of Acyl Chlorides and Alcohols. 11.7 Summary and Conclusions -- References -- Chapter 12 Conclusions and Perspectives -- Index -- EULA. |
| Record Nr. | UNINA-9910555190503321 |
| Weinheim, Germany : , : Wiley-VCH, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon monoxide in organic synthesis : carbonylation chemistry / / edited by Bartolo Gabriele
| Carbon monoxide in organic synthesis : carbonylation chemistry / / edited by Bartolo Gabriele |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2022] |
| Descrizione fisica | 1 online resource (431 pages) |
| Disciplina | 547.2 |
| Soggetto topico | Carbonyl compounds - Synthesis |
| ISBN |
3-527-82935-0
3-527-82933-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Introduction: Carbon Monoxide as Synthon in Organic Synthesis -- References -- Part I Carbonylations Promoted by First Row Transition Metal Catalysts -- Chapter 2 Cobalt‐Catalyzed Carbonylations -- 2.1 Introduction -- 2.2 Carbon Monoxide and Its Surrogates -- 2.3 Hydroformylation of Alkenes -- 2.4 Carbonylation of Alkynes by the Pauson-Khand [2+2+1] Reaction -- 2.5 Carbonylation of Methanol -- 2.6 Carbonylation of Heterocycles -- 2.7 Carbonylation of Alkyl and Aryl Halides -- 2.8 C H Bond Carbonylations -- 2.9 Miscellaneous Co‐Catalyzed Carbonylations -- 2.10 Summary and Conclusions -- References -- Chapter 3 Nickel‐Catalyzed Carbonylations -- 3.1 Introduction -- 3.2 Nickel Halides in Carbonylation Reaction -- 3.3 Ni‐Chelates as Precatalysts -- 3.4 Nanoparticles as Active Catalysts -- 3.5 Dinickel Complexes as Catalysts -- 3.6 Ni/AC as a Promising Heterogeneous Catalyst -- 3.7 Use of CO Surrogates with Nickel Catalysts -- 3.7.1 Metal Carbonyls as CO Surrogates -- 3.7.2 Formates as CO Surrogates -- 3.7.3 Acid or Acid Chlorides as CO Surrogates -- 3.8 Other Prominent Roles of Nickel in Carbonylation -- 3.9 Conclusion and Future Outlook -- References -- Chapter 4 Carbonylations Catalyzed by Other First Row Transition‐Metal Catalysts (Manganese, Iron, Copper) -- 4.1 Introduction -- 4.2 Synthesis of Ketones -- 4.3 Synthesis of Esters -- 4.4 Synthesis of Amides -- 4.5 Synthesis of Other Products -- 4.6 Summary and Conclusions -- References -- Part II Carbonylations Promoted by Second Row Transition Metal Catalysts -- Chapter 5 Ruthenium‐Catalyzed Carbonylations -- 5.1 Introduction -- 5.2 CH Activation of Nitrogen‐Containing Arene Derivatives -- 5.3 Ruthenium‐Catalyzed Carbonylations of Olefins and Nitroarenes -- 5.3.1 Ruthenium‐Catalyzed Hydroformylations.
5.3.2 Ruthenium‐Catalyzed Alkoxycarbonylation of Olefins -- 5.3.3 Carbonylation of Nitroarenes -- 5.4 Ruthenium‐Catalyzed Carbonylation of Amines and Alcohols -- 5.5 Ruthenium‐Catalyzed Cyclocarbonylations -- 5.6 Ruthenium‐Catalyzed Reactions Using Syngas -- 5.6.1 Fischer-Tropsch Synthesis -- 5.6.2 Synthesis of Oxo Products from Syngas -- 5.7 Synthesis of Oxo Products from H2 and CO2 -- 5.8 Conclusions -- References -- Chapter 6 Rhodium‐Catalyzed Carbonylations -- 6.1 Introduction -- 6.2 Hydroformylation -- 6.2.1 Catalyst Recovery -- 6.2.2 Aqueous Biphase Hydroformylation -- 6.2.3 Enantioselective Hydroformylation -- 6.2.4 Tandem Hydroformylation -- 6.2.5 Syngas Surrogates -- 6.3 Carbonylation -- 6.4 Some Relevant Patents and Patent Applications (2015-2020) -- 6.4.1 Hydroformylation -- 6.4.2 Preparation of Acetic Acid and Similar Compounds and Derivatives -- 6.4.3 Alcohols -- 6.5 Summary and Conclusions -- References -- Chapter 7 Palladium(0)‐Catalyzed Carbonylations -- 7.1 Introduction -- 7.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives -- 7.2.1 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives from Aryl Halides -- 7.2.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives from Alkynes -- 7.2.3 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ester Derivatives Using Benzyl Amines -- 7.3 Palladium(0)‐Catalyzed Carbonylative Synthesis of Amide Derivatives -- 7.3.1 Palladium(0)‐Catalyzed Carbonylative Synthesis of β‐Lactams -- 7.3.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Five, Six, Seven‐Membered Cyclic Amides -- 7.3.3 Palladium(0)‐Catalyzed Carbonylative Synthesis of Benzamide Derivatives -- 7.4 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ketone Derivatives -- 7.4.1 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ketone Derivatives from Aryl Halides. 7.4.2 Palladium(0)‐Catalyzed Carbonylative Synthesis of Ketone Derivatives from Other Substrates -- 7.5 Palladium(0)‐Catalyzed Carbonylative Synthesis of α,β‐Alkynyl Ketones Derivatives -- 7.6 Palladium(0)‐Catalyzed Carbonylative Synthesis of Other Carbonyl Compounds -- 7.7 Summary and Conclusions -- References -- Chapter 8 Palladium(II)‐Catalyzed Carbonylations -- 8.1 Introduction -- 8.2 Palladium(II)‐Catalyzed Carbonylation of Alkanes and Saturated C H Bonds -- 8.3 Palladium(II)‐Catalyzed Carbonylation of Arenes and Heteroarenes -- 8.4 Palladium(II)‐Catalyzed Carbonylation of Alkenes -- 8.4.1 Palladium(II)‐Catalyzed Carbonylation of Unfunctionalized Alkenes, Dienes, and Allenes -- 8.4.2 Palladium(II)‐Catalyzed Carbonylation of Functionalized Alkenes and Allenes -- 8.5 Palladium(II)‐Catalyzed Carbonylation of Alkynes -- 8.5.1 Palladium(II)‐Catalyzed Carbonylation of Unfunctionalized Alkynes -- 8.5.2 Palladium(II)‐Catalyzed Carbonylation of Functionalized Alkynes -- 8.6 Palladium(II)‐Catalyzed Carbonylation of Other Substrates -- 8.7 Summary and Conclusions -- References -- Chapter 9 Carbonylations Catalyzed by Other Second‐Row Transition Metal Catalysts -- 9.1 Introduction -- 9.2 Zirconium Compounds as Carbonylation Catalysts -- 9.2.1 Carbonylation with Carbon Monoxide on Sulfated‐Doped Zirconia as the Solid Acid Catalyst -- 9.2.2 Carbonylation of Zirconocene Complexes -- 9.3 Silver Compounds in Carbonylation Reactions -- 9.3.1 Koch‐Type Reactions in the Presence of Silver Carbonyl Ion Catalyst -- 9.3.2 Koch‐Type Reactions in the Presence of Silver Lewis Acids under CO Atmosphere -- 9.3.3 Carbonylative Coupling Reactions Promoted by Metal-Silver Bimetallic Catalysts -- 9.4 Molybdenum Compounds in Carbonylation Reactions -- 9.4.1 Formal Carbonylation Processes: Carbonylation of Ethylene and Methanol. 9.4.2 Molybdenum Carbonyl Complexes as Catalysts and CO Source in Intermolecular Carbonylation Coupling Reactions of Aryl or Alkenyl Halides -- 9.4.3 Molybdenum Carbonyl Complexes as Both Catalysts and CO Source in Intramolecular Carbonylation Coupling Reactions -- 9.4.4 Metal‐Catalyzed Coupling Procedures Using Molybdenum as the CO Source -- 9.4.4.1 Intermolecular Cross‐Coupling Procedures -- 9.4.4.2 Cascade and Intramolecular Cross‐Coupling Procedures -- 9.4.4.3 Carbonylative Cross‐Coupling in the Presence of Transmetalation Partners -- 9.5 Summary and Conclusions -- References -- Part III Miscellaneous Carbonylation Reactions -- Chapter 10 Carbonylations Promoted by Third‐Row Transition Metal Catalysts -- 10.1 Introduction -- 10.2 Methanol Carbonylation -- 10.2.1 Acetic Acid Production -- 10.2.2 Process Considerations and Mechanism for Rh Catalyst -- 10.2.3 Iridium Catalysts -- 10.2.3.1 Mechanism for Iridium Catalyst -- 10.2.3.2 Role of Promoters in Iridium‐Catalyzed Methanol Carbonylation -- 10.2.3.3 Recent Developments -- 10.3 Hydroformylation -- 10.3.1 Iridium Catalysts -- 10.3.2 Platinum Catalysts -- 10.3.3 Osmium Catalysts -- 10.4 Other Carbonylation Reactions -- 10.4.1 Alkoxycarbonylation of Alkenes -- 10.4.2 Carbonylation Reactions Involving Alkynes -- 10.4.3 Oxidative Carbonylations -- 10.5 Summary and Conclusions -- References -- Chapter 11 Transition Metal‐Free Carbonylation Processes -- 11.1 Introduction -- 11.2 Transition‐Metal‐Free Carbonylation for the Synthesis of Aldehydes and Ketones -- 11.3 Transition‐Metal‐Free Carbonylation for the Synthesis of Esters and Lactones -- 11.4 Transition‐Metal‐Free Carbonylation for the Synthesis of Amides -- 11.5 Transition‐Metal‐Free Carbonylation for the Synthesis of Acids and Anhydrides -- 11.6 Transition‐Metal‐Free Carbonylation for the Synthesis of Acyl Chlorides and Alcohols. 11.7 Summary and Conclusions -- References -- Chapter 12 Conclusions and Perspectives -- Index -- EULA. |
| Record Nr. | UNINA-9910830285703321 |
| Weinheim, Germany : , : Wiley-VCH, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic Synthesis via Transition Metal-Catalysis
| Organic Synthesis via Transition Metal-Catalysis |
| Autore | Gabriele Bartolo |
| Pubbl/distr/stampa | Basel, : MDPI - Multidisciplinary Digital Publishing Institute, 2022 |
| Descrizione fisica | 1 electronic resource (144 p.) |
| Soggetto topico | Research & information: general |
| Soggetto non controllato |
palladium
indole indomethacin C-H functionalization sulfoximide C-H activation benzothiazine rhodium catalysis synthesis organosulfur compounds S-S bond cleavage chemical equilibrium reversible reaction alkynes annulation benzimidazoxazinones heterocycles polycyclic heterocycles heterocyclization zinc direct arylation pincer complexes vanadium(IV) complexes biological activity catalytic properties 8-hydroxyquinoline cytotoxicity studies hydroformylation hydrogenation tandem reaction |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910557611103321 |
Gabriele Bartolo
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| Basel, : MDPI - Multidisciplinary Digital Publishing Institute, 2022 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||