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Autore: | Fu Ming-Chen |
Titolo: | Studies on Green Synthetic Reactions Based on Formic Acid from Biomass / / by Ming-Chen Fu |
Pubblicazione: | Singapore : , : Springer Singapore : , : Imprint : Springer, , 2020 |
Edizione: | 1st ed. 2020. |
Descrizione fisica: | 1 online resource (XIV, 105 p. 189 illus., 24 illus. in color.) |
Disciplina: | 660.0286 |
Soggetto topico: | Catalysis |
Green chemistry | |
Organic chemistry | |
Green Chemistry | |
Organic Chemistry | |
Nota di contenuto: | Introduction -- Conversion of Formic Acid as C1 building block on Organic Synthesis -- Non-Metal Boron-Catalyzed N-methylation Conversion of Amines with Formic Acid -- Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling -- Efficient Pd-Catalyzed Carboxylation of Allylic Alcohols with Formic Acid -- Conclusions. |
Sommario/riassunto: | This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. . |
Titolo autorizzato: | Studies on Green Synthetic Reactions Based on Formic Acid from Biomass |
ISBN: | 981-15-7623-8 |
Formato: | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione: | Inglese |
Record Nr.: | 9910416142703321 |
Lo trovi qui: | Univ. Federico II |
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