Studies on Green Synthetic Reactions Based on Formic Acid from Biomass / / by Ming-Chen Fu

• Autore: Fu Ming-Chen
• Pubblicazione: Singapore : , : Springer Singapore : , : Imprint : Springer, , 2020
• Edizione: 1st ed. 2020.
• Descrizione fisica: 1 online resource (XIV, 105 p. 189 illus., 24 illus. in color.)
• Disciplina: 660.0286
• Soggetto topico: Catalysis; Green chemistry; Organic chemistry; Green Chemistry; Organic Chemistry
• Nota di contenuto: Introduction -- Conversion of Formic Acid as C1 building block on Organic Synthesis -- Non-Metal Boron-Catalyzed N-methylation Conversion of Amines with Formic Acid -- Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling -- Efficient Pd-Catalyzed Carboxylation of Allylic Alcohols with Formic Acid -- Conclusions.
• Sommario/riassunto: This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. .
• Titolo autorizzato: Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
• ISBN: 981-15-7623-8
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910416142703321
• Lo trovi qui: Univ. Federico II
• Serie: Springer Theses, Recognizing Outstanding Ph.D. Research, . 2190-5053