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Molecular orbitals and organic chemical reactions / / Ian Fleming
| Molecular orbitals and organic chemical reactions / / Ian Fleming |
| Autore | Fleming Ian <1935-> |
| Edizione | [Reference ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2010 |
| Descrizione fisica | 1 online resource (529 p.) |
| Disciplina | 547/.2 |
| Soggetto topico |
Molecular orbitals
Chemical bonds Physical organic chemistry |
| ISBN |
1-119-96467-9
1-282-55013-6 9786612550133 0-470-68949-8 0-470-68950-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CONTENTS; Preface; 1 Molecular Orbital Theory; 1.1 The Atomic Orbitals of a Hydrogen Atom; 1.2 Molecules Made from Hydrogen Atoms; 1.3 C-H and C-C Bonds; 1.4 Conjugation-Hückel Theory; 1.5 Aromaticity; 1.6 Strained Bonds-Cyclopropanes and Cyclobutanes; 1.7 Heteronuclear Bonds, C-M, C-X and C=O; 1.8 The Tau Bond Model; 1.9 Spectroscopic Methods; 2 Molecular Orbitals and the Structures of Organic Molecules; 2.1 The Effects of Conjugation; 2.2 Hyperconjugation- Conjugation; 2.3 The Configurations and Conformations of Molecules; 2.4 The Effect of Conjugation on Electron Distribution
2.5 Other Noncovalent Interactions3 Chemical Reactions-How Far and How Fast; 3.1 Factors Affecting the Position of an Equilibrium; 3.2 The Principle of Hard and Soft Acids and Bases (HSAB); 3.3 Transition Structures; 3.4 The Perturbation Theory of Reactivity; 3.5 The Salem-Klopman Equation; 3.6 Hard and Soft Nucleophiles and Electrophiles; 3.7 Other Factors Affecting Chemical Reactivity; 4 Ionic Reactions-Reactivity; 4.1 Single Electron Transfer (SET) in Ionic Reactions; 4.2 Nucleophilicity; 4.3 Ambident Nucleophiles; 4.4 Electrophilicity; 4.5 Ambident Electrophiles; 4.6 Carbenes 5 Ionic Reactions-Stereochemistry5.1 The Stereochemistry of the FundamentalOrganic Reactions; 5.2 Diastereoselectivity; 6 Thermal Pericyclic Reactions; 6.1 The Four Classes of Pericyclic Reactions; 6.2 Evidence for the Concertedness of Bond Makingand Breaking; 6.3 Symmetry-allowed and Symmetry-forbidden Reactions; 6.4 Explanations for the Woodward-Hoffmann Rules; 6.5 Secondary Effects; 7 Radical Reactions; 7.1 Nucleophilic and Electrophilic Radicals; 7.2 The Abstraction of Hydrogen and Halogen Atoms; 7.3 The Addition of Radicals to Bonds 7.4 Synthetic Applications of the Chemoselectivity of Radicals7.5 Stereochemistry in some Radical Reactions; 7.6 Ambident Radicals; 7.7 Radical Coupling; 8 Photochemical Reactions; 8.1 Photochemical Reactions in General; 8.2 Photochemical Ionic Reactions; 8.3 Photochemical Pericyclic Reactions and Related Stepwise Reactions; 8.4 Photochemically Induced Radical Reactions; 8.5 Chemiluminescence; References; Index |
| Record Nr. | UNINA-9910139364603321 |
Fleming Ian <1935->
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| Hoboken, N.J., : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Spectroscopic Methods in Organic Chemistry / / by Ian Fleming, Dudley Williams
| Spectroscopic Methods in Organic Chemistry / / by Ian Fleming, Dudley Williams |
| Autore | Fleming Ian <1935-> |
| Edizione | [7th ed. 2019.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2019 |
| Descrizione fisica | 1 online resource (XI, 432 p. 466 illus., 16 illus. in color.) |
| Disciplina | 547.30858 |
| Soggetto topico |
Química orgànica
Espectroscòpia Spectroscopy Mass spectrometry Microscopy Organic chemistry Spectroscopy/Spectrometry Mass Spectrometry Spectroscopy and Microscopy Organic Chemistry |
| Soggetto genere / forma | Llibres electrònics |
| ISBN | 3-030-18252-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Chapter 1:Mass Spectra -- Chapter 2: Ultraviolet and visible spectra -- Chapter 3: Infrared spectra -- Chapter 4: 1D-NMR spectra -- Chapter 5: 2D-NMR spectra -- Chapter 6: Worked examples in structure determination -- Chapter 7: Problem sets -- Index. |
| Record Nr. | UNINA-9910370253703321 |
|
Fleming Ian <1935->
|
||
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2019 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||