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Biodegradable polyesters / / edited by Stoyko Fakirov
| Biodegradable polyesters / / edited by Stoyko Fakirov |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (370 p.) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Biodegradable plastics |
| ISBN |
1-5231-1008-2
3-527-65697-9 3-527-65695-2 3-527-65698-7 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Cover; Contents; List of Contributors; List of Abbreviations and Symbols; Preface; Chapter 1 Biodegradable Polyesters: Synthesis, Properties, Applications; 1.1 Historical Overview on the Origin of Polymer Science and Synthesis of Polyamides and Polyesters; 1.1.1 Synthesis of Polyamides; 1.1.2 Initial Knowledge about Polyesters; 1.2 Publication Trend of Representative Biodegradable and Nonbiodegradable Polyesters in the Past Century; 1.3 Biodegradable Polyesters; 1.3.1 Biodegradable Aliphatic Polyesters and Their Copolymers; 1.3.1.1 Poly(lactic acid)
1.3.1.2 Polyglycolide or Poly(glycolic acid)1.3.1.3 Poly(caprolactone); 1.4 Concluding Remarks; Acknowledgment; References; Chapter 2 Functional (Bio)degradable Polyesters by Radical Ring-Opening Polymerization; 2.1 Introduction; 2.2 Radical Ring-Opening Polymerization (RROP) of Cyclic Ketene Acetals; 2.2.1 Starting Monomers: Cyclic Ketene Acetals; 2.2.2 Radical Ring-Opening Polymerization Mechanism; 2.2.3 Functional Polyesters by Conventional and Controlled Radical Homopolymerization of CKAs; 2.2.4 Functional Polyesters by Copolymerization of CKAs and Vinyl Monomers; 2.3 Conclusions References Chapter 3 Microbial Synthesis of Biodegradable Polyesters: Processes, Products, Applications; 3.1 Introduction; 3.2 Biogenesis of Microbial Polyhydroxyalkanoate Granules; 3.3 The Diversity of Biopolyesters; 3.4 Polyester (PHA) Synthases are the Key Enzymes; 3.5 Catalytic Reaction Mechanism; 3.6 PHA Inclusions: Self-Assembly and Structure; 3.7 Industrial Production of Bacterial Polyhydroxyalkanoates: PHAs via Fermentation; 3.8 Application Opportunities of Bacterial Polyhydroxyalkanoates; 3.8.1 In Energy Industry: Biofuels Based on PHAs 3.8.2 In Material Industry: PHAs as Polymeric Materials 3.8.2.1 PHAs as Biodegradable Plastics and Fiber Materials; 3.8.2.2 PHAs as Medical Implant Materials; 3.8.2.3 PHAs as Drug Delivery Carrier; 3.8.3 Fine Chemical Industry: PHA Chiral Monomers; 3.8.4 Application of PHA Granule Surface Proteins; 3.8.5 Production of Tailor-Made Biopolyester Nanoparticles and Potential Applications; 3.8.6 Future Development of PHA-Based Industry; 3.8.6.1 The Development of Low-Cost PHA Production Technology; 3.8.6.2 Unusual PHAs with Special Properties; 3.8.6.3 High Value Added Applications 3.8.6.4 Other Future Applications 3.8.6.5 Microbial Synthesis of Poly(lactic acid) (PLA); 3.8.7 Applications of PHA Inclusions as Functionalized Biobeads; 3.8.7.1 Bioseparations; 3.8.7.2 Drug Delivery; 3.8.7.3 Protein Purification; 3.8.7.4 Enzyme Immobilization; 3.8.7.5 Diagnostics and Imaging; 3.8.7.6 Vaccine Delivery; 3.9 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Synthesis, Properties, and Mathematical Modeling of Biodegradable Aliphatic Polyesters Based on 1,3-Propanediol and Dicarboxylic Acids; 4.1 Introduction; 4.1.1 Aliphatic Polyesters 4.1.2 Production of 1,3-Propanediol |
| Record Nr. | UNINA-9910132410003321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Biodegradable polyesters / / edited by Stoyko Fakirov
| Biodegradable polyesters / / edited by Stoyko Fakirov |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (370 p.) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Biodegradable plastics |
| ISBN |
9783527656981 (ebook)
3-527-65697-9 3-527-65695-2 3-527-65698-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Cover; Contents; List of Contributors; List of Abbreviations and Symbols; Preface; Chapter 1 Biodegradable Polyesters: Synthesis, Properties, Applications; 1.1 Historical Overview on the Origin of Polymer Science and Synthesis of Polyamides and Polyesters; 1.1.1 Synthesis of Polyamides; 1.1.2 Initial Knowledge about Polyesters; 1.2 Publication Trend of Representative Biodegradable and Nonbiodegradable Polyesters in the Past Century; 1.3 Biodegradable Polyesters; 1.3.1 Biodegradable Aliphatic Polyesters and Their Copolymers; 1.3.1.1 Poly(lactic acid)
1.3.1.2 Polyglycolide or Poly(glycolic acid)1.3.1.3 Poly(caprolactone); 1.4 Concluding Remarks; Acknowledgment; References; Chapter 2 Functional (Bio)degradable Polyesters by Radical Ring-Opening Polymerization; 2.1 Introduction; 2.2 Radical Ring-Opening Polymerization (RROP) of Cyclic Ketene Acetals; 2.2.1 Starting Monomers: Cyclic Ketene Acetals; 2.2.2 Radical Ring-Opening Polymerization Mechanism; 2.2.3 Functional Polyesters by Conventional and Controlled Radical Homopolymerization of CKAs; 2.2.4 Functional Polyesters by Copolymerization of CKAs and Vinyl Monomers; 2.3 Conclusions References Chapter 3 Microbial Synthesis of Biodegradable Polyesters: Processes, Products, Applications; 3.1 Introduction; 3.2 Biogenesis of Microbial Polyhydroxyalkanoate Granules; 3.3 The Diversity of Biopolyesters; 3.4 Polyester (PHA) Synthases are the Key Enzymes; 3.5 Catalytic Reaction Mechanism; 3.6 PHA Inclusions: Self-Assembly and Structure; 3.7 Industrial Production of Bacterial Polyhydroxyalkanoates: PHAs via Fermentation; 3.8 Application Opportunities of Bacterial Polyhydroxyalkanoates; 3.8.1 In Energy Industry: Biofuels Based on PHAs 3.8.2 In Material Industry: PHAs as Polymeric Materials 3.8.2.1 PHAs as Biodegradable Plastics and Fiber Materials; 3.8.2.2 PHAs as Medical Implant Materials; 3.8.2.3 PHAs as Drug Delivery Carrier; 3.8.3 Fine Chemical Industry: PHA Chiral Monomers; 3.8.4 Application of PHA Granule Surface Proteins; 3.8.5 Production of Tailor-Made Biopolyester Nanoparticles and Potential Applications; 3.8.6 Future Development of PHA-Based Industry; 3.8.6.1 The Development of Low-Cost PHA Production Technology; 3.8.6.2 Unusual PHAs with Special Properties; 3.8.6.3 High Value Added Applications 3.8.6.4 Other Future Applications 3.8.6.5 Microbial Synthesis of Poly(lactic acid) (PLA); 3.8.7 Applications of PHA Inclusions as Functionalized Biobeads; 3.8.7.1 Bioseparations; 3.8.7.2 Drug Delivery; 3.8.7.3 Protein Purification; 3.8.7.4 Enzyme Immobilization; 3.8.7.5 Diagnostics and Imaging; 3.8.7.6 Vaccine Delivery; 3.9 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Synthesis, Properties, and Mathematical Modeling of Biodegradable Aliphatic Polyesters Based on 1,3-Propanediol and Dicarboxylic Acids; 4.1 Introduction; 4.1.1 Aliphatic Polyesters 4.1.2 Production of 1,3-Propanediol |
| Record Nr. | UNINA-9910825637803321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of condensation thermoplastic elastomers [[electronic resource] /] / Stokyo Fakirov
| Handbook of condensation thermoplastic elastomers [[electronic resource] /] / Stokyo Fakirov |
| Autore | Fakirov Stoyko |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, 2005 |
| Descrizione fisica | 1 online resource (645 p.) |
| Disciplina | 620.194 |
| Altri autori (Persone) | FakirovStoyko |
| Soggetto topico |
Elastomers
Thermoplastics Condensation products (Chemistry) |
| ISBN |
1-280-52119-8
9786610521197 3-527-60661-0 3-527-60689-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Handbook of Condensation Thermoplastic Elastomer; Preface; Contents; Contributors; PART I INTRODUCTION; Chapter 1 Creation and Development of Thermoplastic Elastomers, and Their Position Among Organic Materials; 1. Birth and development of TPEs: a brief survey; 2. Main routes to thermoplastic elastomer preparation; 2.1. Living anionic polymerization; 2.2. Living cationic polymerization; 2.3. Controlled radical polymerization; 2.4. Polycondensation and polyaddition; 2.5. Chemical modification and grafting; 2.6. Preparation by blending; 2.7. Preparation by dynamic vulcanization
3. Techniques used in the characterization of TPEs3.1. Chromatography; 3.2. Spectrometric techniques; 3.3. Scattering techniques; 3.4. Microscopies; 3.5. Controlled degradation; 3.6. Thermal techniques; 4. Properties and processing of TPEs; 4.1. Injection molding; 4.2. Compression molding; 4.3. Extrusion; 4.4. Blow processings; 4.5. Thermoforming; 4.6. Reactive processings; 4.7. Degradation in processing; 5. Position of TPEs among organic materials and their applications; 6. Future trends; References Chapter 2 Polycondensation Reactions in Thermoplastic Elastomer Chemistry: State of the Art, Trends, and Future Developments1. Introduction; 2. Preparation of block copolymers by polycondensation. A critical review; 2.1. General considerations; 2.2. Direct polycondensation of α,ω-difunctional oligomers; 2.3. Polycondensation of an α,ω-difunctional oligomer with the precursors of another block; 2.4. Oligomer-coupling reactions; 2.5. Characterization techniques. Side reactions; 3. New structures; 3.1. Block copolymers containing liquid crystalline structures 3.2. Liquid crystalline sequences as part of the backbone3.3. Liquid crystalline sequences as side chains; 3.4. Metallo-supramolecular block copolymers; 3.5. Block copolymers prepared from metal-containing macrocycles; 3.6. The use of microorganisms; 4. Conclusions; References; PART II POLYESTER-BASED THERMOPLASTIC ELASTOMERS; Chapter 3 Polyester Thermoplastic Elastomers: Synthesis, Properties, and Some Applications; 1. Introduction; 2. Chemical structure of polyester elastomers; 3. Poly(alkylene oxide) flexible segment-based polyester elastomers 4. Modified poly(butylene terephthalate) rigid segment-based polyester elastomers5. Branched polyester elastomers; 6. Synthesis of poly(ether ester) block copolymers; 7. Other multiblock polyester elastomers; 8. Polyester thermoplastic elastomers from blends; 9. A new processing aspect: weldability of polyester elastomers; 10. Polyester elastomers for biomedical application; 11. Conclusions and outlook; References; Chapter 4 Terpoly(Ester-b-Ether-b-Amide) Thermoplastic Elastomers: Synthesis, Structure, and Properties; 1. Introduction; 2. Chemical structure of terpoly(ester-b-ether-b-amide)s 3. Synthesis of triblock -(GT-b-PO4-b-PA)(n)- polymers |
| Record Nr. | UNINA-9910144710303321 |
Fakirov Stoyko
|
||
| Weinheim ; ; [Great Britain], : Wiley-VCH, 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of condensation thermoplastic elastomers [[electronic resource] /] / Stokyo Fakirov
| Handbook of condensation thermoplastic elastomers [[electronic resource] /] / Stokyo Fakirov |
| Autore | Fakirov Stoyko |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, 2005 |
| Descrizione fisica | 1 online resource (645 p.) |
| Disciplina | 620.194 |
| Altri autori (Persone) | FakirovStoyko |
| Soggetto topico |
Elastomers
Thermoplastics Condensation products (Chemistry) |
| ISBN |
1-280-52119-8
9786610521197 3-527-60661-0 3-527-60689-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Handbook of Condensation Thermoplastic Elastomer; Preface; Contents; Contributors; PART I INTRODUCTION; Chapter 1 Creation and Development of Thermoplastic Elastomers, and Their Position Among Organic Materials; 1. Birth and development of TPEs: a brief survey; 2. Main routes to thermoplastic elastomer preparation; 2.1. Living anionic polymerization; 2.2. Living cationic polymerization; 2.3. Controlled radical polymerization; 2.4. Polycondensation and polyaddition; 2.5. Chemical modification and grafting; 2.6. Preparation by blending; 2.7. Preparation by dynamic vulcanization
3. Techniques used in the characterization of TPEs3.1. Chromatography; 3.2. Spectrometric techniques; 3.3. Scattering techniques; 3.4. Microscopies; 3.5. Controlled degradation; 3.6. Thermal techniques; 4. Properties and processing of TPEs; 4.1. Injection molding; 4.2. Compression molding; 4.3. Extrusion; 4.4. Blow processings; 4.5. Thermoforming; 4.6. Reactive processings; 4.7. Degradation in processing; 5. Position of TPEs among organic materials and their applications; 6. Future trends; References Chapter 2 Polycondensation Reactions in Thermoplastic Elastomer Chemistry: State of the Art, Trends, and Future Developments1. Introduction; 2. Preparation of block copolymers by polycondensation. A critical review; 2.1. General considerations; 2.2. Direct polycondensation of α,ω-difunctional oligomers; 2.3. Polycondensation of an α,ω-difunctional oligomer with the precursors of another block; 2.4. Oligomer-coupling reactions; 2.5. Characterization techniques. Side reactions; 3. New structures; 3.1. Block copolymers containing liquid crystalline structures 3.2. Liquid crystalline sequences as part of the backbone3.3. Liquid crystalline sequences as side chains; 3.4. Metallo-supramolecular block copolymers; 3.5. Block copolymers prepared from metal-containing macrocycles; 3.6. The use of microorganisms; 4. Conclusions; References; PART II POLYESTER-BASED THERMOPLASTIC ELASTOMERS; Chapter 3 Polyester Thermoplastic Elastomers: Synthesis, Properties, and Some Applications; 1. Introduction; 2. Chemical structure of polyester elastomers; 3. Poly(alkylene oxide) flexible segment-based polyester elastomers 4. Modified poly(butylene terephthalate) rigid segment-based polyester elastomers5. Branched polyester elastomers; 6. Synthesis of poly(ether ester) block copolymers; 7. Other multiblock polyester elastomers; 8. Polyester thermoplastic elastomers from blends; 9. A new processing aspect: weldability of polyester elastomers; 10. Polyester elastomers for biomedical application; 11. Conclusions and outlook; References; Chapter 4 Terpoly(Ester-b-Ether-b-Amide) Thermoplastic Elastomers: Synthesis, Structure, and Properties; 1. Introduction; 2. Chemical structure of terpoly(ester-b-ether-b-amide)s 3. Synthesis of triblock -(GT-b-PO4-b-PA)(n)- polymers |
| Record Nr. | UNINA-9910830245503321 |
|
Fakirov Stoyko
|
||
| Weinheim ; ; [Great Britain], : Wiley-VCH, 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of engineering biopolymers : homopolymers, blends, and composites
| Handbook of engineering biopolymers : homopolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Hanser, 2007 |
| Disciplina | 620.1/923 |
| Soggetto topico |
Biopolymers - Analysis
Manufactures - Materials Chemical & Materials Engineering Engineering & Applied Sciences Materials Science |
| ISBN | 1-68015-262-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9911006992603321 |
| [Place of publication not identified], : Hanser, 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites
| Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (1392 pages) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Thermoplastic composites Chemical Engineering Chemical & Materials Engineering Engineering & Applied Sciences |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-56069-X
9786610560691 3-527-60196-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910146051103321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites
| Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (1392 pages) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Thermoplastic composites Chemical Engineering Chemical & Materials Engineering Engineering & Applied Sciences |
| ISBN |
1-280-56069-X
9786610560691 3-527-60196-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830672603321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites
| Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (1392 pages) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Thermoplastic composites Chemical Engineering Chemical & Materials Engineering Engineering & Applied Sciences |
| ISBN |
1-280-56069-X
9786610560691 3-527-60196-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9911019846503321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Nano-size Polymers : Preparation, Properties, Applications / / edited by Stoyko Fakirov
| Nano-size Polymers : Preparation, Properties, Applications / / edited by Stoyko Fakirov |
| Edizione | [1st ed. 2016.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2016 |
| Descrizione fisica | 1 online resource (399 p.) |
| Disciplina | 620.11 |
| Soggetto topico |
Nanotechnology
Polymers Chemical engineering Polymer Sciences Nanotechnology and Microengineering Industrial Chemistry/Chemical Engineering |
| ISBN | 3-319-39715-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Part 1. Introduction -- Nano-Polymer Materials: How to Generate Them and Do We Need Them? -- Part 2. Chemical Approaches for Preparation of Nano-Size Polymers -- Nanosized Polymer Structures via Self-Assembly and Co-Assembly Approaches -- Direct Synthesis of Nano-size Polymers by Microemulsion Polymerization -- Part 3. Physical Approaches for Preparation of Nano-Size Polymers -- Electrospinning: Current Status and Future Trends -- Synthesis and Properties of Cellulose Nanowhiskers and Their Nanocomposites -- From Polymer Blends to Nano-Size Materials with Controlled Nanomorphology -- Electrospun Polymer Nanofiber Separators and Electrolyte Membranes for Energy Storage and Conversion Applications -- Converting of Bulk Polymers into Nanofibrils via Hot Stretching of Polymer Blends -- Nano-Size Polymers via Precipitation of Polymer Solutions -- Fabrication and Properties of Spin-Coated Polymer Films -- Part 4. Application Opportunities of Nano-Size Polymers -- Electrospinning- Commercial Applications, Challenges and Opportunities -- Nanofibrillar Single Polymer Composites: Preparation and Mechanical Properties -- Template-Assisted Approaches for Preparation of Nanosized Polymer Structures. |
| Record Nr. | UNINA-9910254042103321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Oriented polymer materials [[electronic resource] /] / edited by Stoyko Fakirov
| Oriented polymer materials [[electronic resource] /] / edited by Stoyko Fakirov |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, 2002 |
| Descrizione fisica | 1 online resource (536 p.) |
| Disciplina |
547.84
620.192 |
| Altri autori (Persone) | FakirovStoyko |
| Soggetto topico | Polymers |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-84269-9
9786611842697 3-527-61505-9 3-527-61504-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Oriented Polymer Materials; CONTENTS; Chapter 1. Problems of the physics of the oriented state of polymers; 1 . Introductory considerations; 1.1. Interplay of fundamental and applied problems . Molecular cybernetics; 1.2. Principal routes to the formation of uniaxially oriented structures in polymers; 2 . Configurational information and orientation phenomena in synthetic polymers; 2.1. Direct generation of orientational order from solutions and melts . Orientational hardening, orientational crystallization, and orientational catastrophes; 2.2. Assemblage; liquid crystalline polymers
2.3. Reconstruction3. Failure under load; 4. Some specific properties of superoriented polymers; 5. Technological implications; 6. General conclusions and summary; 6.1. What is clear?; 6.2. What is incomprehensible?; 6.3. What needs better understanding?; References; Chapter 2. Structural basis of high-strength high-modulus polymers; 1. Introduction; 2. Structural transformation in semicrystalline polymers on stretching; 2.1. Deformation mechanisms at small strain; 2.2. Folded-extended chain solid phase transition in the neck region 2.3. Micro- and macrofibrillar structure in oriented polymers and its plastic deformation2.4. Drawing arrest and fracture of oriented polymers; 2.5. Alternative mechanisms of drawing; 3. Deformation-induced strengthening of semicrystalline polymers; 3.1. Structural kinetic approach to the enhancement of polymer characteristics by deformation; 3.2. Physical criteria for the optimization of the drawing process; 3.3. Optimal molecular weight and molecular weight distribution; 4. Mechanical properties of highly oriented polymers; 5. Thermal properties of superstrong high-modulus polymers 6. Structural peculiarities of highly oriented polymersReferences; Chapter 3. X-ray diffraction by quasiperiodic polymer structures; 1. Introduction; 2. Qualitative phenomenological aspects; 2.1. Fibre diagrams; 2.2. Crystal density, chain cross section and chain conformation; 2.3. Anisotropy perpendicular to the chain direction, planes of plates; 2.4. Position sphere; 2.5. Lattice distortions of the first and second kind . Distortion parameter; 2.6. Special lattice types; 2.7. Small-angle scattering, fibrils, layer lattices; 3 . Basics of experiments; 3.1. X-ray spectrum and absorption 4 . Theoretical relationships4.1. Structure factor; 4.2. The Ewald sphere; 4.3. Pair distribution; 4.4. A special application example; 5 . Simple lattice models; 5.1. Ideal periodic lattices; 5.2. Distortions of the first kind; 5.3. Distortions of the second kind; 5.4. Inhomogeneous coordination statistics; References; Chapter 4. Characterization of polymer deformation by vibrational spectroscopy; 1. Introduction; 2. Experimental and instrumentation; 3. Orientational measurements by infrared dichroism; 4. Segmental mobility in liquid crystalline side-chain polymers 5. Rheo-optical FT-IR studies of the poly(ethylene terephthalate) film forming process |
| Record Nr. | UNINA-9910144236503321 |
| Weinheim, : Wiley-VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
