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Molecular clusters of the main group elements / / Matthias Driess, Heinrich Nöth, (eds.)
| Molecular clusters of the main group elements / / Matthias Driess, Heinrich Nöth, (eds.) |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2004 |
| Descrizione fisica | 1 online resource (462 p.) |
| Disciplina |
539.6
541 |
| Soggetto topico |
Microclusters
Chemical elements |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-56087-8
9786610560875 3-527-61437-0 3-527-60244-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Molecular Clusters of the Main Group Elements; Contents; Preface; List of Contributors; 1 Theory and Concepts in Main-Group Cluster Chemistry; 1.1 Introduction; 1.1.1 Three-center Bonding in Boranes: Lipscomb's Equations of Balance; 1.1.2 Polyhedral Skeletal Electron Pair Theory: The Wade-Mingos Rules; 1.1.3 Aromaticity in Three-dimensional Clusters; 1.1.3.1 From Polygonal Aromatics to Deltahedral Boranes; 1.1.3.2 Interstitial Polygonal Aromatic-Deltahedral Borane Relationships; 1.1.3.3 Aromaticity Evaluations of Three-dimensional Structures: Nucleus-Independent Chemical Shift (NICS)
1.1.3.4 Spherical Aromaticity1.1.4 Bare Ionic Post-transition Metal Clusters: The Zintl Phases; 1.1.5 Clusters of the Heavier Group 13 Metals; 1.1.5.1 Apparently Hypoelectronic Deltahedra in Bare Clusters of Indium and Thallium: Polyhedra with Flattened Vertices; 1.1.5.2 Organometallic Deltahedral Clusters of the Heavier Group 13 Metals and More Complicated Structures Derived from Deltahedra; 1.1.5.3 Giant Aluminum Clusters with Shell Structures Consisting of Nested Polyhedra: Pieces of Icosahedral Quasicrystals; 1.1.6 Conclusion and Outlook; References; 2.1 Homonuclear Boron Clusters 2.1.1 Introduction2.1.2 General Principles and Systematic Naming; 2.1.2.1 Structures and Bonding; 2.1.3 Synthetic Methods; 2.1.3.1 Diborane Pyrolysis; 2.1.3.2 The Anionic Route; 2.1.3.3 Platinum-catalyzed Dehydrocoupling; 2.1.3.4 Cluster Expansion and Cluster Contraction Reactions; 2.1.4 Chemistry of Selected Polyboranes; 2.1.4.1 Chemistry of Triborane B(3)H(7); 2.1.4.2 Chemistry of Tetraboranes; 2.1.4.2.1 arachno-Tetraborane(10); 2.1.4.2.2 Derivatives of nido-Tetraborane(8), B(4)H(8), and closo-Tetraborane(6), B(4)H(6); 2.1.4.3 Chemistry of Pentaborane(9); 2.1.4.4 Chemistry of Decaborane(14) 2.1.5 Chemistry of Selected nido- and closo-Polyborane Anions2.1.5.1 Chemistry of closo-B(6)H(6)(2-); 2.1.5.2 Chemistry of the Nonahydro-closo-nonaborate(2-); 2.1.5.3 Reaction of Decahydro-closo-decaborate(2-); 2.1.5.4 Chemistry of the nido-Decaborate B(10)H(13)(-); 2.1.5.5 Chemistry of Undecahydro-closo-undecaborate B(11)H(11)(2-); 2.1.5.6 Chemistry of the Dodecahydro-closo-dodecaborate; 2.1.5.6.1 Protonation and Alkylation of B(12)H(12)(2-); 2.1.5.6.2 Halogeno-, Hydroxo-, Alkoxo- and Amine closo-dodecaborates; 2.1.5.7 Chemistry of B(20)H(18)(2-) Anions 2.1.6 Substituted Neutral Polyboranes of Type B(y)X(y)2.1.6.1 Overview; 2.1.6.2 Structures; 2.1.6.3 Synthesis; 2.1.6.4 Reactions; References; 2.2 Boron Clusters in Medical Applications; 2.2.1 Introduction; 2.2.2 Dicarba-closo-dodecaborane, C(2)B(10)H(12), and Derivatives; 2.2.2.1 Preparation and Reactions of C(2)B(10) Cage Compounds; 2.2.2.2 Design and Classification of BNCT Reagents Containing C(2)B(10) Cages; 2.2.2.3 Amino Acids; 2.2.2.4 Nucleic Acid Precursors; 2.2.2.5 DNA Binders; 2.2.2.6 Porphyrins; 2.2.2.7 Combination of C(2)B(10) and Gadolinium-containing Species 2.2.3 Derivatives of the nido-carborane C(2)B(9)H(12)(2-) |
| Record Nr. | UNINA-9910146238003321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Molecular clusters of the main group elements / / Matthias Driess, Heinrich Nöth, (eds.)
| Molecular clusters of the main group elements / / Matthias Driess, Heinrich Nöth, (eds.) |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2004 |
| Descrizione fisica | 1 online resource (462 p.) |
| Disciplina |
539.6
541 |
| Soggetto topico |
Microclusters
Chemical elements |
| ISBN |
1-280-56087-8
9786610560875 3-527-61437-0 3-527-60244-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Molecular Clusters of the Main Group Elements; Contents; Preface; List of Contributors; 1 Theory and Concepts in Main-Group Cluster Chemistry; 1.1 Introduction; 1.1.1 Three-center Bonding in Boranes: Lipscomb's Equations of Balance; 1.1.2 Polyhedral Skeletal Electron Pair Theory: The Wade-Mingos Rules; 1.1.3 Aromaticity in Three-dimensional Clusters; 1.1.3.1 From Polygonal Aromatics to Deltahedral Boranes; 1.1.3.2 Interstitial Polygonal Aromatic-Deltahedral Borane Relationships; 1.1.3.3 Aromaticity Evaluations of Three-dimensional Structures: Nucleus-Independent Chemical Shift (NICS)
1.1.3.4 Spherical Aromaticity1.1.4 Bare Ionic Post-transition Metal Clusters: The Zintl Phases; 1.1.5 Clusters of the Heavier Group 13 Metals; 1.1.5.1 Apparently Hypoelectronic Deltahedra in Bare Clusters of Indium and Thallium: Polyhedra with Flattened Vertices; 1.1.5.2 Organometallic Deltahedral Clusters of the Heavier Group 13 Metals and More Complicated Structures Derived from Deltahedra; 1.1.5.3 Giant Aluminum Clusters with Shell Structures Consisting of Nested Polyhedra: Pieces of Icosahedral Quasicrystals; 1.1.6 Conclusion and Outlook; References; 2.1 Homonuclear Boron Clusters 2.1.1 Introduction2.1.2 General Principles and Systematic Naming; 2.1.2.1 Structures and Bonding; 2.1.3 Synthetic Methods; 2.1.3.1 Diborane Pyrolysis; 2.1.3.2 The Anionic Route; 2.1.3.3 Platinum-catalyzed Dehydrocoupling; 2.1.3.4 Cluster Expansion and Cluster Contraction Reactions; 2.1.4 Chemistry of Selected Polyboranes; 2.1.4.1 Chemistry of Triborane B(3)H(7); 2.1.4.2 Chemistry of Tetraboranes; 2.1.4.2.1 arachno-Tetraborane(10); 2.1.4.2.2 Derivatives of nido-Tetraborane(8), B(4)H(8), and closo-Tetraborane(6), B(4)H(6); 2.1.4.3 Chemistry of Pentaborane(9); 2.1.4.4 Chemistry of Decaborane(14) 2.1.5 Chemistry of Selected nido- and closo-Polyborane Anions2.1.5.1 Chemistry of closo-B(6)H(6)(2-); 2.1.5.2 Chemistry of the Nonahydro-closo-nonaborate(2-); 2.1.5.3 Reaction of Decahydro-closo-decaborate(2-); 2.1.5.4 Chemistry of the nido-Decaborate B(10)H(13)(-); 2.1.5.5 Chemistry of Undecahydro-closo-undecaborate B(11)H(11)(2-); 2.1.5.6 Chemistry of the Dodecahydro-closo-dodecaborate; 2.1.5.6.1 Protonation and Alkylation of B(12)H(12)(2-); 2.1.5.6.2 Halogeno-, Hydroxo-, Alkoxo- and Amine closo-dodecaborates; 2.1.5.7 Chemistry of B(20)H(18)(2-) Anions 2.1.6 Substituted Neutral Polyboranes of Type B(y)X(y)2.1.6.1 Overview; 2.1.6.2 Structures; 2.1.6.3 Synthesis; 2.1.6.4 Reactions; References; 2.2 Boron Clusters in Medical Applications; 2.2.1 Introduction; 2.2.2 Dicarba-closo-dodecaborane, C(2)B(10)H(12), and Derivatives; 2.2.2.1 Preparation and Reactions of C(2)B(10) Cage Compounds; 2.2.2.2 Design and Classification of BNCT Reagents Containing C(2)B(10) Cages; 2.2.2.3 Amino Acids; 2.2.2.4 Nucleic Acid Precursors; 2.2.2.5 DNA Binders; 2.2.2.6 Porphyrins; 2.2.2.7 Combination of C(2)B(10) and Gadolinium-containing Species 2.2.3 Derivatives of the nido-carborane C(2)B(9)H(12)(2-) |
| Record Nr. | UNINA-9910829860303321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||