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Cyclodextrins and their complexes [[electronic resource] ] : chemistry, analytical methods, applications / / edited by Helena Dodziuk
| Cyclodextrins and their complexes [[electronic resource] ] : chemistry, analytical methods, applications / / edited by Helena Dodziuk |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (509 p.) |
| Disciplina | 547.78 |
| Altri autori (Persone) | DodziukHelena |
| Soggetto topico |
Cyclodextrins
Chemistry, Technical |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-72348-3
9786610723485 3-527-60898-2 3-527-60844-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cyclodextrins and Their Complexes; Contents; Preface; List of Contributors; 1 Molecules with Holes - Cyclodextrins; 1.1 Introduction; 1.2 Cyclodextrin Properties; 1.3 Cyclodextrin Nonrigidity [94, 95]; 1.4 Models of Chiral Recognition by Cyclodextrins; References; 2 Modification Reactions of Cyclodextrins and the Chemistry of Modified Cyclodextrins; 2.1 Scope of This Chapter; 2.2 Modification Reactions of Cyclodextrins; 2.2.1 Modification Reactions at the Primary Side; 2.2.1.1 Mono-modification at the C6-Position; 2.2.1.2 Per-modification at the C6-Position
2.2.1.3 Multi-modification at the C6-Position2.2.2 Modification Reactions at the Secondary Side; 2.2.2.1 Mono-modification at the C2-Position; 2.2.2.2 Mono-modification at Any One of the C2-, C3-, or C6-Positions; 2.2.2.3 Per-modification at the C3-, C2-, or C6-Position; 2.2.3 Per-modification Reactions at All Three Positions; 2.2.4 Enzymatic Modification Reactions of Cyclodextrins; 2.2.5 Construction Reactions for Cyclodextrin Ring Formation; 2.3 Chemistry of Modified Cyclodextrins; 2.3.1 Cyclodextrin Dimers and Trimers; 2.3.2 Charged Cyclodextrins 2.3.3 Chemosensors Using Modified Cyclodextrins2.3.4 Cyclodextrin Analogues; 2.3.5 Cyclodextrins Conjugated with Other Kinds of Hosts; 2.3.6 Cyclodextrin-Peptide Conjugates; 2.3.7 Cyclodextrin-Saccharide Conjugates; 2.3.8 Metallocavitands Using Modified Cyclodextrins; References; 3 Polymers Involving Cyclodextrin Moieties; 3.1 Supramolecular Polymers Formed by Cyclodextrin Derivatives; 3.1.1 Introduction; 3.1.2 Preparation of Mono-substituted Cyclodextrins; 3.1.3 Formation of Inclusion Complexes [30, 31]; 3.1.4 Polymer Formation by Intermolecular Interactions; 3.1.5 Supramolecular Dimers 3.1.6 Formation of Supramolecular Trimers3.1.7 Cyclic Daisy Chain [31, 42]; 3.1.8 Supramolecular Polymers [45]; 3.1.9 Poly[2]rotaxanes (Daisy Chain); 3.1.10 Helical Supramolecular Polymers [45, 46]; 3.1.11 Alternating α-, β-Cyclodextrin Supramolecular Polymers [47]; 3.1.12 Supramolecular [2]rotaxane Polymer [43]; 3.1.13 Conclusion; 3.2 Supramolecular Complexes of Polymers Bearing Cyclodextrin Moieties with Guest Molecules; References; 4 Cyclodextrin Catalysis; 4.1 Introduction; 4.2 Covalent Catalysis; 4.3 General Acid-Base Catalysis by OH Groups; 4.4 Noncovalent Catalysis 4.4.1 Regulation of the Mutual Conformation of Reactants4.4.2 Regulation of Photoreactions; 4.4.3 Use of the CyD Cavity as a Specific Reaction Field; 4.5 Catalysis by Chemically Modified CyD; 4.6 Phase-transfer Catalysis; 4.7 Conclusion; References; 5 Chromatographic Studies of Molecular and Chiral Recognition; 5.1 Introduction; 5.2 Determination of the Stoichiometry and Stability of the Complexes; 5.3 Thermodynamics; References; 6 The Application of Cyclodextrins for Enantioseparations; 6.1 Introduction; 6.2 Gas Chromatography 6.3 High-performance Liquid Chromatography and Related Techniques |
| Record Nr. | UNINA-9910144321203321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cyclodextrins and their complexes [[electronic resource] ] : chemistry, analytical methods, applications / / edited by Helena Dodziuk
| Cyclodextrins and their complexes [[electronic resource] ] : chemistry, analytical methods, applications / / edited by Helena Dodziuk |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (509 p.) |
| Disciplina | 547.78 |
| Altri autori (Persone) | DodziukHelena |
| Soggetto topico |
Cyclodextrins
Chemistry, Technical |
| ISBN |
1-280-72348-3
9786610723485 3-527-60898-2 3-527-60844-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cyclodextrins and Their Complexes; Contents; Preface; List of Contributors; 1 Molecules with Holes - Cyclodextrins; 1.1 Introduction; 1.2 Cyclodextrin Properties; 1.3 Cyclodextrin Nonrigidity [94, 95]; 1.4 Models of Chiral Recognition by Cyclodextrins; References; 2 Modification Reactions of Cyclodextrins and the Chemistry of Modified Cyclodextrins; 2.1 Scope of This Chapter; 2.2 Modification Reactions of Cyclodextrins; 2.2.1 Modification Reactions at the Primary Side; 2.2.1.1 Mono-modification at the C6-Position; 2.2.1.2 Per-modification at the C6-Position
2.2.1.3 Multi-modification at the C6-Position2.2.2 Modification Reactions at the Secondary Side; 2.2.2.1 Mono-modification at the C2-Position; 2.2.2.2 Mono-modification at Any One of the C2-, C3-, or C6-Positions; 2.2.2.3 Per-modification at the C3-, C2-, or C6-Position; 2.2.3 Per-modification Reactions at All Three Positions; 2.2.4 Enzymatic Modification Reactions of Cyclodextrins; 2.2.5 Construction Reactions for Cyclodextrin Ring Formation; 2.3 Chemistry of Modified Cyclodextrins; 2.3.1 Cyclodextrin Dimers and Trimers; 2.3.2 Charged Cyclodextrins 2.3.3 Chemosensors Using Modified Cyclodextrins2.3.4 Cyclodextrin Analogues; 2.3.5 Cyclodextrins Conjugated with Other Kinds of Hosts; 2.3.6 Cyclodextrin-Peptide Conjugates; 2.3.7 Cyclodextrin-Saccharide Conjugates; 2.3.8 Metallocavitands Using Modified Cyclodextrins; References; 3 Polymers Involving Cyclodextrin Moieties; 3.1 Supramolecular Polymers Formed by Cyclodextrin Derivatives; 3.1.1 Introduction; 3.1.2 Preparation of Mono-substituted Cyclodextrins; 3.1.3 Formation of Inclusion Complexes [30, 31]; 3.1.4 Polymer Formation by Intermolecular Interactions; 3.1.5 Supramolecular Dimers 3.1.6 Formation of Supramolecular Trimers3.1.7 Cyclic Daisy Chain [31, 42]; 3.1.8 Supramolecular Polymers [45]; 3.1.9 Poly[2]rotaxanes (Daisy Chain); 3.1.10 Helical Supramolecular Polymers [45, 46]; 3.1.11 Alternating α-, β-Cyclodextrin Supramolecular Polymers [47]; 3.1.12 Supramolecular [2]rotaxane Polymer [43]; 3.1.13 Conclusion; 3.2 Supramolecular Complexes of Polymers Bearing Cyclodextrin Moieties with Guest Molecules; References; 4 Cyclodextrin Catalysis; 4.1 Introduction; 4.2 Covalent Catalysis; 4.3 General Acid-Base Catalysis by OH Groups; 4.4 Noncovalent Catalysis 4.4.1 Regulation of the Mutual Conformation of Reactants4.4.2 Regulation of Photoreactions; 4.4.3 Use of the CyD Cavity as a Specific Reaction Field; 4.5 Catalysis by Chemically Modified CyD; 4.6 Phase-transfer Catalysis; 4.7 Conclusion; References; 5 Chromatographic Studies of Molecular and Chiral Recognition; 5.1 Introduction; 5.2 Determination of the Stoichiometry and Stability of the Complexes; 5.3 Thermodynamics; References; 6 The Application of Cyclodextrins for Enantioseparations; 6.1 Introduction; 6.2 Gas Chromatography 6.3 High-performance Liquid Chromatography and Related Techniques |
| Record Nr. | UNINA-9910830826103321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cyclodextrins and their complexes [[electronic resource] ] : chemistry, analytical methods, applications / / edited by Helena Dodziuk
| Cyclodextrins and their complexes [[electronic resource] ] : chemistry, analytical methods, applications / / edited by Helena Dodziuk |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (509 p.) |
| Disciplina | 547.78 |
| Altri autori (Persone) | DodziukHelena |
| Soggetto topico |
Cyclodextrins
Chemistry, Technical |
| ISBN |
1-280-72348-3
9786610723485 3-527-60898-2 3-527-60844-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cyclodextrins and Their Complexes; Contents; Preface; List of Contributors; 1 Molecules with Holes - Cyclodextrins; 1.1 Introduction; 1.2 Cyclodextrin Properties; 1.3 Cyclodextrin Nonrigidity [94, 95]; 1.4 Models of Chiral Recognition by Cyclodextrins; References; 2 Modification Reactions of Cyclodextrins and the Chemistry of Modified Cyclodextrins; 2.1 Scope of This Chapter; 2.2 Modification Reactions of Cyclodextrins; 2.2.1 Modification Reactions at the Primary Side; 2.2.1.1 Mono-modification at the C6-Position; 2.2.1.2 Per-modification at the C6-Position
2.2.1.3 Multi-modification at the C6-Position2.2.2 Modification Reactions at the Secondary Side; 2.2.2.1 Mono-modification at the C2-Position; 2.2.2.2 Mono-modification at Any One of the C2-, C3-, or C6-Positions; 2.2.2.3 Per-modification at the C3-, C2-, or C6-Position; 2.2.3 Per-modification Reactions at All Three Positions; 2.2.4 Enzymatic Modification Reactions of Cyclodextrins; 2.2.5 Construction Reactions for Cyclodextrin Ring Formation; 2.3 Chemistry of Modified Cyclodextrins; 2.3.1 Cyclodextrin Dimers and Trimers; 2.3.2 Charged Cyclodextrins 2.3.3 Chemosensors Using Modified Cyclodextrins2.3.4 Cyclodextrin Analogues; 2.3.5 Cyclodextrins Conjugated with Other Kinds of Hosts; 2.3.6 Cyclodextrin-Peptide Conjugates; 2.3.7 Cyclodextrin-Saccharide Conjugates; 2.3.8 Metallocavitands Using Modified Cyclodextrins; References; 3 Polymers Involving Cyclodextrin Moieties; 3.1 Supramolecular Polymers Formed by Cyclodextrin Derivatives; 3.1.1 Introduction; 3.1.2 Preparation of Mono-substituted Cyclodextrins; 3.1.3 Formation of Inclusion Complexes [30, 31]; 3.1.4 Polymer Formation by Intermolecular Interactions; 3.1.5 Supramolecular Dimers 3.1.6 Formation of Supramolecular Trimers3.1.7 Cyclic Daisy Chain [31, 42]; 3.1.8 Supramolecular Polymers [45]; 3.1.9 Poly[2]rotaxanes (Daisy Chain); 3.1.10 Helical Supramolecular Polymers [45, 46]; 3.1.11 Alternating α-, β-Cyclodextrin Supramolecular Polymers [47]; 3.1.12 Supramolecular [2]rotaxane Polymer [43]; 3.1.13 Conclusion; 3.2 Supramolecular Complexes of Polymers Bearing Cyclodextrin Moieties with Guest Molecules; References; 4 Cyclodextrin Catalysis; 4.1 Introduction; 4.2 Covalent Catalysis; 4.3 General Acid-Base Catalysis by OH Groups; 4.4 Noncovalent Catalysis 4.4.1 Regulation of the Mutual Conformation of Reactants4.4.2 Regulation of Photoreactions; 4.4.3 Use of the CyD Cavity as a Specific Reaction Field; 4.5 Catalysis by Chemically Modified CyD; 4.6 Phase-transfer Catalysis; 4.7 Conclusion; References; 5 Chromatographic Studies of Molecular and Chiral Recognition; 5.1 Introduction; 5.2 Determination of the Stoichiometry and Stability of the Complexes; 5.3 Thermodynamics; References; 6 The Application of Cyclodextrins for Enantioseparations; 6.1 Introduction; 6.2 Gas Chromatography 6.3 High-performance Liquid Chromatography and Related Techniques |
| Record Nr. | UNINA-9910841312003321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Strained hydrocarbons [[electronic resource] ] : beyond the van't Hoff and Le Bel hypothesis / / edited by Helena Dodziuk
| Strained hydrocarbons [[electronic resource] ] : beyond the van't Hoff and Le Bel hypothesis / / edited by Helena Dodziuk |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (495 p.) |
| Disciplina |
547.01
547/.01 |
| Altri autori (Persone) | DodziukHelena |
| Soggetto topico |
Hydrocarbons
Chemistry, Organic |
| ISBN |
1-282-11847-1
9786612118470 3-527-62713-8 3-527-62714-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Strained Hydrocarbons; Foreword; Preface; Contents; List of Contributors; 1 Introduction; 1.1 Initial Remarks; 1.2 Hydrocarbons with Unusual Spatial Structure: the Need to Finance Basic Research; 1.3 Computations on Strained Hydrocarbons; 1.4 Gallery of Molecules That Could Have Been Included in This Book; 1.4.1 Introductory Remarks; 1.4.2 Saturated Hydrocarbons; 1.4.3 Distorted Double Bonds; 1.4.4 Benzene Rings with Nontypical Spatial Structures; 1.4.5 Cumulenes; 1.4.6 Acetylenes; References; 2 Distorted Saturated Hydrocarbons; 2.1 Molecules with Inverted Carbon Atoms; 2.1.1 Introduction
2.1.2 Small-ring Propellanes: Computational and Physicochemical Studies2.1.3 Small-ring Propellanes: Experimental Results; 2.1.3.1 Preparation and Reactivity of [1.1.1]Propellane; 2.1.3.2 Preparation and Reactivity of [2.1.1]Propellane and [2.2.1]Propellane; 2.1.3.3 [1.1.1]Propellane as the Precursor for the Synthesis of Other Unusual Molecules; 2.1.4 New Hypothetical Molecules with Inverted Carbon Atoms; 2.2 Molecules with Planar and Pyramidal Carbon Atoms; 2.3 A Theoretical Approach to the Study and Design of Prismane Systems; 2.3.1 Introduction; 2.3.2 Prismanes; 2.3.3 Expanded Prismanes 2.3.3.1 Asteranes2.3.3.2 Ethynyl-expanded Prismanes; 2.3.4 Dehydroprismanes; 2.3.5 Polyprismanes; 2.3.5.1 Cubane Oligomers; 2.3.5.2 Fused Prismanes; 2.3.6 Conclusions; 2.4 (CH)(2n) Cage Structures, 'in'-'out' Isomerism in Perhydrogenated Fullerenes and Planar Cyclohexane Rings; 2.4.1 (CH)(2n) Cage Structures; 2.4.1.1 Tetrahedrane; 2.4.1.2 Triprismane; 2.4.1.3 Cubane 61, Cuneane 100 and Octabisvalene 101 C(8)H(8); 2.4.1.4 C(10)H(10) Saturated Cages; 2.4.1.5 C(12)H(12) Saturated Cages; 2.4.1.6 Higher [n]Prismanes, Dodecahedrane 2.4.1.7 'In'-'out' Isomerism in Perhydrogenated Fullerenes C(60)H(60)2.4.1.8 Summary; 2.4.2 Planar Cyclohexane Rings; 2.5 Ultralong C-C Bonds; 2.5.1 Introduction; 2.5.2 Ultralong C-C Bonds Confined in a Stiff Molecular Frame; 2.5.3 Tetraphenylnaphthocyclobutene as a Scaffold to Produce Ultralong C-C Bonds; 2.5.4 'Clumped' Hexaphenylethane Derivatives with Elongated and Ultralong C-C Bonds; 2.5.5 HPE Derivatives with a Super-ultralong C-C Bond; 2.5.6 'Expandability' of the Ultralong C-C Bond: Conformational Isomorphs with Different Bond Lengths; 2.5.7 Future Outlook; 2.6 Ultrashort C-C Bonds 2.6.1 Introduction2.6.2 Tricyclo[2.1.0.0(2,5)]pentanes: Ultrashort Endocyclic Bridging C-C Bonds; 2.6.3 Coupled Cage Compounds: Ultrashort Exocyclic Intercage C-C Bonds; 2.6.4 Sterically Congested in-Methylcyclophanes: Ultrashort C-C(Me) Bonds; 2.6.5 Conclusions; References; 3 Distorted Alkenes; 3.1 Nonplanar Alkenes; 3.1.1 Introduction and Context; 3.1.2 Bridgehead Alkenes; 3.1.2.1 t-Butyl-substituted Ethylenes; 3.1.2.2 Investigations of t-Butylated Ethylenes and Other Acyclic Alkenes; 3.1.2.3 Cyclo and Bicycloalkenes ... and on to Polycyclic Analogs 3.1.2.4 Adamantylideneadamantane and its Derivatives |
| Record Nr. | UNINA-9910139791503321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Strained hydrocarbons [[electronic resource] ] : beyond the van't Hoff and Le Bel hypothesis / / edited by Helena Dodziuk
| Strained hydrocarbons [[electronic resource] ] : beyond the van't Hoff and Le Bel hypothesis / / edited by Helena Dodziuk |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (495 p.) |
| Disciplina |
547.01
547/.01 |
| Altri autori (Persone) | DodziukHelena |
| Soggetto topico |
Hydrocarbons
Chemistry, Organic |
| ISBN |
1-282-11847-1
9786612118470 3-527-62713-8 3-527-62714-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Strained Hydrocarbons; Foreword; Preface; Contents; List of Contributors; 1 Introduction; 1.1 Initial Remarks; 1.2 Hydrocarbons with Unusual Spatial Structure: the Need to Finance Basic Research; 1.3 Computations on Strained Hydrocarbons; 1.4 Gallery of Molecules That Could Have Been Included in This Book; 1.4.1 Introductory Remarks; 1.4.2 Saturated Hydrocarbons; 1.4.3 Distorted Double Bonds; 1.4.4 Benzene Rings with Nontypical Spatial Structures; 1.4.5 Cumulenes; 1.4.6 Acetylenes; References; 2 Distorted Saturated Hydrocarbons; 2.1 Molecules with Inverted Carbon Atoms; 2.1.1 Introduction
2.1.2 Small-ring Propellanes: Computational and Physicochemical Studies2.1.3 Small-ring Propellanes: Experimental Results; 2.1.3.1 Preparation and Reactivity of [1.1.1]Propellane; 2.1.3.2 Preparation and Reactivity of [2.1.1]Propellane and [2.2.1]Propellane; 2.1.3.3 [1.1.1]Propellane as the Precursor for the Synthesis of Other Unusual Molecules; 2.1.4 New Hypothetical Molecules with Inverted Carbon Atoms; 2.2 Molecules with Planar and Pyramidal Carbon Atoms; 2.3 A Theoretical Approach to the Study and Design of Prismane Systems; 2.3.1 Introduction; 2.3.2 Prismanes; 2.3.3 Expanded Prismanes 2.3.3.1 Asteranes2.3.3.2 Ethynyl-expanded Prismanes; 2.3.4 Dehydroprismanes; 2.3.5 Polyprismanes; 2.3.5.1 Cubane Oligomers; 2.3.5.2 Fused Prismanes; 2.3.6 Conclusions; 2.4 (CH)(2n) Cage Structures, 'in'-'out' Isomerism in Perhydrogenated Fullerenes and Planar Cyclohexane Rings; 2.4.1 (CH)(2n) Cage Structures; 2.4.1.1 Tetrahedrane; 2.4.1.2 Triprismane; 2.4.1.3 Cubane 61, Cuneane 100 and Octabisvalene 101 C(8)H(8); 2.4.1.4 C(10)H(10) Saturated Cages; 2.4.1.5 C(12)H(12) Saturated Cages; 2.4.1.6 Higher [n]Prismanes, Dodecahedrane 2.4.1.7 'In'-'out' Isomerism in Perhydrogenated Fullerenes C(60)H(60)2.4.1.8 Summary; 2.4.2 Planar Cyclohexane Rings; 2.5 Ultralong C-C Bonds; 2.5.1 Introduction; 2.5.2 Ultralong C-C Bonds Confined in a Stiff Molecular Frame; 2.5.3 Tetraphenylnaphthocyclobutene as a Scaffold to Produce Ultralong C-C Bonds; 2.5.4 'Clumped' Hexaphenylethane Derivatives with Elongated and Ultralong C-C Bonds; 2.5.5 HPE Derivatives with a Super-ultralong C-C Bond; 2.5.6 'Expandability' of the Ultralong C-C Bond: Conformational Isomorphs with Different Bond Lengths; 2.5.7 Future Outlook; 2.6 Ultrashort C-C Bonds 2.6.1 Introduction2.6.2 Tricyclo[2.1.0.0(2,5)]pentanes: Ultrashort Endocyclic Bridging C-C Bonds; 2.6.3 Coupled Cage Compounds: Ultrashort Exocyclic Intercage C-C Bonds; 2.6.4 Sterically Congested in-Methylcyclophanes: Ultrashort C-C(Me) Bonds; 2.6.5 Conclusions; References; 3 Distorted Alkenes; 3.1 Nonplanar Alkenes; 3.1.1 Introduction and Context; 3.1.2 Bridgehead Alkenes; 3.1.2.1 t-Butyl-substituted Ethylenes; 3.1.2.2 Investigations of t-Butylated Ethylenes and Other Acyclic Alkenes; 3.1.2.3 Cyclo and Bicycloalkenes ... and on to Polycyclic Analogs 3.1.2.4 Adamantylideneadamantane and its Derivatives |
| Record Nr. | UNINA-9910830959503321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Strained hydrocarbons [[electronic resource] ] : beyond the van't Hoff and Le Bel hypothesis / / edited by Helena Dodziuk
| Strained hydrocarbons [[electronic resource] ] : beyond the van't Hoff and Le Bel hypothesis / / edited by Helena Dodziuk |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (495 p.) |
| Disciplina |
547.01
547/.01 |
| Altri autori (Persone) | DodziukHelena |
| Soggetto topico |
Hydrocarbons
Chemistry, Organic |
| ISBN |
1-282-11847-1
9786612118470 3-527-62713-8 3-527-62714-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Strained Hydrocarbons; Foreword; Preface; Contents; List of Contributors; 1 Introduction; 1.1 Initial Remarks; 1.2 Hydrocarbons with Unusual Spatial Structure: the Need to Finance Basic Research; 1.3 Computations on Strained Hydrocarbons; 1.4 Gallery of Molecules That Could Have Been Included in This Book; 1.4.1 Introductory Remarks; 1.4.2 Saturated Hydrocarbons; 1.4.3 Distorted Double Bonds; 1.4.4 Benzene Rings with Nontypical Spatial Structures; 1.4.5 Cumulenes; 1.4.6 Acetylenes; References; 2 Distorted Saturated Hydrocarbons; 2.1 Molecules with Inverted Carbon Atoms; 2.1.1 Introduction
2.1.2 Small-ring Propellanes: Computational and Physicochemical Studies2.1.3 Small-ring Propellanes: Experimental Results; 2.1.3.1 Preparation and Reactivity of [1.1.1]Propellane; 2.1.3.2 Preparation and Reactivity of [2.1.1]Propellane and [2.2.1]Propellane; 2.1.3.3 [1.1.1]Propellane as the Precursor for the Synthesis of Other Unusual Molecules; 2.1.4 New Hypothetical Molecules with Inverted Carbon Atoms; 2.2 Molecules with Planar and Pyramidal Carbon Atoms; 2.3 A Theoretical Approach to the Study and Design of Prismane Systems; 2.3.1 Introduction; 2.3.2 Prismanes; 2.3.3 Expanded Prismanes 2.3.3.1 Asteranes2.3.3.2 Ethynyl-expanded Prismanes; 2.3.4 Dehydroprismanes; 2.3.5 Polyprismanes; 2.3.5.1 Cubane Oligomers; 2.3.5.2 Fused Prismanes; 2.3.6 Conclusions; 2.4 (CH)(2n) Cage Structures, 'in'-'out' Isomerism in Perhydrogenated Fullerenes and Planar Cyclohexane Rings; 2.4.1 (CH)(2n) Cage Structures; 2.4.1.1 Tetrahedrane; 2.4.1.2 Triprismane; 2.4.1.3 Cubane 61, Cuneane 100 and Octabisvalene 101 C(8)H(8); 2.4.1.4 C(10)H(10) Saturated Cages; 2.4.1.5 C(12)H(12) Saturated Cages; 2.4.1.6 Higher [n]Prismanes, Dodecahedrane 2.4.1.7 'In'-'out' Isomerism in Perhydrogenated Fullerenes C(60)H(60)2.4.1.8 Summary; 2.4.2 Planar Cyclohexane Rings; 2.5 Ultralong C-C Bonds; 2.5.1 Introduction; 2.5.2 Ultralong C-C Bonds Confined in a Stiff Molecular Frame; 2.5.3 Tetraphenylnaphthocyclobutene as a Scaffold to Produce Ultralong C-C Bonds; 2.5.4 'Clumped' Hexaphenylethane Derivatives with Elongated and Ultralong C-C Bonds; 2.5.5 HPE Derivatives with a Super-ultralong C-C Bond; 2.5.6 'Expandability' of the Ultralong C-C Bond: Conformational Isomorphs with Different Bond Lengths; 2.5.7 Future Outlook; 2.6 Ultrashort C-C Bonds 2.6.1 Introduction2.6.2 Tricyclo[2.1.0.0(2,5)]pentanes: Ultrashort Endocyclic Bridging C-C Bonds; 2.6.3 Coupled Cage Compounds: Ultrashort Exocyclic Intercage C-C Bonds; 2.6.4 Sterically Congested in-Methylcyclophanes: Ultrashort C-C(Me) Bonds; 2.6.5 Conclusions; References; 3 Distorted Alkenes; 3.1 Nonplanar Alkenes; 3.1.1 Introduction and Context; 3.1.2 Bridgehead Alkenes; 3.1.2.1 t-Butyl-substituted Ethylenes; 3.1.2.2 Investigations of t-Butylated Ethylenes and Other Acyclic Alkenes; 3.1.2.3 Cyclo and Bicycloalkenes ... and on to Polycyclic Analogs 3.1.2.4 Adamantylideneadamantane and its Derivatives |
| Record Nr. | UNINA-9910841400403321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||