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Electric field enhanced membrane separation system [[electronic resource] ] : principles and typical applications / / Sirshendu De, Biswajit Sarkar and Sunando DasGupta
Electric field enhanced membrane separation system [[electronic resource] ] : principles and typical applications / / Sirshendu De, Biswajit Sarkar and Sunando DasGupta
Autore De Sirshendu
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (214 p.)
Disciplina 660/.28424
Altri autori (Persone) SarkarBiswajit
DasGuptaSunando
Soggetto topico Membrane separation
Electric fields
Soggetto genere / forma Electronic books.
ISBN 1-61728-389-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910460016503321
De Sirshendu  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Electric field enhanced membrane separation system [[electronic resource] ] : principles and typical applications / / Sirshendu De, Biswajit Sarkar and Sunando DasGupta
Electric field enhanced membrane separation system [[electronic resource] ] : principles and typical applications / / Sirshendu De, Biswajit Sarkar and Sunando DasGupta
Autore De Sirshendu
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (214 p.)
Disciplina 660/.28424
Altri autori (Persone) SarkarBiswajit
DasGuptaSunando
Soggetto topico Membrane separation
Electric fields
ISBN 1-61728-389-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910785182303321
De Sirshendu  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Electric field enhanced membrane separation system [[electronic resource] ] : principles and typical applications / / Sirshendu De, Biswajit Sarkar and Sunando DasGupta
Electric field enhanced membrane separation system [[electronic resource] ] : principles and typical applications / / Sirshendu De, Biswajit Sarkar and Sunando DasGupta
Autore De Sirshendu
Edizione [1st ed.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (214 p.)
Disciplina 660/.28424
Altri autori (Persone) SarkarBiswajit
DasGuptaSunando
Soggetto topico Membrane separation
Electric fields
ISBN 1-61728-389-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Intro -- ELECTRIC FIELD ENHANCED MEMBRANE SEPARATION SYSTEM: PRINCIPLES AND TYPICAL APPLICATIONS -- ELECTRIC FIELD ENHANCED MEMBRANE SEPARATION SYSTEM: PRINCIPLES AND TYPICAL APPLICATIONS -- CONTENTS -- PREFACE -- Chapter 1 INTRODUCTION -- 1.1. APPLICATION OF MEMBRANE SEPARATION PROCESSES -- 1.1.1. Electro-painting -- 1.1.2. Water Purification -- 1.1.3. Textile Industry -- 1.1.4. Dairy Industry -- 1.1.5. Soy Protein Extraction -- 1.1.6. Fruit Juice Clarification -- 1.1.7. Biotechnological Application -- 1.1.8. Pulp and Paper Industry -- 1.1.9. Sugar Processing Industry -- 1.1.10. Tanning and Leather Industry -- 1.2. ADVANTAGE OF MEMBRANE SEPARATION PROCESSES -- 1.3. LIMITATIONS OF MEMBRANE SEPARATION PROCESSES -- 1.3.1. Concentration Polarization -- 1.3.2. Irreversible Membrane Fouling -- 1.4. APPROACHES TO IMPROVE MEMBRANE PERFORMANCE -- 1.4.1. Surface Modification -- 1.4.1.1. Chemical Treatment and Physical Coating -- 1.4.1.2. Plasma Treatment -- 1.4.1.3. Ion Beam Irradiation -- 1.4.1.4. Grafting Polymers -- 1.4.2. Change of Hydrodynamic Conditions -- 1.4.2.1. Turbulent Flow -- 1.4.2.2. Unsteady Flows and Induction of Instabilities -- 1.4.2.2.1. Turbulence Promoter -- 1.4.2.2.2. Gas Sparging -- 1.4.2.3. Secondary Flow -- 1.4.2.4. Pulsatile Flow -- 1.4.3. Change of Physico-chemical Environment of the Solution -- 1.4.4. External Field -- REFERENCES -- Chapter 2 CLARIFICATION OF CITRUS FRUIT JUICE -- ABSTRACT -- NOMENCLATURE -- Greek Letters -- 2.1. IMPORTANCE AND TECHNIQUES OF CLARIFICATION OF FRUIT JUICE -- 2.2. APPLICATION OF EXTERNAL FIELD -- 2.2.1. Application of Electric Field during Fruit Juice Clarification -- 2.3. MEMBRANE EXPERIMENT -- 2.3.1. Cross-flow Electro-ultrafiltration Cell -- 2.3.2. Procedure for Conducting Experiments -- 2.3.2.1. Materials -- 2.3.2.2. Operating Conditions -- 2.3.2.3. Preparation of Feed.
2.3.2.4. Conduction of Experiments -- 2.3.2.5. Analysis of the Feed and Permeate -- Variation of Zeta Potential of Synthetic Juice (A Mixture of Pectin and Sucrose) with pH -- 2.3.2.6. Optical Studies -- 2.4. PREDICTION OF THE PERMEATE FLUX AND DEPOSITION THICKNESS -- 2.4.1. Analysis of Transient Flux -- 2.4.1.1. Theoretical Aspects -- 2.4.1.2. Analysis of Transient Flux Decline of Synthetic Juice -- Effect of Constant Electric Field -- Optical Quantification of Gel Layer Thickness -- Effect of Pulsed Electric Field -- 2.4.1.3. Mosambi (Citrus Sinensis (L.) Osbeck) Juice -- Effect of Constant Electric Field -- Effect of Pulsed Electric Field -- 2.4.2. Analysis of Steady State Flux -- 2.4.2.1. Theoretical Aspect -- 2.4.2.2 Analysis of Steady State Flux of Synthetic Juice -- Effect of Constant Electric Field -- Effect of Transmembrane Pressure -- Effect of Cross Flow Velocity -- Variation of Permeate Flux with Axial Position -- Effect of Pulsed Electric Field -- Effect of Pulse Ratio -- Effect of Cross Flow Velocity -- Estimation of Electric Power Consumption per Unit Volume of Permeate -- 2.4.2.3. Analysis of Steady State Flux of Mosambi (Citrus Sinensis (L.) Osbeck) Juice -- Theoretical Aspect -- Effect of Constant Electric Field on Permeate Flux -- Effect of Cross Flow Velocity on Permeate Flux -- Effect of Pulsed Electric Field -- Effect of Pulse Ratio -- Effect of Cross Flow Velocity -- Characterization of Clarified Mosambi Juice -- Power Consumption and pH Variation -- 2.5. CONCLUSION -- REFERENCES -- Chapter 3 SEPARATION AND FRACTIONATION OF PROTEIN SOLUTION -- ABSTRACT -- NOMENCLATURE -- Greek Letters -- Subscript -- Superscript -- 3.1. ELECTRIC FIELD ASSISTED ULTRAFILTRATION OF PROTEIN FROM AQUEOUS SOLUTION -- 3.1.1. Mass Transfer Analysis during Electric Field Assisted Ultrafiltration -- Estimation of Mass Transfer Coefficient.
Prediction of cm1 and vw -- Algorithm Used for Estimation of cm and vw -- 3.1.2. Importance of Membrane Surface Charge -- Electro-kinetic Theory -- Calculation of Zeta Potential and Surface Charge Density of Membrane -- 3.1.3. Detailed Experiment -- 3.1.3.1. Ultrafiltration of BSA from Aqueous Solution -- Membrane and Materials -- Electro-ultrafiltration Cell and Operating Conditions -- Steps Used during Experiment -- Preparation of Feed Solution -- Conduction of Experiments -- Analysis of the Feed and Permeate -- 3.1.3.2. Evaluation of Membrane Surface Charge -- Membrane -- Preparation of Feed Solution -- Streaming Potential Measurement -- Zeta Potential and Surface Charge Density of Membrane -- 3.1.4. Osmotic Pressure of Protein Solution -- 3.1.4.1. Effect of pH and Solute Concentration on Osmotic Pressure of BSA -- 3.1.4.2. Effect of pH and Solute Concentration on Osmotic Pressure of Lysozyme -- 3.1.5. Quantification of Permeate Flux and Membrane Surface Concentration -- 3.1.5.1. Effect of Electric Field on Concentration Boundary Layer Thickness -- 3.1.5.2. Effect of Electric Field on the Variation of Membrane Surface Concentration and Permeate Flux along the Length of the Channel -- 3.1.5.3. Effect of Electric Field on the Membrane Surface Concentration and Permeate Flux -- 3.1.5.4. Effect of Pressure on the Permeate Flux -- 3.1.5.5. Effect of Cross Flow Velocity on Permeate Flux -- 3.1.5.6. Variation of Mass Transfer Coefficient -- 3.1.5.7. Effect of Solution pH during Ultrafiltration of BSA from Aqueous Solution -- 3.2. ELECTRIC FIELD ENHANCED FRACTIONATION OF BSA AND LYSOZYME -- 3.2.1. Theoretical Aspects -- Algorithm for Numerical Calculation -- 3.2.2. Detailed Experiment -- 3.2.2.1. Membrane and Materials -- 3.2.2.2. Electro-ultrafiltration Cell -- 3.2.2.3. Experimental Design -- 3.2.2.4. Procedure -- Conduction of Experiments.
Analysis of the Feed and Permeate -- 3.2.3. Quantification of Permeate Flux and Solute Retention -- 3.2.3.1. Effect of Pressure on Permeate Flux and Observed Retention during Ultrafiltration of Single Protein Solution -- 3.2.3.2. Effect of Solution pH -- 3.2.3.3. Effect of Electric Field on Observed Retention and Permeate Flux -- 3.2.3.4. Effect of Cross Flow Velocity on Permeate Flux and Observed Retention -- 3.2.3.5. Effect of Pressure on Permeate Flux and Observed Retention -- 3.2.3.6. Effect of Electric Field on Membrane Surface Concentration -- 3.3. CONCLUSIONS -- APPENDIX 1 -- Calculation of Osmotic Pressure -- Electrostatic Interaction -- London-van der Waals Interaction -- Entropic Pressure -- REFERENCES -- Chapter 4 ELECTRIC FIELD ASSISTED MICELLAR ENHANCED ULTRAFILTRATION -- ABSTRACT -- NOMENCLETURE -- Greek Letters -- 4.1. INTRODUCTION -- Dye Removal: A Case Study -- 4.2. PRINCIPLE OF ELECTRIC FIELD ASSISTED MEUF -- 4.3. LIMITING FLUX PHENOMENA -- 4.3.1. Calculation of Limiting Pressure and Limiting Flux -- 4.4. MEMBRANE EXPERIMENTS -- 4.4.1. Chemicals -- 4.4.2. Membrane -- 4.4.3. Cross Flow Cell and Operating Conditions -- 4.4.4. The Steps Used in Experiment -- 4.4.5. Analysis of Feed and Permeate -- 4.4.5.1. Concentration of SDS and Methylene Blue -- 4.4.5.2. Measurement of Viscosity, Conductivity and pH -- 4.4.6. Determination of Particle Size -- 4.4.7. Determination of Gel Porosity -- 4.5. ANALYSIS OF PERMEATE FLUX, GEL-LAYER THICKNESS AND SOLUTE RETENTION -- 4.5.1. Electric Field Assisted MEUF of Pure Surfactant Solution -- 4.5.1.1. Variation of Gel Layer Thickness with Pressure -- 4.5.1.2. Effect of Pressure on Permeate Flux -- In Absence of Electric Field -- In Presence of Electric Field -- 4.5.1.3. Effect of Pressure on Gel Layer Thickness -- 4.5.1.4. Effect of Electric Field on Permeate Flux.
4.5.1.5. Effect of Electric Field on Gel Layer Thickness -- 4.5.2. Electric Field Assisted MEUF of SDS Solution Containing of Methylene Blue Dye -- 4.5.2.1. Effect of Surfactant to Dye Concentration Ratio -- 4.5.2.2. Effect of Electric Field -- 4.5.2.3. Effect of Cross Flow Velocity -- 4.5.2.4. Effect of Pressure -- 4.6. CONCLUSION -- REFERENCES -- INDEX -- Blank Page.
Record Nr. UNINA-9910828739803321
De Sirshendu  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Treatment of tannery effluents by membrane separation technology [[electronic resource] /] / Sirshendu De, Chandan Das and Sunando DasGupta
Treatment of tannery effluents by membrane separation technology [[electronic resource] /] / Sirshendu De, Chandan Das and Sunando DasGupta
Autore De Sirshendu
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (166 p.)
Disciplina 675/.230286
Altri autori (Persone) DasChandan
DasGuptaSunando
Collana Chemical engineering methods and technology series
Soggetto topico Tanneries - Waste disposal
Sewage - Purification
Membrane separation
Water - Purification - Membrane filtration
Soggetto genere / forma Electronic books.
ISBN 1-61728-596-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910458213703321
De Sirshendu  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Treatment of tannery effluents by membrane separation technology [[electronic resource] /] / Sirshendu De, Chandan Das and Sunando DasGupta
Treatment of tannery effluents by membrane separation technology [[electronic resource] /] / Sirshendu De, Chandan Das and Sunando DasGupta
Autore De Sirshendu
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (166 p.)
Disciplina 675/.230286
Altri autori (Persone) DasChandan
DasGuptaSunando
Collana Chemical engineering methods and technology series
Soggetto topico Tanneries - Waste disposal
Sewage - Purification
Membrane separation
Water - Purification - Membrane filtration
ISBN 1-61728-596-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910791479903321
De Sirshendu  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Treatment of tannery effluents by membrane separation technology [[electronic resource] /] / Sirshendu De, Chandan Das and Sunando DasGupta
Treatment of tannery effluents by membrane separation technology [[electronic resource] /] / Sirshendu De, Chandan Das and Sunando DasGupta
Autore De Sirshendu
Edizione [1st ed.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (166 p.)
Disciplina 675/.230286
Altri autori (Persone) DasChandan
DasGuptaSunando
Collana Chemical engineering methods and technology series
Soggetto topico Tanneries - Waste disposal
Sewage - Purification
Membrane separation
Water - Purification - Membrane filtration
ISBN 1-61728-596-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Intro -- TREATMENT OF TANNERY EFFLUENTSBY MEMBRANE SEPARATIONTECHNOLOGY -- CONTENTS -- PREFACE -- INTRODUCTION -- TANNERY AS SOURCE OF POLLUTING EFFLUENT -- REFERENCES -- TREATMENT METHODS -- CONVENTIONAL METHODS OF TREATMENT PROCESS -- LIMITATIONS OF CONVENTIONAL PROCESSES -- MEMBRANE BASED PROCESSES -- REFERENCES -- TREATMENT OF SOAKING EFFLUENT -- ABSTRACT -- 3.1. SOAKING EFFLUENT -- 3.2. PRETREATMENT -- 3.3. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 3.3.1. Membranes -- 3.3.2. Membrane Experiments -- Stirred Cell and Operating Conditions -- 3.3.3. Performance Testing of Various Membranes -- 3.4. DETAILED STUDY OF TREATMENT OF SOAKING EFFLUENT -- 3.4.1. Cross Flow Cell and Operating Conditions -- 3.4.2. Analysis of Transient Flux Decline -- Nanofiltration -- Reverse Osmosis -- 3.4.3. Analysis of Steady State Flux -- Nanofiltration -- Reverse Osmosis -- 3.4.4. Analysis of Various Resistances -- 3.4.5. Enhancement of Steady State Permeate Flux -- Nanofiltration -- Reverse Osmosis -- 3.4.6. Permeate Quality Analysis -- Nanofiltration -- Reverse Osmosis -- 3.4.7. Sludge Characterization -- CONCLUSION -- REFERENCES -- TREATMENT OF LIMING EFFLUENT -- ABSTRACT -- 4.1. EFFLUENT CONTENT -- 4.2. PRETREATMENT -- 4.3. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 4.3.1. Membranes -- 4.3.2. Membrane Experiments -- 4.3.3. Performance Testing of Various Membranes -- 4.4. DETAILED STUDY OF TREATMENT OF LIMING EFFLUENT -- 4.4.1. Cross Flow Cell and Operating Conditions -- 4.4.2. Analysis of Transient Flux Decline -- Ultrafiltration -- Nanofiltration -- 4.4.3. Analysis of Steady State Flux -- Ultrafiltration -- Nanofiltration -- 4.4.4. Analysis of Various Resistances -- 4.4.5. Enhancement of Steady State Permeate Flux -- Ultrafiltration -- Nanofiltration -- 4.4.6. Permeate Quality Analysis -- Ultrafiltration -- Nanofiltration.
4.4.7. Sludge Characterization -- CONCLUSION -- REFERENCES -- TREATMENT OF DELIMING-BATING EFFLUENT -- ABSTRACT -- 5.1. EFFLUENT CONTENT -- 5.2. PRETREATMENT -- 5.3. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 5.3.1. Membranes -- 5.3.2. Membrane Experiments -- 5.3.3. Performance Testing of Various Membranes -- 5.4. DETAILED STUDY OF TREATMENT OF DELIMING-BATINGEFFLUENT -- 5.4.1. Cross Flow Cell and Operating Conditions -- 5.4.2. Analysis of Transient Flux Decline -- Ultrafiltration -- Nanofiltration -- 5.4.3. Analysis of Steady State Flux -- Ultrafiltration -- Nanofiltration -- 5.4.4. Analysis of Various Resistances -- 5.4.5. Enhancement of Steady State Permeate Flux -- Ultrafiltration -- Nanofiltration -- 5.4.6. Permeate Quality Analysis -- Ultrafiltration -- Nanofiltration -- 5.4.7. Sludge Characterization -- CONCLUSION -- REFERENCES -- TREATMENT OF PICKLING EFFLUENT -- ABSTRACT -- 6.1. EFFLUENT CONTENT -- 6.2. PRETREATMENT -- 6.3. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 6.3.1. Membranes -- 6.3.2. Membrane Experiments -- Stirred Cell and Operating Conditions -- 6.3.3. Performance Testing of Various Membranes -- 6.4. DETAILED STUDY OF TREATMENT OF PICKLING EFFLUENT -- 6.4.1. Cross Flow Cell and Operating Conditions -- 6.4.2. Analysis of Transient Flux Decline -- 6.4.3 Analysis of Steady State Flux -- 6.4.4. Analysis of Various Resistances -- 6.4.5. Permeate Quality Analysis -- 6.4.6. Sludge Characterization -- CONCLUSION -- REFERENCES -- TREATMENT OF DEGREASING EFFLUENT -- ABSTRACT -- 7.1. EFFLUENT CONTENT -- 7.2. PRETREATMENT -- 7.3. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 7.3.1. Membranes -- 7.3.2. Membrane Experiments -- 7.3.3. Performance Testing of Various Membranes -- 7.4. DETAILED STUDY OF TREATMENT OF DEGREASING EFFLUENT -- 7.4.1. Cross Flow Cell and Operating Conditions -- 7.4.2. Analysis of Transient Flux Decline.
7.4.3. Analysis of Steady State Flux -- 7.4.4. Analysis of Various Resistances -- 7.4.5. Enhancement of Steady State Permeate Flux -- 7.4.6. Permeate Quality Analysis -- 7.4.7. Sludge Characterization -- CONCLUSION -- REFERENCES -- TREATMENT OF TANNING EFFLUENT -- ABSTRACT -- 8.1. TANNING EFFLUENT -- 8.2. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 8.2.1. Membranes -- 8.2.2. Membrane Experiments -- 8.2.3. Performance Testing of Various Membranes -- 8.3. DETAILED STUDY OF TREATMENT OF TANNING EFFLUENT -- 8.3.1. Cross Flow Cell and Operating Conditions -- 8.3.2. Analysis of Transient Flux Decline -- Nanofiltration -- Reverse Osmosis -- 8.3.3. Analysis of Steady State Flux -- Nanofiltration -- Reverse Osmosis -- 8.3.4. Analysis of Various Resistances -- 8.3.5. Enhancement of Steady State Permeate Flux -- Nanofiltration -- 8.3.6. Permeate Quality Analysis -- Nanofiltration -- Reverse Osmosis -- CONCLUSION -- REFERENCES -- TREATMENT OF DYEING EFFLUENT -- ABSTRACT -- 9.1. DYEING EFFLUENT -- 9.2. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 9.2.1. Membranes -- 9.2.2. Membrane Experiments -- Stirred Cell and Operating Conditions -- 9.2.3. Performance Testing of Various Membranes -- 9.3. DETAILED STUDY OF TREATMENT OF DYEING EFFLUENT -- 9.3.1. Cross Flow Cell and Operating Conditions -- 9.3.2. Optical Studies and Image Analysis -- 9.3.3. Analysis of Transient Flux Decline -- Nanofiltration -- Reverse Osmosis -- 9.3.4. Analysis of Steady State Permeate Flux -- Nanofiltration -- Reverse Osmosis -- 9.3.5. Analysis of Various Resistance -- Nanofiltration -- Reverse Osmosis -- 9.3.6. Microscopy Based Quantification of Fouling -- Nanofiltration -- Reverse Osmosis -- 9.3.7. Enhancement of Steady State Permeate Flux -- Nanofiltration -- Reverse Osmosis -- 9.3.8. Permeate Quality Analysis -- Nanofiltration -- Reverse Osmosis -- CONCLUSION -- REFERENCES.
TREATMENT OF FATLIQUORING EFFLUENT -- ABSTRACT -- 10.1. EFFLUENT CONTENT -- 10.2. PRETREATMENT -- 10.3. SELECTION OF MEMBRANE SEPARATION PROCESSES -- 10.3.1. Membranes -- 10.3.2. Membrane Experiments -- Stirred Cell and Operating Conditions -- 10.3.3. Performance Testing of Various Membranes -- 10.4. DETAILED STUDY OF TREATMENT OF FATLIQUORINGEFFLUENT -- 10.4.1. Cross Flow Cell and Operating Conditions -- 10.4.2. Analysis of Transient Flux Decline -- Nanofiltration -- Reverse Osmosis -- 10.4.3. Analysis of Steady State Flux -- Nanofiltration -- Reverse Osmosis -- 10.4.3. Analysis of Various Resistances -- 10.4.4. Enhancement of Steady State Permeate Flux -- Nanofiltration -- Reverse Osmosis -- 10.4.5. Permeate Quality Analysis -- 10.4.6. Sludge Characterization -- CONCLUSION -- REFERENCES -- INDEX.
Record Nr. UNINA-9910807215203321
De Sirshendu  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui