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The organometallic chemistry of the transition metals / / Robert H. Crabtree
| The organometallic chemistry of the transition metals / / Robert H. Crabtree |
| Autore | Crabtree Robert H. <1948-> |
| Edizione | [6th edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2014 |
| Descrizione fisica | 1 online resource (522 p.) |
| Disciplina | 547/.056 |
| Soggetto topico |
Organometallic chemistry
Organotransition metal compounds Compostos organometàl·lics de transició |
| Soggetto genere / forma | Llibres electrònics |
| ISBN |
1-118-78824-9
1-118-78830-3 1-118-78844-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back Bonding
Frontier Orbitalsπ-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive Species Kinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; η1 and η2-Acyl and Vinyls; 3.2 Other σ-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal Carbonyls Preparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical Substitution Carbonyls |
| Record Nr. | UNINA-9910790935003321 |
Crabtree Robert H. <1948->
|
||
| Hoboken, New Jersey : , : Wiley, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The organometallic chemistry of the transition metals / / Robert H. Crabtree
| The organometallic chemistry of the transition metals / / Robert H. Crabtree |
| Autore | Crabtree Robert H. <1948-> |
| Edizione | [6th edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2014 |
| Descrizione fisica | 1 online resource (522 p.) |
| Disciplina | 547/.056 |
| Soggetto topico |
Organometallic chemistry
Organotransition metal compounds Compostos organometàl·lics de transició |
| Soggetto genere / forma | Llibres electrònics |
| ISBN |
1-118-78824-9
1-118-78830-3 1-118-78844-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back Bonding
Frontier Orbitalsπ-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive Species Kinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; η1 and η2-Acyl and Vinyls; 3.2 Other σ-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal Carbonyls Preparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical Substitution Carbonyls |
| Record Nr. | UNINA-9910809662703321 |
|
Crabtree Robert H. <1948->
|
||
| Hoboken, New Jersey : , : Wiley, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||