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Iridium catalysts for organic reactions / / Luis A. Oro, Carmen Claver, editors ; with contributions by I. Cano [and nineteen others]
| Iridium catalysts for organic reactions / / Luis A. Oro, Carmen Claver, editors ; with contributions by I. Cano [and nineteen others] |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2021] |
| Descrizione fisica | 1 online resource (viii, 456 pages) : illustrations |
| Disciplina | 547.2 |
| Collana | Topics in organometallic chemistry |
| Soggetto topico |
Organic compounds - Synthesis
Iridium catalysts Asymmetric synthesis |
| ISBN | 3-030-69083-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Preface -- Contents -- Iridium-Catalyzed Dehydrogenative Reactions -- 1 Introduction -- 2 Dehydrogenation of Alkanes -- 3 Dehydrogenation of Heterocyclic Compounds -- 3.1 Dehydrogenation of N-Heterocyclic Compounds -- 3.2 Dehydrogenation of Other Heterocyclic Compounds -- 3.3 N-Heteroarene Synthesis via Combination of Ring Construction-Dehydrogenation -- 4 Dehydrogenation of Alcohols -- 4.1 Dehydrogenative Oxidation of Alcohols to Aldehydes and Ketones -- 4.2 Dehydrogenative Oxidation of Primary Alcohols to Esters, Carboxylic Acids, and Acetals -- 4.3 Dehydrogenative Decarbonylation of Primary Alcohols -- 4.4 Dehydrogenative Cross-Coupling Reactions Involving Alcohols -- 4.5 Synthesis of N-Heterocycles Based on Alcohol Dehydrogenation -- 4.6 Other Reactions Based on Alcohol Dehydrogenation -- 5 Dehydrogenation of Formic Acid -- 6 Dehydrogenative Borylation -- 6.1 Aryl and Alkyl Group Borylation -- 6.2 Terminal Alkyne Borylation -- 7 Miscellaneous -- 8 Summary -- References -- Recent Advances in Iridium-Catalysed Transfer Hydrogenation Reactions -- 1 Introduction -- 2 Half-Sandwich Iridium Complexes -- 2.1 Transfer Hydrogenation of C=O, C=N and C=C Bonds -- 2.2 Transfer Hydrogenation of CO2 -- 2.3 Transfer Hydrogenation in Water -- 2.4 Biological Transfer Hydrogenation -- 3 Carbene Iridium Complexes -- 4 Pincer Iridium Complexes -- 5 Other Iridium Complexes -- 6 Transfer Hydrogenation of α,β-Unsaturated (and Non-conjugated) Alkene-Carbonyl Substrates -- 6.1 Transfer Hydrogenation of α,β-Unsaturated Aldehydes -- 6.2 Transfer Hydrogenation of α,β-Unsaturated Ketones -- 6.3 Transfer Hydrogenation of Non-conjugated Unsaturated Aldehydes and Ketones -- 7 Transfer Hydrogenation of N-Heterocycles -- 8 Transfer Hydrogenation and Sustainability -- 9 Mechanistic Aspects -- 10 Conclusions -- References -- Iridium-Catalyzed Asymmetric Hydrogenation.
1 Introduction -- 2 Ir-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Olefins or with Poorly Coordinative Groups -- 2.1 Di- and Trisubstituted Unfunctionalized Olefins or with Poorly Coordinative Groups -- 2.1.1 Phosphine-Oxazoline Ligands -- 2.1.2 Aminophosphine-Oxazoline Ligands -- 2.1.3 Phosphinite-Oxazoline Ligands -- 2.1.4 Phosphite-Oxazoline Ligands -- 2.1.5 Phosphorus-Other Nitrogen Donor Ligands -- 2.1.6 Carbene-Nitrogen Ligands -- 2.1.7 Application of P-O/S Ligands -- 2.2 Tetrasubstituted Unfunctionalized Olefins or with Poorly Coordinative Groups -- 3 Ir-Catalyzed Asymmetric Hydrogenation of Olefins Containing Coordinating Groups -- 3.1 Ir-Catalyzed Asymmetric Hydrogenation of Carboxylic Acids -- 3.2 Ir-Catalyzed Asymmetric Hydrogenation of Nitroolefins -- 3.3 Ir-Catalyzed Asymmetric Hydrogenation of Enamines, Enamides, and Allylic Amines -- 4 Asymmetric Ir-Catalyzed Hydrogenation of Imines -- 4.1 Asymmetric Hydrogenation Using Cationic Catalyst Precursors -- 4.2 Asymmetric Hydrogenation Using Neutral Catalyst Precursors -- 5 Ir-Catalyzed Asymmetric Hydrogenation of Ketones -- 5.1 P-Donor-Based Ligands -- 5.2 Non-P-Donor-Based Ligands -- 6 Conclusions -- References -- Iridium-Catalyzed Undirected Homogeneous C-H Borylation Reaction -- 1 Introduction -- 2 C-H Borylation of Heteroarenes -- 3 C-H Borylation of Arenes -- 4 C-H Borylation of Alkanes -- References -- Iridium-Catalyzed Silylation -- 1 Introduction -- 2 Hydrosilylation Reactions -- 2.1 Hydrosilylation of Ketones -- 2.2 Hydrosilylation of Imines -- 2.3 Hydrosilylation of Alkenes -- 2.4 Hydrosilylation of Alkynes -- 2.5 Hydrosilylation of Cyclopropanes -- 3 Silylation of C-H Bonds -- 3.1 Silylation of Alkynes and Alkenes -- 3.2 Silylation of Arenes and Heteroarenes -- 3.3 Silylation of Alkanes -- 4 Concluding Remarks -- References. Iridium Catalysts for Hydrogen Isotope Exchange -- 1 Introduction -- 1.1 Isotopes and Isotopic Labeling -- 1.2 Applications of Hydrogen Isotope Exchange -- 1.3 Synthetic Methods in HIE -- 2 Ortho-Directed Iridium-Catalyzed HIE -- 2.1 Early Developments in Ortho-Directed HIE -- 2.2 Contemporary Methods in Ortho-Directed HIE -- 3 Beyond Ortho-Directed HIE -- 3.1 Directed sp3 C-H HIE Methods -- 3.2 Non-ortho-HIE on Aromatic Substrates -- 3.3 Vinyl HIE Processes -- 3.4 Beyond C-H Labeling -- 4 Concluding Remarks -- References -- Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide -- 1 Introduction -- 2 Recent Advances on Iridium-Catalyzed CO2 Hydrogenation -- 2.1 Iridium-Catalyzed Formic Acid or Formate Preparation from CO2 and H2 -- 2.2 Iridium-Catalyzed Methanol Preparation from Direct Hydrogenation of CO2 -- 2.3 Miscellaneous -- 3 Recent Advances on Iridium-Catalyzed CO2 Hydrosilylation -- 3.1 Iridium-Catalyzed CO2 Hydrosilylation to Silylformate -- 3.2 Iridium-Catalyzed Reduction of CO2 to Methoxysilanes with Silicon-Hydrides -- 3.3 Iridium-Catalyzed Reduction of CO2 to Methane with Silicon-Hydrides -- 4 Concluding Remarks -- References -- Electroreduction of Carbon Dioxide by Homogeneous Iridium Catalysts -- 1 Introduction -- 2 Electroreduction of Carbon Dioxide to Formate -- 2.1 Homogeneous Catalysts -- 2.2 Immobilized Catalysts -- 3 Electroreduction of Carbon Dioxide to Carbon Monoxide -- 4 Electroreduction of Carbon Dioxide to Oxalate -- 5 Conclusion -- References -- Homogenous Iridium Catalysts for Biomass Conversion -- 1 Introduction -- 2 Recent Trends in Iridium-Catalyzed Valorization of Bio-derived Alcohols -- 2.1 Iridium-Catalyzed Reactions Using Ethylene Glycol -- 2.1.1 Iridium-Catalyzed Selective Cross-Coupling of Ethylene Glycol -- 2.1.2 Iridium-Catalyzed Oxidation of Ethylene Glycol Towards Glycolic Acid. 2.2 Iridium-Catalyzed Hydrogen Transfer Initiated Dehydration of 1,3-Propanediol to Aldehydes -- 2.3 Iridium-Catalyzed Direct Amination of Isohexides -- 2.4 Iridium-Catalyzed Conversion of Glycerol -- 2.4.1 Iridium-Catalyzed Oxidative Conversion of Glycerol -- 2.4.2 Iridium-Catalyzed Deoxygenation of Glycerol -- 2.4.3 Iridium-Catalyzed Carbonylation of Glycerol to Monocarboxylic Acids -- 2.4.4 Iridium-Catalyzed Chemoselective Dehydrogenation of Glycerol -- 2.4.5 Iridium-Catalyzed Acetalization of Glycerol -- 2.5 Iridium-Catalyzed Cyclizations of Bio-Derived Alcohols -- 2.6 Poly(Silyl Ethers) Via Iridium-Catalyzed Dehydrocoupling Polymerization -- 3 Iridium-Catalyzed Transformations of Bio-Based Furan Compounds -- 3.1 Iridium-Catalyzed Synthesis of 1-Hydroxyhexane-2,5-Dione -- 3.2 Conversion of Furfural Compounds to Ketones -- 3.3 Iridium-Catalyzed (Transfer)Hydrogenation of Furfurals -- 3.4 Selective Hydrogenation of 5-Hydroxymethyl Furfural to 2,5-Bis(Hydroxymethyl)Furan -- 4 Iridium-Catalyzed Conversions of Levulinic Acid -- 4.1 Hydrogenation to GVL -- 4.2 Reductive Amination to Pyrrolidinones -- 5 Iridium-Catalyzed Dehydrogenation of Biomass Compounds -- 5.1 Hydrogen Generation from Biomass -- 5.2 Biomass Molecules as Hydrogen Donors for Transfer Hydrogenation -- 5.3 Iridium-Catalyzed Dehydrogenation of Sugars to Sugar Acids -- 6 Iridium-Catalyzed Conversion of Lignin -- 7 Iridium-Catalyzed Transformations of Fatty Acids -- 7.1 Vegetable Oil as a Feedstock -- 7.2 Iridium-Catalyzed Transformations of Fatty Acids -- 7.2.1 Hydrogenation -- 7.2.2 Decarbonylation -- 7.2.3 Hydroformylation -- 7.2.4 Trialkylsilylation -- 7.2.5 Hydroboration -- 8 Conclusion -- References -- Iridium Nanoparticles for Hydrogenation Reactions -- 1 Introduction -- 2 Hydrogenation Reactions Catalysed by Ligand-Stabilised Iridium Nanoparticles. 3 Hydrogenation Reactions Catalysed by Iridium Nanoparticles Stabilised in Ionic Liquids -- 4 Hydrogenation Reactions Catalysed by Iridium Nanoparticles Stabilised by Polymers -- 5 Hydrogenation Reactions Catalysed by Iridium Nanoparticles Generated In Situ Without Stabilising Agent -- 6 Supported Ir NPs -- 6.1 Ir NPs Supported on Carbon Materials -- 6.2 Metal Oxide-Supported Ir NPs -- 6.2.1 Ir NPs Supported on TiO2 -- 6.2.2 Ir NPs Supported on ZrO2 -- 6.2.3 Ir NPs Supported on MoOx -- 6.2.4 Ir NPs Supported on Magnetic NPs -- 6.2.5 Ir NPs Supported on MgO -- 6.2.6 Ir NPs Supported on Al2O3 -- 6.2.7 Ir NPs Supported on AlO(OH) -- 6.3 SiO2-Supported Ir NPs -- 6.4 Zeolite-Supported Ir NPs -- 6.5 Ir NPs Supported on Metal-Organic Frameworks (MOFs) -- 7 Concluding Remarks -- References -- Correction to: Chapters -- Correction to: Iridium Catalysts for Organic Reactions -- Correction to: L. A. Oro, C. Claver (eds.), Iridium Catalysts for Organic Reactions, Topics in Organometallic Chemistry 69, ht... |
| Record Nr. | UNINA-9910768466003321 |
| Cham, Switzerland : , : Springer, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Iridium complexes in organic synthesis [[electronic resource] /] / edited by Luis A. Oro and Carmen Claver
| Iridium complexes in organic synthesis [[electronic resource] /] / edited by Luis A. Oro and Carmen Claver |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (xvii, 396 pages) : illustrations (some color) |
| Disciplina | 547.215 |
| Altri autori (Persone) |
OroLuis A
ClaverCarmen |
| Soggetto topico |
Organic compounds - Synthesis
Iridium catalysts Asymmetric synthesis |
| ISBN |
1-282-02533-3
9786612025334 3-527-62307-8 3-527-62308-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Iridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation
1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand? 2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity 3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction 5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols 5.6.4 Amidation of Alcohols with Hydroxylamine |
| Record Nr. | UNINA-9910145256403321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Iridium complexes in organic synthesis [[electronic resource] /] / edited by Luis A. Oro and Carmen Claver
| Iridium complexes in organic synthesis [[electronic resource] /] / edited by Luis A. Oro and Carmen Claver |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (xvii, 396 pages) : illustrations (some color) |
| Disciplina | 547.215 |
| Altri autori (Persone) |
OroLuis A
ClaverCarmen |
| Soggetto topico |
Organic compounds - Synthesis
Iridium catalysts Asymmetric synthesis |
| ISBN |
1-282-02533-3
9786612025334 3-527-62307-8 3-527-62308-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Iridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation
1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand? 2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity 3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction 5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols 5.6.4 Amidation of Alcohols with Hydroxylamine |
| Record Nr. | UNINA-9910830692603321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Iridium complexes in organic synthesis / / edited by Luis A. Oro and Carmen Claver
| Iridium complexes in organic synthesis / / edited by Luis A. Oro and Carmen Claver |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (xvii, 396 pages) : illustrations (some color) |
| Disciplina | 547.215 |
| Altri autori (Persone) |
OroLuis A
ClaverCarmen |
| Soggetto topico |
Organic compounds - Synthesis
Iridium catalysts Asymmetric synthesis |
| ISBN |
1-282-02533-3
9786612025334 3-527-62307-8 3-527-62308-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Iridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation
1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand? 2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity 3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction 5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols 5.6.4 Amidation of Alcohols with Hydroxylamine |
| Record Nr. | UNINA-9910877482203321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Recent Advances in Nanoparticle Catalysis / / edited by Piet W.N.M. van Leeuwen, Carmen Claver
| Recent Advances in Nanoparticle Catalysis / / edited by Piet W.N.M. van Leeuwen, Carmen Claver |
| Edizione | [1st ed. 2020.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2020 |
| Descrizione fisica | 1 online resource (XI, 454 p. 383 illus., 181 illus. in color.) |
| Disciplina | 541.395 |
| Collana | Molecular Catalysis |
| Soggetto topico |
Nanochemistry
Catalysis Organic chemistry Inorganic chemistry Green chemistry Organic Chemistry Inorganic Chemistry Green Chemistry |
| ISBN | 3-030-45823-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | 1. Introduction -- 2. Small size Nanoclusters in Catalysis -- 3. Precise nano clusters as catalysts -- 4. Catalysts via Atomic Layer Deposition -- 5. Magnetic heating of nano catalysts -- 6. Earth-abundant metal nanocatalysis in alternative solvents -- 7. MNP catalysis in Ionic Liquids -- 8. Metal NPs confined in CNT -- 9. Covalent assembly of metal nanoparticles – strategy for synthesis and catalytic -- 10. Catalysis with MNPs on N-doped carbon -- 11. Catalysis with MNPs in MOFs -- 12. Oxidation Pending -- 13. RuNPs for labelling of NMR probes in biochemistry -- 14. Nanoparticle hydrogenation of alkynes -- 15. Selective hydrogenation of aldehydes -- 16. Ligand effects in Ruthenium Nanoparticle Catalysis. |
| Record Nr. | UNINA-9910412152103321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2020 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rhodium Catalysis / / edited by Carmen Claver
| Rhodium Catalysis / / edited by Carmen Claver |
| Edizione | [1st ed. 2018.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2018 |
| Descrizione fisica | 1 online resource (VII, 288 p.) |
| Disciplina | 541.395 |
| Collana | Topics in Organometallic Chemistry |
| Soggetto topico |
Organometallic chemistry
Catalysis Physical chemistry Organometallic Chemistry Physical Chemistry |
| ISBN | 3-319-66665-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Rhodium catalyzed C-B bond formation -- Rhodium catalyzed tandem reactions -- Rhodium catalyzed hydroformylation -- Rh catalyzed thiolation of olefins -- Rh-catalyzed decarbonylation reactions -- Enantioselective catalysis with Rhodium / Phosphoramidite catalysts -- CO2 reduction reactions by rhodium-based catalysts -- Rh catalyzed Pauson-Khand. |
| Record Nr. | UNINA-9910767501903321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2018 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver
| Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver |
| Edizione | [1st ed. 2002.] |
| Pubbl/distr/stampa | Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina | 547/.1393 |
| Altri autori (Persone) |
LeeuwenP. W. N. M. van (Piet W. N. M.)
ClaverCarmen |
| Collana | Catalysis by metal complexes |
| Soggetto topico |
Hydroformylation
Rhodium catalysts |
| Soggetto genere / forma | Electronic books. |
| ISBN |
9786610205394
1-59124-840-X 9780306469472 1-280-20539-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | to hydroformylation -- Hydroformylation with unmodified rhodium catalysts -- Rhodium Phosphite Catalysts -- Phosphines as ligands -- Asymmetric hydroformylation -- Hydroformylation in Organic Synthesis -- Aqueous biphasic hydroformylation -- Process aspects of rhodium-catalyzed hydroformylation -- Catalyst preparation and decomposition -- Novel developments in hydroformylation. |
| Record Nr. | UNINA-9910454990403321 |
| Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver
| Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver |
| Edizione | [1st ed. 2002.] |
| Pubbl/distr/stampa | Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina | 547/.1393 |
| Altri autori (Persone) |
LeeuwenP. W. N. M. van (Piet W. N. M.)
ClaverCarmen |
| Collana | Catalysis by metal complexes |
| Soggetto topico |
Hydroformylation
Rhodium catalysts |
| ISBN |
9786610205394
1-59124-840-X 9780306469472 1-280-20539-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | to hydroformylation -- Hydroformylation with unmodified rhodium catalysts -- Rhodium Phosphite Catalysts -- Phosphines as ligands -- Asymmetric hydroformylation -- Hydroformylation in Organic Synthesis -- Aqueous biphasic hydroformylation -- Process aspects of rhodium-catalyzed hydroformylation -- Catalyst preparation and decomposition -- Novel developments in hydroformylation. |
| Record Nr. | UNINA-9910779960203321 |
| Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rhodium catalyzed hydroformylation / / edited by Piet W.N.M. van Leeuwen and Carmen Claver
| Rhodium catalyzed hydroformylation / / edited by Piet W.N.M. van Leeuwen and Carmen Claver |
| Edizione | [1st ed. 2002.] |
| Pubbl/distr/stampa | Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina | 547/.1393 |
| Altri autori (Persone) |
LeeuwenP. W. N. M. van (Piet W. N. M.)
ClaverCarmen |
| Collana | Catalysis by metal complexes |
| Soggetto topico |
Hydroformylation
Rhodium catalysts |
| ISBN |
9786610205394
1-59124-840-X 9780306469472 1-280-20539-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | to hydroformylation -- Hydroformylation with unmodified rhodium catalysts -- Rhodium Phosphite Catalysts -- Phosphines as ligands -- Asymmetric hydroformylation -- Hydroformylation in Organic Synthesis -- Aqueous biphasic hydroformylation -- Process aspects of rhodium-catalyzed hydroformylation -- Catalyst preparation and decomposition -- Novel developments in hydroformylation. |
| Record Nr. | UNINA-9910806870703321 |
| Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||