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Principles and applications of emulsion polymerization [[electronic resource] /] / Chorng-Shyan Chern
| Principles and applications of emulsion polymerization [[electronic resource] /] / Chorng-Shyan Chern |
| Autore | Chern Chorng-Shyan |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2008 |
| Descrizione fisica | 1 online resource (268 p.) |
| Disciplina |
668.9
668.92 |
| Soggetto topico | Emulsion polymerization |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-75190-1
9786611751906 0-470-37794-1 0-470-37793-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF EMULSION POLYMERIZATION; CONTENTS; Preface; 1 Introduction; 1.1 Free Radical Polymerization; 1.1.1 Free Radical Polymerization Mechanisms; 1.1.2 Free Radical Polymerization Kinetics; 1.2 Emulsion Polymerization; 1.2.1 Conventional Emulsion Polymerization; 1.2.2 Emulsion Polymerization Processes; 1.2.3 Miniemulsion Polymerization; 1.2.4 Microemulsion Polymerization; 1.2.5 Inverse Emulsion Polymerization; 1.3 Colloidal Stability; 1.3.1 A Critical but Often Ignored Issue; 1.3.2 Electrostatic Interactions; 1.3.3 Steric Interactions; 1.3.4 Mechanical Stability
1.4 Some Performance Properties for Industrial Applications1.4.1 Rheology; 1.4.2 Film Formation; References; 2 Interfacial Phenomena; 2.1 Thermodynamic Consideration; 2.1.1 Emulsification of Oil in Water; 2.1.2 Interfaces; 2.1.3 Surfactant Molecules Adsorbed at an Interface; 2.2 Surfactants; 2.2.1 Critical Micelle Concentration (CMC); 2.2.2 Hydrophile-Lipophile Balance (HLB); 2.2.3 Solubility Parameter; 2.3 Colloidal Stability; 2.3.1 Van der Waals Forces; 2.3.2 Electrostatic Interactions; 2.3.3 Steric Interactions; 2.3.4 Kinetics of Flocculation; References; 3 Particle Nucleation Mechanisms 3.1 Micellar Nucleation3.1.1 Harkins-Smith-Ewart Theory; 3.1.2 Competitive Absorption of Free Radicals by Micelles and Particle Nuclei; 3.2 Homogeneous Nucleation; 3.2.1 Formation of Particle Nuclei in the Continuous Aqueous Phase; 3.2.2 Hansen-Ugelstad-Fitch-Tsai (HUFT) Model; 3.3 Coagulative Nucleation; 3.3.1 General Features of Coagulative Nucleation; 3.3.2 Coagulative Nucleation Model Development; 3.4 Mixed Mode of Particle Nucleation Mechanisms; 3.5 Surfactant-Free Emulsion Polymerization; 3.6 Experimental Work on Particle Nucleation; 3.6.1 A Dilemma about Particle Nucleation Mechanisms 3.6.2 Some Representative Experimental Data of Particle Nucleation3.6.3 Some Potential Techniques for Studying Particle Nucleation; 3.6.4 Effects of Surfactant Concentration on Particle Nucleation; 3.7 Nonionic and Mixed Surfactant Systems; 3.7.1 Nonionic Surfactant Systems; 3.7.2 Mixed Anionic and Nonionic Surfactant Systems; References; 4 Emulsion Polymerization Kinetics; 4.1 Emulsion Polymerization Kinetics; 4.1.1 Smith-Ewart Theory; 4.1.2 Pioneering Kinetic Models for Predicting Average Number of Free Radicals per Particle; 4.2 Absorption of Free Radicals by Latex Particles 4.2.1 Collision- and Diffusion-Controlled Models4.2.2 Propagation-Controlled Model; 4.2.3 Some Controversial Issues; 4.3 Desorption of Free Radicals Out of Latex Particles; 4.3.1 Desorption of Free Radicals in Emulsion Homopolymerization Systems; 4.3.2 Desorption of Free Radicals in Emulsion Copolymerization Systems; 4.3.3 Effect of Interfacial Properties on Desorption of Free Radicals; 4.4 Growth of Latex Particles; 4.4.1 Thermodynamic Consideration; 4.4.2 Concentrations of Comonomers in Emulsion Copolymerization Systems; 4.4.3 Competitive Growth of Latex Particles 4.5 Polymer Molecular Weight |
| Record Nr. | UNINA-9910144135703321 |
Chern Chorng-Shyan
|
||
| Hoboken, N.J., : Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Principles and applications of emulsion polymerization [[electronic resource] /] / Chorng-Shyan Chern
| Principles and applications of emulsion polymerization [[electronic resource] /] / Chorng-Shyan Chern |
| Autore | Chern Chorng-Shyan |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2008 |
| Descrizione fisica | 1 online resource (268 p.) |
| Disciplina |
668.9
668.92 |
| Soggetto topico | Emulsion polymerization |
| ISBN |
1-281-75190-1
9786611751906 0-470-37794-1 0-470-37793-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF EMULSION POLYMERIZATION; CONTENTS; Preface; 1 Introduction; 1.1 Free Radical Polymerization; 1.1.1 Free Radical Polymerization Mechanisms; 1.1.2 Free Radical Polymerization Kinetics; 1.2 Emulsion Polymerization; 1.2.1 Conventional Emulsion Polymerization; 1.2.2 Emulsion Polymerization Processes; 1.2.3 Miniemulsion Polymerization; 1.2.4 Microemulsion Polymerization; 1.2.5 Inverse Emulsion Polymerization; 1.3 Colloidal Stability; 1.3.1 A Critical but Often Ignored Issue; 1.3.2 Electrostatic Interactions; 1.3.3 Steric Interactions; 1.3.4 Mechanical Stability
1.4 Some Performance Properties for Industrial Applications1.4.1 Rheology; 1.4.2 Film Formation; References; 2 Interfacial Phenomena; 2.1 Thermodynamic Consideration; 2.1.1 Emulsification of Oil in Water; 2.1.2 Interfaces; 2.1.3 Surfactant Molecules Adsorbed at an Interface; 2.2 Surfactants; 2.2.1 Critical Micelle Concentration (CMC); 2.2.2 Hydrophile-Lipophile Balance (HLB); 2.2.3 Solubility Parameter; 2.3 Colloidal Stability; 2.3.1 Van der Waals Forces; 2.3.2 Electrostatic Interactions; 2.3.3 Steric Interactions; 2.3.4 Kinetics of Flocculation; References; 3 Particle Nucleation Mechanisms 3.1 Micellar Nucleation3.1.1 Harkins-Smith-Ewart Theory; 3.1.2 Competitive Absorption of Free Radicals by Micelles and Particle Nuclei; 3.2 Homogeneous Nucleation; 3.2.1 Formation of Particle Nuclei in the Continuous Aqueous Phase; 3.2.2 Hansen-Ugelstad-Fitch-Tsai (HUFT) Model; 3.3 Coagulative Nucleation; 3.3.1 General Features of Coagulative Nucleation; 3.3.2 Coagulative Nucleation Model Development; 3.4 Mixed Mode of Particle Nucleation Mechanisms; 3.5 Surfactant-Free Emulsion Polymerization; 3.6 Experimental Work on Particle Nucleation; 3.6.1 A Dilemma about Particle Nucleation Mechanisms 3.6.2 Some Representative Experimental Data of Particle Nucleation3.6.3 Some Potential Techniques for Studying Particle Nucleation; 3.6.4 Effects of Surfactant Concentration on Particle Nucleation; 3.7 Nonionic and Mixed Surfactant Systems; 3.7.1 Nonionic Surfactant Systems; 3.7.2 Mixed Anionic and Nonionic Surfactant Systems; References; 4 Emulsion Polymerization Kinetics; 4.1 Emulsion Polymerization Kinetics; 4.1.1 Smith-Ewart Theory; 4.1.2 Pioneering Kinetic Models for Predicting Average Number of Free Radicals per Particle; 4.2 Absorption of Free Radicals by Latex Particles 4.2.1 Collision- and Diffusion-Controlled Models4.2.2 Propagation-Controlled Model; 4.2.3 Some Controversial Issues; 4.3 Desorption of Free Radicals Out of Latex Particles; 4.3.1 Desorption of Free Radicals in Emulsion Homopolymerization Systems; 4.3.2 Desorption of Free Radicals in Emulsion Copolymerization Systems; 4.3.3 Effect of Interfacial Properties on Desorption of Free Radicals; 4.4 Growth of Latex Particles; 4.4.1 Thermodynamic Consideration; 4.4.2 Concentrations of Comonomers in Emulsion Copolymerization Systems; 4.4.3 Competitive Growth of Latex Particles 4.5 Polymer Molecular Weight |
| Record Nr. | UNINA-9910830503503321 |
|
Chern Chorng-Shyan
|
||
| Hoboken, N.J., : Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Principles and applications of emulsion polymerization / / Chorng-Shyan Chern
| Principles and applications of emulsion polymerization / / Chorng-Shyan Chern |
| Autore | Chern Chorng-Shyan |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2008 |
| Descrizione fisica | 1 online resource (268 p.) |
| Disciplina | 668.9/2 |
| Soggetto topico | Emulsion polymerization |
| ISBN |
1-281-75190-1
9786611751906 0-470-37794-1 0-470-37793-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF EMULSION POLYMERIZATION; CONTENTS; Preface; 1 Introduction; 1.1 Free Radical Polymerization; 1.1.1 Free Radical Polymerization Mechanisms; 1.1.2 Free Radical Polymerization Kinetics; 1.2 Emulsion Polymerization; 1.2.1 Conventional Emulsion Polymerization; 1.2.2 Emulsion Polymerization Processes; 1.2.3 Miniemulsion Polymerization; 1.2.4 Microemulsion Polymerization; 1.2.5 Inverse Emulsion Polymerization; 1.3 Colloidal Stability; 1.3.1 A Critical but Often Ignored Issue; 1.3.2 Electrostatic Interactions; 1.3.3 Steric Interactions; 1.3.4 Mechanical Stability
1.4 Some Performance Properties for Industrial Applications1.4.1 Rheology; 1.4.2 Film Formation; References; 2 Interfacial Phenomena; 2.1 Thermodynamic Consideration; 2.1.1 Emulsification of Oil in Water; 2.1.2 Interfaces; 2.1.3 Surfactant Molecules Adsorbed at an Interface; 2.2 Surfactants; 2.2.1 Critical Micelle Concentration (CMC); 2.2.2 Hydrophile-Lipophile Balance (HLB); 2.2.3 Solubility Parameter; 2.3 Colloidal Stability; 2.3.1 Van der Waals Forces; 2.3.2 Electrostatic Interactions; 2.3.3 Steric Interactions; 2.3.4 Kinetics of Flocculation; References; 3 Particle Nucleation Mechanisms 3.1 Micellar Nucleation3.1.1 Harkins-Smith-Ewart Theory; 3.1.2 Competitive Absorption of Free Radicals by Micelles and Particle Nuclei; 3.2 Homogeneous Nucleation; 3.2.1 Formation of Particle Nuclei in the Continuous Aqueous Phase; 3.2.2 Hansen-Ugelstad-Fitch-Tsai (HUFT) Model; 3.3 Coagulative Nucleation; 3.3.1 General Features of Coagulative Nucleation; 3.3.2 Coagulative Nucleation Model Development; 3.4 Mixed Mode of Particle Nucleation Mechanisms; 3.5 Surfactant-Free Emulsion Polymerization; 3.6 Experimental Work on Particle Nucleation; 3.6.1 A Dilemma about Particle Nucleation Mechanisms 3.6.2 Some Representative Experimental Data of Particle Nucleation3.6.3 Some Potential Techniques for Studying Particle Nucleation; 3.6.4 Effects of Surfactant Concentration on Particle Nucleation; 3.7 Nonionic and Mixed Surfactant Systems; 3.7.1 Nonionic Surfactant Systems; 3.7.2 Mixed Anionic and Nonionic Surfactant Systems; References; 4 Emulsion Polymerization Kinetics; 4.1 Emulsion Polymerization Kinetics; 4.1.1 Smith-Ewart Theory; 4.1.2 Pioneering Kinetic Models for Predicting Average Number of Free Radicals per Particle; 4.2 Absorption of Free Radicals by Latex Particles 4.2.1 Collision- and Diffusion-Controlled Models4.2.2 Propagation-Controlled Model; 4.2.3 Some Controversial Issues; 4.3 Desorption of Free Radicals Out of Latex Particles; 4.3.1 Desorption of Free Radicals in Emulsion Homopolymerization Systems; 4.3.2 Desorption of Free Radicals in Emulsion Copolymerization Systems; 4.3.3 Effect of Interfacial Properties on Desorption of Free Radicals; 4.4 Growth of Latex Particles; 4.4.1 Thermodynamic Consideration; 4.4.2 Concentrations of Comonomers in Emulsion Copolymerization Systems; 4.4.3 Competitive Growth of Latex Particles 4.5 Polymer Molecular Weight |
| Record Nr. | UNINA-9910877590103321 |
|
Chern Chorng-Shyan
|
||
| Hoboken, N.J., : Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||