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Biomimetic Radical Chemistry and Applications 2021
| Biomimetic Radical Chemistry and Applications 2021 |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | Basel, : MDPI - Multidisciplinary Digital Publishing Institute, 2022 |
| Descrizione fisica | 1 electronic resource (244 p.) |
| Soggetto topico |
Research & information: general
Chemistry Inorganic chemistry |
| Soggetto non controllato |
guanine
guanyl radical tautomerism guanine radical cation oligonucleotides DNA G-quadruplex time-resolved spectroscopies reactive oxygen species (ROS) oxidation catalase mimics peroxide diiron-peroxo complexes structure/activity kinetic studies biomimetic chemistry cysteine ketone reduction free radicals pulse radiolysis kinetics DNA oxidation DNA hole transfer molecular dynamics quantum dynamics electron transfer charge transfer quantum coherence chemiluminescence reaction mechanisms singlet oxygen reactive oxygen species light emission crosslink dimerization protein oxidation radicals di-tyrosine di-tryptophan disulfides thiols aggregation proteomics mass spectrometry collagen riboflavin hyaluronic acid EPR spectroscopy keratoconus STEM DNA biosensor chemical nucleases DNA-drug interaction copper complexes metallodrugs MEP pathway antibiotics IspH LytB [4Fe-4S] cluster reductive dehydroxylation bioorganometallic intermediate inhibitors methionine neighboring group effect hydroxyl radical triplet state of carboxybenzophenone one-electron oxidants laser flash photolysis peptides proteins |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910576882903321 |
Chatgilialoglu Chryssostomos
|
||
| Basel, : MDPI - Multidisciplinary Digital Publishing Institute, 2022 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910146249703321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910829802503321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910840573903321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||