Iridium catalysts for organic reactions / / Luis A. Oro, Carmen Claver, editors ; with contributions by I. Cano [and nineteen others]

• Pubblicazione: Cham, Switzerland : , : Springer, , [2021]; ©2021
• Descrizione fisica: 1 online resource (viii, 456 pages) : illustrations
• Disciplina: 547.2
• Soggetto topico: Organic compounds - Synthesis; Iridium catalysts; Asymmetric synthesis
• Persona (resp. second.): ClaverCarmen; CanoI; OroLuis A.
• Nota di bibliografia: Includes bibliographical references.
• Nota di contenuto: Intro -- Preface -- Contents -- Iridium-Catalyzed Dehydrogenative Reactions -- 1 Introduction -- 2 Dehydrogenation of Alkanes -- 3 Dehydrogenation of Heterocyclic Compounds -- 3.1 Dehydrogenation of N-Heterocyclic Compounds -- 3.2 Dehydrogenation of Other Heterocyclic Compounds -- 3.3 N-Heteroarene Synthesis via Combination of Ring Construction-Dehydrogenation -- 4 Dehydrogenation of Alcohols -- 4.1 Dehydrogenative Oxidation of Alcohols to Aldehydes and Ketones -- 4.2 Dehydrogenative Oxidation of Primary Alcohols to Esters, Carboxylic Acids, and Acetals -- 4.3 Dehydrogenative Decarbonylation of Primary Alcohols -- 4.4 Dehydrogenative Cross-Coupling Reactions Involving Alcohols -- 4.5 Synthesis of N-Heterocycles Based on Alcohol Dehydrogenation -- 4.6 Other Reactions Based on Alcohol Dehydrogenation -- 5 Dehydrogenation of Formic Acid -- 6 Dehydrogenative Borylation -- 6.1 Aryl and Alkyl Group Borylation -- 6.2 Terminal Alkyne Borylation -- 7 Miscellaneous -- 8 Summary -- References -- Recent Advances in Iridium-Catalysed Transfer Hydrogenation Reactions -- 1 Introduction -- 2 Half-Sandwich Iridium Complexes -- 2.1 Transfer Hydrogenation of C=O, C=N and C=C Bonds -- 2.2 Transfer Hydrogenation of CO2 -- 2.3 Transfer Hydrogenation in Water -- 2.4 Biological Transfer Hydrogenation -- 3 Carbene Iridium Complexes -- 4 Pincer Iridium Complexes -- 5 Other Iridium Complexes -- 6 Transfer Hydrogenation of α,β-Unsaturated (and Non-conjugated) Alkene-Carbonyl Substrates -- 6.1 Transfer Hydrogenation of α,β-Unsaturated Aldehydes -- 6.2 Transfer Hydrogenation of α,β-Unsaturated Ketones -- 6.3 Transfer Hydrogenation of Non-conjugated Unsaturated Aldehydes and Ketones -- 7 Transfer Hydrogenation of N-Heterocycles -- 8 Transfer Hydrogenation and Sustainability -- 9 Mechanistic Aspects -- 10 Conclusions -- References -- Iridium-Catalyzed Asymmetric Hydrogenation. ; 1 Introduction -- 2 Ir-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Olefins or with Poorly Coordinative Groups -- 2.1 Di- and Trisubstituted Unfunctionalized Olefins or with Poorly Coordinative Groups -- 2.1.1 Phosphine-Oxazoline Ligands -- 2.1.2 Aminophosphine-Oxazoline Ligands -- 2.1.3 Phosphinite-Oxazoline Ligands -- 2.1.4 Phosphite-Oxazoline Ligands -- 2.1.5 Phosphorus-Other Nitrogen Donor Ligands -- 2.1.6 Carbene-Nitrogen Ligands -- 2.1.7 Application of P-O/S Ligands -- 2.2 Tetrasubstituted Unfunctionalized Olefins or with Poorly Coordinative Groups -- 3 Ir-Catalyzed Asymmetric Hydrogenation of Olefins Containing Coordinating Groups -- 3.1 Ir-Catalyzed Asymmetric Hydrogenation of Carboxylic Acids -- 3.2 Ir-Catalyzed Asymmetric Hydrogenation of Nitroolefins -- 3.3 Ir-Catalyzed Asymmetric Hydrogenation of Enamines, Enamides, and Allylic Amines -- 4 Asymmetric Ir-Catalyzed Hydrogenation of Imines -- 4.1 Asymmetric Hydrogenation Using Cationic Catalyst Precursors -- 4.2 Asymmetric Hydrogenation Using Neutral Catalyst Precursors -- 5 Ir-Catalyzed Asymmetric Hydrogenation of Ketones -- 5.1 P-Donor-Based Ligands -- 5.2 Non-P-Donor-Based Ligands -- 6 Conclusions -- References -- Iridium-Catalyzed Undirected Homogeneous C-H Borylation Reaction -- 1 Introduction -- 2 C-H Borylation of Heteroarenes -- 3 C-H Borylation of Arenes -- 4 C-H Borylation of Alkanes -- References -- Iridium-Catalyzed Silylation -- 1 Introduction -- 2 Hydrosilylation Reactions -- 2.1 Hydrosilylation of Ketones -- 2.2 Hydrosilylation of Imines -- 2.3 Hydrosilylation of Alkenes -- 2.4 Hydrosilylation of Alkynes -- 2.5 Hydrosilylation of Cyclopropanes -- 3 Silylation of C-H Bonds -- 3.1 Silylation of Alkynes and Alkenes -- 3.2 Silylation of Arenes and Heteroarenes -- 3.3 Silylation of Alkanes -- 4 Concluding Remarks -- References. ; Iridium Catalysts for Hydrogen Isotope Exchange -- 1 Introduction -- 1.1 Isotopes and Isotopic Labeling -- 1.2 Applications of Hydrogen Isotope Exchange -- 1.3 Synthetic Methods in HIE -- 2 Ortho-Directed Iridium-Catalyzed HIE -- 2.1 Early Developments in Ortho-Directed HIE -- 2.2 Contemporary Methods in Ortho-Directed HIE -- 3 Beyond Ortho-Directed HIE -- 3.1 Directed sp3 C-H HIE Methods -- 3.2 Non-ortho-HIE on Aromatic Substrates -- 3.3 Vinyl HIE Processes -- 3.4 Beyond C-H Labeling -- 4 Concluding Remarks -- References -- Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide -- 1 Introduction -- 2 Recent Advances on Iridium-Catalyzed CO2 Hydrogenation -- 2.1 Iridium-Catalyzed Formic Acid or Formate Preparation from CO2 and H2 -- 2.2 Iridium-Catalyzed Methanol Preparation from Direct Hydrogenation of CO2 -- 2.3 Miscellaneous -- 3 Recent Advances on Iridium-Catalyzed CO2 Hydrosilylation -- 3.1 Iridium-Catalyzed CO2 Hydrosilylation to Silylformate -- 3.2 Iridium-Catalyzed Reduction of CO2 to Methoxysilanes with Silicon-Hydrides -- 3.3 Iridium-Catalyzed Reduction of CO2 to Methane with Silicon-Hydrides -- 4 Concluding Remarks -- References -- Electroreduction of Carbon Dioxide by Homogeneous Iridium Catalysts -- 1 Introduction -- 2 Electroreduction of Carbon Dioxide to Formate -- 2.1 Homogeneous Catalysts -- 2.2 Immobilized Catalysts -- 3 Electroreduction of Carbon Dioxide to Carbon Monoxide -- 4 Electroreduction of Carbon Dioxide to Oxalate -- 5 Conclusion -- References -- Homogenous Iridium Catalysts for Biomass Conversion -- 1 Introduction -- 2 Recent Trends in Iridium-Catalyzed Valorization of Bio-derived Alcohols -- 2.1 Iridium-Catalyzed Reactions Using Ethylene Glycol -- 2.1.1 Iridium-Catalyzed Selective Cross-Coupling of Ethylene Glycol -- 2.1.2 Iridium-Catalyzed Oxidation of Ethylene Glycol Towards Glycolic Acid. ; 2.2 Iridium-Catalyzed Hydrogen Transfer Initiated Dehydration of 1,3-Propanediol to Aldehydes -- 2.3 Iridium-Catalyzed Direct Amination of Isohexides -- 2.4 Iridium-Catalyzed Conversion of Glycerol -- 2.4.1 Iridium-Catalyzed Oxidative Conversion of Glycerol -- 2.4.2 Iridium-Catalyzed Deoxygenation of Glycerol -- 2.4.3 Iridium-Catalyzed Carbonylation of Glycerol to Monocarboxylic Acids -- 2.4.4 Iridium-Catalyzed Chemoselective Dehydrogenation of Glycerol -- 2.4.5 Iridium-Catalyzed Acetalization of Glycerol -- 2.5 Iridium-Catalyzed Cyclizations of Bio-Derived Alcohols -- 2.6 Poly(Silyl Ethers) Via Iridium-Catalyzed Dehydrocoupling Polymerization -- 3 Iridium-Catalyzed Transformations of Bio-Based Furan Compounds -- 3.1 Iridium-Catalyzed Synthesis of 1-Hydroxyhexane-2,5-Dione -- 3.2 Conversion of Furfural Compounds to Ketones -- 3.3 Iridium-Catalyzed (Transfer)Hydrogenation of Furfurals -- 3.4 Selective Hydrogenation of 5-Hydroxymethyl Furfural to 2,5-Bis(Hydroxymethyl)Furan -- 4 Iridium-Catalyzed Conversions of Levulinic Acid -- 4.1 Hydrogenation to GVL -- 4.2 Reductive Amination to Pyrrolidinones -- 5 Iridium-Catalyzed Dehydrogenation of Biomass Compounds -- 5.1 Hydrogen Generation from Biomass -- 5.2 Biomass Molecules as Hydrogen Donors for Transfer Hydrogenation -- 5.3 Iridium-Catalyzed Dehydrogenation of Sugars to Sugar Acids -- 6 Iridium-Catalyzed Conversion of Lignin -- 7 Iridium-Catalyzed Transformations of Fatty Acids -- 7.1 Vegetable Oil as a Feedstock -- 7.2 Iridium-Catalyzed Transformations of Fatty Acids -- 7.2.1 Hydrogenation -- 7.2.2 Decarbonylation -- 7.2.3 Hydroformylation -- 7.2.4 Trialkylsilylation -- 7.2.5 Hydroboration -- 8 Conclusion -- References -- Iridium Nanoparticles for Hydrogenation Reactions -- 1 Introduction -- 2 Hydrogenation Reactions Catalysed by Ligand-Stabilised Iridium Nanoparticles. ; 3 Hydrogenation Reactions Catalysed by Iridium Nanoparticles Stabilised in Ionic Liquids -- 4 Hydrogenation Reactions Catalysed by Iridium Nanoparticles Stabilised by Polymers -- 5 Hydrogenation Reactions Catalysed by Iridium Nanoparticles Generated In Situ Without Stabilising Agent -- 6 Supported Ir NPs -- 6.1 Ir NPs Supported on Carbon Materials -- 6.2 Metal Oxide-Supported Ir NPs -- 6.2.1 Ir NPs Supported on TiO2 -- 6.2.2 Ir NPs Supported on ZrO2 -- 6.2.3 Ir NPs Supported on MoOx -- 6.2.4 Ir NPs Supported on Magnetic NPs -- 6.2.5 Ir NPs Supported on MgO -- 6.2.6 Ir NPs Supported on Al2O3 -- 6.2.7 Ir NPs Supported on AlO(OH) -- 6.3 SiO2-Supported Ir NPs -- 6.4 Zeolite-Supported Ir NPs -- 6.5 Ir NPs Supported on Metal-Organic Frameworks (MOFs) -- 7 Concluding Remarks -- References -- Correction to: Chapters -- Correction to: Iridium Catalysts for Organic Reactions -- Correction to: L. A. Oro, C. Claver (eds.), Iridium Catalysts for Organic Reactions, Topics in Organometallic Chemistry 69, ht...
• Titolo autorizzato: Iridium Catalysts for Organic Reactions
• ISBN: 3-030-69083-0
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910768466003321
• Lo trovi qui: Univ. Federico II
• Serie: Topics in organometallic chemistry ; ; 69.