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Solvent effects in chemistry / / Erwin Buncel, Robert A. Stairs
| Solvent effects in chemistry / / Erwin Buncel, Robert A. Stairs |
| Autore | Buncel E. |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (528 p.) |
| Disciplina | 541/.34 |
| Soggetto topico |
Solvation
Chemical reactions Solvents |
| ISBN |
1-5231-1055-4
1-119-04429-4 1-119-04430-8 1-119-04419-7 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COVER; TABLE OF CONTENTS; TITLE PAGE; PREFACE TO THE SECOND EDITION; PREFACE TO THE FIRST EDITION; 1 PHYSICOCHEMICAL FOUNDATIONS; 1.1 GENERALITIES; 1.2 CLASSIFICATION OF SOLVENTS; 1.3 SOLVENTS IN THE WORKPLACE AND THE ENVIRONMENT; 1.4 SOME ESSENTIAL THERMODYNAMICS AND KINETICS: TENDENCY AND RATE; 1.5 EQUILIBRIUM CONSIDERATIONS; 1.6 THERMODYNAMIC TRANSFER FUNCTIONS; 1.7 KINETIC CONSIDERATIONS: COLLISION THEORY; 1.8 TRANSITION-STATE THEORY; 1.9 REACTIONS IN SOLUTION; 1.10 DIFFUSION-CONTROLLED REACTIONS; 1.11 REACTION IN SOLUTION AND THE TRANSITION-STATE THEORY; PROBLEMS; 2 UNREACTIVE SOLVENTS
2.1 INTERMOLECULAR POTENTIALS 2.2 ACTIVITY AND EQUILIBRIUM IN NONELECTROLYTE SOLUTIONS; 2.3 KINETIC SOLVENT EFFECTS; 2.4 SOLVENT POLARITY; 2.5 ELECTROSTATIC FORCES; 2.6 ELECTROLYTES IN SOLUTION; 2.7 SOLVATION; 2.8 SINGLE ION SOLVATION; 2.9 IONIC ASSOCIATION; 2.10 SOLVENT MIXTURES; 2.11 SALT EFFECTS; PROBLEMS; 3 REACTIVE SOLVENTS; 3.1 SPECIFIC SOLUTE/SOLVENT INTERACTIONS; 3.2 HYDROGEN BONDING; 3.3 ACIDS AND BASES IN SOLVENTS; 3.4 BRØNSTED-LOWRY ACIDS AND BASES; 3.5 ACIDITY FUNCTIONS; 3.6 ACIDS AND BASES IN KINETICS; 3.7 LEWIS ACIDS AND BASES; 3.8 HARD AND SOFT ACIDS AND BASES (HSAB) 3.9 SCALES OF HARDNESS OR SOFTNESS 3.10 ACIDS AND BASES IN REACTIVE APROTIC SOLVENTS; 3.11 EXTREMES OF ACIDITY AND BASICITY; 3.12 OXIDATION AND REDUCTION; 3.13 ACIDITY/REDOX DIAGRAMS; 3.14 UNIFICATION OF ACID-BASE AND REDOX CONCEPTS; PROBLEMS; 4 CHEMOMETRICS: SOLVENT EFFECTS AND STATISTICS; 4.1 LINEAR FREE ENERGY RELATIONSHIPS; 4.2 CORRELATIONS BETWEEN EMPIRICAL PARAMETERS AND OTHER MEASURABLE SOLVENT PROPERTIES; 4.3 REPRESENTATION OF CORRELATION DATA ON THE HEMISPHERE; 4.4 SOME PARTICULAR CASES; 4.5 ACIDITY AND BASICITY PARAMETERS; 4.6 BASE SOFTNESS PARAMETERS; 4.7 CONCLUSION 5 THEORIES OF SOLVENT EFFECTS 5.1 INTRODUCTION: MODELING; 5.2 QUANTUM-MECHANICAL METHODS; 5.3 STATISTICAL-MECHANICAL METHODS; 5.4 INTEGRAL EQUATION THEORIES; 5.5 SOLVATION CALCULATIONS; 5.6 SOME RESULTS; PROBLEMS; 6 DIPOLAR APROTIC SOLVENTS; 6.1 INTRODUCTION; 6.2 ACIDITIES IN DMSO AND THE H-SCALE IN DMSO-H2O MIXTURES; 6.3 USE OF THERMODYNAMIC TRANSFER FUNCTIONS; 6.4 CLASSIFICATION OF RATE PROFILE-MEDIUM EFFECT REACTION TYPES; 6.5 BIMOLECULAR NUCLEOPHILIC SUBSTITUTION; 6.6 PROTON TRANSFER; 6.7 D2-HO EXCHANGE; PROBLEMS; 7 EXAMPLES OF OTHER SOLVENT CLASSES; 7.1 INTRODUCTION; 7.2 ACIDIC SOLVENTS 7.3 BASIC SOLVENTS 7.4 CHIRAL SOLVENTS; 8 NEW SOLVENTS AND GREEN CHEMISTRY; 8.1 NEOTERIC SOLVENTS; 8.2 SUPERCRITICAL FLUIDS; 8.3 IONIC LIQUIDS; 8.4 LOW-TRANSITION-TEMPERATURE MIXTURES; 8.5 BIO-BASED SOLVENTS; 8.6 FLUOROUS SOLVENTS; 8.7 SWITCHABLE SOLVENTS; 8.8 GREEN SOLVENT CHEMISTRY; 9 CONCLUDING OBSERVATIONS; 9.1 CHOOSING A SOLVENT; 9.2 ENVOI; APPENDIX; ANSWERS; CHAPTER 1; CHAPTER 2; CHAPTER 3; CHAPTER 6; REFERENCES; INDEX; END USER LICENSE AGREEMENT |
| Record Nr. | UNINA-9910131369403321 |
Buncel E.
|
||
| Hoboken, New Jersey : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Solvent effects in chemistry / / Erwin Buncel, Robert A. Stairs
| Solvent effects in chemistry / / Erwin Buncel, Robert A. Stairs |
| Autore | Buncel E. |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (528 p.) |
| Disciplina | 541/.34 |
| Soggetto topico |
Solvation
Chemical reactions Solvents |
| ISBN |
1-5231-1055-4
1-119-04429-4 1-119-04430-8 1-119-04419-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COVER; TABLE OF CONTENTS; TITLE PAGE; PREFACE TO THE SECOND EDITION; PREFACE TO THE FIRST EDITION; 1 PHYSICOCHEMICAL FOUNDATIONS; 1.1 GENERALITIES; 1.2 CLASSIFICATION OF SOLVENTS; 1.3 SOLVENTS IN THE WORKPLACE AND THE ENVIRONMENT; 1.4 SOME ESSENTIAL THERMODYNAMICS AND KINETICS: TENDENCY AND RATE; 1.5 EQUILIBRIUM CONSIDERATIONS; 1.6 THERMODYNAMIC TRANSFER FUNCTIONS; 1.7 KINETIC CONSIDERATIONS: COLLISION THEORY; 1.8 TRANSITION-STATE THEORY; 1.9 REACTIONS IN SOLUTION; 1.10 DIFFUSION-CONTROLLED REACTIONS; 1.11 REACTION IN SOLUTION AND THE TRANSITION-STATE THEORY; PROBLEMS; 2 UNREACTIVE SOLVENTS
2.1 INTERMOLECULAR POTENTIALS 2.2 ACTIVITY AND EQUILIBRIUM IN NONELECTROLYTE SOLUTIONS; 2.3 KINETIC SOLVENT EFFECTS; 2.4 SOLVENT POLARITY; 2.5 ELECTROSTATIC FORCES; 2.6 ELECTROLYTES IN SOLUTION; 2.7 SOLVATION; 2.8 SINGLE ION SOLVATION; 2.9 IONIC ASSOCIATION; 2.10 SOLVENT MIXTURES; 2.11 SALT EFFECTS; PROBLEMS; 3 REACTIVE SOLVENTS; 3.1 SPECIFIC SOLUTE/SOLVENT INTERACTIONS; 3.2 HYDROGEN BONDING; 3.3 ACIDS AND BASES IN SOLVENTS; 3.4 BRØNSTED-LOWRY ACIDS AND BASES; 3.5 ACIDITY FUNCTIONS; 3.6 ACIDS AND BASES IN KINETICS; 3.7 LEWIS ACIDS AND BASES; 3.8 HARD AND SOFT ACIDS AND BASES (HSAB) 3.9 SCALES OF HARDNESS OR SOFTNESS 3.10 ACIDS AND BASES IN REACTIVE APROTIC SOLVENTS; 3.11 EXTREMES OF ACIDITY AND BASICITY; 3.12 OXIDATION AND REDUCTION; 3.13 ACIDITY/REDOX DIAGRAMS; 3.14 UNIFICATION OF ACID-BASE AND REDOX CONCEPTS; PROBLEMS; 4 CHEMOMETRICS: SOLVENT EFFECTS AND STATISTICS; 4.1 LINEAR FREE ENERGY RELATIONSHIPS; 4.2 CORRELATIONS BETWEEN EMPIRICAL PARAMETERS AND OTHER MEASURABLE SOLVENT PROPERTIES; 4.3 REPRESENTATION OF CORRELATION DATA ON THE HEMISPHERE; 4.4 SOME PARTICULAR CASES; 4.5 ACIDITY AND BASICITY PARAMETERS; 4.6 BASE SOFTNESS PARAMETERS; 4.7 CONCLUSION 5 THEORIES OF SOLVENT EFFECTS 5.1 INTRODUCTION: MODELING; 5.2 QUANTUM-MECHANICAL METHODS; 5.3 STATISTICAL-MECHANICAL METHODS; 5.4 INTEGRAL EQUATION THEORIES; 5.5 SOLVATION CALCULATIONS; 5.6 SOME RESULTS; PROBLEMS; 6 DIPOLAR APROTIC SOLVENTS; 6.1 INTRODUCTION; 6.2 ACIDITIES IN DMSO AND THE H-SCALE IN DMSO-H2O MIXTURES; 6.3 USE OF THERMODYNAMIC TRANSFER FUNCTIONS; 6.4 CLASSIFICATION OF RATE PROFILE-MEDIUM EFFECT REACTION TYPES; 6.5 BIMOLECULAR NUCLEOPHILIC SUBSTITUTION; 6.6 PROTON TRANSFER; 6.7 D2-HO EXCHANGE; PROBLEMS; 7 EXAMPLES OF OTHER SOLVENT CLASSES; 7.1 INTRODUCTION; 7.2 ACIDIC SOLVENTS 7.3 BASIC SOLVENTS 7.4 CHIRAL SOLVENTS; 8 NEW SOLVENTS AND GREEN CHEMISTRY; 8.1 NEOTERIC SOLVENTS; 8.2 SUPERCRITICAL FLUIDS; 8.3 IONIC LIQUIDS; 8.4 LOW-TRANSITION-TEMPERATURE MIXTURES; 8.5 BIO-BASED SOLVENTS; 8.6 FLUOROUS SOLVENTS; 8.7 SWITCHABLE SOLVENTS; 8.8 GREEN SOLVENT CHEMISTRY; 9 CONCLUDING OBSERVATIONS; 9.1 CHOOSING A SOLVENT; 9.2 ENVOI; APPENDIX; ANSWERS; CHAPTER 1; CHAPTER 2; CHAPTER 3; CHAPTER 6; REFERENCES; INDEX; END USER LICENSE AGREEMENT |
| Record Nr. | UNINA-9910807295403321 |
|
Buncel E.
|
||
| Hoboken, New Jersey : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||