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Electrochemical phase formation and growth [[electronic resource] ] : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz
| Electrochemical phase formation and growth [[electronic resource] ] : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz |
| Autore | Budevski E (Evgeni) |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH, c1996 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
541.37
670.7/32 670.732 |
| Altri autori (Persone) |
StaikovGeorgi
LorenzW. J |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electroplating
Metals - Surfaces Crystal growth |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-75852-3
9786611758523 3-527-61493-1 3-527-61492-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Electrochemical Phase Formation and Growth; Contents; 1 Fundamentals of Electrocrystallization of Metals; 1.1 Thermodynamic and Kinetic Aspects; 1.2 Metal Deposition Mechanisms; 1.3 Topics of this Book; 2 Crystalline Metal Surfaces; 2.1 Structural Aspects; Close-packed 2D and 3D crystal structures; Crystal imperfections and surface inhomogeneities; Surface reconstruction; Surface roughness and the kink position; Step roughness; 2.2 Atomic Dynamics; Atom exchange frequencies; Local, partial, and overall current densities; Kink atoms and the Nernst equilibrium potential
Exchange current density of kink atomsConcentration of adatoms; Exchange current density of adatoms; Mean residence time and surface displacement of adatoms; 2.3 Surface Profile Mobility; Surface diffusion and mean displacement of adatoms; Surface diffusion . The exact solution; Direct transfer; Current density on a stepped crystal face; 2.4 Conclusions; 3 Underpotential Deposition of Metals-2D Phases; 3.1 Historical Background; 3.2 Phenomenology; 3.3 Thermodynamics; Thermodynamic formalism; Adsorption isotherm models; Experimental results; 3.4 Structures of 2D Meads Phases Degree of registryInternal strain; Electrochemical results; Comparative and ex situ UHV results; In situ surface analytical results; 3.5 Kinetics; Quasi-homogeneous substrate surface approach; Inhomogeneous substrate surface approach; Phase transitions; 3.6 2D and 3D Me-S Alloy Formation; Phenomenology; Thermodynamics; Structures of 2D and 3D Me-alloys; Kinetics; 3.7 Conclusion; 4 Initial Stages of Bulk Phase Formation; 4.1 Equilibrium Form of Crystals and Forms of Growth; Equilibrium form; Crystal-substrate interaction; Gibbs-Wulff-Kaishew theorem; Two dimensional crystal; Forms of growth Energy of cluster formation3D nucleation; 2D nucleation; Gibbs-Thomson equation; 4.2 Nucleation Rate; Classical approach (Volmer and Weber); Kinetic approach (Becker and Doering); Binding energies and energy of nucleation; Atomistic model; Nucleation rate equation; Small cluster model; Experimental results; 4.3 3D Phase Formation on UPD Modified Foreign Substrate Surfaces; UPD-OPD transitions; Nucleation and growth; Epitaxy; Experimental results; 4.4 Conclusions; 5 Growth of Crystalline Faces; 5.1 Dislocation-Free Crystal Faces; Preparation of single crystal faces by electrodeposition Double pulse techniqueNucleation rate-overvoltage dependence; Time distribution of the nucleation events; Form of growth of monatomic layers; Propagation rate of monatomic steps; Space distribution of nucleation events; Propagation rate of polyatomic steps; Mechanism of metal deposition and adatom concentration; 5.2 Growth Kinetics of Perfect Faces; Mononuclear layer-by-layer growth; Multinuclear monolayer formation; Deposition kinetics on quasi-perfect crystal faces; 5.3 Real Crystal Faces; Dislocations; Spiral growth mechanism; Theory of spiral growth; Growth morphology Steady state and transient current densities |
| Record Nr. | UNINA-9910144261803321 |
Budevski E (Evgeni)
|
||
| Weinheim ; ; New York, : VCH, c1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electrochemical phase formation and growth [[electronic resource] ] : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz
| Electrochemical phase formation and growth [[electronic resource] ] : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz |
| Autore | Budevski E (Evgeni) |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH, c1996 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
541.37
670.7/32 670.732 |
| Altri autori (Persone) |
StaikovGeorgi
LorenzW. J |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electroplating
Metals - Surfaces Crystal growth |
| ISBN |
1-281-75852-3
9786611758523 3-527-61493-1 3-527-61492-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Electrochemical Phase Formation and Growth; Contents; 1 Fundamentals of Electrocrystallization of Metals; 1.1 Thermodynamic and Kinetic Aspects; 1.2 Metal Deposition Mechanisms; 1.3 Topics of this Book; 2 Crystalline Metal Surfaces; 2.1 Structural Aspects; Close-packed 2D and 3D crystal structures; Crystal imperfections and surface inhomogeneities; Surface reconstruction; Surface roughness and the kink position; Step roughness; 2.2 Atomic Dynamics; Atom exchange frequencies; Local, partial, and overall current densities; Kink atoms and the Nernst equilibrium potential
Exchange current density of kink atomsConcentration of adatoms; Exchange current density of adatoms; Mean residence time and surface displacement of adatoms; 2.3 Surface Profile Mobility; Surface diffusion and mean displacement of adatoms; Surface diffusion . The exact solution; Direct transfer; Current density on a stepped crystal face; 2.4 Conclusions; 3 Underpotential Deposition of Metals-2D Phases; 3.1 Historical Background; 3.2 Phenomenology; 3.3 Thermodynamics; Thermodynamic formalism; Adsorption isotherm models; Experimental results; 3.4 Structures of 2D Meads Phases Degree of registryInternal strain; Electrochemical results; Comparative and ex situ UHV results; In situ surface analytical results; 3.5 Kinetics; Quasi-homogeneous substrate surface approach; Inhomogeneous substrate surface approach; Phase transitions; 3.6 2D and 3D Me-S Alloy Formation; Phenomenology; Thermodynamics; Structures of 2D and 3D Me-alloys; Kinetics; 3.7 Conclusion; 4 Initial Stages of Bulk Phase Formation; 4.1 Equilibrium Form of Crystals and Forms of Growth; Equilibrium form; Crystal-substrate interaction; Gibbs-Wulff-Kaishew theorem; Two dimensional crystal; Forms of growth Energy of cluster formation3D nucleation; 2D nucleation; Gibbs-Thomson equation; 4.2 Nucleation Rate; Classical approach (Volmer and Weber); Kinetic approach (Becker and Doering); Binding energies and energy of nucleation; Atomistic model; Nucleation rate equation; Small cluster model; Experimental results; 4.3 3D Phase Formation on UPD Modified Foreign Substrate Surfaces; UPD-OPD transitions; Nucleation and growth; Epitaxy; Experimental results; 4.4 Conclusions; 5 Growth of Crystalline Faces; 5.1 Dislocation-Free Crystal Faces; Preparation of single crystal faces by electrodeposition Double pulse techniqueNucleation rate-overvoltage dependence; Time distribution of the nucleation events; Form of growth of monatomic layers; Propagation rate of monatomic steps; Space distribution of nucleation events; Propagation rate of polyatomic steps; Mechanism of metal deposition and adatom concentration; 5.2 Growth Kinetics of Perfect Faces; Mononuclear layer-by-layer growth; Multinuclear monolayer formation; Deposition kinetics on quasi-perfect crystal faces; 5.3 Real Crystal Faces; Dislocations; Spiral growth mechanism; Theory of spiral growth; Growth morphology Steady state and transient current densities |
| Record Nr. | UNISA-996203158703316 |
|
Budevski E (Evgeni)
|
||
| Weinheim ; ; New York, : VCH, c1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Electrochemical phase formation and growth [[electronic resource] ] : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz
| Electrochemical phase formation and growth [[electronic resource] ] : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz |
| Autore | Budevski E (Evgeni) |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH, c1996 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
541.37
670.7/32 670.732 |
| Altri autori (Persone) |
StaikovGeorgi
LorenzW. J |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electroplating
Metals - Surfaces Crystal growth |
| ISBN |
1-281-75852-3
9786611758523 3-527-61493-1 3-527-61492-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Electrochemical Phase Formation and Growth; Contents; 1 Fundamentals of Electrocrystallization of Metals; 1.1 Thermodynamic and Kinetic Aspects; 1.2 Metal Deposition Mechanisms; 1.3 Topics of this Book; 2 Crystalline Metal Surfaces; 2.1 Structural Aspects; Close-packed 2D and 3D crystal structures; Crystal imperfections and surface inhomogeneities; Surface reconstruction; Surface roughness and the kink position; Step roughness; 2.2 Atomic Dynamics; Atom exchange frequencies; Local, partial, and overall current densities; Kink atoms and the Nernst equilibrium potential
Exchange current density of kink atomsConcentration of adatoms; Exchange current density of adatoms; Mean residence time and surface displacement of adatoms; 2.3 Surface Profile Mobility; Surface diffusion and mean displacement of adatoms; Surface diffusion . The exact solution; Direct transfer; Current density on a stepped crystal face; 2.4 Conclusions; 3 Underpotential Deposition of Metals-2D Phases; 3.1 Historical Background; 3.2 Phenomenology; 3.3 Thermodynamics; Thermodynamic formalism; Adsorption isotherm models; Experimental results; 3.4 Structures of 2D Meads Phases Degree of registryInternal strain; Electrochemical results; Comparative and ex situ UHV results; In situ surface analytical results; 3.5 Kinetics; Quasi-homogeneous substrate surface approach; Inhomogeneous substrate surface approach; Phase transitions; 3.6 2D and 3D Me-S Alloy Formation; Phenomenology; Thermodynamics; Structures of 2D and 3D Me-alloys; Kinetics; 3.7 Conclusion; 4 Initial Stages of Bulk Phase Formation; 4.1 Equilibrium Form of Crystals and Forms of Growth; Equilibrium form; Crystal-substrate interaction; Gibbs-Wulff-Kaishew theorem; Two dimensional crystal; Forms of growth Energy of cluster formation3D nucleation; 2D nucleation; Gibbs-Thomson equation; 4.2 Nucleation Rate; Classical approach (Volmer and Weber); Kinetic approach (Becker and Doering); Binding energies and energy of nucleation; Atomistic model; Nucleation rate equation; Small cluster model; Experimental results; 4.3 3D Phase Formation on UPD Modified Foreign Substrate Surfaces; UPD-OPD transitions; Nucleation and growth; Epitaxy; Experimental results; 4.4 Conclusions; 5 Growth of Crystalline Faces; 5.1 Dislocation-Free Crystal Faces; Preparation of single crystal faces by electrodeposition Double pulse techniqueNucleation rate-overvoltage dependence; Time distribution of the nucleation events; Form of growth of monatomic layers; Propagation rate of monatomic steps; Space distribution of nucleation events; Propagation rate of polyatomic steps; Mechanism of metal deposition and adatom concentration; 5.2 Growth Kinetics of Perfect Faces; Mononuclear layer-by-layer growth; Multinuclear monolayer formation; Deposition kinetics on quasi-perfect crystal faces; 5.3 Real Crystal Faces; Dislocations; Spiral growth mechanism; Theory of spiral growth; Growth morphology Steady state and transient current densities |
| Record Nr. | UNINA-9910830791003321 |
|
Budevski E (Evgeni)
|
||
| Weinheim ; ; New York, : VCH, c1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electrochemical phase formation and growth : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz
| Electrochemical phase formation and growth : an introduction to the initial stages of metal deposition / / E. Budevski, G. Staikov, W.J. Lorenz |
| Autore | Budevski E (Evgeni) |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH, c1996 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
541.37
670.7/32 670.732 |
| Altri autori (Persone) |
StaikovGeorgi
LorenzW. J |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electroplating
Metals - Surfaces Crystal growth |
| ISBN |
1-281-75852-3
9786611758523 3-527-61493-1 3-527-61492-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Electrochemical Phase Formation and Growth; Contents; 1 Fundamentals of Electrocrystallization of Metals; 1.1 Thermodynamic and Kinetic Aspects; 1.2 Metal Deposition Mechanisms; 1.3 Topics of this Book; 2 Crystalline Metal Surfaces; 2.1 Structural Aspects; Close-packed 2D and 3D crystal structures; Crystal imperfections and surface inhomogeneities; Surface reconstruction; Surface roughness and the kink position; Step roughness; 2.2 Atomic Dynamics; Atom exchange frequencies; Local, partial, and overall current densities; Kink atoms and the Nernst equilibrium potential
Exchange current density of kink atomsConcentration of adatoms; Exchange current density of adatoms; Mean residence time and surface displacement of adatoms; 2.3 Surface Profile Mobility; Surface diffusion and mean displacement of adatoms; Surface diffusion . The exact solution; Direct transfer; Current density on a stepped crystal face; 2.4 Conclusions; 3 Underpotential Deposition of Metals-2D Phases; 3.1 Historical Background; 3.2 Phenomenology; 3.3 Thermodynamics; Thermodynamic formalism; Adsorption isotherm models; Experimental results; 3.4 Structures of 2D Meads Phases Degree of registryInternal strain; Electrochemical results; Comparative and ex situ UHV results; In situ surface analytical results; 3.5 Kinetics; Quasi-homogeneous substrate surface approach; Inhomogeneous substrate surface approach; Phase transitions; 3.6 2D and 3D Me-S Alloy Formation; Phenomenology; Thermodynamics; Structures of 2D and 3D Me-alloys; Kinetics; 3.7 Conclusion; 4 Initial Stages of Bulk Phase Formation; 4.1 Equilibrium Form of Crystals and Forms of Growth; Equilibrium form; Crystal-substrate interaction; Gibbs-Wulff-Kaishew theorem; Two dimensional crystal; Forms of growth Energy of cluster formation3D nucleation; 2D nucleation; Gibbs-Thomson equation; 4.2 Nucleation Rate; Classical approach (Volmer and Weber); Kinetic approach (Becker and Doering); Binding energies and energy of nucleation; Atomistic model; Nucleation rate equation; Small cluster model; Experimental results; 4.3 3D Phase Formation on UPD Modified Foreign Substrate Surfaces; UPD-OPD transitions; Nucleation and growth; Epitaxy; Experimental results; 4.4 Conclusions; 5 Growth of Crystalline Faces; 5.1 Dislocation-Free Crystal Faces; Preparation of single crystal faces by electrodeposition Double pulse techniqueNucleation rate-overvoltage dependence; Time distribution of the nucleation events; Form of growth of monatomic layers; Propagation rate of monatomic steps; Space distribution of nucleation events; Propagation rate of polyatomic steps; Mechanism of metal deposition and adatom concentration; 5.2 Growth Kinetics of Perfect Faces; Mononuclear layer-by-layer growth; Multinuclear monolayer formation; Deposition kinetics on quasi-perfect crystal faces; 5.3 Real Crystal Faces; Dislocations; Spiral growth mechanism; Theory of spiral growth; Growth morphology Steady state and transient current densities |
| Record Nr. | UNINA-9910877455603321 |
|
Budevski E (Evgeni)
|
||
| Weinheim ; ; New York, : VCH, c1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||