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Advanced organic chemistry [[electronic resource] ] : reaction mechanisms / / Reinhard Bruckner
Advanced organic chemistry [[electronic resource] ] : reaction mechanisms / / Reinhard Bruckner
Autore Bruckner Reinhard <1955->
Pubbl/distr/stampa San Diego, : Harcourt/Academic Press, c2002
Descrizione fisica 1 online resource (661 p.)
Disciplina 547/.139
Collana Advanced organic chemistry series
Soggetto topico Organic reaction mechanisms
Soggetto genere / forma Electronic books.
ISBN 1-281-46679-4
9786611466794
0-08-049880-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity
2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions
3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition
4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes
5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution
Record Nr. UNINA-9910458258703321
Bruckner Reinhard <1955->  
San Diego, : Harcourt/Academic Press, c2002
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]]
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]]
Autore Bruckner Reinhard <1955->
Pubbl/distr/stampa San Diego, : Harcourt/Academic Press, c2002
Descrizione fisica 1 online resource (661 p.)
Disciplina 547/.139
Collana Advanced organic chemistry series
Soggetto topico Organic reaction mechanisms
ISBN 1-281-46679-4
9786611466794
0-08-049880-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity
2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions
3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition
4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes
5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution
Record Nr. UNINA-9910784534903321
Bruckner Reinhard <1955->  
San Diego, : Harcourt/Academic Press, c2002
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner
Autore Bruckner Reinhard <1955->
Edizione [1st ed.]
Pubbl/distr/stampa San Diego, : Harcourt/Academic Press, c2002
Descrizione fisica 1 online resource (661 p.)
Disciplina 547/.139
Collana Advanced organic chemistry series
Soggetto topico Organic reaction mechanisms
ISBN 9786611466794
9781281466792
1281466794
9780080498805
0080498809
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity
2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions
3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition
4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes
5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution
Altri titoli varianti Reaction mechanisms
Record Nr. UNINA-9910956928403321
Bruckner Reinhard <1955->  
San Diego, : Harcourt/Academic Press, c2002
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui