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Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn
| Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (483 p.) |
| Disciplina | 541.395 |
| Altri autori (Persone) |
BolmCarsten
HahnF. Ekkehardt |
| Soggetto topico |
Catalysis
Activation (Chemistry) |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-02201-6
9786612022012 3-527-62546-1 3-527-62547-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activating Unreactive Substrates: The Role of Secondary Interactions; Contents; Preface; List of Contributors; 1 Chemistry of Metalated Container Molecules; 1.1 Introduction; 1.2 Metalated Container Molecules: A Brief Overview; 1.3 Metalated Container Molecules of Binucleating Supporting Ligands; 1.3.1 Synthesis; 1.3.2 Coordination Chemistry of Binucleating Supporting Ligands; 1.3.3 Effects of N-alkylation on the Molecular and Electronic Structures of the Complexes; 1.3.4 The Ligand Matrix as a Medium; 1.3.5 Variation, Coordination Modes and Activation of Coligands
1.3.6 Reactivity of the Complexes1.4 Conclusions; References; 2 The Chemistry of Superbasic Guanidines; 2.1 Properties of the Guanidine Functionality; 2.2 Design of Superbasic Proton Sponges; 2.3 Some Perspectives in Proton Sponge Chemistry; 2.4 Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations; 2.5 The Chemistry of Guanidine Copper Complexes; 2.6 The Chemistry of Guanidine Zinc Complexes; 2.7 Conclusions; References; 3 Iron Complexes and Dioxygen Activation; 3.1 Introduction; 3.2 Dinuclear Iron Peroxo Complexes; 3.3 Tripodal Tetradentate Ligands and Derivatives 3.3.1 Tmpa3.3.2 Uns-penp; 3.4 Mononuclear Iron Peroxo Complexes; 3.5 Mononuclear Iron Oxo Species; 3.6 Work in Progress; 3.7 Conclusions; References; 4 Tuning of Structures and Properties of Bispidine Complexes; 4.1 Introduction; 4.2 Jahn-Teller Isomerism with Copper(II) Bispidines; 4.3 Stabilization of High-spin Ferryl Complexes; 4.4 Jahn-Teller-distorted Cobalt(III) Complexes; 4.5 Conclusions; References; 5 Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis; 5.1 Introduction; 5.2 Phosphine Ligands 5.2.1 Cooperative Effects for Ligand Self-organization5.2.2 Phosphines with Pyrazole and Pyrimidine Substituents; 5.3 Nitrogen Donor Ligands Without Phosphorus Sites; 5.4 Conclusion; References; 6 Square-Pyramidal Coordinated Phosphine Iron Fragments: A Tale of the Unexpected; 6.1 Introduction; 6.2 Polyphosphine Ligands with Three and Four Coordinating Arms; 6.3 C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands; 6.4 Mechanistic Considerations; 6.5 Conclusion; References 7 Regioselective Catalytic Activity of Complexes with NH,NR-substituted Heterocyclic Carbene Ligands7.1 Introduction; 7.2 Concept of Regioselective Substrate Activation; 7.3 Synthesis of Complexes with NH,NR-stabilized NHC Ligands; 7.4 Preparation of Substrates for Catalytic Experiments; 7.5 Catalysis Experiments; 7.6 Conclusions and Summary; References; 8 Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo-supramolecular Chemistry; 8.1 Introduction 8.2 Syntheses and Electronic Structures of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes |
| Record Nr. | UNINA-9910146101703321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn
| Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (483 p.) |
| Disciplina | 541.395 |
| Altri autori (Persone) |
BolmCarsten
HahnF. Ekkehardt |
| Soggetto topico |
Catalysis
Activation (Chemistry) |
| ISBN |
1-282-02201-6
9786612022012 3-527-62546-1 3-527-62547-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activating Unreactive Substrates: The Role of Secondary Interactions; Contents; Preface; List of Contributors; 1 Chemistry of Metalated Container Molecules; 1.1 Introduction; 1.2 Metalated Container Molecules: A Brief Overview; 1.3 Metalated Container Molecules of Binucleating Supporting Ligands; 1.3.1 Synthesis; 1.3.2 Coordination Chemistry of Binucleating Supporting Ligands; 1.3.3 Effects of N-alkylation on the Molecular and Electronic Structures of the Complexes; 1.3.4 The Ligand Matrix as a Medium; 1.3.5 Variation, Coordination Modes and Activation of Coligands
1.3.6 Reactivity of the Complexes1.4 Conclusions; References; 2 The Chemistry of Superbasic Guanidines; 2.1 Properties of the Guanidine Functionality; 2.2 Design of Superbasic Proton Sponges; 2.3 Some Perspectives in Proton Sponge Chemistry; 2.4 Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations; 2.5 The Chemistry of Guanidine Copper Complexes; 2.6 The Chemistry of Guanidine Zinc Complexes; 2.7 Conclusions; References; 3 Iron Complexes and Dioxygen Activation; 3.1 Introduction; 3.2 Dinuclear Iron Peroxo Complexes; 3.3 Tripodal Tetradentate Ligands and Derivatives 3.3.1 Tmpa3.3.2 Uns-penp; 3.4 Mononuclear Iron Peroxo Complexes; 3.5 Mononuclear Iron Oxo Species; 3.6 Work in Progress; 3.7 Conclusions; References; 4 Tuning of Structures and Properties of Bispidine Complexes; 4.1 Introduction; 4.2 Jahn-Teller Isomerism with Copper(II) Bispidines; 4.3 Stabilization of High-spin Ferryl Complexes; 4.4 Jahn-Teller-distorted Cobalt(III) Complexes; 4.5 Conclusions; References; 5 Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis; 5.1 Introduction; 5.2 Phosphine Ligands 5.2.1 Cooperative Effects for Ligand Self-organization5.2.2 Phosphines with Pyrazole and Pyrimidine Substituents; 5.3 Nitrogen Donor Ligands Without Phosphorus Sites; 5.4 Conclusion; References; 6 Square-Pyramidal Coordinated Phosphine Iron Fragments: A Tale of the Unexpected; 6.1 Introduction; 6.2 Polyphosphine Ligands with Three and Four Coordinating Arms; 6.3 C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands; 6.4 Mechanistic Considerations; 6.5 Conclusion; References 7 Regioselective Catalytic Activity of Complexes with NH,NR-substituted Heterocyclic Carbene Ligands7.1 Introduction; 7.2 Concept of Regioselective Substrate Activation; 7.3 Synthesis of Complexes with NH,NR-stabilized NHC Ligands; 7.4 Preparation of Substrates for Catalytic Experiments; 7.5 Catalysis Experiments; 7.6 Conclusions and Summary; References; 8 Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo-supramolecular Chemistry; 8.1 Introduction 8.2 Syntheses and Electronic Structures of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes |
| Record Nr. | UNINA-9910830494203321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn
| Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (483 p.) |
| Disciplina | 541.395 |
| Altri autori (Persone) |
BolmCarsten
HahnF. Ekkehardt |
| Soggetto topico |
Catalysis
Activation (Chemistry) |
| ISBN |
1-282-02201-6
9786612022012 3-527-62546-1 3-527-62547-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activating Unreactive Substrates: The Role of Secondary Interactions; Contents; Preface; List of Contributors; 1 Chemistry of Metalated Container Molecules; 1.1 Introduction; 1.2 Metalated Container Molecules: A Brief Overview; 1.3 Metalated Container Molecules of Binucleating Supporting Ligands; 1.3.1 Synthesis; 1.3.2 Coordination Chemistry of Binucleating Supporting Ligands; 1.3.3 Effects of N-alkylation on the Molecular and Electronic Structures of the Complexes; 1.3.4 The Ligand Matrix as a Medium; 1.3.5 Variation, Coordination Modes and Activation of Coligands
1.3.6 Reactivity of the Complexes1.4 Conclusions; References; 2 The Chemistry of Superbasic Guanidines; 2.1 Properties of the Guanidine Functionality; 2.2 Design of Superbasic Proton Sponges; 2.3 Some Perspectives in Proton Sponge Chemistry; 2.4 Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations; 2.5 The Chemistry of Guanidine Copper Complexes; 2.6 The Chemistry of Guanidine Zinc Complexes; 2.7 Conclusions; References; 3 Iron Complexes and Dioxygen Activation; 3.1 Introduction; 3.2 Dinuclear Iron Peroxo Complexes; 3.3 Tripodal Tetradentate Ligands and Derivatives 3.3.1 Tmpa3.3.2 Uns-penp; 3.4 Mononuclear Iron Peroxo Complexes; 3.5 Mononuclear Iron Oxo Species; 3.6 Work in Progress; 3.7 Conclusions; References; 4 Tuning of Structures and Properties of Bispidine Complexes; 4.1 Introduction; 4.2 Jahn-Teller Isomerism with Copper(II) Bispidines; 4.3 Stabilization of High-spin Ferryl Complexes; 4.4 Jahn-Teller-distorted Cobalt(III) Complexes; 4.5 Conclusions; References; 5 Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis; 5.1 Introduction; 5.2 Phosphine Ligands 5.2.1 Cooperative Effects for Ligand Self-organization5.2.2 Phosphines with Pyrazole and Pyrimidine Substituents; 5.3 Nitrogen Donor Ligands Without Phosphorus Sites; 5.4 Conclusion; References; 6 Square-Pyramidal Coordinated Phosphine Iron Fragments: A Tale of the Unexpected; 6.1 Introduction; 6.2 Polyphosphine Ligands with Three and Four Coordinating Arms; 6.3 C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands; 6.4 Mechanistic Considerations; 6.5 Conclusion; References 7 Regioselective Catalytic Activity of Complexes with NH,NR-substituted Heterocyclic Carbene Ligands7.1 Introduction; 7.2 Concept of Regioselective Substrate Activation; 7.3 Synthesis of Complexes with NH,NR-stabilized NHC Ligands; 7.4 Preparation of Substrates for Catalytic Experiments; 7.5 Catalysis Experiments; 7.6 Conclusions and Summary; References; 8 Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo-supramolecular Chemistry; 8.1 Introduction 8.2 Syntheses and Electronic Structures of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes |
| Record Nr. | UNINA-9910840524803321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosulfur chemistry in asymmetric synthesis [[electronic resource] /] / edited by Takeshi Toru and Carsten Bolm
| Organosulfur chemistry in asymmetric synthesis [[electronic resource] /] / edited by Takeshi Toru and Carsten Bolm |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2008 |
| Descrizione fisica | 1 online resource (450 p.) |
| Disciplina | 547.06045 |
| Altri autori (Persone) |
ToruTakeshi
BolmCarsten |
| Soggetto topico |
Organosulfur compounds
Asymmetric synthesis Enantioselective catalysis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-94717-2
9786611947170 3-527-62323-X 3-527-62324-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosulfur Chemistry in Asymmetric Synthesis; Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Chiral Sulfoxides; 1.1 Chiral Sulfoxides; 1.1.1 Introduction; 1.1.2 The Main Routes to Chiral Sulfoxides; 1.2 Use of Chiral Sulfur Precursors; 1.2.1 Sulfinates (Andersen Method); 1.2.2 Diastereoselective Formation of Sulfinates; 1.2.3 Sulfinates from Sulfites; 1.2.4 Sulfinamides; 1.3 Catalytic Enantioselective Sulfide Oxidation; 1.3.1 Titanium Complexes; 1.3.1.1 Diesters of Tartaric Acid; 1.3.1.2 C(2)-Symmetric 1,2-Diols as Ligands; 1.3.1.3 Binaphthol and Derivatives
1.3.1.4 C(3)-Symmetric Triethanolamine Ligands1.3.1.5 Ti (Salen) Catalysts; 1.3.2 Manganese Complexes; 1.3.3 Vanadium Complexes; 1.3.4 Molybdenum Complexes; 1.3.5 Iron Complexes; 1.3.6 Miscellaneous; 1.4 Catalytic Arylation of Sulfenate Anions; 1.5 Enantioselective Oxidation of Sulfides; 1.6 Summary; References; 2 Asymmetric Synthesis of Optically Active Sulfinic Acid Esters; 2.1 Introduction; 2.2 Enantiomeric Sulfinic Acid Esters; 2.3 Diastereomeric Sulfinic Acid Esters; References; 3 Asymmetric Transformations Mediated by Sulfinyl Groups; 3.1 Introduction 3.2 Nucleophilic Additions to C=O and C=N Bonds Mediated by α-Sulfinyl Groups3.2.1 β-Ketosulfoxides; 3.2.1.1 Reduction Reactions; 3.2.1.2 Alkylation Reactions; 3.2.1.3 Aldol Reaction with β-Ketosulfoxides Acting as Electrophiles; 3.2.1.4 Hydrocyanation Reactions; 3.2.2 β-Imino(enamino)sulfoxides; 3.3 Conjugate Additions to α,β-Unsaturated Sulfoxides; 3.3.1 Nucleophilic Additions; 3.3.1.1 (E) and (Z)-2-Substituted Vinyl Sulfoxides; 3.3.1.2 1-Substituted Vinyl Sulfoxides; 3.3.2 Tandem Reactions; 3.3.3 Radical Conjugate Additions and Other Reactions; 3.4 Cycloadditions 3.4.1 Asymmetric Diels-Alder Reactions3.4.1.1 Sulfinyl Dienophiles; 3.4.1.2 Sulfinyl Dienes; 3.4.2 Asymmetric Hetero Diels-Alder Reactions; 3.4.3 Asymmetric 1,3-Dipolar Cycloadditions; 3.4.3.1 Reactions with Nitrones; 3.4.3.2 Reactions with Azomethine Ylides; 3.4.3.3 Reactions with Nitrile Oxides; 3.4.3.4 Reactions with Diazoalkanes; 3.4.3.5 Reactions with Other Dipoles; 3.4.4 Other Asymmetric Cycloadditions; 3.5 Asymmetric Processes Stereocontrolled by Remote Sulfoxides; 3.5.1 Nucleophilic Processes; 3.5.1.1 Reactions with Sulfinylated Electrophiles 3.5.1.2 Reactions with Sulfinylated Nucleophiles3.6 Asymmetric Pummerer Reaction; References; 4 Synthesis and Applications of Chiral Dithioacetal Derivatives; 4.1 Introduction; 4.2 Lithiated Dithianes; 4.3 Alternative Methods; 4.4 Oxidation Methods for the Construction of Chiral Dithioacetal Derivatives and Applications in Synthesis; 4.5 Applications of Chiral Dithioacetal Derivatives in Natural Product and Biologically Active Compound Synthesis; 4.6 Summary; References; 5 Synthesis and Use of Chiral Sulfur Ylides; 5.1 Introduction; 5.1.1 Reactions of Sulfonium Ylides 5.1.2 Methods of Preparation |
| Record Nr. | UNINA-9910144113103321 |
| Weinheim, : Wiley-VCH, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosulfur chemistry in asymmetric synthesis [[electronic resource] /] / edited by Takeshi Toru and Carsten Bolm
| Organosulfur chemistry in asymmetric synthesis [[electronic resource] /] / edited by Takeshi Toru and Carsten Bolm |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2008 |
| Descrizione fisica | 1 online resource (450 p.) |
| Disciplina | 547.06045 |
| Altri autori (Persone) |
ToruTakeshi
BolmCarsten |
| Soggetto topico |
Organosulfur compounds
Asymmetric synthesis Enantioselective catalysis |
| ISBN |
1-281-94717-2
9786611947170 3-527-62323-X 3-527-62324-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosulfur Chemistry in Asymmetric Synthesis; Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Chiral Sulfoxides; 1.1 Chiral Sulfoxides; 1.1.1 Introduction; 1.1.2 The Main Routes to Chiral Sulfoxides; 1.2 Use of Chiral Sulfur Precursors; 1.2.1 Sulfinates (Andersen Method); 1.2.2 Diastereoselective Formation of Sulfinates; 1.2.3 Sulfinates from Sulfites; 1.2.4 Sulfinamides; 1.3 Catalytic Enantioselective Sulfide Oxidation; 1.3.1 Titanium Complexes; 1.3.1.1 Diesters of Tartaric Acid; 1.3.1.2 C(2)-Symmetric 1,2-Diols as Ligands; 1.3.1.3 Binaphthol and Derivatives
1.3.1.4 C(3)-Symmetric Triethanolamine Ligands1.3.1.5 Ti (Salen) Catalysts; 1.3.2 Manganese Complexes; 1.3.3 Vanadium Complexes; 1.3.4 Molybdenum Complexes; 1.3.5 Iron Complexes; 1.3.6 Miscellaneous; 1.4 Catalytic Arylation of Sulfenate Anions; 1.5 Enantioselective Oxidation of Sulfides; 1.6 Summary; References; 2 Asymmetric Synthesis of Optically Active Sulfinic Acid Esters; 2.1 Introduction; 2.2 Enantiomeric Sulfinic Acid Esters; 2.3 Diastereomeric Sulfinic Acid Esters; References; 3 Asymmetric Transformations Mediated by Sulfinyl Groups; 3.1 Introduction 3.2 Nucleophilic Additions to C=O and C=N Bonds Mediated by α-Sulfinyl Groups3.2.1 β-Ketosulfoxides; 3.2.1.1 Reduction Reactions; 3.2.1.2 Alkylation Reactions; 3.2.1.3 Aldol Reaction with β-Ketosulfoxides Acting as Electrophiles; 3.2.1.4 Hydrocyanation Reactions; 3.2.2 β-Imino(enamino)sulfoxides; 3.3 Conjugate Additions to α,β-Unsaturated Sulfoxides; 3.3.1 Nucleophilic Additions; 3.3.1.1 (E) and (Z)-2-Substituted Vinyl Sulfoxides; 3.3.1.2 1-Substituted Vinyl Sulfoxides; 3.3.2 Tandem Reactions; 3.3.3 Radical Conjugate Additions and Other Reactions; 3.4 Cycloadditions 3.4.1 Asymmetric Diels-Alder Reactions3.4.1.1 Sulfinyl Dienophiles; 3.4.1.2 Sulfinyl Dienes; 3.4.2 Asymmetric Hetero Diels-Alder Reactions; 3.4.3 Asymmetric 1,3-Dipolar Cycloadditions; 3.4.3.1 Reactions with Nitrones; 3.4.3.2 Reactions with Azomethine Ylides; 3.4.3.3 Reactions with Nitrile Oxides; 3.4.3.4 Reactions with Diazoalkanes; 3.4.3.5 Reactions with Other Dipoles; 3.4.4 Other Asymmetric Cycloadditions; 3.5 Asymmetric Processes Stereocontrolled by Remote Sulfoxides; 3.5.1 Nucleophilic Processes; 3.5.1.1 Reactions with Sulfinylated Electrophiles 3.5.1.2 Reactions with Sulfinylated Nucleophiles3.6 Asymmetric Pummerer Reaction; References; 4 Synthesis and Applications of Chiral Dithioacetal Derivatives; 4.1 Introduction; 4.2 Lithiated Dithianes; 4.3 Alternative Methods; 4.4 Oxidation Methods for the Construction of Chiral Dithioacetal Derivatives and Applications in Synthesis; 4.5 Applications of Chiral Dithioacetal Derivatives in Natural Product and Biologically Active Compound Synthesis; 4.6 Summary; References; 5 Synthesis and Use of Chiral Sulfur Ylides; 5.1 Introduction; 5.1.1 Reactions of Sulfonium Ylides 5.1.2 Methods of Preparation |
| Record Nr. | UNINA-9910830668303321 |
| Weinheim, : Wiley-VCH, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosulfur chemistry in asymmetric synthesis [[electronic resource] /] / edited by Takeshi Toru and Carsten Bolm
| Organosulfur chemistry in asymmetric synthesis [[electronic resource] /] / edited by Takeshi Toru and Carsten Bolm |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2008 |
| Descrizione fisica | 1 online resource (450 p.) |
| Disciplina | 547.06045 |
| Altri autori (Persone) |
ToruTakeshi
BolmCarsten |
| Soggetto topico |
Organosulfur compounds
Asymmetric synthesis Enantioselective catalysis |
| ISBN |
1-281-94717-2
9786611947170 3-527-62323-X 3-527-62324-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosulfur Chemistry in Asymmetric Synthesis; Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Chiral Sulfoxides; 1.1 Chiral Sulfoxides; 1.1.1 Introduction; 1.1.2 The Main Routes to Chiral Sulfoxides; 1.2 Use of Chiral Sulfur Precursors; 1.2.1 Sulfinates (Andersen Method); 1.2.2 Diastereoselective Formation of Sulfinates; 1.2.3 Sulfinates from Sulfites; 1.2.4 Sulfinamides; 1.3 Catalytic Enantioselective Sulfide Oxidation; 1.3.1 Titanium Complexes; 1.3.1.1 Diesters of Tartaric Acid; 1.3.1.2 C(2)-Symmetric 1,2-Diols as Ligands; 1.3.1.3 Binaphthol and Derivatives
1.3.1.4 C(3)-Symmetric Triethanolamine Ligands1.3.1.5 Ti (Salen) Catalysts; 1.3.2 Manganese Complexes; 1.3.3 Vanadium Complexes; 1.3.4 Molybdenum Complexes; 1.3.5 Iron Complexes; 1.3.6 Miscellaneous; 1.4 Catalytic Arylation of Sulfenate Anions; 1.5 Enantioselective Oxidation of Sulfides; 1.6 Summary; References; 2 Asymmetric Synthesis of Optically Active Sulfinic Acid Esters; 2.1 Introduction; 2.2 Enantiomeric Sulfinic Acid Esters; 2.3 Diastereomeric Sulfinic Acid Esters; References; 3 Asymmetric Transformations Mediated by Sulfinyl Groups; 3.1 Introduction 3.2 Nucleophilic Additions to C=O and C=N Bonds Mediated by α-Sulfinyl Groups3.2.1 β-Ketosulfoxides; 3.2.1.1 Reduction Reactions; 3.2.1.2 Alkylation Reactions; 3.2.1.3 Aldol Reaction with β-Ketosulfoxides Acting as Electrophiles; 3.2.1.4 Hydrocyanation Reactions; 3.2.2 β-Imino(enamino)sulfoxides; 3.3 Conjugate Additions to α,β-Unsaturated Sulfoxides; 3.3.1 Nucleophilic Additions; 3.3.1.1 (E) and (Z)-2-Substituted Vinyl Sulfoxides; 3.3.1.2 1-Substituted Vinyl Sulfoxides; 3.3.2 Tandem Reactions; 3.3.3 Radical Conjugate Additions and Other Reactions; 3.4 Cycloadditions 3.4.1 Asymmetric Diels-Alder Reactions3.4.1.1 Sulfinyl Dienophiles; 3.4.1.2 Sulfinyl Dienes; 3.4.2 Asymmetric Hetero Diels-Alder Reactions; 3.4.3 Asymmetric 1,3-Dipolar Cycloadditions; 3.4.3.1 Reactions with Nitrones; 3.4.3.2 Reactions with Azomethine Ylides; 3.4.3.3 Reactions with Nitrile Oxides; 3.4.3.4 Reactions with Diazoalkanes; 3.4.3.5 Reactions with Other Dipoles; 3.4.4 Other Asymmetric Cycloadditions; 3.5 Asymmetric Processes Stereocontrolled by Remote Sulfoxides; 3.5.1 Nucleophilic Processes; 3.5.1.1 Reactions with Sulfinylated Electrophiles 3.5.1.2 Reactions with Sulfinylated Nucleophiles3.6 Asymmetric Pummerer Reaction; References; 4 Synthesis and Applications of Chiral Dithioacetal Derivatives; 4.1 Introduction; 4.2 Lithiated Dithianes; 4.3 Alternative Methods; 4.4 Oxidation Methods for the Construction of Chiral Dithioacetal Derivatives and Applications in Synthesis; 4.5 Applications of Chiral Dithioacetal Derivatives in Natural Product and Biologically Active Compound Synthesis; 4.6 Summary; References; 5 Synthesis and Use of Chiral Sulfur Ylides; 5.1 Introduction; 5.1.1 Reactions of Sulfonium Ylides 5.1.2 Methods of Preparation |
| Record Nr. | UNINA-9910840842003321 |
| Weinheim, : Wiley-VCH, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Transition metals for organic synthesis : building blocks and fine chemicals / / Matthias Beller, Carsten Bolm
| Transition metals for organic synthesis : building blocks and fine chemicals / / Matthias Beller, Carsten Bolm |
| Edizione | [Second and expanded edition] |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley-VCH, 2004 |
| Descrizione fisica | 1 online resource (2 volumes) |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Transition metal compounds Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN | 3-527-61940-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910144277703321 |
| [Place of publication not identified], : Wiley-VCH, 2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals
| Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals |
| Autore | Beller Matthias |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH Imprint, 1998 |
| Descrizione fisica | 1 online resource (xxxiii, 595 pages) : illustrations |
| Disciplina | 541.395 |
| Soggetto topico |
Organic compounds - Synthesis
Transition metal catalysts Transition metals |
| ISBN | 3-527-61939-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Volume 1 -- pt. 1. General -- Basic aspects of organic synthesis with transition metals / Barry M. Trost -- Concepts for the use of transition metals in industrial fine chemical synthesis / Wilhelm Keim -- pt. 2. Transition metal-catalyzed reactions -- New opportunities in hydroformylation: selected syntheses of intermediates and fine chemicals / Carlo Botteghi -- Hydrocarboxylation and hydroesterification reactions catalyzed by transition metal complexes / Bassam El Ali -- Palladium-catalyzed carbonylation of allylic and propargylic compounds / Jiro Tsuji -- Amidocarbonylation / Klaus Kühlein -- Transition metal-catalyzed alkene and alkyne hydrocyanations / Albert L. Casalnuovo -- Cyclopropanation / Andreas Pfaltz -- Cyclomerization of alkynes / Helmut Bönnemann -- Intramolecular hydroacylation and reductive cyclizaton / William E. Crowe -- Isomerization of olefin and the related reactions / Sei Otsuka -- Transition metal-catalyzed cross coupling reactions / Holger Geissler -- Transition metal-catalyzed C-N and C-O bond-forming reactions / Matthias Beller -- Catalytic enantioselective alkylation of alkenes by chiral metallocenes / Amir H. Hoveyda -- Palladium-catalyzed olefinations of aryl halides (Heck reactions) and related transformations / M. Beller -- Coupling reactions involving CH activation / Gerald Dyker -- Palladium-catalyzed allylic substitutions / Andreas Heumann -- Pallidium-catalyzed cyclization of allylic acetates with alkenes and allenes / Takashi Takahashi -- Application of olefin metathesis / Matthias Schuster -- Homometallic lanthanoids in synthesis: lanthanide triflate-catalyzed synthetic reactions / Shu Kobayashi -- Heterometallic lanthanoids in organic synthesis / Masakatsu Shibasaki -- Metal-catalyzed addition of cyanides to aldehydes / Nobuki Oguni -- pt. 3. Transition metal-mediated reactions -- Fischer-type carbene complexes / Karl Heinz Dötz -- Titanium-carbene mediated reactions / Nicos A. Petasis -- The McMurray reaction and related transformations / Alois Fürstner -- Vanadium mediated couplings / Heiner Jendralla -- Chromium(II)-mediated C-C coupling reactions / David M. Hodgson -- Samarium-mediated reactions / Xin Gu -- Manganese(III)-based oxidative free-radical cyclizations / Barry B. Snider -- Titanium-mediated reactions / Rudolf O. Duthaler -- Zinc-mediated reactions / Paul Knochel -- Conjugate addition reactions / Alexandre Alexakis -- Carbometalation reactions / Ilane Marek -- Iron Acyl complexes / Karola Rück-Braun -- Iron-diene complexes / Hans-Joachim Knölker -- Chromium-arene complexes / Hans-Günther Schmalz -- Pauson-Khand reactions / N. Jeong . Volume 2 -- pt. 1. Reductions -- Homogeneous hydrogenations / Armin Börner -- Heterogeneous hydrogenation: a valuable tool for the synthetic chemist / H.U. Blaster -- Transferhydrogenations / Serafino Gladiali -- Hydrosilylations / Keiji Yamamoto -- Metal-catalyzed hydroboration reactions / Gregory C. Fu -- The reduction of imines and enamines with transition metal hydrides / Bakthan Singaram -- pt. 2. Oxidations -- Basics of oxidations / Karl Anker Jøorgensen -- Carbon-hydrogen bond oxidations catalyzed by transition metal complexes / Bernard Meunier -- Allylic oxidations -- Metal-catalyzed Baeyer-Villiger reactions / Carsten Bolm -- Asymmetric dihydroxylation / Hartmuth C. Kolb -- Asymmetric aminohydroxylation / Hartmuth C. Kolb -- Epoxidations -- Wacker oxidations / Ben L. Feringa -- Hydroamination of alkenes and alkynes / Thomas E. Müller -- Heteropolyanions for organic synthesis / Ronny Neumann -- Rhenium-catalyzed epoxidations / R.W. Fischer -- Aerobic, metal-catalyzed oxidation of alcohols / Istvän E. Markõ -- Oxidations of heteroatoms -- pt. 3. Special topics -- Supported transition metals catalysis / J.M. Basset -- Transition metals for fine chemicals and organic synthesis, two-phase catalysis / D. Sinou -- Transition metals in photocatalysis / H. Hennig -- Transition metals in radiation induced reactions for organic synthesis: applications of ultrasound / Dietmar Peters -- Applications of microwaves / Jürgen Herwig -- Application of high pressure in catalysis / Oliver Reiser. |
| Record Nr. | UNISA-996197428203316 |
Beller Matthias
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| [Place of publication not identified], : Wiley VCH Imprint, 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
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