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Luminescence of lanthanide ions in coordination compounds and nanomaterials / / edited by Ana de Bettencourt-Dias
| Luminescence of lanthanide ions in coordination compounds and nanomaterials / / edited by Ana de Bettencourt-Dias |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2014 |
| Descrizione fisica | 1 online resource (387 p.) |
| Disciplina | 546/.41 |
| Soggetto topico |
Nanostructured materials
Luminescence Rare earth metals - Optical properties Coordination compounds |
| ISBN |
1-118-68281-5
1-118-68276-9 1-118-68274-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials; Contents; List of Contributors; Preface; 1 Introduction to Lanthanide Ion Luminescence; 1.1 History of Lanthanide Ion Luminescence; 1.2 Electronic Configuration of the +III Oxidation State; 1.2.1 The 4f Orbitals; 1.2.2 Energy Level Term Symbols; 1.3 The Nature of the f-f Transitions; 1.3.1 Hamiltonian in Central Field Approximation and Coulomb Interactions; 1.3.2 Spin-Orbit Coupling; 1.3.3 Crystal Field or Stark Effects; 1.3.4 The Crystal Field Parameters Bkq and Symmetry; 1.3.5 Energies of Crystal Field Split Terms
1.3.6 Zeeman Effect 1.3.7 Point Charge Electrostatic Model; 1.3.8 Other Methods to Estimate Crystal Field Parameters; 1.3.9 Allowed and Forbidden f-f Transitions; 1.3.10 Induced Electric Dipole Transitions and Their Intensity - Judd-Ofelt Theory; 1.3.11 Transition Probabilities and Branching Ratios; 1.3.12 Hypersensitive Transitions; 1.3.13 Emission Efficiency and Rate Constants; 1.4 Sensitisation Mechanism; 1.4.1 The Antenna Effect; 1.4.2 Non-Radiative Quenching; References; 2 Spectroscopic Techniques and Instrumentation; 2.1 Introduction; 2.2 Instrumentation in Luminescence Spectroscopy 2.2.1 Challenges in Design and Interpretation of Lanthanide Luminescence Experiments 2.2.2 Common Luminescence Experiments; 2.2.3 Basic Design Elements and Configurations in Luminescence Spectrometers; 2.2.4 Luminescence Spectrometer Components and Characteristics; 2.2.5 Recent Advances in Luminescence Instrumentation; 2.3 Measurement of Quantum Yields of Luminescence in the Solid State and in Solution; 2.3.1 Measurement Against a Standard in Solution; 2.3.2 Measurement Against a Standard in the Solid State; 2.3.3 Absolute Measurement with an Integrating Sphere; 2.4 Excited State Lifetimes 2.4.1 Number of Coordinated Solvent Molecules References; 3 Circularly Polarised Luminescence; 3.1 Introduction; 3.1.1 General Aspects: Molecular Chirality; 3.1.2 Chiroptical Tools: from CD to CPL Spectroscopy; 3.2 Theoretical Principles; 3.2.1 General Theory; 3.2.2 CPL Intensity Calculations, Selection Rules, Luminescence Selectivity, and Spectra-Structure Relationship; 3.3 CPL Measurements; 3.3.1 Instrumentation; 3.3.2 Calibration and Standards; 3.3.3 Artifacts in CPL Measurements; 3.3.4 Proposed Instrumental Improvements to Record Eu(III)-Based CPL Signals; 3.4 Survey of CPL Applications 3.4.1 Ln(III)-Containing Systems 3.4.2 Ln(III) Complexes with Achiral Ligands; 3.4.3 Ln(III) Complexes with Chiral Ligands; 3.5 Chiral Ln(III) Complexes to Probe Biologically Relevant Systems; 3.5.1 Sensing through Coordination to the Metal Centre; 3.5.2 Sensing through Coordination to the Antenna/Receptor Groups; 3.6 Concluding Remarks; References; 4 Luminescence Bioimaging with Lanthanide Complexes; 4.1 Introduction; 4.2 Luminescence Microscopy; 4.2.1 Classical Optical Microscopy: a Short Survey; 4.2.2 Principle of Luminescence Microscopy 4.2.3 Principle of Time-resolved Luminescence Microscopy |
| Record Nr. | UNINA-9910132173603321 |
| Chichester, England : , : Wiley, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Luminescence of lanthanide ions in coordination compounds and nanomaterials / / edited by Ana de Bettencourt-Dias
| Luminescence of lanthanide ions in coordination compounds and nanomaterials / / edited by Ana de Bettencourt-Dias |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2014 |
| Descrizione fisica | 1 online resource (387 p.) |
| Disciplina | 546/.41 |
| Soggetto topico |
Nanostructured materials
Luminescence Rare earth metals - Optical properties Coordination compounds |
| ISBN |
1-118-68281-5
1-118-68276-9 1-118-68274-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials; Contents; List of Contributors; Preface; 1 Introduction to Lanthanide Ion Luminescence; 1.1 History of Lanthanide Ion Luminescence; 1.2 Electronic Configuration of the +III Oxidation State; 1.2.1 The 4f Orbitals; 1.2.2 Energy Level Term Symbols; 1.3 The Nature of the f-f Transitions; 1.3.1 Hamiltonian in Central Field Approximation and Coulomb Interactions; 1.3.2 Spin-Orbit Coupling; 1.3.3 Crystal Field or Stark Effects; 1.3.4 The Crystal Field Parameters Bkq and Symmetry; 1.3.5 Energies of Crystal Field Split Terms
1.3.6 Zeeman Effect 1.3.7 Point Charge Electrostatic Model; 1.3.8 Other Methods to Estimate Crystal Field Parameters; 1.3.9 Allowed and Forbidden f-f Transitions; 1.3.10 Induced Electric Dipole Transitions and Their Intensity - Judd-Ofelt Theory; 1.3.11 Transition Probabilities and Branching Ratios; 1.3.12 Hypersensitive Transitions; 1.3.13 Emission Efficiency and Rate Constants; 1.4 Sensitisation Mechanism; 1.4.1 The Antenna Effect; 1.4.2 Non-Radiative Quenching; References; 2 Spectroscopic Techniques and Instrumentation; 2.1 Introduction; 2.2 Instrumentation in Luminescence Spectroscopy 2.2.1 Challenges in Design and Interpretation of Lanthanide Luminescence Experiments 2.2.2 Common Luminescence Experiments; 2.2.3 Basic Design Elements and Configurations in Luminescence Spectrometers; 2.2.4 Luminescence Spectrometer Components and Characteristics; 2.2.5 Recent Advances in Luminescence Instrumentation; 2.3 Measurement of Quantum Yields of Luminescence in the Solid State and in Solution; 2.3.1 Measurement Against a Standard in Solution; 2.3.2 Measurement Against a Standard in the Solid State; 2.3.3 Absolute Measurement with an Integrating Sphere; 2.4 Excited State Lifetimes 2.4.1 Number of Coordinated Solvent Molecules References; 3 Circularly Polarised Luminescence; 3.1 Introduction; 3.1.1 General Aspects: Molecular Chirality; 3.1.2 Chiroptical Tools: from CD to CPL Spectroscopy; 3.2 Theoretical Principles; 3.2.1 General Theory; 3.2.2 CPL Intensity Calculations, Selection Rules, Luminescence Selectivity, and Spectra-Structure Relationship; 3.3 CPL Measurements; 3.3.1 Instrumentation; 3.3.2 Calibration and Standards; 3.3.3 Artifacts in CPL Measurements; 3.3.4 Proposed Instrumental Improvements to Record Eu(III)-Based CPL Signals; 3.4 Survey of CPL Applications 3.4.1 Ln(III)-Containing Systems 3.4.2 Ln(III) Complexes with Achiral Ligands; 3.4.3 Ln(III) Complexes with Chiral Ligands; 3.5 Chiral Ln(III) Complexes to Probe Biologically Relevant Systems; 3.5.1 Sensing through Coordination to the Metal Centre; 3.5.2 Sensing through Coordination to the Antenna/Receptor Groups; 3.6 Concluding Remarks; References; 4 Luminescence Bioimaging with Lanthanide Complexes; 4.1 Introduction; 4.2 Luminescence Microscopy; 4.2.1 Classical Optical Microscopy: a Short Survey; 4.2.2 Principle of Luminescence Microscopy 4.2.3 Principle of Time-resolved Luminescence Microscopy |
| Record Nr. | UNINA-9910819772803321 |
| Chichester, England : , : Wiley, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||