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Electronic structure and properties of transition metal compounds [[electronic resource] ] : introduction to the theory / / Isaac B. Bersuker
| Electronic structure and properties of transition metal compounds [[electronic resource] ] : introduction to the theory / / Isaac B. Bersuker |
| Autore | Bersuker I. B (Isaak Borisovich) |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | New York, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (797 p.) |
| Disciplina |
546.6
546/.6 |
| Collana | Textbook for graduate and advanced undergraduate students |
| Soggetto topico |
Transition metal compounds
Chemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
0-470-92085-8
1-282-68470-1 9786612684708 0-470-57305-8 0-470-57304-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRONIC STRUCTURE AND PROPERTIES OF TRANSITION METAL COMPOUNDS; CONTENTS; Preface; Foreword to the First Edition; Mathematical Symbols; Abbreviations; 1 Introduction: Subject and Methods; 1.1 Objectives; Molecular Engineering and Intuitive Guesswork; Main Objectives of This Book in Comparison with Other Sources; 1.2 Definitions of Chemical Bonding and Transition Metal Coordination System; Chemical Bonding as an Electronic Phenomenon; Definition of Coordination System; 1.3 The Schrödinger Equation; Formulation; Role of Approximations; Summary Notes; References; 2 Atomic States
2.1 One-Electron StatesAngular and Radial Functions; Orbital Overlaps: Hybridized Functions; Spin-Orbital Interaction; Relativistic Atomic Functions; 2.2 Multielectron States: Energy Terms; Electronic Configurations and Terms; Multielectron Wavefunctions; Slater-Condon and Racah Parameters; The Hartree-Fock Method; Summary Notes; Questions; Exercises and Problems; References; 3 Symmetry Ideas and Group-Theoretical Description; 3.1 Symmetry Transformations and Matrices; 3.2 Groups of Symmetry Transformations; Example 3.1. The Symmetry Group of an Octahedral O(h) System and Its Classes 3.3 Representations of Groups and Matrices of Representations3.4 Classification of Molecular Terms and Vibrations, Selection Rules, and Wigner-Eckart Theorem; Example 3.2. Energy Terms of Electronic Configuration e(2); 3.5 Construction of Symmetrized Molecular Orbitals and Normal Vibrations; Example 3.3. Construction of E(g)-Symmetry-Adapted σ MOs for Octahedral O(h) Systems; Example 3.4. Construction of T(2g)-Symmetry-Adapted π MOs for Octahedral O(h) Systems; Example 3.5. Normal Coordinates of a Regular Triangular Molecule X(3); 3.6 The Notion of Double Groups; Summary Notes; Exercises References4 Crystal Field Theory; 4.1 Introduction; Brief History; Main Assumptions; 4.2 Splitting of the Energy Levels of One d Electron in Ligand Fields; Qualitative Aspects and Visual Interpretation; Calculation of the Splitting Magnitude; Example 4.1. Splitting of a d-Electron Term in Octahedral Crystal Fields; Group-Theoretical Analysis; 4.3 Several d Electrons; Case of a Weak Field; Strong Crystal Fields and Low- and High-Spin Complexes; Example 4.2. High- and Low-Spin Octahedral Complexes of Iron; Energy Terms of Strong-Field Configurations Example 5.1. Shortcomings of Mulliken's Definition of Atomic Charges in Molecules |
| Record Nr. | UNINA-9910139203903321 |
Bersuker I. B (Isaak Borisovich)
|
||
| New York, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electronic structure and properties of transition metal compounds [[electronic resource] ] : introduction to the theory / / Isaac B. Bersuker
| Electronic structure and properties of transition metal compounds [[electronic resource] ] : introduction to the theory / / Isaac B. Bersuker |
| Autore | Bersuker I. B (Isaak Borisovich) |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | New York, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (797 p.) |
| Disciplina |
546.6
546/.6 |
| Collana | Textbook for graduate and advanced undergraduate students |
| Soggetto topico |
Transition metal compounds
Chemistry |
| ISBN |
0-470-92085-8
1-282-68470-1 9786612684708 0-470-57305-8 0-470-57304-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRONIC STRUCTURE AND PROPERTIES OF TRANSITION METAL COMPOUNDS; CONTENTS; Preface; Foreword to the First Edition; Mathematical Symbols; Abbreviations; 1 Introduction: Subject and Methods; 1.1 Objectives; Molecular Engineering and Intuitive Guesswork; Main Objectives of This Book in Comparison with Other Sources; 1.2 Definitions of Chemical Bonding and Transition Metal Coordination System; Chemical Bonding as an Electronic Phenomenon; Definition of Coordination System; 1.3 The Schrödinger Equation; Formulation; Role of Approximations; Summary Notes; References; 2 Atomic States
2.1 One-Electron StatesAngular and Radial Functions; Orbital Overlaps: Hybridized Functions; Spin-Orbital Interaction; Relativistic Atomic Functions; 2.2 Multielectron States: Energy Terms; Electronic Configurations and Terms; Multielectron Wavefunctions; Slater-Condon and Racah Parameters; The Hartree-Fock Method; Summary Notes; Questions; Exercises and Problems; References; 3 Symmetry Ideas and Group-Theoretical Description; 3.1 Symmetry Transformations and Matrices; 3.2 Groups of Symmetry Transformations; Example 3.1. The Symmetry Group of an Octahedral O(h) System and Its Classes 3.3 Representations of Groups and Matrices of Representations3.4 Classification of Molecular Terms and Vibrations, Selection Rules, and Wigner-Eckart Theorem; Example 3.2. Energy Terms of Electronic Configuration e(2); 3.5 Construction of Symmetrized Molecular Orbitals and Normal Vibrations; Example 3.3. Construction of E(g)-Symmetry-Adapted σ MOs for Octahedral O(h) Systems; Example 3.4. Construction of T(2g)-Symmetry-Adapted π MOs for Octahedral O(h) Systems; Example 3.5. Normal Coordinates of a Regular Triangular Molecule X(3); 3.6 The Notion of Double Groups; Summary Notes; Exercises References4 Crystal Field Theory; 4.1 Introduction; Brief History; Main Assumptions; 4.2 Splitting of the Energy Levels of One d Electron in Ligand Fields; Qualitative Aspects and Visual Interpretation; Calculation of the Splitting Magnitude; Example 4.1. Splitting of a d-Electron Term in Octahedral Crystal Fields; Group-Theoretical Analysis; 4.3 Several d Electrons; Case of a Weak Field; Strong Crystal Fields and Low- and High-Spin Complexes; Example 4.2. High- and Low-Spin Octahedral Complexes of Iron; Energy Terms of Strong-Field Configurations Example 5.1. Shortcomings of Mulliken's Definition of Atomic Charges in Molecules |
| Record Nr. | UNINA-9910830368203321 |
|
Bersuker I. B (Isaak Borisovich)
|
||
| New York, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electronic structure and properties of transition metal compounds : introduction to the theory / / Isaac B. Bersuker
| Electronic structure and properties of transition metal compounds : introduction to the theory / / Isaac B. Bersuker |
| Autore | Bersuker I. B (Isaak Borisovich) |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | New York, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (797 p.) |
| Disciplina | 546/.6 |
| Collana | Textbook for graduate and advanced undergraduate students |
| Soggetto topico |
Transition metal compounds
Chemistry |
| ISBN |
0-470-92085-8
1-282-68470-1 9786612684708 0-470-57305-8 0-470-57304-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRONIC STRUCTURE AND PROPERTIES OF TRANSITION METAL COMPOUNDS; CONTENTS; Preface; Foreword to the First Edition; Mathematical Symbols; Abbreviations; 1 Introduction: Subject and Methods; 1.1 Objectives; Molecular Engineering and Intuitive Guesswork; Main Objectives of This Book in Comparison with Other Sources; 1.2 Definitions of Chemical Bonding and Transition Metal Coordination System; Chemical Bonding as an Electronic Phenomenon; Definition of Coordination System; 1.3 The Schrödinger Equation; Formulation; Role of Approximations; Summary Notes; References; 2 Atomic States
2.1 One-Electron StatesAngular and Radial Functions; Orbital Overlaps: Hybridized Functions; Spin-Orbital Interaction; Relativistic Atomic Functions; 2.2 Multielectron States: Energy Terms; Electronic Configurations and Terms; Multielectron Wavefunctions; Slater-Condon and Racah Parameters; The Hartree-Fock Method; Summary Notes; Questions; Exercises and Problems; References; 3 Symmetry Ideas and Group-Theoretical Description; 3.1 Symmetry Transformations and Matrices; 3.2 Groups of Symmetry Transformations; Example 3.1. The Symmetry Group of an Octahedral O(h) System and Its Classes 3.3 Representations of Groups and Matrices of Representations3.4 Classification of Molecular Terms and Vibrations, Selection Rules, and Wigner-Eckart Theorem; Example 3.2. Energy Terms of Electronic Configuration e(2); 3.5 Construction of Symmetrized Molecular Orbitals and Normal Vibrations; Example 3.3. Construction of E(g)-Symmetry-Adapted σ MOs for Octahedral O(h) Systems; Example 3.4. Construction of T(2g)-Symmetry-Adapted π MOs for Octahedral O(h) Systems; Example 3.5. Normal Coordinates of a Regular Triangular Molecule X(3); 3.6 The Notion of Double Groups; Summary Notes; Exercises References4 Crystal Field Theory; 4.1 Introduction; Brief History; Main Assumptions; 4.2 Splitting of the Energy Levels of One d Electron in Ligand Fields; Qualitative Aspects and Visual Interpretation; Calculation of the Splitting Magnitude; Example 4.1. Splitting of a d-Electron Term in Octahedral Crystal Fields; Group-Theoretical Analysis; 4.3 Several d Electrons; Case of a Weak Field; Strong Crystal Fields and Low- and High-Spin Complexes; Example 4.2. High- and Low-Spin Octahedral Complexes of Iron; Energy Terms of Strong-Field Configurations Example 5.1. Shortcomings of Mulliken's Definition of Atomic Charges in Molecules |
| Record Nr. | UNINA-9910877192603321 |
|
Bersuker I. B (Isaak Borisovich)
|
||
| New York, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||