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Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
| Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger |
| Autore | Berkessel Albrecht |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 547.215 |
| Altri autori (Persone) | GrögerHarald |
| Soggetto topico |
Asymmetric synthesis
Catalysis Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-51952-5
9786610519521 3-527-60467-7 3-527-60405-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References 4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles 4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center 5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions 6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center |
| Record Nr. | UNINA-9910142560503321 |
Berkessel Albrecht
|
||
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
| Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger |
| Autore | Berkessel Albrecht |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 547.215 |
| Altri autori (Persone) | GrögerHarald |
| Soggetto topico |
Asymmetric synthesis
Catalysis Organic compounds - Synthesis |
| ISBN |
1-280-51952-5
9786610519521 3-527-60467-7 3-527-60405-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References 4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles 4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center 5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions 6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center |
| Record Nr. | UNISA-996203314103316 |
|
Berkessel Albrecht
|
||
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
| Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger |
| Autore | Berkessel Albrecht |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 547.215 |
| Altri autori (Persone) | GrögerHarald |
| Soggetto topico |
Asymmetric synthesis
Catalysis Organic compounds - Synthesis |
| ISBN |
1-280-51952-5
9786610519521 3-527-60467-7 3-527-60405-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References 4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles 4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center 5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions 6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center |
| Record Nr. | UNINA-9910829871003321 |
|
Berkessel Albrecht
|
||
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
| Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger |
| Autore | Berkessel Albrecht |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 547.215 |
| Altri autori (Persone) | GrögerHarald |
| Soggetto topico |
Asymmetric synthesis
Catalysis Organic compounds - Synthesis |
| ISBN |
1-280-51952-5
9786610519521 3-527-60467-7 3-527-60405-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References 4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles 4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center 5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions 6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center |
| Record Nr. | UNINA-9910841425003321 |
|
Berkessel Albrecht
|
||
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||