Crystals and crystallinity in polymers : diffraction analysis of ordered and disordered crystals / / Claudio De Rosa, Finizia Auriemma |
Autore | De Rosa Claudio |
Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2014] |
Descrizione fisica | 1 online resource (464 pages) |
Disciplina | 547/.7 |
Altri autori (Persone) | AuriemmaFinizia |
Collana | New York Academy of Sciences |
Soggetto topico |
Crystalline polymers
Crystallization |
ISBN |
1-118-69079-6
1-118-69044-3 1-118-69059-1 |
Classificazione | TEC009010 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Machine generated contents note: Chapter 1 Configuration and Conformation of Macromolecules in Polymer Crystals 1.1 Crystals of polymers 1.2 Constitution and configuration of crystalline polymers 1.3 Conformation 1.4 Relationships among internal parameters of macromolecules 1.5 Conformation of polymer chains in the crystalline state 1.6 Helical conformations in isotactic and syndiotactic polymers 1.7 Conformational energy calculations 1.8 Helical conformation and optical activity 1.9 Alternating copolymers 1.10 Polydienes 1.11 Non helical chain conformations of isotactic polymers References Chapter 1 Chapter 2 Packing of macromolecules in polymer crystals 2.1 General principles 2.2 The principle of density (entropy)-driven phase formation in polymers 2.3 Symmetry breaking 2.4 Impact of chain folding on crystal structure symmetry 2.5 Frustrated Polymer Crystal Structures 2.6 Chiral crystallization of polymers with helical chain conformations 2.7 Packing effects on the conformation of polymer chains in the crystals: the case of aliphatic polyamides References Chapter 2 Chapter 3 3.1 X-ray diffraction of semicrystalline polymers 3.2 Fourier synthesis and the phase problem in crystallography 3.3 X-ray fiber diffraction analysis 3.4 Determination of parameters of the unit cell and indexing of the diffraction pattern 3.5 Measure of the integrated intensities of the reflections and corrections for geometrical (Lorentz), polarization and absorption factors 3.6 Calculation of Structure Factors 3.7 Structural refinement 3.8 Form of diffraction pattern and broadening due to the Laue function References Chapter 3 Chapter 4 Defects and Disorder in Polymer Crystals 4.1 Classification of different types of structural disorder 4.2 Crystals with partial three-dimensional order (Class A)Disorder with three-dimensional periodicity maintained only for some characterizing points of the structure 4.3 Solid mesophases References Chapter 4 Chapter 5 Methods of Analysis of Diffuse Scattering from Disordered Structures of Polymers 5.1 Structural disorder and diffuse scattering 5.2 Methods of diffraction analysis from disordered crystals 5.3 Long Range Order in Disordered Lattices of Class A 5.4 Short Range Order in Disordered Crystals of Class A 5.5 Short Range Order in Disordered Crystals with Substitution type Disorder 5.6 Short Range vs Long Range Order in Disordered Crystals of Class B and C (Solid Mesophases) 5.7 Disordered Models with Perturbations Occurring over Continuous Ranges 5.8 Basic formulas for the calculation of X-ray Diffraction Intensity from Disordered Model Structures of Polymers 5.9 Examples of calculation of average diffracted intensity of structures disordered in one dimension 5.10 Integration method of diffraction intensity for cylindrically and spherical surfaces in the reciprocal space References Chapter 5 Chapter 6 Crystal habit 6.1 Basic remark 6.2 Rounded lateral habits 6.3 Chain folding, molecular orientation and sectorization 6.4 Twinning and secondary nucleation theory 6.5 Homoepitaxy, morphology, stem orientation and polymorphism References Chapter 6 Chapter 7 Influence of Crystal Defects and Structural Disorder on the Physical and Mechanical Properties of Polymeric Materials 7.1 Introduction 7.2 Stress induced phase transformations during deformation 7.3 Isotactic polypropylene 7.4 Syndiotactic Polypropylene References Chapter 7. |
Record Nr. | UNINA-9910139017803321 |
De Rosa Claudio | ||
Hoboken, New Jersey : , : Wiley, , [2014] | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Crystals and crystallinity in polymers : diffraction analysis of ordered and disordered crystals / / Claudio De Rosa, Finizia Auriemma |
Autore | De Rosa Claudio |
Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2014] |
Descrizione fisica | 1 online resource (464 pages) |
Disciplina | 547/.7 |
Altri autori (Persone) | AuriemmaFinizia |
Collana | New York Academy of Sciences |
Soggetto topico |
Crystalline polymers
Crystallization |
ISBN |
1-118-69079-6
1-118-69044-3 1-118-69059-1 |
Classificazione | TEC009010 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Machine generated contents note: Chapter 1 Configuration and Conformation of Macromolecules in Polymer Crystals 1.1 Crystals of polymers 1.2 Constitution and configuration of crystalline polymers 1.3 Conformation 1.4 Relationships among internal parameters of macromolecules 1.5 Conformation of polymer chains in the crystalline state 1.6 Helical conformations in isotactic and syndiotactic polymers 1.7 Conformational energy calculations 1.8 Helical conformation and optical activity 1.9 Alternating copolymers 1.10 Polydienes 1.11 Non helical chain conformations of isotactic polymers References Chapter 1 Chapter 2 Packing of macromolecules in polymer crystals 2.1 General principles 2.2 The principle of density (entropy)-driven phase formation in polymers 2.3 Symmetry breaking 2.4 Impact of chain folding on crystal structure symmetry 2.5 Frustrated Polymer Crystal Structures 2.6 Chiral crystallization of polymers with helical chain conformations 2.7 Packing effects on the conformation of polymer chains in the crystals: the case of aliphatic polyamides References Chapter 2 Chapter 3 3.1 X-ray diffraction of semicrystalline polymers 3.2 Fourier synthesis and the phase problem in crystallography 3.3 X-ray fiber diffraction analysis 3.4 Determination of parameters of the unit cell and indexing of the diffraction pattern 3.5 Measure of the integrated intensities of the reflections and corrections for geometrical (Lorentz), polarization and absorption factors 3.6 Calculation of Structure Factors 3.7 Structural refinement 3.8 Form of diffraction pattern and broadening due to the Laue function References Chapter 3 Chapter 4 Defects and Disorder in Polymer Crystals 4.1 Classification of different types of structural disorder 4.2 Crystals with partial three-dimensional order (Class A)Disorder with three-dimensional periodicity maintained only for some characterizing points of the structure 4.3 Solid mesophases References Chapter 4 Chapter 5 Methods of Analysis of Diffuse Scattering from Disordered Structures of Polymers 5.1 Structural disorder and diffuse scattering 5.2 Methods of diffraction analysis from disordered crystals 5.3 Long Range Order in Disordered Lattices of Class A 5.4 Short Range Order in Disordered Crystals of Class A 5.5 Short Range Order in Disordered Crystals with Substitution type Disorder 5.6 Short Range vs Long Range Order in Disordered Crystals of Class B and C (Solid Mesophases) 5.7 Disordered Models with Perturbations Occurring over Continuous Ranges 5.8 Basic formulas for the calculation of X-ray Diffraction Intensity from Disordered Model Structures of Polymers 5.9 Examples of calculation of average diffracted intensity of structures disordered in one dimension 5.10 Integration method of diffraction intensity for cylindrically and spherical surfaces in the reciprocal space References Chapter 5 Chapter 6 Crystal habit 6.1 Basic remark 6.2 Rounded lateral habits 6.3 Chain folding, molecular orientation and sectorization 6.4 Twinning and secondary nucleation theory 6.5 Homoepitaxy, morphology, stem orientation and polymorphism References Chapter 6 Chapter 7 Influence of Crystal Defects and Structural Disorder on the Physical and Mechanical Properties of Polymeric Materials 7.1 Introduction 7.2 Stress induced phase transformations during deformation 7.3 Isotactic polypropylene 7.4 Syndiotactic Polypropylene References Chapter 7. |
Record Nr. | UNINA-9910824898903321 |
De Rosa Claudio | ||
Hoboken, New Jersey : , : Wiley, , [2014] | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Polymer Crystallization I : From Chain Microstructure to Processing / / edited by Finizia Auriemma, Giovanni Carlo Alfonso, Claudio De Rosa |
Edizione | [1st ed. 2017.] |
Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017 |
Descrizione fisica | 1 online resource (VII, 292 p. 185 illus., 77 illus. in color.) |
Disciplina | 547.7 |
Collana | Advances in Polymer Science |
Soggetto topico |
Polymers
Phase transitions (Statistical physics) Materials—Surfaces Thin films Solid state physics Surfaces (Physics) Interfaces (Physical sciences) Polymer Sciences Phase Transitions and Multiphase Systems Surfaces and Interfaces, Thin Films Solid State Physics Surface and Interface Science, Thin Films |
ISBN | 3-319-49203-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Crystallization of Statistical Copolymers -- A molecular view of properties of random copolymers of propene -- Crystallization of Cyclic Polymers -- Crystallization of Precision Ethylene Copolymers -- Supramolecular Crystals and Crystallization -- Self-nucleation of crystalline phases within homopolymers, polymer blends, copolymers and nanocomposites -- Crystal nucleation of polymers at high supercooling of the melt. . |
Record Nr. | UNINA-9910254142103321 |
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Polymer Crystallization II : From Chain Microstructure to Processing / / edited by Finizia Auriemma, Giovanni Carlo Alfonso, Claudio De Rosa |
Edizione | [1st ed. 2017.] |
Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017 |
Descrizione fisica | 1 online resource (VII, 297 p. 125 illus., 90 illus. in color.) |
Disciplina | 547.7 |
Collana | Advances in Polymer Science |
Soggetto topico |
Polymers
Phase transitions (Statistical physics) Materials—Surfaces Thin films Solid state physics Surfaces (Physics) Interfaces (Physical sciences) Polymer Sciences Phase Transitions and Multiphase Systems Surfaces and Interfaces, Thin Films Solid State Physics Surface and Interface Science, Thin Films |
ISBN | 3-319-50684-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Concomitant crystallization and cross-nucleation in polymorphic polymers -- Epitaxial effects on polymer crystallization -- Micro-Structure of Banded Polymer Spherulites: New Insights from Synchrotron Nano-Focus X-ray Scattering -- Real-time fast structuring of polymers using synchrotron WAXD/SAXS techniques -- Strain-induced crystallization in natural rubber -- Non-isothermal crystallization of semi-crystalline polymers: The influence of cooling rate and pressure -- Modeling fow-induced crystallization. |
Record Nr. | UNINA-9910254142003321 |
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|