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Fundamentals and applications of organic electrochemistry : synthesis, materials, devices / / Toshio Fuchigami, Mahito Atobe, Shinsuke Inagi
| Fundamentals and applications of organic electrochemistry : synthesis, materials, devices / / Toshio Fuchigami, Mahito Atobe, Shinsuke Inagi |
| Autore | Fuchigami Toshio |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2015 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina | 547/.137 |
| Soggetto topico |
Organic electrochemistry
Electrochemistry Chemistry, Organic |
| ISBN |
1-118-67074-4
1-118-67075-2 1-118-67073-6 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fundamentals and Applications of Organic Electrochemistry: Synthesis, Materials, Devices; Contents; About the Authors; Preface; Introduction; 1. Fundamental Principles of Organic Electrochemistry: Fundamental Aspects of Electrochemistry Dealing with Organic Molecules; 1.1 FORMATION OF ELECTRICAL DOUBLE LAYER; 1.2 ELECTRODE POTENTIALS (REDOX POTENTIALS); 1.3 ACTIVATION ENERGY AND OVERPOTENTIAL; 1.4 CURRENTS CONTROLLED BY ELECTRON TRANSFER AND MASS TRANSPORT; References; 2. Method for Study of Organic Electrochemistry: Electrochemical Measurements of Organic Molecules; 2.1 WORKING ELECTRODES
2.2 REFERENCE ELECTRODES2.3 AUXILIARY ELECTRODES; 2.4 SOLVENTS AND SUPPORTING ELECTROLYTES; 2.5 CELLS AND POWER SOURCES; 2.6 STEADY-STATE AND NON-STEADY-STATES POLARIZATION CURVES; 2.7 POTENTIALS IN ELECTROCHEMICAL MEASUREMENTS; 2.8 UTILIZATION OF VOLTAMMETRY FOR THE STUDY OF ORGANIC ELECTROSYNTHESIS; 2.8.1 Voltammetric Analysis for Selective Electrosynthesis; 2.8.2 Clarification of the Reaction Mechanism; 2.8.3 Voltammetry for Selection of Mediator; 2.8.4 Voltammetry for Selection of Electrode Material; References; 3. Methods for Organic Electrosynthesis; 3.1 SELECTION OF ELECTROLYTIC CELLS 3.2 CONSTANT CURRENT ELECTROLYSIS AND CONSTANT POTENTIAL ELECTROLYSIS3.3 DIRECT ELECTROLYSIS AND INDIRECT ELECTROLYSIS; 3.4 ELECTRODE MATERIALS AND REFERENCE ELECTRODES; 3.5 ELECTROLYTIC SOLVENTS AND SUPPORTING ELECTROLYTES; 3.6 STIRRING; 3.7 TRACKING OF REACTANT AND PRODUCT; 3.8 WORK-UP, ISOLATION AND DETERMINATION OF PRODUCTS; 3.9 CURRENT EFFICIENCY AND EFFECT OF THE POWER UNIT; References; 4. Organic Electrode Reactions; 4.1 GENERAL CHARACTERISTICS OF ELECTRODE REACTIONS; 4.2 MECHANISM OF ORGANIC ELECTRODE REACTIONS; 4.3 CHARACTERISTICS OF ORGANIC ELECTROLYTIC REACTIONS; 4.3.1 Umpolung 4.3.2 Selectivity4.3.2.1 Chemoselectivity; 4.3.2.2 Reaction Pathway Selectivity; 4.3.2.3 Regioselectivity; 4.3.2.4 Stereoselectivity; 4.3.2.5 Selectivity Depending on Electrode Materials; 4.4 MOLECULAR ORBITALS AND ELECTRONS RELATED TO ELECTRON TRANSFER; 4.5 ELECTROAUXILIARIES; 4.5.1 Electroauxiliaries Based on Molecular Orbital Interactions; 4.5.2 Electroauxiliaries Based on Readily Electron-Transferable Functional Groups; 4.5.3 Electroauxiliaries Based on Intermolecular Coordination Effects; 4.5.4 Electroauxiliaries Based on Intramolecular Coordination Effects 4.6 REACTION PATTERN OF ORGANIC ELECTRODE REACTIONS4.6.1 Transformation Type of Functional Group; 4.6.2 Addition Type; 4.6.3 Insertion Type; 4.6.4 Substitution Type; 4.6.5 Substitutive Exchange Type; 4.6.6 Elimination Type; 4.6.7 Dimerization Type; 4.6.8 Crossed Dimerization; 4.6.9 Cyclization Type; 4.6.10 Polymorphism Formation Type; 4.6.11 Polymerization Type; 4.6.12 Cleavage Type; 4.6.13 Metalation Type; 4.6.14 Asymmetric Synthesis Type; 4.7 ELECTROCHEMICALLY GENERATED REACTIVE SPECIES; 4.7.1 Carbon Species; 4.7.1.1 Anodically Generated Carbon Species 4.7.1.2 Cathodically Generated Carbon Species |
| Record Nr. | UNINA-9910132156503321 |
Fuchigami Toshio
|
||
| Chichester, England : , : Wiley, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fundamentals and applications of organic electrochemistry : synthesis, materials, devices / / Toshio Fuchigami, Mahito Atobe, Shinsuke Inagi
| Fundamentals and applications of organic electrochemistry : synthesis, materials, devices / / Toshio Fuchigami, Mahito Atobe, Shinsuke Inagi |
| Autore | Fuchigami Toshio |
| Pubbl/distr/stampa | London, England : , : John Wiley & Sons, Inc., , [2014] |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina | 547/.137 |
| Soggetto topico |
Chemistry, Organic
Electrochemistry Organic electrochemistry |
| ISBN |
1-118-67074-4
1-118-67075-2 1-118-67073-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fundamentals and Applications of Organic Electrochemistry: Synthesis, Materials, Devices; Contents; About the Authors; Preface; Introduction; 1. Fundamental Principles of Organic Electrochemistry: Fundamental Aspects of Electrochemistry Dealing with Organic Molecules; 1.1 FORMATION OF ELECTRICAL DOUBLE LAYER; 1.2 ELECTRODE POTENTIALS (REDOX POTENTIALS); 1.3 ACTIVATION ENERGY AND OVERPOTENTIAL; 1.4 CURRENTS CONTROLLED BY ELECTRON TRANSFER AND MASS TRANSPORT; References; 2. Method for Study of Organic Electrochemistry: Electrochemical Measurements of Organic Molecules; 2.1 WORKING ELECTRODES
2.2 REFERENCE ELECTRODES2.3 AUXILIARY ELECTRODES; 2.4 SOLVENTS AND SUPPORTING ELECTROLYTES; 2.5 CELLS AND POWER SOURCES; 2.6 STEADY-STATE AND NON-STEADY-STATES POLARIZATION CURVES; 2.7 POTENTIALS IN ELECTROCHEMICAL MEASUREMENTS; 2.8 UTILIZATION OF VOLTAMMETRY FOR THE STUDY OF ORGANIC ELECTROSYNTHESIS; 2.8.1 Voltammetric Analysis for Selective Electrosynthesis; 2.8.2 Clarification of the Reaction Mechanism; 2.8.3 Voltammetry for Selection of Mediator; 2.8.4 Voltammetry for Selection of Electrode Material; References; 3. Methods for Organic Electrosynthesis; 3.1 SELECTION OF ELECTROLYTIC CELLS 3.2 CONSTANT CURRENT ELECTROLYSIS AND CONSTANT POTENTIAL ELECTROLYSIS3.3 DIRECT ELECTROLYSIS AND INDIRECT ELECTROLYSIS; 3.4 ELECTRODE MATERIALS AND REFERENCE ELECTRODES; 3.5 ELECTROLYTIC SOLVENTS AND SUPPORTING ELECTROLYTES; 3.6 STIRRING; 3.7 TRACKING OF REACTANT AND PRODUCT; 3.8 WORK-UP, ISOLATION AND DETERMINATION OF PRODUCTS; 3.9 CURRENT EFFICIENCY AND EFFECT OF THE POWER UNIT; References; 4. Organic Electrode Reactions; 4.1 GENERAL CHARACTERISTICS OF ELECTRODE REACTIONS; 4.2 MECHANISM OF ORGANIC ELECTRODE REACTIONS; 4.3 CHARACTERISTICS OF ORGANIC ELECTROLYTIC REACTIONS; 4.3.1 Umpolung 4.3.2 Selectivity4.3.2.1 Chemoselectivity; 4.3.2.2 Reaction Pathway Selectivity; 4.3.2.3 Regioselectivity; 4.3.2.4 Stereoselectivity; 4.3.2.5 Selectivity Depending on Electrode Materials; 4.4 MOLECULAR ORBITALS AND ELECTRONS RELATED TO ELECTRON TRANSFER; 4.5 ELECTROAUXILIARIES; 4.5.1 Electroauxiliaries Based on Molecular Orbital Interactions; 4.5.2 Electroauxiliaries Based on Readily Electron-Transferable Functional Groups; 4.5.3 Electroauxiliaries Based on Intermolecular Coordination Effects; 4.5.4 Electroauxiliaries Based on Intramolecular Coordination Effects 4.6 REACTION PATTERN OF ORGANIC ELECTRODE REACTIONS4.6.1 Transformation Type of Functional Group; 4.6.2 Addition Type; 4.6.3 Insertion Type; 4.6.4 Substitution Type; 4.6.5 Substitutive Exchange Type; 4.6.6 Elimination Type; 4.6.7 Dimerization Type; 4.6.8 Crossed Dimerization; 4.6.9 Cyclization Type; 4.6.10 Polymorphism Formation Type; 4.6.11 Polymerization Type; 4.6.12 Cleavage Type; 4.6.13 Metalation Type; 4.6.14 Asymmetric Synthesis Type; 4.7 ELECTROCHEMICALLY GENERATED REACTIVE SPECIES; 4.7.1 Carbon Species; 4.7.1.1 Anodically Generated Carbon Species 4.7.1.2 Cathodically Generated Carbon Species |
| Record Nr. | UNINA-9910678133403321 |
|
Fuchigami Toshio
|
||
| London, England : , : John Wiley & Sons, Inc., , [2014] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||