Polymer reaction engineering [[electronic resource] /] / edited by José M. Asua |
Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
Descrizione fisica | 1 online resource (394 p.) |
Disciplina | 668.9/2 |
Altri autori (Persone) | AsuaJosé M |
Soggetto topico |
Polymerization
Polymer engineering |
ISBN |
1-281-30914-1
9786611309145 0-470-69213-8 0-470-69142-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Polymer Reaction Engineering; Contents; Contributors; Preface; Notation; Acronyms; 1 Introduction to Polymerization Processes; 1.1 Microstructural features of polymers and their effect on properties; 1.1.1 Chemical composition and monomer sequence distribution; 1.1.2 Molecular weight distribution; 1.1.3 Polymer architecture; 1.1.4 Chain configuration; 1.1.5 Morphology; 1.1.6 Effect of processing and compounding on the microstructure of the polymeric materials; 1.2 Classes of polymerizations; 1.2.1 Chain-growth polymerization; 1.2.2 Step-growth polymerization; 1.3 Polymerization techniques
1.4 Main commercial polymers 1.4.1 Polyolefins; 1.4.2 Styrenic polymers; 1.4.3 Poly(vinyl chloride); 1.4.4 Waterborne dispersed polymers; 1.4.5 Polyesters and polyamides; 1.4.6 Thermosets; 1.5 Polymerization reactors; References; 2 Coordination Polymerization; 2.1 Polyolefin types: microstructural classification and analytical techniques; 2.1.1 Polyethylene types; 2.1.2 Polypropylene types; 2.1.3 Polyolefin microstructural characterization techniques; 2.2 Catalysts for olefin polymerization; 2.2.1 Coordination catalyst types; 2.2.2 Polymerization mechanism 2.3 Polymerization kinetics for single- and multiple-site catalysts 2.3.1 Homopolymerization; 2.3.2 Copolymerization; 2.3.3 Long-chain branch formation; 2.4 Inter- and intraparticle mass and heat transfer resistances; 2.4.1 Particle fragmentation and morphology control; 2.4.2 Single particle models: inter- and intraparticle mass and heat transfer; 2.5 Industrial olefin polymerization reactors; 2.5.1 Reactor configurations and designs; 2.5.2 Polyethylene manufacturing processes; 2.5.3 Polypropylene manufacturing processes; 2.5.4Mathematical models for industrial reactors; Acknowledgments References 3 Free-Radical Polymerization: Homogeneous Systems; 3.1 Free-radical polymers: properties and applications; 3.2 FRP mechanisms and kinetics; 3.2.1 Homopolymerization; 3.2.2 Copolymerization; 3.2.3 Diffusion-controlled reactions; 3.2.4 Kinetic balances for modeling polymer MWs; 3.3 Controlled radical polymerization; 3.3.1 Stable free-radical polymerization; 3.3.2 Atom transfer radical polymerization; 3.3.3 Reverse addition-fragmentation chain transferpolymerization; 3.4 Polymer reaction engineering aspects; 3.4.1 Heat removal and temperature programming; 3.4.2 Batch reactors 3.4.3 Semibatch (semicontinuous) reactors 3.4.4 Continuous stirred-tank reactors; 3.4.5 Tubular reactors; 3.5 A ""roadmap"" for mathematical modeling; References; 4 Free-Radical Polymerization: Heterogeneous Systems; 4.1 Introduction; 4.2 High-impact polystyrene; 4.2.1 Interrelationship between microstructure and application properties; 4.2.2 Modeling HIPS polymerization; 4.2.3 Optimizing final properties: melt flow index in a continuous HIPS process; 4.2.4 Final remarks for HIPS; 4.3 Vinyl chloride monomer bulk polymerization; 4.3.1 Kinetic mechanism; 4.3.2 PVC morphology; Acknowledgments References |
Record Nr. | UNINA-9910145584603321 |
Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Polymer reaction engineering [[electronic resource] /] / edited by José M. Asua |
Edizione | [1st ed.] |
Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
Descrizione fisica | 1 online resource (394 p.) |
Disciplina | 668.9/2 |
Altri autori (Persone) | AsuaJosé M |
Soggetto topico |
Polymerization
Polymer engineering |
ISBN |
1-281-30914-1
9786611309145 0-470-69213-8 0-470-69142-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Polymer Reaction Engineering; Contents; Contributors; Preface; Notation; Acronyms; 1 Introduction to Polymerization Processes; 1.1 Microstructural features of polymers and their effect on properties; 1.1.1 Chemical composition and monomer sequence distribution; 1.1.2 Molecular weight distribution; 1.1.3 Polymer architecture; 1.1.4 Chain configuration; 1.1.5 Morphology; 1.1.6 Effect of processing and compounding on the microstructure of the polymeric materials; 1.2 Classes of polymerizations; 1.2.1 Chain-growth polymerization; 1.2.2 Step-growth polymerization; 1.3 Polymerization techniques
1.4 Main commercial polymers 1.4.1 Polyolefins; 1.4.2 Styrenic polymers; 1.4.3 Poly(vinyl chloride); 1.4.4 Waterborne dispersed polymers; 1.4.5 Polyesters and polyamides; 1.4.6 Thermosets; 1.5 Polymerization reactors; References; 2 Coordination Polymerization; 2.1 Polyolefin types: microstructural classification and analytical techniques; 2.1.1 Polyethylene types; 2.1.2 Polypropylene types; 2.1.3 Polyolefin microstructural characterization techniques; 2.2 Catalysts for olefin polymerization; 2.2.1 Coordination catalyst types; 2.2.2 Polymerization mechanism 2.3 Polymerization kinetics for single- and multiple-site catalysts 2.3.1 Homopolymerization; 2.3.2 Copolymerization; 2.3.3 Long-chain branch formation; 2.4 Inter- and intraparticle mass and heat transfer resistances; 2.4.1 Particle fragmentation and morphology control; 2.4.2 Single particle models: inter- and intraparticle mass and heat transfer; 2.5 Industrial olefin polymerization reactors; 2.5.1 Reactor configurations and designs; 2.5.2 Polyethylene manufacturing processes; 2.5.3 Polypropylene manufacturing processes; 2.5.4Mathematical models for industrial reactors; Acknowledgments References 3 Free-Radical Polymerization: Homogeneous Systems; 3.1 Free-radical polymers: properties and applications; 3.2 FRP mechanisms and kinetics; 3.2.1 Homopolymerization; 3.2.2 Copolymerization; 3.2.3 Diffusion-controlled reactions; 3.2.4 Kinetic balances for modeling polymer MWs; 3.3 Controlled radical polymerization; 3.3.1 Stable free-radical polymerization; 3.3.2 Atom transfer radical polymerization; 3.3.3 Reverse addition-fragmentation chain transferpolymerization; 3.4 Polymer reaction engineering aspects; 3.4.1 Heat removal and temperature programming; 3.4.2 Batch reactors 3.4.3 Semibatch (semicontinuous) reactors 3.4.4 Continuous stirred-tank reactors; 3.4.5 Tubular reactors; 3.5 A ""roadmap"" for mathematical modeling; References; 4 Free-Radical Polymerization: Heterogeneous Systems; 4.1 Introduction; 4.2 High-impact polystyrene; 4.2.1 Interrelationship between microstructure and application properties; 4.2.2 Modeling HIPS polymerization; 4.2.3 Optimizing final properties: melt flow index in a continuous HIPS process; 4.2.4 Final remarks for HIPS; 4.3 Vinyl chloride monomer bulk polymerization; 4.3.1 Kinetic mechanism; 4.3.2 PVC morphology; Acknowledgments References |
Record Nr. | UNISA-996201966603316 |
Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. di Salerno | ||
|
Polymer reaction engineering [[electronic resource] /] / edited by José M. Asua |
Edizione | [1st ed.] |
Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
Descrizione fisica | 1 online resource (394 p.) |
Disciplina | 668.9/2 |
Altri autori (Persone) | AsuaJosé M |
Soggetto topico |
Polymerization
Polymer engineering |
ISBN |
1-281-30914-1
9786611309145 0-470-69213-8 0-470-69142-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Polymer Reaction Engineering; Contents; Contributors; Preface; Notation; Acronyms; 1 Introduction to Polymerization Processes; 1.1 Microstructural features of polymers and their effect on properties; 1.1.1 Chemical composition and monomer sequence distribution; 1.1.2 Molecular weight distribution; 1.1.3 Polymer architecture; 1.1.4 Chain configuration; 1.1.5 Morphology; 1.1.6 Effect of processing and compounding on the microstructure of the polymeric materials; 1.2 Classes of polymerizations; 1.2.1 Chain-growth polymerization; 1.2.2 Step-growth polymerization; 1.3 Polymerization techniques
1.4 Main commercial polymers 1.4.1 Polyolefins; 1.4.2 Styrenic polymers; 1.4.3 Poly(vinyl chloride); 1.4.4 Waterborne dispersed polymers; 1.4.5 Polyesters and polyamides; 1.4.6 Thermosets; 1.5 Polymerization reactors; References; 2 Coordination Polymerization; 2.1 Polyolefin types: microstructural classification and analytical techniques; 2.1.1 Polyethylene types; 2.1.2 Polypropylene types; 2.1.3 Polyolefin microstructural characterization techniques; 2.2 Catalysts for olefin polymerization; 2.2.1 Coordination catalyst types; 2.2.2 Polymerization mechanism 2.3 Polymerization kinetics for single- and multiple-site catalysts 2.3.1 Homopolymerization; 2.3.2 Copolymerization; 2.3.3 Long-chain branch formation; 2.4 Inter- and intraparticle mass and heat transfer resistances; 2.4.1 Particle fragmentation and morphology control; 2.4.2 Single particle models: inter- and intraparticle mass and heat transfer; 2.5 Industrial olefin polymerization reactors; 2.5.1 Reactor configurations and designs; 2.5.2 Polyethylene manufacturing processes; 2.5.3 Polypropylene manufacturing processes; 2.5.4Mathematical models for industrial reactors; Acknowledgments References 3 Free-Radical Polymerization: Homogeneous Systems; 3.1 Free-radical polymers: properties and applications; 3.2 FRP mechanisms and kinetics; 3.2.1 Homopolymerization; 3.2.2 Copolymerization; 3.2.3 Diffusion-controlled reactions; 3.2.4 Kinetic balances for modeling polymer MWs; 3.3 Controlled radical polymerization; 3.3.1 Stable free-radical polymerization; 3.3.2 Atom transfer radical polymerization; 3.3.3 Reverse addition-fragmentation chain transferpolymerization; 3.4 Polymer reaction engineering aspects; 3.4.1 Heat removal and temperature programming; 3.4.2 Batch reactors 3.4.3 Semibatch (semicontinuous) reactors 3.4.4 Continuous stirred-tank reactors; 3.4.5 Tubular reactors; 3.5 A ""roadmap"" for mathematical modeling; References; 4 Free-Radical Polymerization: Heterogeneous Systems; 4.1 Introduction; 4.2 High-impact polystyrene; 4.2.1 Interrelationship between microstructure and application properties; 4.2.2 Modeling HIPS polymerization; 4.2.3 Optimizing final properties: melt flow index in a continuous HIPS process; 4.2.4 Final remarks for HIPS; 4.3 Vinyl chloride monomer bulk polymerization; 4.3.1 Kinetic mechanism; 4.3.2 PVC morphology; Acknowledgments References |
Record Nr. | UNINA-9910816205503321 |
Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|