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Metallofoldamers [[electronic resource] ] : supramolecular architectures from helicates to biomimetics / / edited by Galia Maayan and Markus Albrecht
| Metallofoldamers [[electronic resource] ] : supramolecular architectures from helicates to biomimetics / / edited by Galia Maayan and Markus Albrecht |
| Pubbl/distr/stampa | Chichester, West Sussex, U.K., : John Wiley & Sons, Inc., 2013 |
| Descrizione fisica | 1 online resource (463 p.) |
| Disciplina | 547/.7 |
| Altri autori (Persone) |
MaayanGalia G
AlbrechtM (Markus) |
| Soggetto topico |
Metallofoldamers
Oligomers Supramolecular chemistry |
| ISBN |
1-118-51741-5
1-299-18879-6 1-118-51742-3 1-118-51743-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Metallofoldamers: Supramolecular Architectures from Helicates to Biomimetics; Contents; List of Contributors; Foreword; Preface; 1 Metalloproteins and Metallopeptides - Natural Metallofoldamers; 1.1 Introduction; 1.2 Metalloproteins; 1.2.1 Metalloproteins are Nature's "Metallofoldamers!"; 1.2.2 Metal-Triggered Conformational Change of Proteins; 1.2.3 Conformational Change of Metalloproteins Caused by Ligand Binding; 1.2.4 Protein Misfolding: Causes and Implications - Cu, Zn-Superoxide Dismutase; 1.3 Metallopeptides; 1.3.1 Antibiotic Metallopeptides
1.3.2 Metallopeptides in Neurodegenerative Diseases1.3.3 Other Metallopeptides; 1.4 Conclusion and Perspectives; Acknowledgements; References; 2 Introduction to Unnatural Foldamers; 2.1 General Definition of Foldamers; 2.2 Biotic Foldamers; 2.2.1 Homogeneous Foldamers; 2.2.2 β-Peptides; 2.2.3 γ-Peptides; 2.2.4 Hybrid Foldamers; 2.2.5 Aliphatic Urea Foldamers; 2.2.6 Foldamers of α-Aminoxy Acids; 2.2.7 Foldamers Containing Amido Groups; 2.3 Abiotic Foldamers; 2.4 Organization Induced by External Agents; 2.4.1 Organization Induced by Solvents; 2.4.2 Organization Induced by Anions 2.5 Applications2.6 Conclusions and Outlook; References; 3 Self-Assembly Principles of Helicates; 3.1 Introduction; 3.2 Thermodynamic Considerations in Self-Assembly; 3.2.1 Mononuclear Coordination Complexes; 3.2.2 Extension to Polynuclear Edifices; 3.3 Cooperativity in Self-Assembly; 3.3.1 Allosteric Cooperativity; 3.3.2 Chelate Cooperativity; 3.3.3 Interannular Cooperativity; 3.4 Kinetic Aspects of Multicomponent Organization; 3.5 Understanding Self-Assembly Processes; 3.5.1 Assessment of Cooperativity; 3.5.2 Thermodynamic Modelling; 3.5.3 Solvation Energies and Electrostatic Interactions 3.6 Secondary Structure and Stabilizing Interactions3.7 Conclusions; References; 4 Structural Aspects of Helicates; 4.1 Introduction; 4.2 Structural Dynamics; 4.3 Template Effects; 4.4 Sequence Selectivity; 4.5 Self-Sorting Effects in Helicate Formation; 4.6 Diastereoselectivity I - "Meso"-Helicate versus Helicate Formation; 4.7 Diastereoselectivity II - Enantiomerically Pure Helicates from Chiral Ligands; 4.7.1 2,2'-Bipyridine Ligands; 4.7.2 2,2':6',2''-Terpyridine and 2,2':6',2'':6'',2-Quaterpyridine Ligands; 4.7.3 2-Pyridylimine Ligands; 4.7.4 Further Hexadentate N-Donor Ligands 4.7.5 Oxazoline Ligands4.7.6 P-Donor Ligands; 4.7.7 Hydroxamic Acid Ligands; 4.7.8 β-Diketonate Ligands; 4.7.9 Catecholate Ligands and Other Dianionic Ligand Units; 4.7.10 Non-Covalently Assembled Ligand Strands; 4.8 Summary and Outlook; References; 5 Helical Structures Featuring Thiolato Donors; 5.1 Introduction; 5.2 Coordination Chemistry of Bis- and Tris(Benzene-o-Dithiolato) Ligands; 5.2.1 Mononuclear Chelate Complexes; 5.2.2 Dinuclear Double-Stranded Complexes; 5.2.3 Dinuclear Triple-Stranded Complexes; 5.2.4 Coordination Chemistry of Tripodal Tris(Benzene-o-Dithiolato) Ligands 5.3 Coordination Chemistry of Mixed Bis(Benzene-o-Dithiol)/Catechol Ligands |
| Record Nr. | UNINA-9910141500703321 |
| Chichester, West Sussex, U.K., : John Wiley & Sons, Inc., 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metallofoldamers : supramolecular architectures from helicates to biomimetics / / edited by Galia Maayan and Markus Albrecht
| Metallofoldamers : supramolecular architectures from helicates to biomimetics / / edited by Galia Maayan and Markus Albrecht |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, West Sussex, U.K., : John Wiley & Sons, Inc., 2013 |
| Descrizione fisica | 1 online resource (463 p.) |
| Disciplina | 547/.7 |
| Altri autori (Persone) |
MaayanGalia G
AlbrechtM (Markus) |
| Soggetto topico |
Metallofoldamers
Oligomers Supramolecular chemistry |
| ISBN |
1-118-51741-5
1-299-18879-6 1-118-51742-3 1-118-51743-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Metallofoldamers: Supramolecular Architectures from Helicates to Biomimetics; Contents; List of Contributors; Foreword; Preface; 1 Metalloproteins and Metallopeptides - Natural Metallofoldamers; 1.1 Introduction; 1.2 Metalloproteins; 1.2.1 Metalloproteins are Nature's "Metallofoldamers!"; 1.2.2 Metal-Triggered Conformational Change of Proteins; 1.2.3 Conformational Change of Metalloproteins Caused by Ligand Binding; 1.2.4 Protein Misfolding: Causes and Implications - Cu, Zn-Superoxide Dismutase; 1.3 Metallopeptides; 1.3.1 Antibiotic Metallopeptides
1.3.2 Metallopeptides in Neurodegenerative Diseases1.3.3 Other Metallopeptides; 1.4 Conclusion and Perspectives; Acknowledgements; References; 2 Introduction to Unnatural Foldamers; 2.1 General Definition of Foldamers; 2.2 Biotic Foldamers; 2.2.1 Homogeneous Foldamers; 2.2.2 β-Peptides; 2.2.3 γ-Peptides; 2.2.4 Hybrid Foldamers; 2.2.5 Aliphatic Urea Foldamers; 2.2.6 Foldamers of α-Aminoxy Acids; 2.2.7 Foldamers Containing Amido Groups; 2.3 Abiotic Foldamers; 2.4 Organization Induced by External Agents; 2.4.1 Organization Induced by Solvents; 2.4.2 Organization Induced by Anions 2.5 Applications2.6 Conclusions and Outlook; References; 3 Self-Assembly Principles of Helicates; 3.1 Introduction; 3.2 Thermodynamic Considerations in Self-Assembly; 3.2.1 Mononuclear Coordination Complexes; 3.2.2 Extension to Polynuclear Edifices; 3.3 Cooperativity in Self-Assembly; 3.3.1 Allosteric Cooperativity; 3.3.2 Chelate Cooperativity; 3.3.3 Interannular Cooperativity; 3.4 Kinetic Aspects of Multicomponent Organization; 3.5 Understanding Self-Assembly Processes; 3.5.1 Assessment of Cooperativity; 3.5.2 Thermodynamic Modelling; 3.5.3 Solvation Energies and Electrostatic Interactions 3.6 Secondary Structure and Stabilizing Interactions3.7 Conclusions; References; 4 Structural Aspects of Helicates; 4.1 Introduction; 4.2 Structural Dynamics; 4.3 Template Effects; 4.4 Sequence Selectivity; 4.5 Self-Sorting Effects in Helicate Formation; 4.6 Diastereoselectivity I - "Meso"-Helicate versus Helicate Formation; 4.7 Diastereoselectivity II - Enantiomerically Pure Helicates from Chiral Ligands; 4.7.1 2,2'-Bipyridine Ligands; 4.7.2 2,2':6',2''-Terpyridine and 2,2':6',2'':6'',2-Quaterpyridine Ligands; 4.7.3 2-Pyridylimine Ligands; 4.7.4 Further Hexadentate N-Donor Ligands 4.7.5 Oxazoline Ligands4.7.6 P-Donor Ligands; 4.7.7 Hydroxamic Acid Ligands; 4.7.8 β-Diketonate Ligands; 4.7.9 Catecholate Ligands and Other Dianionic Ligand Units; 4.7.10 Non-Covalently Assembled Ligand Strands; 4.8 Summary and Outlook; References; 5 Helical Structures Featuring Thiolato Donors; 5.1 Introduction; 5.2 Coordination Chemistry of Bis- and Tris(Benzene-o-Dithiolato) Ligands; 5.2.1 Mononuclear Chelate Complexes; 5.2.2 Dinuclear Double-Stranded Complexes; 5.2.3 Dinuclear Triple-Stranded Complexes; 5.2.4 Coordination Chemistry of Tripodal Tris(Benzene-o-Dithiolato) Ligands 5.3 Coordination Chemistry of Mixed Bis(Benzene-o-Dithiol)/Catechol Ligands |
| Record Nr. | UNINA-9910825996403321 |
| Chichester, West Sussex, U.K., : John Wiley & Sons, Inc., 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||