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Organic stereochemistry : experimental and computational methods / / Hua-Jie Zhu
| Organic stereochemistry : experimental and computational methods / / Hua-Jie Zhu |
| Autore | Zhu Hua-Jie |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2015 |
| Descrizione fisica | 1 online resource (337 p.) |
| Disciplina | 541.223 |
| Soggetto topico |
Stereochemistry
Physical organic chemistry |
| ISBN |
3-527-68817-X
3-527-68816-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title Page; Copyright; Contents; Preface; Acknowledgments; List of Abbreviations; Part I Fundamentals; Chapter 1 Chirality; 1.1 Introduction; 1.2 Tetrahedron of Carbon; 1.2.1 Terpenoids; 1.2.2 Flavonoids; 1.2.3 Alkaloids; 1.2.4 Steroids; 1.2.5 Glycosides; 1.2.6 Others; 1.3 Other Stereogenic Centers; 1.4 Optical Characteristics; 1.4.1 Measurement of OR; 1.4.2 ECD and Its Definition; 1.4.3 Outline of VCD; 1.4.4 Outline of ROA; References; Chapter 2 Non-optical Method in Configuration Study; 2.1 13C NMR Spectra; 2.1.1 NMR and Atomic Structure; 2.1.2 13C NMR Calculation; 2.1.3 1H NMR
2.1.4 13C NMR Prediction and Conformational Search2.2 X-Ray Diffraction and Mosher Method; 2.2.1 X-Ray Diffraction; 2.2.2 Mosher Method; 2.3 Transition State Energy and Chirality Selectivity; 2.4 Separation of Chiral Compounds; 2.4.1 Chiral Organic Bases; 2.4.2 Chiral Organic Acids; 2.4.3 Chiral Organic Alcohols; 2.4.4 Others; References; Part II Techniques; Chapter 3 Optical Rotation (Rotatory Dispersion, ORD); 3.1 Introduction; 3.2 Quantum Theory; 3.3 Matrix Model; 3.3.1 Matrix Basis; 3.3.2 Explanation of General OR Characteristics; 3.3.2.1 Sample Calculations 3.3.2.2 Calculated Values in Same Series of Compounds3.4 ORD; 3.5 Application; 3.5.1 AC Assignment for Mono-Stereogenic Center Compounds; 3.5.2 Matrix Model Application; 3.5.3 AC Assignment for Poly-Stereogenic Center Compounds; 3.5.4 Using ORD Method; References; Chapter 4 Electronic Circular Dichroism; 4.1 Exciton Chirality CD; 4.2 ECD Characteristics for Chiral Metallic Compounds; 4.3 Quantum Theory Basis; 4.4 Principle Using ECD; 4.5 Application; 4.5.1 Procedure to Do ECD; 4.5.2 ECD Application; 5.4.1 VCD Application; 4.5.3 UV Correction; References Chapter 5 Vibrational Circular Dichroism and Raman Optical Activity5.1 Exciton Chirality; 5.2 Quantum Theory Basis; 5.2.1 VCD and IR; 5.2.2 ROA and Raman Scattering; 5.3 Principles Using VCD and ROA; 5.4 Application; 5.4.2 ROA Application; References; Chapter 6 Combinational Use of Different Methods; 6.1 Tactics to Select Methods; 6.1.1 13C NMR Methods; 6.1.2 OR and ORD; 6.1.3 Matrix; 6.1.4 ECD; 6.1.5 VCD Method; 6.2 Examples and Discussion; 6.3 Revised Structures; 6.3.1 ORD Method; 6.3.2 Combinational Use of OR and ECD; 6.3.3 VCD and ECD; 6.3.4 Comprehensive Use of OR, ECD, and VCD ReferencesPart III Reactions; Chapter 7 Enantioselective Reaction; 7.1 Enantioselective Addition; 7.1.1 Organic Zn- or Zn-Ti Reagent; 7.1.2 Organic Cu-Zn, Cu-Li Reagent; 7.1.3 Organo-Fe Complexes; 7.1.4 Other Organo-Metallic Complexes; 7.1.5 Organo-Si Reagents; 7.2 Enantioselective Reduction; 7.2.1 Green Chemistry; 7.6.2 Auto-Self Catalysis; 7.3 Enantioselective Oxidation; 7.4 Prediction of ee Using Calculations; 7.5 Catalyst Types; 7.5.1 Amino Alcohols; 7.5.2 Chiral Ligands Containing N-O Group; 7.5.3 Chiral Axial Catalysts; 7.5.4 Solid-Supported Chiral Compounds 7.5.5 Spiral Chiral Compounds |
| Record Nr. | UNINA-9910809459903321 |
Zhu Hua-Jie
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| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic synthesis : strategy and control / Paul Wyatt and Stuart Warren
| Organic synthesis : strategy and control / Paul Wyatt and Stuart Warren |
| Autore | Wyatt, Paul |
| Pubbl/distr/stampa | Chichester, England : John Wiley, 2007 |
| Descrizione fisica | vi, 909 p. : ill. ; 26 cm |
| Disciplina | 547.2 |
| Altri autori (Persone) | Warren, Stuart G.author |
| Soggetto topico |
Organic compounds - Synthesis
Stereochemistry |
| ISBN | 9780471929635 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991002394339707536 |
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Wyatt, Paul
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| Chichester, England : John Wiley, 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Organocatalysis : stereoselective eactions and applications in organic synthesis / / edited by Maurizio Benaglia
| Organocatalysis : stereoselective eactions and applications in organic synthesis / / edited by Maurizio Benaglia |
| Pubbl/distr/stampa | Berlin ; ; Boston : , : Walter de Gruyter GmbH, , [2021] |
| Descrizione fisica | 1 online resource (XII, 439 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Chemistry, Organic Stereochemistry |
| Soggetto non controllato |
Asymmetric Synthesis
Catalysis Organic Synthesis Organocatalysis |
| ISBN |
3-11-058872-2
3-11-059005-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Frontmatter -- Preface -- Contents -- Contributors List -- 1 Domino and one-pot syntheses of biologically active compounds using diphenylprolinol silyl ether -- 2 Recent advances in reactions promoted by amino acids and oligopeptides -- 3 Amino-cinchona derivatives -- 4 Chiral imidazolidinones: A class of priviliged organocatalysts in stereoselective organic synthesis -- 5 Phase-transfer catalysis and the ion pair concept -- 6 Stereoselective organocascades: from fundamentals to recent developments -- 7 Basic principles of substrate activation through non-covalent bond interactions -- 8 Recent developments in stereoselective organocatalytic oxyfunctionalizations -- 9 Stereoselective synergystic organo photoredox catalysis with enamines and iminiums -- 10 Stereoselective organocatalysis and flow chemistry -- 11 Enantioselective organocatalytic approaches to active pharmaceutical ingredients – selected industrial examples -- Index |
| Record Nr. | UNINA-9910554490003321 |
| Berlin ; ; Boston : , : Walter de Gruyter GmbH, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Quaternary stereocenters [[electronic resource] ] : challenges and solutions for organic synthesis / / edited by Jens Christoffers, Angelika Baro
| Quaternary stereocenters [[electronic resource] ] : challenges and solutions for organic synthesis / / edited by Jens Christoffers, Angelika Baro |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (362 p.) |
| Disciplina | 547.1223 |
| Altri autori (Persone) |
ChristoffersJens
BaroAngelika |
| Soggetto topico |
Stereochemistry
Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-85406-5
9786610854066 3-527-60685-8 3-527-60697-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Quaternary Stereocenters; Contents; Foreword; Preface; List of Contributors; Symbols and Abbreviations; 1 Important Natural Products; 1.1 Introduction; 1.2 Alkylation of Tertiary Carbon Centers; 1.3 Cycloaddition to Alkenes; 1.3.1 Diels-Alder Reaction; 1.3.2 Other Types of Cycloaddition; 1.4 Rearrangement Reactions; 1.5 Carbometallation Reactions; 1.5.1 Addition of a Carbon Nucleophile to a β,β-Disubstituted α,β-Unsaturated Enone; 1.5.2 Asymmetric and Diastereomeric Addition of a Carbon Nucleophile to Unactivated Alkenes Catalyzed by Palladium [42]; 1.6 C-H Functionalization Reactions
1.7 Asymmetric Modification of Enantiotopic/Diastereotopic Substituents of Quaternary Carbon Centers1.8 Summary; 2 Important Pharmaceuticals and Intermediates; 2.1 The Chirality of Drugs and Agrochemicals; 2.2 Steroids; 2.3 Pharmaceuticals and Agrochemicals Based on α-Dialkylated Amino Acids; 2.4 Azole Antimycotics; 2.5 Alkaloids; 2.6 HIV Inhibitors; 2.7 β-Lactam Antibiotics; 2.8 The Tetracyclines; 2.9 Summary and Outlook; 3 Aldol Reactions; 3.1 Introduction; 3.2 Metal Enolates; 3.2.1 Lithium Enolates; 3.2.2 Titanium and Zirconium Enolates; 3.2.3 Boron Enolates; 3.3 Catalytic Aldol Additions 3.3.1 Fluoride-ion-mediated Aldol Addition3.3.2 Lewis-acid-mediated Mukaiyama-type Aldol Reactions; 3.3.3 Direct Aldol Additions; 3.3.4 Organocatalysis; 3.3.5 Enzyme and Antibody Catalysis; 3.4 Conclusions; 3.5 Note Added in Proof; 4 Michael Reactions and Conjugate Additions; 4.1 Introduction; 4.2 Chiral Brönstedt Bases; 4.2.1 Cinchona Alkaloids; 4.2.2 Polymer-bound Alkaloids; 4.2.3 Organocatalysis; 4.2.4 Miscellaneous Examples; 4.3 Chiral Metal Complexes; 4.3.1 Cobalt and Copper Catalysis; 4.3.2 Rhodium Catalysis; 4.3.3 Heterobimetallic Catalysis; 4.3.4 Miscellaneous Examples 4.4 Chiral Auxiliaries4.4.1 α-Phenethylamine; 4.4.2 L-Valine Ester; 4.4.3 L-Valine Diethylamide; 4.4.4 Miscellaneous Examples; 5 Rearrangement Reactions; 5.1 Introduction; 5.2 Applications; 5.2.1 The Claisen Rearrangement; 5.2.2 The Overman Rearrangement; 5.2.3 The Cope Rearrangement; 5.2.4 The Wittig Rearrangement; 5.2.5 Semipinacol Rearrangements; 5.2.6 Miscellaneous; 5.3 Summary; 6 Cycloaddition Reactions; 6.1 Introduction; 6.2 [2+1] Cycloaddition Reactions; 6.3 [2+2] Cycloaddition Reactions; 6.4 1,3-Dipolar Cycloaddition Reactions; 6.4.1 Nitrone Cycloadditions 6.4.2 Other 1,3-Dipolar Cycloadditions6.5 Diels-Alder Reactions; 6.6 Hetero-Diels-Alder Reactions; 6.6.1 The Carbonyl Group as Dienophile; 6.6.2 α,β-Unsaturated Carbonyl Derivatives as Heterodienes; 6.6.3 Imine Derivatives as Heterodienophiles; 6.7 Consecutive Cycloaddition Reactions; 7 Asymmetric Cross-coupling and Mizoroki-Heck Reactions; 7.1 The Asymmetric Heck Reaction; 7.1.1 Introduction; 7.1.2 Mizoroki-Heck Reaction Mechanism; 7.1.3 Asymmetric Formation of Quaternary Carbon Centers; 7.2 Metal-catalyzed Cross-coupling Reactions; 7.2.1 Palladium-catalyzed α-Arylation 7.2.2 Palladium-catalyzed α-Vinylation |
| Record Nr. | UNINA-9910144324603321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Quaternary stereocenters [[electronic resource] ] : challenges and solutions for organic synthesis / / edited by Jens Christoffers, Angelika Baro
| Quaternary stereocenters [[electronic resource] ] : challenges and solutions for organic synthesis / / edited by Jens Christoffers, Angelika Baro |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (362 p.) |
| Disciplina | 547.1223 |
| Altri autori (Persone) |
ChristoffersJens
BaroAngelika |
| Soggetto topico |
Stereochemistry
Organic compounds - Synthesis |
| ISBN |
1-280-85406-5
9786610854066 3-527-60685-8 3-527-60697-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Quaternary Stereocenters; Contents; Foreword; Preface; List of Contributors; Symbols and Abbreviations; 1 Important Natural Products; 1.1 Introduction; 1.2 Alkylation of Tertiary Carbon Centers; 1.3 Cycloaddition to Alkenes; 1.3.1 Diels-Alder Reaction; 1.3.2 Other Types of Cycloaddition; 1.4 Rearrangement Reactions; 1.5 Carbometallation Reactions; 1.5.1 Addition of a Carbon Nucleophile to a β,β-Disubstituted α,β-Unsaturated Enone; 1.5.2 Asymmetric and Diastereomeric Addition of a Carbon Nucleophile to Unactivated Alkenes Catalyzed by Palladium [42]; 1.6 C-H Functionalization Reactions
1.7 Asymmetric Modification of Enantiotopic/Diastereotopic Substituents of Quaternary Carbon Centers1.8 Summary; 2 Important Pharmaceuticals and Intermediates; 2.1 The Chirality of Drugs and Agrochemicals; 2.2 Steroids; 2.3 Pharmaceuticals and Agrochemicals Based on α-Dialkylated Amino Acids; 2.4 Azole Antimycotics; 2.5 Alkaloids; 2.6 HIV Inhibitors; 2.7 β-Lactam Antibiotics; 2.8 The Tetracyclines; 2.9 Summary and Outlook; 3 Aldol Reactions; 3.1 Introduction; 3.2 Metal Enolates; 3.2.1 Lithium Enolates; 3.2.2 Titanium and Zirconium Enolates; 3.2.3 Boron Enolates; 3.3 Catalytic Aldol Additions 3.3.1 Fluoride-ion-mediated Aldol Addition3.3.2 Lewis-acid-mediated Mukaiyama-type Aldol Reactions; 3.3.3 Direct Aldol Additions; 3.3.4 Organocatalysis; 3.3.5 Enzyme and Antibody Catalysis; 3.4 Conclusions; 3.5 Note Added in Proof; 4 Michael Reactions and Conjugate Additions; 4.1 Introduction; 4.2 Chiral Brönstedt Bases; 4.2.1 Cinchona Alkaloids; 4.2.2 Polymer-bound Alkaloids; 4.2.3 Organocatalysis; 4.2.4 Miscellaneous Examples; 4.3 Chiral Metal Complexes; 4.3.1 Cobalt and Copper Catalysis; 4.3.2 Rhodium Catalysis; 4.3.3 Heterobimetallic Catalysis; 4.3.4 Miscellaneous Examples 4.4 Chiral Auxiliaries4.4.1 α-Phenethylamine; 4.4.2 L-Valine Ester; 4.4.3 L-Valine Diethylamide; 4.4.4 Miscellaneous Examples; 5 Rearrangement Reactions; 5.1 Introduction; 5.2 Applications; 5.2.1 The Claisen Rearrangement; 5.2.2 The Overman Rearrangement; 5.2.3 The Cope Rearrangement; 5.2.4 The Wittig Rearrangement; 5.2.5 Semipinacol Rearrangements; 5.2.6 Miscellaneous; 5.3 Summary; 6 Cycloaddition Reactions; 6.1 Introduction; 6.2 [2+1] Cycloaddition Reactions; 6.3 [2+2] Cycloaddition Reactions; 6.4 1,3-Dipolar Cycloaddition Reactions; 6.4.1 Nitrone Cycloadditions 6.4.2 Other 1,3-Dipolar Cycloadditions6.5 Diels-Alder Reactions; 6.6 Hetero-Diels-Alder Reactions; 6.6.1 The Carbonyl Group as Dienophile; 6.6.2 α,β-Unsaturated Carbonyl Derivatives as Heterodienes; 6.6.3 Imine Derivatives as Heterodienophiles; 6.7 Consecutive Cycloaddition Reactions; 7 Asymmetric Cross-coupling and Mizoroki-Heck Reactions; 7.1 The Asymmetric Heck Reaction; 7.1.1 Introduction; 7.1.2 Mizoroki-Heck Reaction Mechanism; 7.1.3 Asymmetric Formation of Quaternary Carbon Centers; 7.2 Metal-catalyzed Cross-coupling Reactions; 7.2.1 Palladium-catalyzed α-Arylation 7.2.2 Palladium-catalyzed α-Vinylation |
| Record Nr. | UNINA-9910830617403321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Quaternary stereocenters [[electronic resource] ] : challenges and solutions for organic synthesis / / edited by Jens Christoffers, Angelika Baro
| Quaternary stereocenters [[electronic resource] ] : challenges and solutions for organic synthesis / / edited by Jens Christoffers, Angelika Baro |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (362 p.) |
| Disciplina | 547.1223 |
| Altri autori (Persone) |
ChristoffersJens
BaroAngelika |
| Soggetto topico |
Stereochemistry
Organic compounds - Synthesis |
| ISBN |
1-280-85406-5
9786610854066 3-527-60685-8 3-527-60697-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Quaternary Stereocenters; Contents; Foreword; Preface; List of Contributors; Symbols and Abbreviations; 1 Important Natural Products; 1.1 Introduction; 1.2 Alkylation of Tertiary Carbon Centers; 1.3 Cycloaddition to Alkenes; 1.3.1 Diels-Alder Reaction; 1.3.2 Other Types of Cycloaddition; 1.4 Rearrangement Reactions; 1.5 Carbometallation Reactions; 1.5.1 Addition of a Carbon Nucleophile to a β,β-Disubstituted α,β-Unsaturated Enone; 1.5.2 Asymmetric and Diastereomeric Addition of a Carbon Nucleophile to Unactivated Alkenes Catalyzed by Palladium [42]; 1.6 C-H Functionalization Reactions
1.7 Asymmetric Modification of Enantiotopic/Diastereotopic Substituents of Quaternary Carbon Centers1.8 Summary; 2 Important Pharmaceuticals and Intermediates; 2.1 The Chirality of Drugs and Agrochemicals; 2.2 Steroids; 2.3 Pharmaceuticals and Agrochemicals Based on α-Dialkylated Amino Acids; 2.4 Azole Antimycotics; 2.5 Alkaloids; 2.6 HIV Inhibitors; 2.7 β-Lactam Antibiotics; 2.8 The Tetracyclines; 2.9 Summary and Outlook; 3 Aldol Reactions; 3.1 Introduction; 3.2 Metal Enolates; 3.2.1 Lithium Enolates; 3.2.2 Titanium and Zirconium Enolates; 3.2.3 Boron Enolates; 3.3 Catalytic Aldol Additions 3.3.1 Fluoride-ion-mediated Aldol Addition3.3.2 Lewis-acid-mediated Mukaiyama-type Aldol Reactions; 3.3.3 Direct Aldol Additions; 3.3.4 Organocatalysis; 3.3.5 Enzyme and Antibody Catalysis; 3.4 Conclusions; 3.5 Note Added in Proof; 4 Michael Reactions and Conjugate Additions; 4.1 Introduction; 4.2 Chiral Brönstedt Bases; 4.2.1 Cinchona Alkaloids; 4.2.2 Polymer-bound Alkaloids; 4.2.3 Organocatalysis; 4.2.4 Miscellaneous Examples; 4.3 Chiral Metal Complexes; 4.3.1 Cobalt and Copper Catalysis; 4.3.2 Rhodium Catalysis; 4.3.3 Heterobimetallic Catalysis; 4.3.4 Miscellaneous Examples 4.4 Chiral Auxiliaries4.4.1 α-Phenethylamine; 4.4.2 L-Valine Ester; 4.4.3 L-Valine Diethylamide; 4.4.4 Miscellaneous Examples; 5 Rearrangement Reactions; 5.1 Introduction; 5.2 Applications; 5.2.1 The Claisen Rearrangement; 5.2.2 The Overman Rearrangement; 5.2.3 The Cope Rearrangement; 5.2.4 The Wittig Rearrangement; 5.2.5 Semipinacol Rearrangements; 5.2.6 Miscellaneous; 5.3 Summary; 6 Cycloaddition Reactions; 6.1 Introduction; 6.2 [2+1] Cycloaddition Reactions; 6.3 [2+2] Cycloaddition Reactions; 6.4 1,3-Dipolar Cycloaddition Reactions; 6.4.1 Nitrone Cycloadditions 6.4.2 Other 1,3-Dipolar Cycloadditions6.5 Diels-Alder Reactions; 6.6 Hetero-Diels-Alder Reactions; 6.6.1 The Carbonyl Group as Dienophile; 6.6.2 α,β-Unsaturated Carbonyl Derivatives as Heterodienes; 6.6.3 Imine Derivatives as Heterodienophiles; 6.7 Consecutive Cycloaddition Reactions; 7 Asymmetric Cross-coupling and Mizoroki-Heck Reactions; 7.1 The Asymmetric Heck Reaction; 7.1.1 Introduction; 7.1.2 Mizoroki-Heck Reaction Mechanism; 7.1.3 Asymmetric Formation of Quaternary Carbon Centers; 7.2 Metal-catalyzed Cross-coupling Reactions; 7.2.1 Palladium-catalyzed α-Arylation 7.2.2 Palladium-catalyzed α-Vinylation |
| Record Nr. | UNINA-9910840944603321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang
| Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang |
| Autore | Yang Jaemoon |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2008 |
| Descrizione fisica | 1 online resource (222 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Reaction mechanisms (Chemistry)
Stereochemistry Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-23726-4
9786611237264 0-470-19905-9 0-470-19904-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SIX-MEMBERED TRANSITION STATES IN ORGANIC SYNTHESIS; CONTENTS; Preface; Acknowledgments; Introduction; 1 [3,3]-Sigmatropic Rearrangements; General Considerations; Reactions; 1.1 Claisen Rearrangement; 1.2 Johnson-Claisen Rearrangement; 1.3 Ireland-Claisen Rearrangement; 1.4 Cope Rearrangement; 1.5 Anionic Oxy-Cope Rearrangement; 1.6 Aza-Cope-Mannich Reaction; 2 Aldol Reactions; General Considerations; Reactions; 2.1 Asymmetric Syn-Aldol Reaction; 2.2 Asymmetric Anti-Aldol Reaction; 2.3 Proline-Catalyzed Asymmetric Aldol Reaction; 3 Metal Allylation Reactions; General Considerations; Reactions
3.1 Boron Allylation Reaction3.2 Silicon Allylation Reaction; 4 Stereoselective Reductions; General Considerations; Reactions; 4.1 Diastereoselective Syn-Reduction of β-Hydroxy Ketones; 4.2 Diastereoselective Anti-Reduction of β-Hydroxy Ketones; 4.3 Asymmetric Reduction; List of Copyrighted Materials; Abbreviations; Subject Index; Scheme Index of Natural Products |
| Record Nr. | UNINA-9910145587403321 |
|
Yang Jaemoon
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||
| Hoboken, N.J., : Wiley-Interscience, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang
| Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang |
| Autore | Yang Jaemoon |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2008 |
| Descrizione fisica | 1 online resource (222 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Reaction mechanisms (Chemistry)
Stereochemistry Organic compounds - Synthesis |
| ISBN |
1-281-23726-4
9786611237264 0-470-19905-9 0-470-19904-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SIX-MEMBERED TRANSITION STATES IN ORGANIC SYNTHESIS; CONTENTS; Preface; Acknowledgments; Introduction; 1 [3,3]-Sigmatropic Rearrangements; General Considerations; Reactions; 1.1 Claisen Rearrangement; 1.2 Johnson-Claisen Rearrangement; 1.3 Ireland-Claisen Rearrangement; 1.4 Cope Rearrangement; 1.5 Anionic Oxy-Cope Rearrangement; 1.6 Aza-Cope-Mannich Reaction; 2 Aldol Reactions; General Considerations; Reactions; 2.1 Asymmetric Syn-Aldol Reaction; 2.2 Asymmetric Anti-Aldol Reaction; 2.3 Proline-Catalyzed Asymmetric Aldol Reaction; 3 Metal Allylation Reactions; General Considerations; Reactions
3.1 Boron Allylation Reaction3.2 Silicon Allylation Reaction; 4 Stereoselective Reductions; General Considerations; Reactions; 4.1 Diastereoselective Syn-Reduction of β-Hydroxy Ketones; 4.2 Diastereoselective Anti-Reduction of β-Hydroxy Ketones; 4.3 Asymmetric Reduction; List of Copyrighted Materials; Abbreviations; Subject Index; Scheme Index of Natural Products |
| Record Nr. | UNINA-9910830049403321 |
|
Yang Jaemoon
|
||
| Hoboken, N.J., : Wiley-Interscience, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang
| Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang |
| Autore | Yang Jaemoon |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2008 |
| Descrizione fisica | 1 online resource (222 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Reaction mechanisms (Chemistry)
Stereochemistry Organic compounds - Synthesis |
| ISBN |
1-281-23726-4
9786611237264 0-470-19905-9 0-470-19904-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SIX-MEMBERED TRANSITION STATES IN ORGANIC SYNTHESIS; CONTENTS; Preface; Acknowledgments; Introduction; 1 [3,3]-Sigmatropic Rearrangements; General Considerations; Reactions; 1.1 Claisen Rearrangement; 1.2 Johnson-Claisen Rearrangement; 1.3 Ireland-Claisen Rearrangement; 1.4 Cope Rearrangement; 1.5 Anionic Oxy-Cope Rearrangement; 1.6 Aza-Cope-Mannich Reaction; 2 Aldol Reactions; General Considerations; Reactions; 2.1 Asymmetric Syn-Aldol Reaction; 2.2 Asymmetric Anti-Aldol Reaction; 2.3 Proline-Catalyzed Asymmetric Aldol Reaction; 3 Metal Allylation Reactions; General Considerations; Reactions
3.1 Boron Allylation Reaction3.2 Silicon Allylation Reaction; 4 Stereoselective Reductions; General Considerations; Reactions; 4.1 Diastereoselective Syn-Reduction of β-Hydroxy Ketones; 4.2 Diastereoselective Anti-Reduction of β-Hydroxy Ketones; 4.3 Asymmetric Reduction; List of Copyrighted Materials; Abbreviations; Subject Index; Scheme Index of Natural Products |
| Record Nr. | UNINA-9910841657303321 |
|
Yang Jaemoon
|
||
| Hoboken, N.J., : Wiley-Interscience, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Stereochemistry of organic compounds / / V. K. Ahluwalia
| Stereochemistry of organic compounds / / V. K. Ahluwalia |
| Autore | Ahluwalia V. K. |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2022] |
| Descrizione fisica | 1 online resource (615 pages) |
| Disciplina | 543.62 |
| Soggetto topico |
Organic compounds
Stereochemistry Chemistry, Organic |
| ISBN |
9783030849610
9783030849603 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910523773603321 |
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Ahluwalia V. K.
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| Cham, Switzerland : , : Springer, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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