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Chiral separations and stereochemical elucidation : fundamentals, methods, and applications / / edited by João Marcos Batista Junior [and three others]
| Chiral separations and stereochemical elucidation : fundamentals, methods, and applications / / edited by João Marcos Batista Junior [and three others] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2023] |
| Descrizione fisica | 1 online resource (643 pages) |
| Disciplina | 541.223 |
| Soggetto topico |
Chirality
Stereochemistry |
| ISBN |
1-119-80228-8
1-119-80227-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover -- Title Page -- Copyright Page -- Contents -- List of Contributors -- Preface -- Part I Fundamentals of Chiral Separation -- Chapter 1 Chiral Separation by LC -- 1.1 Introduction -- 1.2 Workflow for LC Chiral Method Development -- 1.3 New Column Technologies -- 1.4 Selected Examples of Fast Separation -- 1.5 Chiral 2D-LC -- 1.5.1 LC-LC and mLC-LC -- 1.5.2 LC × LC and sLC × LC -- 1.6 Future and Perspectives -- References -- Chapter 2 Chiral Separation by GC -- 2.1 Introduction -- 2.2 Chiral Recognition in Gas Chromatography -- 2.2.1 Chiral Recognition by Hydrogen Bonding -- 2.2.2 Chiral Recognition Using Chiral Metal Complexes -- 2.2.3 Chiral Recognition by Host-Guest Interactions -- 2.3 Preparation of Fused-Silica Capillaries for GC with CSPs -- 2.4 Application of CSPs in Chiral Gas Chromatography -- 2.4.1 CSPs with Diamide Selectors -- 2.4.1.1 Chirasil-Val -- 2.4.2 CSPs with CD Selectors -- 2.4.2.1 Heptakis(2,3,6-tri-O-Methyl)-β-Cyclodextrin(Permethyl-β-Cyclodextrin) -- 2.4.2.2 Heptakis(2,3,6-tri-O-Methyl)-β-Cyclodextrin Immobilized to Hydrido Dimethyl Polysiloxane (Chirasil-β-Dex) -- 2.4.2.3 Heptakis(2,6-di-O-Methyl-3-O-Pentyl)-β-Cyclodextrin -- 2.4.2.4 Hexakis-(2,3,6-tri-O-Pentyl)-α-Cyclodextrin -- 2.4.2.5 Heptakis(2,3,6-tri-O-Pentyl)-β-Cyclodextrin -- 2.4.2.6 Hexakis-(3-O-Acetyl-2,6-di-O-Pentyl)-α-Cyclodextrin -- 2.4.2.7 Heptakis(3-O-Acetyl-2,6-di-O-Pentyl)-β-Cyclodextrin -- 2.4.2.8 Octakis(3-O-Butyryl-2,6-di-O-Pentyl)-γ-Cyclodextrin -- 2.4.2.9 Hexakis/Heptakis/Octakis(2,6-di-O-Alkyl-3-O-Trifluoroacetyl)-α/β/γ-Cyclodextrins -- 2.4.2.10 Heptakis(2,3-di-O-Acetyl-6-O-tert-Butyldimethylsilyl)-β-Cyclodextrin (DIAC-6-TBDMS-β-CD) -- 2.4.2.11 Heptakis(2,3-di-O-Methyl-6-O-tert-Butyldimethylsilyl)-β-Cyclodextrin (DIME-6-TBDMS-β-CD) -- 2.4.3 Cyclofructans -- 2.4.4 CSPs with Metal Complexes -- 2.5 Conclusion -- References.
Chapter 3 Chiral Separation by Supercritical Fluid Chromatography -- 3.1 Introduction -- 3.2 Characteristics and Properties of Supercritical Fluids -- 3.3 Development of a Chiral SFC Method -- 3.3.1 Chiral Stationary Phases -- 3.3.2 Mobile Phases -- 3.3.2.1 Mobile Phase: Type of Co-solvent Used -- 3.3.2.2 Mobile Phase: Percentage of Co-solvent Used -- 3.3.2.3 Mobile Phase: Use of Additives -- 3.4 Operating Parameters -- 3.4.1 Effect of the Flow Rate -- 3.4.2 Effect of the Outlet Pressure (Back-pressure) -- 3.4.2.1 Effect of Pressure When the Mobile Phase is a Gas-Like Fluid -- 3.4.2.2 Effect of Pressure When the Mobile Phase is a Liquid-Like Fluid -- 3.4.3 Effect of Temperature -- 3.4.3.1 Effect of Temperature When the Mobile Phase is a Gas-Like Fluid -- 3.4.3.2 Effect of Temperature When the Mobile Phase is a Liquid-Like Fluid -- 3.5 Detection -- 3.6 Scale-Up to Preparative Separation -- 3.7 Conclusion -- References -- Chapter 4 Chiral Separation by Capillary Electrophoresis and Capillary Electrophoresis-Mass Spectrometry: Fundamentals, Recent Developments, and Applications -- 4.1 Introduction -- 4.2 Principles of Chiral CE -- 4.2.1 Electrophoretic Mobility -- 4.2.2 CE Separation Efficiency -- 4.2.3 Chiral Resolution in CE -- 4.2.4 Chiral Micellar Electrokinetic Chromatography and Capillary Electrochromatography -- 4.3 Short History of Chiral CE Modes -- 4.3.1 Chiral CE -- 4.3.2 Chiral MEKC and Chiral CEC -- 4.4 State of the Art and Recent Developments -- 4.4.1 Common Chiral Selectors -- 4.4.2 Ionic Liquids as Chiral Selectors -- 4.4.3 Nanoparticles as Chiral Selector Carriers -- 4.4.4 Microfluidic Chiral CE -- 4.5 Applications of Chiral CE -- 4.5.1 Pharmaceutical Analysis -- 4.5.2 Food Analysis -- 4.5.3 Environmental Analysis -- 4.5.4 Bioanalysis -- 4.5.5 Forensic Analysis -- 4.6 Chiral CE-MS: Strategies and Challenges. 4.6.1 Hyphenation Approaches -- 4.6.1.1 Sheath-Liquid and Sheathless CE-MS Interfacing -- 4.6.1.2 Partial-Filling Techniques -- 4.6.1.3 Counter-Migration Techniques -- 4.6.2 Chiral MEKC-MS -- 4.6.3 Chiral CEC-MS -- 4.7 Conclusions and Perspectives -- References -- Chapter 5 Chiral Separations at Semi and Preparative Scale -- 5.1 Introduction -- 5.2 Selection of Operating Conditions -- 5.3 Batch HPLC Purification -- 5.3.1 Analytical Method Development for Preparative Separations -- 5.3.2 Batch HPLC Examples -- 5.3.2.1 Batch HPLC Example 1 -- 5.3.2.2 Batch HPLC Example 2 -- 5.4 Steady-State Recycle Introduction -- 5.4.1 SSR Example 1 -- 5.5 Simulated Moving Bed Chromatography - Introduction -- 5.5.1 SMB Examples for R& -- D and Separation of Compound 2 -- 5.5.2 Development of a Manufacturing SMB Process (Compound 1) -- 5.5.3 Cost for SMB Processes -- 5.6 Introduction to Supercritical Fluid Chromatography -- 5.6.1 Analytical Method Development for Scale-up to Preparative SFC -- 5.6.2 Preparative SFC Example 1 -- 5.6.3 Preparative SFC Example 2 -- 5.7 Options for Increasing Purification Productivity -- 5.7.1 Closed-Loop Recycling -- 5.7.2 Stacked Injections -- 5.7.3 Choosing the Best Synthetic Intermediate for Separation -- 5.7.3.1 Choosing Synthetic Step for Separation - HPLC/SMB Example -- 5.7.3.2 Choosing Synthetic Step for Separation - SFC Example -- 5.7.4 Use of Non-Commercialized CSP -- 5.7.5 Immobilized CSP for Preparative Resolution -- 5.7.5.1 Processing of Low Solubility Racemate -- 5.7.5.2 Preparative Resolution of EMD 53986 -- 5.8 Choosing a Technique for Preparative Enantioseparation -- 5.9 Conclusion -- References -- Part II Chiral Selectors -- Chapter 6 Polysaccharides -- 6.1 Introduction -- 6.2 The Early Years -- 6.3 Polysaccharide Chiral Separation Mechanism -- 6.4 Coated Chiral Stationary Phases. 6.5 Immobilized Chiral Stationary Phases -- 6.6 Applications of Polysaccharide-Derived CSPs -- 6.6.1 Analytical Applications -- 6.6.1.1 Pharmaceuticals -- 6.6.1.2 Agrochemicals -- 6.6.1.3 Food Analysis -- 6.6.2 Preparative Applications -- 6.7 Summation -- References -- Chapter 7 Macrocyclic Antibiotics and Cyclofructans -- 7.1 Introduction -- 7.2 Macrocyclic Glycopeptides Physicochemical Properties -- 7.3 Using the Chiral Macrocyclic Glycopeptides Stationary Phases -- 7.3.1 Mobile Phases and Chromatographic Modes -- 7.3.2 Chromatographic Enantioseparations -- 7.3.2.1 Amino Acids and Peptides -- 7.3.2.2 Chiral Compounds -- 7.3.2.3 Particle Structure -- 7.4 Using and Protecting Macrocyclic Glycopeptide Chiral Columns -- 7.4.1 Operating Conditions -- 7.4.2 Storage -- 7.5 Cyclofructans -- 7.5.1 Cyclofructan Structure and Properties -- 7.5.2 Chiral Separations with Cyclofructan-Based Stationary Phases -- 7.5.3 Cyclofructan Stationary Phases Used in the HILIC Mode -- 7.5.4 Cyclofructan Stationary Phases Used in Supercritical Fluid Chromatography -- 7.6 Conclusions -- References -- Chapter 8 Cyclodextrins -- 8.1 Introduction -- 8.2 Structure and Properties -- 8.3 Cyclodextrin Complexes -- 8.4 Application in Separation Science -- 8.4.1 Gas Chromatography -- 8.4.1.1 Types of Cyclodextrins -- 8.4.1.2 Types of Columns -- 8.4.1.3 Separation Mechanisms -- 8.4.1.4 Applications -- 8.4.2 Thin-Layer Chromatography -- 8.4.3 High-Performance Liquid Chromatography -- 8.4.3.1 Types of Columns -- 8.4.3.2 Types of Cyclodextrins -- 8.4.3.3 Separation Mechanisms -- 8.4.3.4 Applications -- 8.4.4 Supercritical Fluid Chromatography -- 8.4.5 Capillary Electromigration Techniques -- 8.4.5.1 Types of Cyclodextrins -- 8.4.5.2 Separation Mechanisms -- 8.4.5.3 Migration Modes and Enantiomer Migration Order Using CDs as Selectors -- 8.4.5.4 Applications -- 8.4.6 Membrane Technologies. 8.5 Miscellaneous Applications -- 8.6 Conclusions and Outlook -- References -- Chapter 9 Pirkle Type -- 9.1 Introduction -- 9.2 CSPs Developed by Pirkle's Group: Chronological Evolution -- 9.3 Pirkle-Type CSPs Developed by Other Research Groups -- 9.4 Example of Applications in Analytical and Preparative Scales -- 9.4.1 Analytical Applications -- 9.4.2 Preparative Applications -- 9.5 Conclusions and Perspectives -- References -- Chapter 10 Proteins -- 10.1 Introduction -- 10.2 Preparation of Protein-and Glycoprotein-Based Chiral Stationary Phases -- 10.3 Types of Protein-and Glycoprotein-Based Chiral Stationary Phases -- 10.3.1 Proteins -- 10.3.1.1 Bovine Serum Albumin -- 10.3.1.2 Human Serum Albumin -- 10.3.1.3 Trypsin and α-Chymotrypsin -- 10.3.1.4 Lysozyme and Pepsin -- 10.3.1.5 Fatty Acid-Binding Protein -- 10.3.1.6 Penicillin G Acylase -- 10.3.1.7 Streptavidin -- 10.3.1.8 Lipase -- 10.3.2 Glycoproteins -- 10.3.2.1 Human α1-Acid Glycoprotein -- 10.3.2.2 Chicken Ovomucoid -- 10.3.2.3 Chicken α1-Acid Glycoprotein -- 10.3.2.4 Avidin -- 10.3.2.5 Riboflavin-Binding Protein and Ovotransferrin -- 10.3.2.6 Cellobiohydrolase -- 10.3.2.7 Glucoamylase -- 10.3.2.8 Antibody (Immunoglobulin G) -- 10.3.2.9 Nicotinic Acetylcholine Receptor and Human Liver Organic Cation Transporter -- 10.4 Chiral Recognition Mechanisms on Protein-and Glycoprotein-Based Chiral Stationary Phases -- 10.4.1 Human Serum Albumin -- 10.4.2 Penicillin G Acylase -- 10.4.3 Human α1-Acid Glycoprotein -- 10.4.4 Turkey Ovomucoid -- 10.4.5 Chicken α1-Acid Glycoprotein -- 10.4.6 Cellobiohydrolase -- 10.4.7 Antibody -- 10.4.8 Nicotinic Acetylcholine Receptor and Human Liver Organic Cation Transporter -- 10.5 Conclusions -- References -- Chapter 11 Chiral Stationary Phases Derived from Cinchona Alkaloids -- 11.1 Introduction -- 11.2 Cinchona Alkaloid-Derived Chiral Stationary Phases. 11.3 Chiral Recognition. |
| Record Nr. | UNINA-9910684596903321 |
| Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2023] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cis-trans isomerization in biochemistry [[electronic resource] /] / edited by Christophe Dugave
| Cis-trans isomerization in biochemistry [[electronic resource] /] / edited by Christophe Dugave |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (372 p.) |
| Disciplina |
547.12252
547.7804452 |
| Altri autori (Persone) | DugaveChristophe |
| Soggetto topico |
Biomolecules
Stereochemistry Isomerism Biochemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-72283-5
9786610722839 3-527-60933-4 3-527-60949-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
cis-trans Isomerization in Biochemistry; Contents; Preface; List of Contributors; 1 Nomenclature; 2 General Mechanisms of Cis-Trans Isomerization: A Rapid Survey; 2.1 Introduction; 2.2 Homolytic Cis-Trans Isomerization; 2.3 Heterolytic Cis-Trans Isomerization; 3 Mechanisms of Cis-Trans Isomerization around the Carbon-Carbon Double Bonds via the Triplet State; 3.1 A Concept of a Triplet-Excited Region; 3.2 Triplet-State Isomerization in Retinal; 3.2.1 Cis-Trans Isomerization Examined by Electronic Absorption and Raman Spectroscopies and by High-Performance Liquid Chromatography Analysis
3.2.2 Triplet-Excited Region in All-trans-Retinal Shown in Terms of Stretching Force Constants Determined by Raman Spectroscopy and Normal Coordinate Analysis [9]3.2.3 Dynamic Triplet-Excited Region in Retinal As Revealed by Deuteration Effects on the Quantum Yields of Isomerization via the T(1) State (Okumura, Koyama, unpublished results); 3.2.4 Summary and Future Trends; 3.3 Triplet-State Isomerization in β-Carotene and Spheroidene; 3.3.1 Cis-Trans Isomerization in β-Carotene Studied by Electronic Absorption and Raman Spectroscopies and by HPLC Analysis 3.3.2 Cis-Trans Isomerization in Spheroidene Studied by Time-Resolved Absorption Spectroscopy and by HPLC Analysis [17]3.3.3 The Triplet-Excited Region of All-trans-Spheroidene in Solution and the Triplet-State Structure of 15-cis-Spheroidene Bound to the Bacterial Reaction Center Determined by Raman Spectroscopy and Normal Coordinate Analysis [18]; 3.3.3.1 All-trans-Spheroidene in Solution; 3.3.3.2 15-cis-Spheroidene Bound to the Reaction Center 3.3.4 Conformational Changes and the Inversion of Spin-Polarization Identified by Low-Temperature Electron Paramagnetic Resonance Spectroscopy of the Reaction Center-Bound 15-cis-Spheroidene: A Hypothetical Mechanism of Triplet-Energy Dissipation [19]3.3.5 Summary and Future Trends; 3.4 Spectroscopic and Analytical Techniques for Studying Cis-Trans Isomerization in the T(1) State; 3.4.1 Spectroscopic Techniques: Electronic Absorption, Raman, and Magnetic Resonance Spectroscopies; 3.4.2 A Useful Analytical Technique: Singular-Value Decomposition Followed by Global Fitting [23-25] 4 Retinal Binding Proteins4.1 Retinal Chromophore in Rhodopsins; 4.1.1 Specific Color Regulation of the Retinal Chromophore in Protein; 4.1.2 Unique Photochemistry of the Retinal Chromophore in Protein; 4.2 Photoisomerization in Visual Rhodopsins; 4.2.1 Structure and Function of Visual Rhodopsins; 4.2.2 Primary Process in Vision Studied by Ultrafast Spectroscopy; 4.2.3 Structural Changes of the Chromophore and Protein upon Retinal Photoisomerization; 4.3 Photoisomerization in Archaeal Rhodopsins; 4.3.1 Structure and Function of Archaeal Rhodopsin 4.3.2 Primary Process in Bacterial Photosynthesis and Light Sensor Studied by Ultrafast Spectroscopy |
| Record Nr. | UNINA-9910144307703321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cis-trans isomerization in biochemistry [[electronic resource] /] / edited by Christophe Dugave
| Cis-trans isomerization in biochemistry [[electronic resource] /] / edited by Christophe Dugave |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (372 p.) |
| Disciplina |
547.12252
547.7804452 |
| Altri autori (Persone) | DugaveChristophe |
| Soggetto topico |
Biomolecules
Stereochemistry Isomerism Biochemistry |
| ISBN |
1-280-72283-5
9786610722839 3-527-60933-4 3-527-60949-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
cis-trans Isomerization in Biochemistry; Contents; Preface; List of Contributors; 1 Nomenclature; 2 General Mechanisms of Cis-Trans Isomerization: A Rapid Survey; 2.1 Introduction; 2.2 Homolytic Cis-Trans Isomerization; 2.3 Heterolytic Cis-Trans Isomerization; 3 Mechanisms of Cis-Trans Isomerization around the Carbon-Carbon Double Bonds via the Triplet State; 3.1 A Concept of a Triplet-Excited Region; 3.2 Triplet-State Isomerization in Retinal; 3.2.1 Cis-Trans Isomerization Examined by Electronic Absorption and Raman Spectroscopies and by High-Performance Liquid Chromatography Analysis
3.2.2 Triplet-Excited Region in All-trans-Retinal Shown in Terms of Stretching Force Constants Determined by Raman Spectroscopy and Normal Coordinate Analysis [9]3.2.3 Dynamic Triplet-Excited Region in Retinal As Revealed by Deuteration Effects on the Quantum Yields of Isomerization via the T(1) State (Okumura, Koyama, unpublished results); 3.2.4 Summary and Future Trends; 3.3 Triplet-State Isomerization in β-Carotene and Spheroidene; 3.3.1 Cis-Trans Isomerization in β-Carotene Studied by Electronic Absorption and Raman Spectroscopies and by HPLC Analysis 3.3.2 Cis-Trans Isomerization in Spheroidene Studied by Time-Resolved Absorption Spectroscopy and by HPLC Analysis [17]3.3.3 The Triplet-Excited Region of All-trans-Spheroidene in Solution and the Triplet-State Structure of 15-cis-Spheroidene Bound to the Bacterial Reaction Center Determined by Raman Spectroscopy and Normal Coordinate Analysis [18]; 3.3.3.1 All-trans-Spheroidene in Solution; 3.3.3.2 15-cis-Spheroidene Bound to the Reaction Center 3.3.4 Conformational Changes and the Inversion of Spin-Polarization Identified by Low-Temperature Electron Paramagnetic Resonance Spectroscopy of the Reaction Center-Bound 15-cis-Spheroidene: A Hypothetical Mechanism of Triplet-Energy Dissipation [19]3.3.5 Summary and Future Trends; 3.4 Spectroscopic and Analytical Techniques for Studying Cis-Trans Isomerization in the T(1) State; 3.4.1 Spectroscopic Techniques: Electronic Absorption, Raman, and Magnetic Resonance Spectroscopies; 3.4.2 A Useful Analytical Technique: Singular-Value Decomposition Followed by Global Fitting [23-25] 4 Retinal Binding Proteins4.1 Retinal Chromophore in Rhodopsins; 4.1.1 Specific Color Regulation of the Retinal Chromophore in Protein; 4.1.2 Unique Photochemistry of the Retinal Chromophore in Protein; 4.2 Photoisomerization in Visual Rhodopsins; 4.2.1 Structure and Function of Visual Rhodopsins; 4.2.2 Primary Process in Vision Studied by Ultrafast Spectroscopy; 4.2.3 Structural Changes of the Chromophore and Protein upon Retinal Photoisomerization; 4.3 Photoisomerization in Archaeal Rhodopsins; 4.3.1 Structure and Function of Archaeal Rhodopsin 4.3.2 Primary Process in Bacterial Photosynthesis and Light Sensor Studied by Ultrafast Spectroscopy |
| Record Nr. | UNINA-9910830730203321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cis-trans isomerization in biochemistry [[electronic resource] /] / edited by Christophe Dugave
| Cis-trans isomerization in biochemistry [[electronic resource] /] / edited by Christophe Dugave |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (372 p.) |
| Disciplina |
547.12252
547.7804452 |
| Altri autori (Persone) | DugaveChristophe |
| Soggetto topico |
Biomolecules
Stereochemistry Isomerism Biochemistry |
| ISBN |
1-280-72283-5
9786610722839 3-527-60933-4 3-527-60949-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
cis-trans Isomerization in Biochemistry; Contents; Preface; List of Contributors; 1 Nomenclature; 2 General Mechanisms of Cis-Trans Isomerization: A Rapid Survey; 2.1 Introduction; 2.2 Homolytic Cis-Trans Isomerization; 2.3 Heterolytic Cis-Trans Isomerization; 3 Mechanisms of Cis-Trans Isomerization around the Carbon-Carbon Double Bonds via the Triplet State; 3.1 A Concept of a Triplet-Excited Region; 3.2 Triplet-State Isomerization in Retinal; 3.2.1 Cis-Trans Isomerization Examined by Electronic Absorption and Raman Spectroscopies and by High-Performance Liquid Chromatography Analysis
3.2.2 Triplet-Excited Region in All-trans-Retinal Shown in Terms of Stretching Force Constants Determined by Raman Spectroscopy and Normal Coordinate Analysis [9]3.2.3 Dynamic Triplet-Excited Region in Retinal As Revealed by Deuteration Effects on the Quantum Yields of Isomerization via the T(1) State (Okumura, Koyama, unpublished results); 3.2.4 Summary and Future Trends; 3.3 Triplet-State Isomerization in β-Carotene and Spheroidene; 3.3.1 Cis-Trans Isomerization in β-Carotene Studied by Electronic Absorption and Raman Spectroscopies and by HPLC Analysis 3.3.2 Cis-Trans Isomerization in Spheroidene Studied by Time-Resolved Absorption Spectroscopy and by HPLC Analysis [17]3.3.3 The Triplet-Excited Region of All-trans-Spheroidene in Solution and the Triplet-State Structure of 15-cis-Spheroidene Bound to the Bacterial Reaction Center Determined by Raman Spectroscopy and Normal Coordinate Analysis [18]; 3.3.3.1 All-trans-Spheroidene in Solution; 3.3.3.2 15-cis-Spheroidene Bound to the Reaction Center 3.3.4 Conformational Changes and the Inversion of Spin-Polarization Identified by Low-Temperature Electron Paramagnetic Resonance Spectroscopy of the Reaction Center-Bound 15-cis-Spheroidene: A Hypothetical Mechanism of Triplet-Energy Dissipation [19]3.3.5 Summary and Future Trends; 3.4 Spectroscopic and Analytical Techniques for Studying Cis-Trans Isomerization in the T(1) State; 3.4.1 Spectroscopic Techniques: Electronic Absorption, Raman, and Magnetic Resonance Spectroscopies; 3.4.2 A Useful Analytical Technique: Singular-Value Decomposition Followed by Global Fitting [23-25] 4 Retinal Binding Proteins4.1 Retinal Chromophore in Rhodopsins; 4.1.1 Specific Color Regulation of the Retinal Chromophore in Protein; 4.1.2 Unique Photochemistry of the Retinal Chromophore in Protein; 4.2 Photoisomerization in Visual Rhodopsins; 4.2.1 Structure and Function of Visual Rhodopsins; 4.2.2 Primary Process in Vision Studied by Ultrafast Spectroscopy; 4.2.3 Structural Changes of the Chromophore and Protein upon Retinal Photoisomerization; 4.3 Photoisomerization in Archaeal Rhodopsins; 4.3.1 Structure and Function of Archaeal Rhodopsin 4.3.2 Primary Process in Bacterial Photosynthesis and Light Sensor Studied by Ultrafast Spectroscopy |
| Record Nr. | UNINA-9910841286303321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Dynamic stereochemistry of chiral compounds [[electronic resource] ] : principles and applications / / Christian Wolf
| Dynamic stereochemistry of chiral compounds [[electronic resource] ] : principles and applications / / Christian Wolf |
| Autore | Wolf Christian <1968-> |
| Pubbl/distr/stampa | Cambridge, UK, : RSC Publishing, c2008 |
| Descrizione fisica | 1 online resource (533 p.) |
| Disciplina | 541.223 |
| Soggetto topico |
Stereochemistry
Chirality |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-84755-809-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910455237803321 |
Wolf Christian <1968->
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| Cambridge, UK, : RSC Publishing, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Dynamic stereochemistry of chiral compounds [[electronic resource] ] : principles and applications / / Christian Wolf
| Dynamic stereochemistry of chiral compounds [[electronic resource] ] : principles and applications / / Christian Wolf |
| Autore | Wolf Christian <1968-> |
| Pubbl/distr/stampa | Cambridge, UK, : RSC Publishing, c2008 |
| Descrizione fisica | 1 online resource (533 p.) |
| Disciplina | 541.223 |
| Soggetto topico |
Stereochemistry
Chirality |
| ISBN | 1-84755-809-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910778308803321 |
|
Wolf Christian <1968->
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||
| Cambridge, UK, : RSC Publishing, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Dynamic stereochemistry of chiral compounds [[electronic resource] ] : principles and applications / / Christian Wolf
| Dynamic stereochemistry of chiral compounds [[electronic resource] ] : principles and applications / / Christian Wolf |
| Autore | Wolf Christian <1968-> |
| Pubbl/distr/stampa | Cambridge, UK, : RSC Publishing, c2008 |
| Descrizione fisica | 1 online resource (533 p.) |
| Disciplina | 541.223 |
| Soggetto topico |
Stereochemistry
Chirality |
| ISBN | 1-84755-809-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910828757303321 |
|
Wolf Christian <1968->
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| Cambridge, UK, : RSC Publishing, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Elements of stereochemistry / Ernest L. Eliel ; with a section on coordination compounds by F. Basolo
| Elements of stereochemistry / Ernest L. Eliel ; with a section on coordination compounds by F. Basolo |
| Autore | Basolo, Fred |
| Pubbl/distr/stampa | New York : John Wiley & Sons, c1969 |
| Descrizione fisica | vi, 98 p. : ill. ; 23 cm |
| Disciplina | 541.223 |
| Altri autori (Persone) | Eliel, Ernest Ludwigauthor |
| Soggetto topico | Stereochemistry |
| ISBN | 0471237450 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003464299707536 |
|
Basolo, Fred
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| New York : John Wiley & Sons, c1969 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
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Guida alla stereochimica / F. D. Gunstone
| Guida alla stereochimica / F. D. Gunstone |
| Autore | Gunstone, Frank Denby |
| Pubbl/distr/stampa | Bologna : Zanichelli ; 1979 |
| Descrizione fisica | ix, 93 p. : ill. ; 24 cm |
| Disciplina | 547 |
| Soggetto topico | Stereochemistry |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ita |
| Record Nr. | UNISALENTO-991002462959707536 |
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Gunstone, Frank Denby
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| Bologna : Zanichelli ; 1979 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
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Organic stereochemistry : experimental and computational methods / / Hua-Jie Zhu
| Organic stereochemistry : experimental and computational methods / / Hua-Jie Zhu |
| Autore | Zhu Hua-Jie |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2015 |
| Descrizione fisica | 1 online resource (337 p.) |
| Disciplina | 541.223 |
| Soggetto topico |
Stereochemistry
Physical organic chemistry |
| ISBN |
3-527-68817-X
3-527-68816-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title Page; Copyright; Contents; Preface; Acknowledgments; List of Abbreviations; Part I Fundamentals; Chapter 1 Chirality; 1.1 Introduction; 1.2 Tetrahedron of Carbon; 1.2.1 Terpenoids; 1.2.2 Flavonoids; 1.2.3 Alkaloids; 1.2.4 Steroids; 1.2.5 Glycosides; 1.2.6 Others; 1.3 Other Stereogenic Centers; 1.4 Optical Characteristics; 1.4.1 Measurement of OR; 1.4.2 ECD and Its Definition; 1.4.3 Outline of VCD; 1.4.4 Outline of ROA; References; Chapter 2 Non-optical Method in Configuration Study; 2.1 13C NMR Spectra; 2.1.1 NMR and Atomic Structure; 2.1.2 13C NMR Calculation; 2.1.3 1H NMR
2.1.4 13C NMR Prediction and Conformational Search2.2 X-Ray Diffraction and Mosher Method; 2.2.1 X-Ray Diffraction; 2.2.2 Mosher Method; 2.3 Transition State Energy and Chirality Selectivity; 2.4 Separation of Chiral Compounds; 2.4.1 Chiral Organic Bases; 2.4.2 Chiral Organic Acids; 2.4.3 Chiral Organic Alcohols; 2.4.4 Others; References; Part II Techniques; Chapter 3 Optical Rotation (Rotatory Dispersion, ORD); 3.1 Introduction; 3.2 Quantum Theory; 3.3 Matrix Model; 3.3.1 Matrix Basis; 3.3.2 Explanation of General OR Characteristics; 3.3.2.1 Sample Calculations 3.3.2.2 Calculated Values in Same Series of Compounds3.4 ORD; 3.5 Application; 3.5.1 AC Assignment for Mono-Stereogenic Center Compounds; 3.5.2 Matrix Model Application; 3.5.3 AC Assignment for Poly-Stereogenic Center Compounds; 3.5.4 Using ORD Method; References; Chapter 4 Electronic Circular Dichroism; 4.1 Exciton Chirality CD; 4.2 ECD Characteristics for Chiral Metallic Compounds; 4.3 Quantum Theory Basis; 4.4 Principle Using ECD; 4.5 Application; 4.5.1 Procedure to Do ECD; 4.5.2 ECD Application; 5.4.1 VCD Application; 4.5.3 UV Correction; References Chapter 5 Vibrational Circular Dichroism and Raman Optical Activity5.1 Exciton Chirality; 5.2 Quantum Theory Basis; 5.2.1 VCD and IR; 5.2.2 ROA and Raman Scattering; 5.3 Principles Using VCD and ROA; 5.4 Application; 5.4.2 ROA Application; References; Chapter 6 Combinational Use of Different Methods; 6.1 Tactics to Select Methods; 6.1.1 13C NMR Methods; 6.1.2 OR and ORD; 6.1.3 Matrix; 6.1.4 ECD; 6.1.5 VCD Method; 6.2 Examples and Discussion; 6.3 Revised Structures; 6.3.1 ORD Method; 6.3.2 Combinational Use of OR and ECD; 6.3.3 VCD and ECD; 6.3.4 Comprehensive Use of OR, ECD, and VCD ReferencesPart III Reactions; Chapter 7 Enantioselective Reaction; 7.1 Enantioselective Addition; 7.1.1 Organic Zn- or Zn-Ti Reagent; 7.1.2 Organic Cu-Zn, Cu-Li Reagent; 7.1.3 Organo-Fe Complexes; 7.1.4 Other Organo-Metallic Complexes; 7.1.5 Organo-Si Reagents; 7.2 Enantioselective Reduction; 7.2.1 Green Chemistry; 7.6.2 Auto-Self Catalysis; 7.3 Enantioselective Oxidation; 7.4 Prediction of ee Using Calculations; 7.5 Catalyst Types; 7.5.1 Amino Alcohols; 7.5.2 Chiral Ligands Containing N-O Group; 7.5.3 Chiral Axial Catalysts; 7.5.4 Solid-Supported Chiral Compounds 7.5.5 Spiral Chiral Compounds |
| Record Nr. | UNINA-9910788288903321 |
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Zhu Hua-Jie
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| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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