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The pyrimidines / With an essay by S.F. Mason [[electronic resource]]
| The pyrimidines / With an essay by S.F. Mason [[electronic resource]] |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Interscience Publishers, 1962 |
| Descrizione fisica | 1 online resource (774 p.) : illus |
| Disciplina | 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry Organic Chemistry Physical Sciences & Mathematics |
| ISBN |
0-470-18676-3
0-470-18826-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910841058203321 |
Brown D. J
|
||
| New York, : Interscience Publishers, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason
| The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason |
| Autore | Brown D. J |
| Edizione | [99th ed.] |
| Pubbl/distr/stampa | New York, : Interscience, 1962 |
| Descrizione fisica | 1 online resource (803 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry |
| ISBN |
1-282-30157-8
9786612301575 0-470-18675-5 0-470-18825-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; Chapter I. Introduction to the Pyrimidines; 1.History; 2 . Nomenclature; 3 . The Unique Basis of Pyrimidine Chemistry; A . The "Active" 2-,4-, and 6-Positions; B . The "Aromatic" 5-Position; C . The Effect of Electron-releasing Groups; D . The Effect of Electron-withdrawing Groups; E . Tautomeric Groups; 4 . General Summary of Pyrimidine Chemistry; A . Electrophilic Substitution; (1) Nitration and Nitrosation; (2) Diazo Coupling; (3) Halogenation; (4) Sulphonation; (5) Attack by Chloroform or Chloral; (6) Other Electrophilic Attacks
B . Direct Nucleophilic SubstitutionC . Nucleophilic Metatheses; (1) Replacement of Halogens; (a) By Amino and Substituted-amino Groups; (b) By Methoxy and Similar Groups; (c) By Hydroxy Groups; (d) By Methylthio and Related Groups; (e) By Mercapto Groups; (f) By Sulpho and Thiocyanato Groups; (2) Replacement of Methoxy, Methylthio. and Methylsulphonyl Groups; D . Other Metatheses; (1) Hydroxy- to Chloro-pyrimidines; (2) Hydroxy- to Mercapto-pyrimidines; (3) Mercapto- to Hydroxy-pyrimidines; (4) Mercapto- to Amino-pyrimidines; (5) Amino- to Hydroxy-pyrimidines (6) Amino- to Chloro-pyrimidines(7) Replacements of Quaternary Amino Groups; E . Addition Reactions; (1) Quaternization; (2) Formation of N-Oxides; (3) Addition of Hypobromous Acid; (4) Addition of Water; (5) Addition of Grignard Reagents and Lithium Alkyls; F . Oxidative Reactions; G . Reductive Reactions; (1) Nuclear Reduction; (2) Reductive Removal of Groups; (3) Reductive Modification of Groups; H . The Modification of Substituents; (1) Amino Groups; (2) Hydroxy Groups; (3) Mercapto Groups; (4) Methyl Groups; I . A Free Radical Reaction; 5 . Physical Properties of Pyrimidines A . Electronic StructuresB . Ionization Constants; C . Spectra; D . Dipole Moments; E . Polarography; F . Solubility and Melting Point; Chapter II . The Principal Synthetic Method; 1 . General Scope; 2 . Use of B-Dialdehydes; 3 . Use of B-Aldehydo Ketones; 4 . Use of B-Diketones; 5 . Use of B-Aldehydo Esters; A . Aldehydo Esters with Thioureas; B . The Davidson-Baudisch Synthesis; C . The Use of a-Ethoxymethylene Esters; 6 . Use of B-Keto Esters; A . Keto Esters with Thioureas; B . Keto Esters with Amidines; C . Keto Esters with Guanidines; D . Keto Esters with Urea and Derivatives 7 . Use of B-Diesters (Malonic Esters)A . Malonic Esters and Amidines; B . Malonic Esters with Urea and its Alkyl Derivatives; C . Malonic Esters with Thiourea and Derivatives; D . Malonic Esters with Guanidine and its Alkyl Derivatives; 8 . Use of B-Aldehydo Nitriles; A . Aldehydo Nitriles with Ureas; B . Aldehydo NitriIes with Thioureas; C . Aldehydo Nitriles with Amidines; D . The Whitehead Synthesis of Cytosine Derivatives; E . Aldehydo Nitriles with Guanidine; 9 . Use of B-Keto Nitriles; 10 . Use of B-Ester Nitriles; A . Ester Nitriles with Amidines B . Ester Nitriles with Urea and Alkyl Ureas |
| Record Nr. | UNINA-9910840727703321 |
|
Brown D. J
|
||
| New York, : Interscience, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
