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The pyrimidines [[electronic resource] /] / D.J. Brown; with a chapter by R.F. Evans and sections by W.B. Cowden and M.D. Fenn
| The pyrimidines [[electronic resource] /] / D.J. Brown; with a chapter by R.F. Evans and sections by W.B. Cowden and M.D. Fenn |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Wiley, c1994 |
| Descrizione fisica | 1 online resource (1542 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Heterocyclic compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-24226-1
9786613813381 0-470-18739-5 0-470-18891-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; LIST OF TABLES; List of Tables; CHAPTER 1. INTRODUCTION TO PYRIMIDINE CHEMISTRY; 1.1 History and Reviews; 1.2 Nomenclature; 1.3 Factors in the Uniquity of Pyrimidine Chemistry; 1.3.1 The Activated 2- and 4/6-Positions; Table 1.1 Trivial Names of Pyrimidines; 1.3.2 The Semiaromatic 5-Position; 1.3.3 The Effect of Electron-Donating Groups; 1.3.4 The Effect of Electron-Withdrawing Groups; 1.3.5 The Effect of Tautomeric Groups; 1.4 The Primary Synthesis of Pyrimidines; 1.5 Reactions at the Pyrimidine Ring; 1.5.1 Electrophilic Attack; 1.5.1.1 Nitration
1.5.1.2 Nitrosation1.5.1.3 Diazo Coupling; 1.5.1.4 Halogenation; 1.5.1.5 Sulfonation; 1.5.1.6 C-Formylation; 1.5.1.7 Hydroxy- or Aminomethylation; 1.5.1.8 Formation of Dipyrimidin-5-yl Sulfides; 1.5.2 Nucleophilic Attack; 1.5.2.1 Amination; 1.5.2.2 Hydroxylation; 1.5.2.3 C-Alkylation or Arylation; 1.5.3 Free Radical Attack; 1.5.4 Photochemical Reactions; 1.5.5 Oxidative Reactions; 1.5.6 Nuclear Reduction; 1.5.7 Quaternization at Ring Nitrogen; 1.6 Reactions at Substituents on the Pyrimidine Ring; 1.6.1 Reactions at Alkyl Groups; 1.6.2 Reactions at Aryl Groups 1.6.3 Reactions at Halogeno Substituents1.6.4 Reactions at Tautomeric Oxo Substituents; 1.6.5 Reactions at Nontautomeric Oxo Substituents; 1.6.6 Reactions at Alkoxy Groups; 1.6.7 Reactions at 5-Hydroxy Groups; 1.6.8 Reactions at N-Oxides; 1.6.9 Reactions at Tautomeric Thioxo Substituents; 1.6.10 Reactions at Nontautomeric Thioxo Substituents; 1.6.11 Reactions at Alkylthio Groups; 1.6.12 Reactions at 5-Mercapto Groups; 1.6.13 Reactions at Sulfo and Related Groups; 1.6.14 Reactions at Alkylsulfonyl and Alkylsulfinyl Groups; 1.6.15 Reactions at Amino Groups 1.6.16 Reactions at Nitro, Nitroso, and Arylazo Groups1.6.17 Reactions at Carboxy Groups; 1.6.18 Reactions at Alkoxycarbonyl Groups; 1.6.19 Reactions at Carbamoyl Groups; 1.6.20 Reactions at Cyano Groups; 1.6.21 Reactions at C-Formyl Groups; 1.6.22 Reactions at Other C-Acyl Groups; 1.6.23 Reactions at Cyanato and Thiocyanato Groups; 1.6.24 Reactions at Isocyanato and Isothiocyanato Groups; 1.6.25 Reactions at Nitrile Oxide Groups; CHAPTER 2. PRIMARY SYNTHESES; 2.1 From a Single Six-Atom Synthone; 2.1.1 By Completion of the N1-C2 Bond; 2.1.2 By Completion of the N3-C4 Bond 2.1.3 By Completion of the C4-C5 Bond2.1.4 By Rearrangement of One Pyrimidine into Another; 2.2 From Two Synthones; 2.2.1 By Using a One- and a Five-Atom Synthone; 2.2.1.1 Where the One-Atom Synthone Provides Nl; 2.2.1.2 Where the One-Atom Synthone Provides C2; 2.2.1.3 Where the One-Atom Synthone Provides C4; 2.2.1.4 Where the One-Atom Synthone Provides C5; 2.2.2 By Using a Two- and a Four-Atom Synthone; 2.2.2.1 Where the Two-Atom Synthone Provides Nl + C2; 2.2.2.2 Where the Two-Atom Synthone Provides N3 + C4; 2.2.2.3 Where the Two-Atom Synthone Provides C4 + C5 2.2.3 By Using Two Three-Atom Synthones |
| Record Nr. | UNINA-9910144285403321 |
Brown D. J
|
||
| New York, : Wiley, c1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown; with a chapter by R.F. Evans and sections by W.B. Cowden and M.D. Fenn
| The pyrimidines [[electronic resource] /] / D.J. Brown; with a chapter by R.F. Evans and sections by W.B. Cowden and M.D. Fenn |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Wiley, c1994 |
| Descrizione fisica | 1 online resource (1542 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Heterocyclic compounds |
| ISBN |
1-282-24226-1
9786613813381 0-470-18739-5 0-470-18891-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; LIST OF TABLES; List of Tables; CHAPTER 1. INTRODUCTION TO PYRIMIDINE CHEMISTRY; 1.1 History and Reviews; 1.2 Nomenclature; 1.3 Factors in the Uniquity of Pyrimidine Chemistry; 1.3.1 The Activated 2- and 4/6-Positions; Table 1.1 Trivial Names of Pyrimidines; 1.3.2 The Semiaromatic 5-Position; 1.3.3 The Effect of Electron-Donating Groups; 1.3.4 The Effect of Electron-Withdrawing Groups; 1.3.5 The Effect of Tautomeric Groups; 1.4 The Primary Synthesis of Pyrimidines; 1.5 Reactions at the Pyrimidine Ring; 1.5.1 Electrophilic Attack; 1.5.1.1 Nitration
1.5.1.2 Nitrosation1.5.1.3 Diazo Coupling; 1.5.1.4 Halogenation; 1.5.1.5 Sulfonation; 1.5.1.6 C-Formylation; 1.5.1.7 Hydroxy- or Aminomethylation; 1.5.1.8 Formation of Dipyrimidin-5-yl Sulfides; 1.5.2 Nucleophilic Attack; 1.5.2.1 Amination; 1.5.2.2 Hydroxylation; 1.5.2.3 C-Alkylation or Arylation; 1.5.3 Free Radical Attack; 1.5.4 Photochemical Reactions; 1.5.5 Oxidative Reactions; 1.5.6 Nuclear Reduction; 1.5.7 Quaternization at Ring Nitrogen; 1.6 Reactions at Substituents on the Pyrimidine Ring; 1.6.1 Reactions at Alkyl Groups; 1.6.2 Reactions at Aryl Groups 1.6.3 Reactions at Halogeno Substituents1.6.4 Reactions at Tautomeric Oxo Substituents; 1.6.5 Reactions at Nontautomeric Oxo Substituents; 1.6.6 Reactions at Alkoxy Groups; 1.6.7 Reactions at 5-Hydroxy Groups; 1.6.8 Reactions at N-Oxides; 1.6.9 Reactions at Tautomeric Thioxo Substituents; 1.6.10 Reactions at Nontautomeric Thioxo Substituents; 1.6.11 Reactions at Alkylthio Groups; 1.6.12 Reactions at 5-Mercapto Groups; 1.6.13 Reactions at Sulfo and Related Groups; 1.6.14 Reactions at Alkylsulfonyl and Alkylsulfinyl Groups; 1.6.15 Reactions at Amino Groups 1.6.16 Reactions at Nitro, Nitroso, and Arylazo Groups1.6.17 Reactions at Carboxy Groups; 1.6.18 Reactions at Alkoxycarbonyl Groups; 1.6.19 Reactions at Carbamoyl Groups; 1.6.20 Reactions at Cyano Groups; 1.6.21 Reactions at C-Formyl Groups; 1.6.22 Reactions at Other C-Acyl Groups; 1.6.23 Reactions at Cyanato and Thiocyanato Groups; 1.6.24 Reactions at Isocyanato and Isothiocyanato Groups; 1.6.25 Reactions at Nitrile Oxide Groups; CHAPTER 2. PRIMARY SYNTHESES; 2.1 From a Single Six-Atom Synthone; 2.1.1 By Completion of the N1-C2 Bond; 2.1.2 By Completion of the N3-C4 Bond 2.1.3 By Completion of the C4-C5 Bond2.1.4 By Rearrangement of One Pyrimidine into Another; 2.2 From Two Synthones; 2.2.1 By Using a One- and a Five-Atom Synthone; 2.2.1.1 Where the One-Atom Synthone Provides Nl; 2.2.1.2 Where the One-Atom Synthone Provides C2; 2.2.1.3 Where the One-Atom Synthone Provides C4; 2.2.1.4 Where the One-Atom Synthone Provides C5; 2.2.2 By Using a Two- and a Four-Atom Synthone; 2.2.2.1 Where the Two-Atom Synthone Provides Nl + C2; 2.2.2.2 Where the Two-Atom Synthone Provides N3 + C4; 2.2.2.3 Where the Two-Atom Synthone Provides C4 + C5 2.2.3 By Using Two Three-Atom Synthones |
| Record Nr. | UNINA-9910830285303321 |
|
Brown D. J
|
||
| New York, : Wiley, c1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown; with a chapter by R.F. Evans and sections by W.B. Cowden and M.D. Fenn
| The pyrimidines [[electronic resource] /] / D.J. Brown; with a chapter by R.F. Evans and sections by W.B. Cowden and M.D. Fenn |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Wiley, c1994 |
| Descrizione fisica | 1 online resource (1542 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Heterocyclic compounds |
| ISBN |
1-282-24226-1
9786613813381 0-470-18739-5 0-470-18891-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; LIST OF TABLES; List of Tables; CHAPTER 1. INTRODUCTION TO PYRIMIDINE CHEMISTRY; 1.1 History and Reviews; 1.2 Nomenclature; 1.3 Factors in the Uniquity of Pyrimidine Chemistry; 1.3.1 The Activated 2- and 4/6-Positions; Table 1.1 Trivial Names of Pyrimidines; 1.3.2 The Semiaromatic 5-Position; 1.3.3 The Effect of Electron-Donating Groups; 1.3.4 The Effect of Electron-Withdrawing Groups; 1.3.5 The Effect of Tautomeric Groups; 1.4 The Primary Synthesis of Pyrimidines; 1.5 Reactions at the Pyrimidine Ring; 1.5.1 Electrophilic Attack; 1.5.1.1 Nitration
1.5.1.2 Nitrosation1.5.1.3 Diazo Coupling; 1.5.1.4 Halogenation; 1.5.1.5 Sulfonation; 1.5.1.6 C-Formylation; 1.5.1.7 Hydroxy- or Aminomethylation; 1.5.1.8 Formation of Dipyrimidin-5-yl Sulfides; 1.5.2 Nucleophilic Attack; 1.5.2.1 Amination; 1.5.2.2 Hydroxylation; 1.5.2.3 C-Alkylation or Arylation; 1.5.3 Free Radical Attack; 1.5.4 Photochemical Reactions; 1.5.5 Oxidative Reactions; 1.5.6 Nuclear Reduction; 1.5.7 Quaternization at Ring Nitrogen; 1.6 Reactions at Substituents on the Pyrimidine Ring; 1.6.1 Reactions at Alkyl Groups; 1.6.2 Reactions at Aryl Groups 1.6.3 Reactions at Halogeno Substituents1.6.4 Reactions at Tautomeric Oxo Substituents; 1.6.5 Reactions at Nontautomeric Oxo Substituents; 1.6.6 Reactions at Alkoxy Groups; 1.6.7 Reactions at 5-Hydroxy Groups; 1.6.8 Reactions at N-Oxides; 1.6.9 Reactions at Tautomeric Thioxo Substituents; 1.6.10 Reactions at Nontautomeric Thioxo Substituents; 1.6.11 Reactions at Alkylthio Groups; 1.6.12 Reactions at 5-Mercapto Groups; 1.6.13 Reactions at Sulfo and Related Groups; 1.6.14 Reactions at Alkylsulfonyl and Alkylsulfinyl Groups; 1.6.15 Reactions at Amino Groups 1.6.16 Reactions at Nitro, Nitroso, and Arylazo Groups1.6.17 Reactions at Carboxy Groups; 1.6.18 Reactions at Alkoxycarbonyl Groups; 1.6.19 Reactions at Carbamoyl Groups; 1.6.20 Reactions at Cyano Groups; 1.6.21 Reactions at C-Formyl Groups; 1.6.22 Reactions at Other C-Acyl Groups; 1.6.23 Reactions at Cyanato and Thiocyanato Groups; 1.6.24 Reactions at Isocyanato and Isothiocyanato Groups; 1.6.25 Reactions at Nitrile Oxide Groups; CHAPTER 2. PRIMARY SYNTHESES; 2.1 From a Single Six-Atom Synthone; 2.1.1 By Completion of the N1-C2 Bond; 2.1.2 By Completion of the N3-C4 Bond 2.1.3 By Completion of the C4-C5 Bond2.1.4 By Rearrangement of One Pyrimidine into Another; 2.2 From Two Synthones; 2.2.1 By Using a One- and a Five-Atom Synthone; 2.2.1.1 Where the One-Atom Synthone Provides Nl; 2.2.1.2 Where the One-Atom Synthone Provides C2; 2.2.1.3 Where the One-Atom Synthone Provides C4; 2.2.1.4 Where the One-Atom Synthone Provides C5; 2.2.2 By Using a Two- and a Four-Atom Synthone; 2.2.2.1 Where the Two-Atom Synthone Provides Nl + C2; 2.2.2.2 Where the Two-Atom Synthone Provides N3 + C4; 2.2.2.3 Where the Two-Atom Synthone Provides C4 + C5 2.2.3 By Using Two Three-Atom Synthones |
| Record Nr. | UNINA-9910841668503321 |
|
Brown D. J
|
||
| New York, : Wiley, c1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason
| The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason |
| Autore | Brown D. J |
| Edizione | [99th ed.] |
| Pubbl/distr/stampa | New York, : Interscience, 1962 |
| Descrizione fisica | 1 online resource (803 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-30157-8
9786612301575 0-470-18675-5 0-470-18825-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; Chapter I. Introduction to the Pyrimidines; 1.History; 2 . Nomenclature; 3 . The Unique Basis of Pyrimidine Chemistry; A . The "Active" 2-,4-, and 6-Positions; B . The "Aromatic" 5-Position; C . The Effect of Electron-releasing Groups; D . The Effect of Electron-withdrawing Groups; E . Tautomeric Groups; 4 . General Summary of Pyrimidine Chemistry; A . Electrophilic Substitution; (1) Nitration and Nitrosation; (2) Diazo Coupling; (3) Halogenation; (4) Sulphonation; (5) Attack by Chloroform or Chloral; (6) Other Electrophilic Attacks
B . Direct Nucleophilic SubstitutionC . Nucleophilic Metatheses; (1) Replacement of Halogens; (a) By Amino and Substituted-amino Groups; (b) By Methoxy and Similar Groups; (c) By Hydroxy Groups; (d) By Methylthio and Related Groups; (e) By Mercapto Groups; (f) By Sulpho and Thiocyanato Groups; (2) Replacement of Methoxy, Methylthio. and Methylsulphonyl Groups; D . Other Metatheses; (1) Hydroxy- to Chloro-pyrimidines; (2) Hydroxy- to Mercapto-pyrimidines; (3) Mercapto- to Hydroxy-pyrimidines; (4) Mercapto- to Amino-pyrimidines; (5) Amino- to Hydroxy-pyrimidines (6) Amino- to Chloro-pyrimidines(7) Replacements of Quaternary Amino Groups; E . Addition Reactions; (1) Quaternization; (2) Formation of N-Oxides; (3) Addition of Hypobromous Acid; (4) Addition of Water; (5) Addition of Grignard Reagents and Lithium Alkyls; F . Oxidative Reactions; G . Reductive Reactions; (1) Nuclear Reduction; (2) Reductive Removal of Groups; (3) Reductive Modification of Groups; H . The Modification of Substituents; (1) Amino Groups; (2) Hydroxy Groups; (3) Mercapto Groups; (4) Methyl Groups; I . A Free Radical Reaction; 5 . Physical Properties of Pyrimidines A . Electronic StructuresB . Ionization Constants; C . Spectra; D . Dipole Moments; E . Polarography; F . Solubility and Melting Point; Chapter II . The Principal Synthetic Method; 1 . General Scope; 2 . Use of B-Dialdehydes; 3 . Use of B-Aldehydo Ketones; 4 . Use of B-Diketones; 5 . Use of B-Aldehydo Esters; A . Aldehydo Esters with Thioureas; B . The Davidson-Baudisch Synthesis; C . The Use of a-Ethoxymethylene Esters; 6 . Use of B-Keto Esters; A . Keto Esters with Thioureas; B . Keto Esters with Amidines; C . Keto Esters with Guanidines; D . Keto Esters with Urea and Derivatives 7 . Use of B-Diesters (Malonic Esters)A . Malonic Esters and Amidines; B . Malonic Esters with Urea and its Alkyl Derivatives; C . Malonic Esters with Thiourea and Derivatives; D . Malonic Esters with Guanidine and its Alkyl Derivatives; 8 . Use of B-Aldehydo Nitriles; A . Aldehydo Nitriles with Ureas; B . Aldehydo NitriIes with Thioureas; C . Aldehydo Nitriles with Amidines; D . The Whitehead Synthesis of Cytosine Derivatives; E . Aldehydo Nitriles with Guanidine; 9 . Use of B-Keto Nitriles; 10 . Use of B-Ester Nitriles; A . Ester Nitriles with Amidines B . Ester Nitriles with Urea and Alkyl Ureas |
| Record Nr. | UNINA-9910144285603321 |
|
Brown D. J
|
||
| New York, : Interscience, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines / With an essay by S.F. Mason [[electronic resource]]
| The pyrimidines / With an essay by S.F. Mason [[electronic resource]] |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Interscience Publishers, 1962 |
| Descrizione fisica | 1 online resource (774 p.) : illus |
| Disciplina | 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry Organic Chemistry Physical Sciences & Mathematics |
| Soggetto genere / forma | Electronic books |
| ISBN |
0-470-18676-3
0-470-18826-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910144285303321 |
|
Brown D. J
|
||
| New York, : Interscience Publishers, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason
| The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason |
| Autore | Brown D. J |
| Edizione | [99th ed.] |
| Pubbl/distr/stampa | New York, : Interscience, 1962 |
| Descrizione fisica | 1 online resource (803 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry |
| ISBN |
1-282-30157-8
9786612301575 0-470-18675-5 0-470-18825-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; Chapter I. Introduction to the Pyrimidines; 1.History; 2 . Nomenclature; 3 . The Unique Basis of Pyrimidine Chemistry; A . The "Active" 2-,4-, and 6-Positions; B . The "Aromatic" 5-Position; C . The Effect of Electron-releasing Groups; D . The Effect of Electron-withdrawing Groups; E . Tautomeric Groups; 4 . General Summary of Pyrimidine Chemistry; A . Electrophilic Substitution; (1) Nitration and Nitrosation; (2) Diazo Coupling; (3) Halogenation; (4) Sulphonation; (5) Attack by Chloroform or Chloral; (6) Other Electrophilic Attacks
B . Direct Nucleophilic SubstitutionC . Nucleophilic Metatheses; (1) Replacement of Halogens; (a) By Amino and Substituted-amino Groups; (b) By Methoxy and Similar Groups; (c) By Hydroxy Groups; (d) By Methylthio and Related Groups; (e) By Mercapto Groups; (f) By Sulpho and Thiocyanato Groups; (2) Replacement of Methoxy, Methylthio. and Methylsulphonyl Groups; D . Other Metatheses; (1) Hydroxy- to Chloro-pyrimidines; (2) Hydroxy- to Mercapto-pyrimidines; (3) Mercapto- to Hydroxy-pyrimidines; (4) Mercapto- to Amino-pyrimidines; (5) Amino- to Hydroxy-pyrimidines (6) Amino- to Chloro-pyrimidines(7) Replacements of Quaternary Amino Groups; E . Addition Reactions; (1) Quaternization; (2) Formation of N-Oxides; (3) Addition of Hypobromous Acid; (4) Addition of Water; (5) Addition of Grignard Reagents and Lithium Alkyls; F . Oxidative Reactions; G . Reductive Reactions; (1) Nuclear Reduction; (2) Reductive Removal of Groups; (3) Reductive Modification of Groups; H . The Modification of Substituents; (1) Amino Groups; (2) Hydroxy Groups; (3) Mercapto Groups; (4) Methyl Groups; I . A Free Radical Reaction; 5 . Physical Properties of Pyrimidines A . Electronic StructuresB . Ionization Constants; C . Spectra; D . Dipole Moments; E . Polarography; F . Solubility and Melting Point; Chapter II . The Principal Synthetic Method; 1 . General Scope; 2 . Use of B-Dialdehydes; 3 . Use of B-Aldehydo Ketones; 4 . Use of B-Diketones; 5 . Use of B-Aldehydo Esters; A . Aldehydo Esters with Thioureas; B . The Davidson-Baudisch Synthesis; C . The Use of a-Ethoxymethylene Esters; 6 . Use of B-Keto Esters; A . Keto Esters with Thioureas; B . Keto Esters with Amidines; C . Keto Esters with Guanidines; D . Keto Esters with Urea and Derivatives 7 . Use of B-Diesters (Malonic Esters)A . Malonic Esters and Amidines; B . Malonic Esters with Urea and its Alkyl Derivatives; C . Malonic Esters with Thiourea and Derivatives; D . Malonic Esters with Guanidine and its Alkyl Derivatives; 8 . Use of B-Aldehydo Nitriles; A . Aldehydo Nitriles with Ureas; B . Aldehydo NitriIes with Thioureas; C . Aldehydo Nitriles with Amidines; D . The Whitehead Synthesis of Cytosine Derivatives; E . Aldehydo Nitriles with Guanidine; 9 . Use of B-Keto Nitriles; 10 . Use of B-Ester Nitriles; A . Ester Nitriles with Amidines B . Ester Nitriles with Urea and Alkyl Ureas |
| Record Nr. | UNINA-9910643717103321 |
|
Brown D. J
|
||
| New York, : Interscience, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason
| The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason |
| Autore | Brown D. J |
| Edizione | [99th ed.] |
| Pubbl/distr/stampa | New York, : Interscience, 1962 |
| Descrizione fisica | 1 online resource (803 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry |
| ISBN |
1-282-30157-8
9786612301575 0-470-18675-5 0-470-18825-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; Chapter I. Introduction to the Pyrimidines; 1.History; 2 . Nomenclature; 3 . The Unique Basis of Pyrimidine Chemistry; A . The "Active" 2-,4-, and 6-Positions; B . The "Aromatic" 5-Position; C . The Effect of Electron-releasing Groups; D . The Effect of Electron-withdrawing Groups; E . Tautomeric Groups; 4 . General Summary of Pyrimidine Chemistry; A . Electrophilic Substitution; (1) Nitration and Nitrosation; (2) Diazo Coupling; (3) Halogenation; (4) Sulphonation; (5) Attack by Chloroform or Chloral; (6) Other Electrophilic Attacks
B . Direct Nucleophilic SubstitutionC . Nucleophilic Metatheses; (1) Replacement of Halogens; (a) By Amino and Substituted-amino Groups; (b) By Methoxy and Similar Groups; (c) By Hydroxy Groups; (d) By Methylthio and Related Groups; (e) By Mercapto Groups; (f) By Sulpho and Thiocyanato Groups; (2) Replacement of Methoxy, Methylthio. and Methylsulphonyl Groups; D . Other Metatheses; (1) Hydroxy- to Chloro-pyrimidines; (2) Hydroxy- to Mercapto-pyrimidines; (3) Mercapto- to Hydroxy-pyrimidines; (4) Mercapto- to Amino-pyrimidines; (5) Amino- to Hydroxy-pyrimidines (6) Amino- to Chloro-pyrimidines(7) Replacements of Quaternary Amino Groups; E . Addition Reactions; (1) Quaternization; (2) Formation of N-Oxides; (3) Addition of Hypobromous Acid; (4) Addition of Water; (5) Addition of Grignard Reagents and Lithium Alkyls; F . Oxidative Reactions; G . Reductive Reactions; (1) Nuclear Reduction; (2) Reductive Removal of Groups; (3) Reductive Modification of Groups; H . The Modification of Substituents; (1) Amino Groups; (2) Hydroxy Groups; (3) Mercapto Groups; (4) Methyl Groups; I . A Free Radical Reaction; 5 . Physical Properties of Pyrimidines A . Electronic StructuresB . Ionization Constants; C . Spectra; D . Dipole Moments; E . Polarography; F . Solubility and Melting Point; Chapter II . The Principal Synthetic Method; 1 . General Scope; 2 . Use of B-Dialdehydes; 3 . Use of B-Aldehydo Ketones; 4 . Use of B-Diketones; 5 . Use of B-Aldehydo Esters; A . Aldehydo Esters with Thioureas; B . The Davidson-Baudisch Synthesis; C . The Use of a-Ethoxymethylene Esters; 6 . Use of B-Keto Esters; A . Keto Esters with Thioureas; B . Keto Esters with Amidines; C . Keto Esters with Guanidines; D . Keto Esters with Urea and Derivatives 7 . Use of B-Diesters (Malonic Esters)A . Malonic Esters and Amidines; B . Malonic Esters with Urea and its Alkyl Derivatives; C . Malonic Esters with Thiourea and Derivatives; D . Malonic Esters with Guanidine and its Alkyl Derivatives; 8 . Use of B-Aldehydo Nitriles; A . Aldehydo Nitriles with Ureas; B . Aldehydo NitriIes with Thioureas; C . Aldehydo Nitriles with Amidines; D . The Whitehead Synthesis of Cytosine Derivatives; E . Aldehydo Nitriles with Guanidine; 9 . Use of B-Keto Nitriles; 10 . Use of B-Ester Nitriles; A . Ester Nitriles with Amidines B . Ester Nitriles with Urea and Alkyl Ureas |
| Record Nr. | UNISA-996202929903316 |
|
Brown D. J
|
||
| New York, : Interscience, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
The pyrimidines / With an essay by S.F. Mason [[electronic resource]]
| The pyrimidines / With an essay by S.F. Mason [[electronic resource]] |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Interscience Publishers, 1962 |
| Descrizione fisica | 1 online resource (774 p.) : illus |
| Disciplina | 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry Organic Chemistry Physical Sciences & Mathematics |
| ISBN |
0-470-18676-3
0-470-18826-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISA-996202929603316 |
|
Brown D. J
|
||
| New York, : Interscience Publishers, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason
| The pyrimidines [[electronic resource] /] / D.J. Brown ; with an essay by S.F. Mason |
| Autore | Brown D. J |
| Edizione | [99th ed.] |
| Pubbl/distr/stampa | New York, : Interscience, 1962 |
| Descrizione fisica | 1 online resource (803 p.) |
| Disciplina |
547.593
547/.59/05 547/.593 |
| Collana | Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry |
| ISBN |
1-282-30157-8
9786612301575 0-470-18675-5 0-470-18825-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THE PYRIMIDINES; Contents; Chapter I. Introduction to the Pyrimidines; 1.History; 2 . Nomenclature; 3 . The Unique Basis of Pyrimidine Chemistry; A . The "Active" 2-,4-, and 6-Positions; B . The "Aromatic" 5-Position; C . The Effect of Electron-releasing Groups; D . The Effect of Electron-withdrawing Groups; E . Tautomeric Groups; 4 . General Summary of Pyrimidine Chemistry; A . Electrophilic Substitution; (1) Nitration and Nitrosation; (2) Diazo Coupling; (3) Halogenation; (4) Sulphonation; (5) Attack by Chloroform or Chloral; (6) Other Electrophilic Attacks
B . Direct Nucleophilic SubstitutionC . Nucleophilic Metatheses; (1) Replacement of Halogens; (a) By Amino and Substituted-amino Groups; (b) By Methoxy and Similar Groups; (c) By Hydroxy Groups; (d) By Methylthio and Related Groups; (e) By Mercapto Groups; (f) By Sulpho and Thiocyanato Groups; (2) Replacement of Methoxy, Methylthio. and Methylsulphonyl Groups; D . Other Metatheses; (1) Hydroxy- to Chloro-pyrimidines; (2) Hydroxy- to Mercapto-pyrimidines; (3) Mercapto- to Hydroxy-pyrimidines; (4) Mercapto- to Amino-pyrimidines; (5) Amino- to Hydroxy-pyrimidines (6) Amino- to Chloro-pyrimidines(7) Replacements of Quaternary Amino Groups; E . Addition Reactions; (1) Quaternization; (2) Formation of N-Oxides; (3) Addition of Hypobromous Acid; (4) Addition of Water; (5) Addition of Grignard Reagents and Lithium Alkyls; F . Oxidative Reactions; G . Reductive Reactions; (1) Nuclear Reduction; (2) Reductive Removal of Groups; (3) Reductive Modification of Groups; H . The Modification of Substituents; (1) Amino Groups; (2) Hydroxy Groups; (3) Mercapto Groups; (4) Methyl Groups; I . A Free Radical Reaction; 5 . Physical Properties of Pyrimidines A . Electronic StructuresB . Ionization Constants; C . Spectra; D . Dipole Moments; E . Polarography; F . Solubility and Melting Point; Chapter II . The Principal Synthetic Method; 1 . General Scope; 2 . Use of B-Dialdehydes; 3 . Use of B-Aldehydo Ketones; 4 . Use of B-Diketones; 5 . Use of B-Aldehydo Esters; A . Aldehydo Esters with Thioureas; B . The Davidson-Baudisch Synthesis; C . The Use of a-Ethoxymethylene Esters; 6 . Use of B-Keto Esters; A . Keto Esters with Thioureas; B . Keto Esters with Amidines; C . Keto Esters with Guanidines; D . Keto Esters with Urea and Derivatives 7 . Use of B-Diesters (Malonic Esters)A . Malonic Esters and Amidines; B . Malonic Esters with Urea and its Alkyl Derivatives; C . Malonic Esters with Thiourea and Derivatives; D . Malonic Esters with Guanidine and its Alkyl Derivatives; 8 . Use of B-Aldehydo Nitriles; A . Aldehydo Nitriles with Ureas; B . Aldehydo NitriIes with Thioureas; C . Aldehydo Nitriles with Amidines; D . The Whitehead Synthesis of Cytosine Derivatives; E . Aldehydo Nitriles with Guanidine; 9 . Use of B-Keto Nitriles; 10 . Use of B-Ester Nitriles; A . Ester Nitriles with Amidines B . Ester Nitriles with Urea and Alkyl Ureas |
| Record Nr. | UNINA-9910830542803321 |
|
Brown D. J
|
||
| New York, : Interscience, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The pyrimidines / With an essay by S.F. Mason [[electronic resource]]
| The pyrimidines / With an essay by S.F. Mason [[electronic resource]] |
| Autore | Brown D. J |
| Pubbl/distr/stampa | New York, : Interscience Publishers, 1962 |
| Descrizione fisica | 1 online resource (774 p.) : illus |
| Disciplina | 547/.593 |
| Collana | The Chemistry of heterocyclic compounds |
| Soggetto topico |
Pyrimidines
Chemistry Organic Chemistry Physical Sciences & Mathematics |
| ISBN |
0-470-18676-3
0-470-18826-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830735803321 |
|
Brown D. J
|
||
| New York, : Interscience Publishers, 1962 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
