Magnetic isotope effect in chemistry and biochemistry [[electronic resource] /] / Anatoly Buchachenko |
Autore | Buchachenko A. L (Anatolii Leonidovich) |
Pubbl/distr/stampa | New York, : Nova Science Publishers, c2009 |
Descrizione fisica | 1 online resource (159 p.) |
Disciplina | 541/.38 |
Soggetto topico |
Free radical reactions
Nuclear spin Chemical kinetics Isotopes |
Soggetto genere / forma | Electronic books. |
ISBN | 1-60876-794-9 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910452744003321 |
Buchachenko A. L (Anatolii Leonidovich)
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New York, : Nova Science Publishers, c2009 | ||
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Lo trovi qui: Univ. Federico II | ||
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Magnetic isotope effect in chemistry and biochemistry [[electronic resource] /] / Anatoly Buchachenko |
Autore | Buchachenko A. L (Anatolii Leonidovich) |
Pubbl/distr/stampa | New York, : Nova Science Publishers, c2009 |
Descrizione fisica | 1 online resource (159 p.) |
Disciplina | 541/.38 |
Soggetto topico |
Free radical reactions
Nuclear spin Chemical kinetics Isotopes |
ISBN | 1-60876-794-9 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910779522503321 |
Buchachenko A. L (Anatolii Leonidovich)
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New York, : Nova Science Publishers, c2009 | ||
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Lo trovi qui: Univ. Federico II | ||
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Magnetic isotope effect in chemistry and biochemistry [[electronic resource] /] / Anatoly Buchachenko |
Autore | Buchachenko A. L (Anatolii Leonidovich) |
Edizione | [1st ed.] |
Pubbl/distr/stampa | New York, : Nova Science Publishers, c2009 |
Descrizione fisica | 1 online resource (159 p.) |
Disciplina | 541/.38 |
Soggetto topico |
Free radical reactions
Nuclear spin Chemical kinetics Isotopes |
ISBN | 1-60876-794-9 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Intro -- MAGNETIC ISOTOPE EFFECT IN CHEMISTRY AND BIOCHEMISTRY -- MAGNETIC ISOTOPE EFFECT IN CHEMISTRY AND BIOCHEMISTRY -- CONTENTS -- PREFACE -- INTRODUCTION -- Chapter 1 ENERGY AND ANGULAR MOMENTUM AS THE REACTION CONTROLLING FACTORS -- 1.1. ENERGY -- 1.2. ANGULAR MOMENTUM -- 1.2.1. Rotational Angular Momentum -- 1.2.2. Electron Orbital Momentum -- 1.2.3. Electron Angular Momentum: Spin States and Spin Multiplicity -- 1.2.4. Nuclear Angular Momentum and Nuclear Spin States -- Chapter 2 SPIN CONTROL OF CHEMICAL REACTIONS -- 2.1. SPIN STATES AND CHEMICAL REACTIVITY -- 2.2. MAGNETIC INTERACTIONS AND MAGNETIC EFFECTS -- Chapter 3 MAGNETIC ISOTOPE EFFECT (MIE) -- 3.1. HOW TO DISCRIMINATE CLASSICAL AND MAGNETIC ISOTOPE EFFECTS -- 3.2. MIE: HOW IT FUNCTIONS -- 3.3. MIE AS A TEST OF REACTION MECHANISM -- 3.4. NUCLEAR SPIN POLARIZATION -- 3.5. MIE AND ISOTOPE TECHNOLOGY -- 3.6. MIE: THE ROAD OF DISCOVERIES -- Chapter 4 KINETICS OF ISOTOPE FRACTIONATION -- 4.1. MEASUREMENT OF ISOTOPE COMPOSITION -- 4.2. ANALYSIS OF THE KINETIC SCHEMES -- 4.3. ABSOLUTE MEASURE OF ISOTOPE SEPARATION -- 4.4. DYNAMIC CHARACTERISTICS OF SPIN SELECTIVE NANOREACTOR -- 4.5. IS THERE A LIMIT IN MIE INDUCED ISOTOPE FRACTIONATION? -- Chapter 5 PHYSICS OF THE MIE -- 5.1. SPIN-SELECTIVE NANOREACTOR: HOW IT FUNCTIONS? -- 5.2. SPIN DYNAMICS -- 5.3. MOLECULAR DYNAMICS -- 5.4. CHEMICAL DYNAMICS -- 5.5. GENERALIZED SPIN DYNAMICS -- Chapter 6 MIE FOR DEUTERIUM-HYDROGEN DYAD -- Chapter 7 13C MIE: CONTROLLING FACTORS -- 7.1. SPIN PROHIBITION: HOW IT IS RIGOROUS -- 7.2. HYPERFINE COUPLING AND CHEMICAL REACTIVITY -- 7.3. MIE AS A FUNCTION OF THE MAGNETIC FIELD -- 7.4. VISCOSITY, LIFETIME OF RADICALS AND A SIZE OF MICROREACTORS -- 7.5. SPIN MULTIPLICITY AND COMPETITION OF RADICAL AND NON-RADICAL REACTION CHANNELS -- 7.6. MIE AS A FUNCTION OF MOLECULAR ENERGY.
Chapter 8 OXYGEN MIE -- 8.1. FRACTIONATION OF ISOTOPES IN CHAIN REACTIONS OF MOLECULAR OXYGEN -- 8.2. ADDITION OF MOLECULAR OXYGEN TO RADICALS -- 8.3. INTERACTION OF PEROXY RADICALS (CHAIN TERMINATION REACTION) -- 8.4. TEMPERATURE AND VISCOSITY AS CONTROLLING FACTORS OF CHEMICAL SPIN SELECTIVITY -- 8.5. NONCHAIN PROCESSES: ENDOPEROXIDES - SYNTHESIS AND DECOMPOSITION -- 8.6. GEOCHEMICAL ANOMALIES OF 17О -- Chapter 9 SILICON MIE -- 9.1. PHOTOLYSIS OF PHENYLSILYLKETONE -- 9.2. PHOTOLYSIS OF BENZYLSILYLKETONE -- 9.3. SPIN MULTIPLICITY AND THE SIGN OF MIE -- Chapter 10 MIE FOR SULFUR, GERMANIUM AND TIN NUCLEI -- 10.1. SULFUR -- 10.2. GERMANIUM -- 10.3. TIN -- Chapter 11 URANIUM MIE -- 11.1. SPIN-SELECTIVE REACTIONS OF URANYL -- 11.2. URANIUM NANOREACTOR -- 11.2.1. Proton CIDNP -- 11.2.2. Magnetic Field Effect -- 11.3. FRACTIONATION OF URANIUM ISOTOPES -- Chapter 12 MERCURY MIE -- 12.1. MIE IN PHOTOCHEMICAL REACTIONS -- 12.2. MERCURY MIE IN ENZYMATIC PHOSPHORYLATION BY CREATINE KINASE -- Chapter 13 MAGNESIUM ISOTOPE EFFECTS -- 13.1. CLASSICAL ISOTOPE EFFECTS -- 13.2. MAGNETIC ISOTOPE EFFECTS IN ENZYMATIC PHOSPHORYLATION -- 13.2.1. Materials and Experimental Techniques -- 13.2.2. Experimental Detection of Magnesium Isotope Effects -- 13.2.3. Enzymatic Phosphorylation as a Spin-Selective Reaction -- 13.2.4. Quantitative Measure of Magnesium MIE -- 13.2.5. ATP Hydrolysis: No Isotope Effect -- 13.2.6. Magnetic Field Dependence of the Phosphorylation -- 13.2.7. Magnesium MIE Is a Key to Mechanochemistry of Enzymes as the Molecular Machines -- Chapter 14 MICROWAVE EFFECTS -- 14.1. MICROWAVE MIE -- 14.2. Biological Microwave Effects -- 14.2.1. Resonant Microwave Fields -- 14.2.2. Non-Resonant Low Frequency Fields -- ACKNOWLEDGEMENTS -- REFERENCES -- INDEX. |
Record Nr. | UNINA-9910824161103321 |
Buchachenko A. L (Anatolii Leonidovich)
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New York, : Nova Science Publishers, c2009 | ||
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Lo trovi qui: Univ. Federico II | ||
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Magnetic resonance force microscopy and a single-spin measurement [[electronic resource] /] / Gennady P. Berman ... [et al.] |
Pubbl/distr/stampa | Singapore ; ; Hackensack, N.J., : World Scientific, c2006 |
Descrizione fisica | 1 online resource (236 p.) |
Disciplina | 538.36 |
Altri autori (Persone) | BermanGennady P. <1946-> |
Soggetto topico |
Electron paramagnetic resonance
Magnetic resonance force microscopy Magnetic resonance Nuclear spin |
Soggetto genere / forma | Electronic books. |
ISBN |
1-281-91928-4
9786611919283 1-61583-237-8 981-277-409-2 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Contents; 1 Introduction; 2 Spin Dynamics - Quasiclassical Description; 3 Spin Dynamics - Quantum Description; 4 Mechanical Vibrations of the Cantilever; 5 Single-Spin Detection in Magnetic Force Microscopy (MFM); 5.1 Static displacement of the cantilever tip (CT)
5.2 Decoherence time 6 Transient Process in MFM - The Exact Solution of the Master Equation; 6.1 Hamiltonian and master equation for the spin-CT system; 6.2 Solution for spin diagonal matrix elements ; 6.3 Solution for spin off-diagonal matrix elements 7 Periodic Spin Reversals in Magnetic Resonance Force Microscopy (MRFM) Driven by 7r-Pulses 8 Oscillating Adiabatic Spin Reversals Driven by the Frequency Modulated rf Field; 8.1 Schrödinger dynamics of the CT-spin system; 8.2 Decoherence and thermal diffusion for the CT 9 Oscillating Cantilever-Driven Adiabatic Reversals (OSCAR) Technique in MRFM 9.1 CT-spin dynamics: discussion and estimates; 9.2 Experimental detection of a single spin; 10 CT-Spin Dynamics in the OSCAR Technique; 10.1 Quasiclassical theory: ple geometry 10.2 Quantum theory of the OSCAR MRFM 10.3 OSCAR frequency shift for a realistic setup; 11 Magnetic Noise and Spin Relaxation in OSCAR MRFM; 11.1 OSCAR relaxation in a spin ensemble; 11.2 Reduction of magnetic noise; 11.3 Simple model for quantum jumps 11.4 Reduction of the frequency shift due to the CT-spin entanglement |
Record Nr. | UNINA-9910450693003321 |
Singapore ; ; Hackensack, N.J., : World Scientific, c2006 | ||
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Lo trovi qui: Univ. Federico II | ||
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Magnetic resonance force microscopy and a single-spin measurement [[electronic resource] /] / Gennady P. Berman ... [et al.] |
Pubbl/distr/stampa | Singapore ; ; Hackensack, N.J., : World Scientific, c2006 |
Descrizione fisica | 1 online resource (236 p.) |
Disciplina | 538.36 |
Altri autori (Persone) | BermanGennady P. <1946-> |
Soggetto topico |
Electron paramagnetic resonance
Magnetic resonance force microscopy Magnetic resonance Nuclear spin |
ISBN |
1-281-91928-4
9786611919283 1-61583-237-8 981-277-409-2 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Contents; 1 Introduction; 2 Spin Dynamics - Quasiclassical Description; 3 Spin Dynamics - Quantum Description; 4 Mechanical Vibrations of the Cantilever; 5 Single-Spin Detection in Magnetic Force Microscopy (MFM); 5.1 Static displacement of the cantilever tip (CT)
5.2 Decoherence time 6 Transient Process in MFM - The Exact Solution of the Master Equation; 6.1 Hamiltonian and master equation for the spin-CT system; 6.2 Solution for spin diagonal matrix elements ; 6.3 Solution for spin off-diagonal matrix elements 7 Periodic Spin Reversals in Magnetic Resonance Force Microscopy (MRFM) Driven by 7r-Pulses 8 Oscillating Adiabatic Spin Reversals Driven by the Frequency Modulated rf Field; 8.1 Schrödinger dynamics of the CT-spin system; 8.2 Decoherence and thermal diffusion for the CT 9 Oscillating Cantilever-Driven Adiabatic Reversals (OSCAR) Technique in MRFM 9.1 CT-spin dynamics: discussion and estimates; 9.2 Experimental detection of a single spin; 10 CT-Spin Dynamics in the OSCAR Technique; 10.1 Quasiclassical theory: ple geometry 10.2 Quantum theory of the OSCAR MRFM 10.3 OSCAR frequency shift for a realistic setup; 11 Magnetic Noise and Spin Relaxation in OSCAR MRFM; 11.1 OSCAR relaxation in a spin ensemble; 11.2 Reduction of magnetic noise; 11.3 Simple model for quantum jumps 11.4 Reduction of the frequency shift due to the CT-spin entanglement |
Record Nr. | UNINA-9910777056903321 |
Singapore ; ; Hackensack, N.J., : World Scientific, c2006 | ||
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Lo trovi qui: Univ. Federico II | ||
|
Magnetic resonance force microscopy and a single-spin measurement [[electronic resource] /] / Gennady P. Berman ... [et al.] |
Pubbl/distr/stampa | Singapore ; ; Hackensack, N.J., : World Scientific, c2006 |
Descrizione fisica | 1 online resource (236 p.) |
Disciplina | 538.36 |
Altri autori (Persone) | BermanGennady P. <1946-> |
Soggetto topico |
Electron paramagnetic resonance
Magnetic resonance force microscopy Magnetic resonance Nuclear spin |
ISBN |
1-281-91928-4
9786611919283 1-61583-237-8 981-277-409-2 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Contents; 1 Introduction; 2 Spin Dynamics - Quasiclassical Description; 3 Spin Dynamics - Quantum Description; 4 Mechanical Vibrations of the Cantilever; 5 Single-Spin Detection in Magnetic Force Microscopy (MFM); 5.1 Static displacement of the cantilever tip (CT)
5.2 Decoherence time 6 Transient Process in MFM - The Exact Solution of the Master Equation; 6.1 Hamiltonian and master equation for the spin-CT system; 6.2 Solution for spin diagonal matrix elements ; 6.3 Solution for spin off-diagonal matrix elements 7 Periodic Spin Reversals in Magnetic Resonance Force Microscopy (MRFM) Driven by 7r-Pulses 8 Oscillating Adiabatic Spin Reversals Driven by the Frequency Modulated rf Field; 8.1 Schrödinger dynamics of the CT-spin system; 8.2 Decoherence and thermal diffusion for the CT 9 Oscillating Cantilever-Driven Adiabatic Reversals (OSCAR) Technique in MRFM 9.1 CT-spin dynamics: discussion and estimates; 9.2 Experimental detection of a single spin; 10 CT-Spin Dynamics in the OSCAR Technique; 10.1 Quasiclassical theory: ple geometry 10.2 Quantum theory of the OSCAR MRFM 10.3 OSCAR frequency shift for a realistic setup; 11 Magnetic Noise and Spin Relaxation in OSCAR MRFM; 11.1 OSCAR relaxation in a spin ensemble; 11.2 Reduction of magnetic noise; 11.3 Simple model for quantum jumps 11.4 Reduction of the frequency shift due to the CT-spin entanglement |
Record Nr. | UNINA-9910807202703321 |
Singapore ; ; Hackensack, N.J., : World Scientific, c2006 | ||
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Lo trovi qui: Univ. Federico II | ||
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Modern aspects of spin physics / / Walter Pötz, Jaroslav Fabian, Ulrich Hohenester |
Edizione | [1st ed. 2007.] |
Pubbl/distr/stampa | Berlin, Germany ; ; New York, New York : , : Springer, , [2007] |
Descrizione fisica | 1 online resource (139 p.) |
Disciplina | 539.725 |
Collana | Lecture Notes in Physics |
Soggetto topico |
Nuclear spin
Spintronics |
ISBN |
1-280-80484-X
9786610804849 3-540-38592-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Semiconductor Spintronics -- Lectures on the Spin Pairing Mechanism in High-Temperature Superconductors -- Spin in Quantum Field Theory -- Nucleon Spin. |
Record Nr. | UNINA-9910146622903321 |
Berlin, Germany ; ; New York, New York : , : Springer, , [2007] | ||
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Lo trovi qui: Univ. Federico II | ||
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Modern aspects of spin physics / / Walter Pötz, Jaroslav Fabian, Ulrich Hohenester |
Edizione | [1st ed. 2007.] |
Pubbl/distr/stampa | Berlin, Germany ; ; New York, New York : , : Springer, , [2007] |
Descrizione fisica | 1 online resource (139 p.) |
Disciplina | 539.725 |
Collana | Lecture Notes in Physics |
Soggetto topico |
Nuclear spin
Spintronics |
ISBN |
1-280-80484-X
9786610804849 3-540-38592-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Semiconductor Spintronics -- Lectures on the Spin Pairing Mechanism in High-Temperature Superconductors -- Spin in Quantum Field Theory -- Nucleon Spin. |
Record Nr. | UNISA-996466719903316 |
Berlin, Germany ; ; New York, New York : , : Springer, , [2007] | ||
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Lo trovi qui: Univ. di Salerno | ||
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Non-cooperative equilibria of Fermi systems with long range interactions / / J.-B. Bru, W. de Siqueira Pedra |
Autore | Bru J.-B (Jean-Bernard), <1973-> |
Pubbl/distr/stampa | Providence, Rhode Island : , : American Mathematical Society, , 2012 |
Descrizione fisica | 1 online resource (155 p.) |
Disciplina | 530.155732 |
Collana | Memoirs of the American Mathematical Society |
Soggetto topico |
Thermodynamic equilibrium
Phase rule and equilibrium Mathematical models Nuclear spin Long range order (Solid state physics) |
Soggetto genere / forma | Electronic books. |
ISBN | 1-4704-1003-6 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
""Contents""; ""Preface""; ""Part 1 . Main Results and Discussions""; ""Chapter 1. Fermi Systems on Lattices""; ""1.1. Local fermion algebras""; ""1.2. States of Fermi systems on lattices""; ""1.3. The spaceâ€?averaging functional Î?_{ }""; ""1.4. Local interactions and internal energies""; ""1.5. Energy and entropy densities""; ""Chapter 2. Fermi Systems with Longâ€?Range Interactions""; ""2.1. Fermi systems with longâ€?range interactions""; ""2.2. Examples of applications""; ""2.3. Freeâ€?energy densities and existence of thermodynamics""; ""2.4. Generalized t.i. equilibrium states""
""2.5. Structure of the set \varOmega_{ }^{â?}̄ of generalized t.i. equilibrium states""""2.6. Gibbs states versus generalized equilibrium states""; ""2.7. Thermodynamics and game theory""; ""2.8. Gap equations and effective theories""; ""2.9. Longâ€?range interactions and longâ€?range order (LRO)""; ""2.10. Concluding remarks""; ""Part 2 . Complementary Results""; ""Chapter 3. Periodic Boundary Conditions and Gibbs Equilibrium States""; ""3.1. Interaction kernels""; ""3.2. Periodic boundary conditions""; ""3.3. Pressure and periodic boundary conditions"" ""3.4. Gibbs and generalized t.i. equilibrium states""""Chapter 4. The Set _{â??â??} of â??â??.â??^{ }â€?Invariant States""; ""4.1. GNS representation and the von Neumann ergodic theorem""; ""4.2. The set â?°_{â??â??} of extreme states of â?°_{â??â??}""; ""4.3. Properties of the spaceâ€?averaging functional Î?_{ }""; ""4.4. Von Neumann entropy and entropy density of â??â??â€?periodic states""; ""4.5. The set â?? as a subset of the dual space â??*""; ""4.6. Wellâ€?definiteness of the freeâ€?energy densities on _{â??â??}""; ""Chapter 5. Permutation Invariant Fermi Systems"" ""10.6. The Legendreâ€?Fenchel transform and tangent functionals"" |
Record Nr. | UNINA-9910480982603321 |
Bru J.-B (Jean-Bernard), <1973->
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Providence, Rhode Island : , : American Mathematical Society, , 2012 | ||
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Lo trovi qui: Univ. Federico II | ||
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Non-cooperative equilibria of Fermi systems with long range interactions / / J.-B. Bru, W. de Siqueira Pedra |
Autore | Bru J.-B (Jean-Bernard), <1973-> |
Pubbl/distr/stampa | Providence, Rhode Island : , : American Mathematical Society, , 2012 |
Descrizione fisica | 1 online resource (155 p.) |
Disciplina | 530.155732 |
Collana | Memoirs of the American Mathematical Society |
Soggetto topico |
Thermodynamic equilibrium
Phase rule and equilibrium Mathematical models Nuclear spin Long range order (Solid state physics) |
ISBN | 1-4704-1003-6 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
""Contents""; ""Preface""; ""Part 1 . Main Results and Discussions""; ""Chapter 1. Fermi Systems on Lattices""; ""1.1. Local fermion algebras""; ""1.2. States of Fermi systems on lattices""; ""1.3. The spaceâ€?averaging functional Î?_{ }""; ""1.4. Local interactions and internal energies""; ""1.5. Energy and entropy densities""; ""Chapter 2. Fermi Systems with Longâ€?Range Interactions""; ""2.1. Fermi systems with longâ€?range interactions""; ""2.2. Examples of applications""; ""2.3. Freeâ€?energy densities and existence of thermodynamics""; ""2.4. Generalized t.i. equilibrium states""
""2.5. Structure of the set \varOmega_{ }^{â?}̄ of generalized t.i. equilibrium states""""2.6. Gibbs states versus generalized equilibrium states""; ""2.7. Thermodynamics and game theory""; ""2.8. Gap equations and effective theories""; ""2.9. Longâ€?range interactions and longâ€?range order (LRO)""; ""2.10. Concluding remarks""; ""Part 2 . Complementary Results""; ""Chapter 3. Periodic Boundary Conditions and Gibbs Equilibrium States""; ""3.1. Interaction kernels""; ""3.2. Periodic boundary conditions""; ""3.3. Pressure and periodic boundary conditions"" ""3.4. Gibbs and generalized t.i. equilibrium states""""Chapter 4. The Set _{â??â??} of â??â??.â??^{ }â€?Invariant States""; ""4.1. GNS representation and the von Neumann ergodic theorem""; ""4.2. The set â?°_{â??â??} of extreme states of â?°_{â??â??}""; ""4.3. Properties of the spaceâ€?averaging functional Î?_{ }""; ""4.4. Von Neumann entropy and entropy density of â??â??â€?periodic states""; ""4.5. The set â?? as a subset of the dual space â??*""; ""4.6. Wellâ€?definiteness of the freeâ€?energy densities on _{â??â??}""; ""Chapter 5. Permutation Invariant Fermi Systems"" ""10.6. The Legendreâ€?Fenchel transform and tangent functionals"" |
Record Nr. | UNINA-9910796035103321 |
Bru J.-B (Jean-Bernard), <1973->
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Providence, Rhode Island : , : American Mathematical Society, , 2012 | ||
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Lo trovi qui: Univ. Federico II | ||
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