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Molecular descriptors for chemoinformatics [[electronic resource] /] / Roberto Todeschini and Viviana Consonni
| Molecular descriptors for chemoinformatics [[electronic resource] /] / Roberto Todeschini and Viviana Consonni |
| Autore | Todeschini Roberto |
| Edizione | [2nd ed., rev. and enl.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (1264 p.) |
| Disciplina | 615.19 |
| Altri autori (Persone) | ConsonniViviana |
| Collana | Methods and principles in medicinal chemistry |
| Soggetto topico |
Cheminformatics
Drugs - Design Molecular pharmacology |
| ISBN |
1-282-38002-8
9786612380020 3-527-62876-2 3-527-62877-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Molecular Descriptors for Chemoinformatics; Volume I; Dedication; Contents; The Authors; Acknowledgments; Preface; A Personal Foreword; Introduction; Historical Perspective; QSAR/QSPR Modeling; How to Learn From This Book; User's Guide; Notations and Symbols; Alphabetical Listing; A; B; C; D; E; F; G; H; I; J; K; L; M; N; O; P; Q; R; S; T; U; V; W; X; Y; Z; Greek Alphabet Entries; Numerical Entries; Volume 2; Bibliography; Appendix A: Greek alphabets; Appendix B: Acronyms; Appendix C: Molecular structures |
| Record Nr. | UNINA-9910830627503321 |
Todeschini Roberto
|
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| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Molecular drug properties [[electronic resource] ] : measurement and prediction / / edited by Raimund Mannhold
| Molecular drug properties [[electronic resource] ] : measurement and prediction / / edited by Raimund Mannhold |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2008 |
| Descrizione fisica | 1 online resource (503 p.) |
| Disciplina | 615.7 |
| Altri autori (Persone) | MannholdRaimund <1948-> |
| Collana | Methods and principles in medicinal chemistry |
| Soggetto topico |
Drug development
Drugs - Design |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-01059-X
9786612010590 3-527-62128-8 3-527-62129-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Molecular Drug Properties; Contents; List of Contributors; Preface; A Personal Foreword; Part I Introduction; 1 A Fresh Look at Molecular Structure and Properties; 1.1 Introduction; 1.2 Core Features: The Molecular "Genotype"; 1.2.1 The Argument; 1.2.2 Encoding the Molecular "Genotype"; 1.3 Observable and Computable Properties: The Molecular "Phenotype"; 1.3.1 Overview; 1.3.2 Equilibria; 1.3.3 Stereoelectronic Features; 1.3.4 Recognition Forces and Molecular Interaction Fields (MIFs); 1.3.5 Macroscopic Properties
1.4 Molecular Properties and their Adaptability: The Property Space of Molecular Entities1.4.1 Overview; 1.4.2 The Versatile Behavior of Acetylcholine; 1.4.3 The Carnosine-Carnosinase Complex; 1.4.4 Property Space and Dynamic QSAR Analyses; 1.5 Conclusions; 2 Physicochemical Properties in Drug Profiling; 2.1 Introduction; 2.2 Physicochemical Properties and Pharmacokinetics; 2.2.1 DMPK; 2.2.2 Lipophilicity - Permeability - Absorption; 2.2.3 Estimation of Volume of Distribution from Physical Chemistry; 2.2.4 PPB and Physicochemical Properties; 2.3 Dissolution and Solubility 2.3.1 Calculated Solubility2.4 Ionization (pK(a)); 2.4.1 Calculated pK(a); 2.5 Molecular Size and Shape; 2.5.1 Calculated Size Descriptors; 2.6 H-bonding; 2.6.1 Calculated H-bonding descriptors; 2.7 Lipophilicity; 2.7.1 Calculated log P and log D; 2.8 Permeability; 2.8.1 Artificial Membranes and PAMPA; 2.8.1.1 In Silico PAMPA; 2.8.2 IAM, Immobilized Liposome Chromatography (ILC), Micellar Electrokinetic Chromatography (MEKC) and Biopartitioning Micellar Chromatography (BMC); 2.8.3 Liposome Partitioning; 2.8.4 Biosensors; 2.9 Amphiphilicity; 2.10 Drug-like Properties 2.11 Computation versus Measurement of Physicochemical Properties2.11.1 QSAR Modeling; 2.11.2 In Combo: Using the Best of two Worlds; 2.12 Outlook; Part II Electronic Properties and H-Bonding; 3 Drug Ionization and Physicochemical Profiling; 3.1 Introduction; 3.1.1 Absorption, the Henderson-Hasselbalch Equation and the pH-partition Hypothesis; 3.1.2 "Shift-in-the-pK(a)"; 3.2 Accurate Determination of Ionization Constants; 3.2.1 Definitions - Activity versus Concentration Thermodynamic Scales; 3.2.2 Potentiometric Method; 3.2.3 pH Scales; 3.2.4 Cosolvent Methods 3.2.5 Recent Improvements in the Potentiometric Method Applied to Sparingly Soluble Drugs3.2.6 Spectrophotometric Measurements; 3.2.7 Use of Buffers in UV Spectrophotometry; 3.2.8 pK(a) Prediction Methods and Software; 3.2.9 Tabulations of Ionization Constants; 3.3 "Octanol" and "Membrane" pK(a) in Partition Coefficients Measurement; 3.3.1 Definitions; 3.3.2 Shape of the Log D(oct)-pH Lipophilicity Profiles; 3.3.3 The "diff 3-4" Approximation in log D(oct)-pH Profiles for Monoprotic Molecules 3.3.4 Liposome-Water Partitioning and the "diff 1-2" Approximation in log D(MEM)-pH Profiles for Monoprotic Molecules |
| Record Nr. | UNINA-9910144390803321 |
| Weinheim, : Wiley-VCH, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Molecular drug properties [[electronic resource] ] : measurement and prediction / / edited by Raimund Mannhold
| Molecular drug properties [[electronic resource] ] : measurement and prediction / / edited by Raimund Mannhold |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2008 |
| Descrizione fisica | 1 online resource (503 p.) |
| Disciplina | 615.7 |
| Altri autori (Persone) | MannholdRaimund <1948-> |
| Collana | Methods and principles in medicinal chemistry |
| Soggetto topico |
Drug development
Drugs - Design |
| ISBN |
1-282-01059-X
9786612010590 3-527-62128-8 3-527-62129-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Molecular Drug Properties; Contents; List of Contributors; Preface; A Personal Foreword; Part I Introduction; 1 A Fresh Look at Molecular Structure and Properties; 1.1 Introduction; 1.2 Core Features: The Molecular "Genotype"; 1.2.1 The Argument; 1.2.2 Encoding the Molecular "Genotype"; 1.3 Observable and Computable Properties: The Molecular "Phenotype"; 1.3.1 Overview; 1.3.2 Equilibria; 1.3.3 Stereoelectronic Features; 1.3.4 Recognition Forces and Molecular Interaction Fields (MIFs); 1.3.5 Macroscopic Properties
1.4 Molecular Properties and their Adaptability: The Property Space of Molecular Entities1.4.1 Overview; 1.4.2 The Versatile Behavior of Acetylcholine; 1.4.3 The Carnosine-Carnosinase Complex; 1.4.4 Property Space and Dynamic QSAR Analyses; 1.5 Conclusions; 2 Physicochemical Properties in Drug Profiling; 2.1 Introduction; 2.2 Physicochemical Properties and Pharmacokinetics; 2.2.1 DMPK; 2.2.2 Lipophilicity - Permeability - Absorption; 2.2.3 Estimation of Volume of Distribution from Physical Chemistry; 2.2.4 PPB and Physicochemical Properties; 2.3 Dissolution and Solubility 2.3.1 Calculated Solubility2.4 Ionization (pK(a)); 2.4.1 Calculated pK(a); 2.5 Molecular Size and Shape; 2.5.1 Calculated Size Descriptors; 2.6 H-bonding; 2.6.1 Calculated H-bonding descriptors; 2.7 Lipophilicity; 2.7.1 Calculated log P and log D; 2.8 Permeability; 2.8.1 Artificial Membranes and PAMPA; 2.8.1.1 In Silico PAMPA; 2.8.2 IAM, Immobilized Liposome Chromatography (ILC), Micellar Electrokinetic Chromatography (MEKC) and Biopartitioning Micellar Chromatography (BMC); 2.8.3 Liposome Partitioning; 2.8.4 Biosensors; 2.9 Amphiphilicity; 2.10 Drug-like Properties 2.11 Computation versus Measurement of Physicochemical Properties2.11.1 QSAR Modeling; 2.11.2 In Combo: Using the Best of two Worlds; 2.12 Outlook; Part II Electronic Properties and H-Bonding; 3 Drug Ionization and Physicochemical Profiling; 3.1 Introduction; 3.1.1 Absorption, the Henderson-Hasselbalch Equation and the pH-partition Hypothesis; 3.1.2 "Shift-in-the-pK(a)"; 3.2 Accurate Determination of Ionization Constants; 3.2.1 Definitions - Activity versus Concentration Thermodynamic Scales; 3.2.2 Potentiometric Method; 3.2.3 pH Scales; 3.2.4 Cosolvent Methods 3.2.5 Recent Improvements in the Potentiometric Method Applied to Sparingly Soluble Drugs3.2.6 Spectrophotometric Measurements; 3.2.7 Use of Buffers in UV Spectrophotometry; 3.2.8 pK(a) Prediction Methods and Software; 3.2.9 Tabulations of Ionization Constants; 3.3 "Octanol" and "Membrane" pK(a) in Partition Coefficients Measurement; 3.3.1 Definitions; 3.3.2 Shape of the Log D(oct)-pH Lipophilicity Profiles; 3.3.3 The "diff 3-4" Approximation in log D(oct)-pH Profiles for Monoprotic Molecules 3.3.4 Liposome-Water Partitioning and the "diff 1-2" Approximation in log D(MEM)-pH Profiles for Monoprotic Molecules |
| Record Nr. | UNINA-9910829855203321 |
| Weinheim, : Wiley-VCH, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Molecular insight of drug design / / edited by Arli Aditya Parikesit
| Molecular insight of drug design / / edited by Arli Aditya Parikesit |
| Pubbl/distr/stampa | London, England : , : IntechOpen, , [2018] |
| Descrizione fisica | 1 online resource (x, 119 pages) : illustrations |
| Disciplina | 570.285 |
| Soggetto topico |
Bioinformatics
Computational biology Drugs - Design |
| ISBN |
1-83881-609-7
1-78923-633-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910317796003321 |
| London, England : , : IntechOpen, , [2018] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Nanotechnology and drug delivery / / editor, Professor Dr. Jose L. Arias, Department of Pharmacy and Pharmaceutical Technology Faculty of Pharmacy University of Granada Campus Universitario de Cartuja s/n, 18071 Granada, Spain
| Nanotechnology and drug delivery / / editor, Professor Dr. Jose L. Arias, Department of Pharmacy and Pharmaceutical Technology Faculty of Pharmacy University of Granada Campus Universitario de Cartuja s/n, 18071 Granada, Spain |
| Pubbl/distr/stampa | Boca Raton : , : CRC Press, , [2015] |
| Descrizione fisica | 1 online resource (378 p.) |
| Disciplina |
620.1/18
620.118 |
| Soggetto topico |
Drug delivery systems
Nanoparticles Drugs - Design Nanotechnology |
| ISBN |
0-429-07353-4
1-4665-9948-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Preface to The Book Series; Preface to Volume 1; Contents; CHAPTER 1: Key Aspects in Nanotechnology and Drug Delivery; CHAPTER 2: Drug Delivery and Release from Polymeric Nanomaterials; CHAPTER 3: Nano-Sized Polymeric Drug Carrier Systems; CHAPTER 4: Reversible Cross-Linked Polymeric Nanoplatform in Drug Delivery; CHAPTER 5: Cyclodextrins in Drug Delivery; CHAPTER 6: Drug Delivery Systems Based on Tyrosine-derived Nanospheres (TyroSpheresTM); CHAPTER 7: Carbon Nanotubes for Drug Delivery Applications; CHAPTER 8: Metallic Nanoparticulate Drug Delivery Systems
CHAPTER 9: Porous Silica Nanoparticles for Drug Delivery and Controlled ReleaseCHAPTER 10: Iron Oxides in Drug Delivery; CHAPTER 11: Nanoengineered Magnetic Field-Induced Targeted Drug Delivery System with Stimuli-Responsive Release; Color Plate Section; Back Cover |
| Record Nr. | UNINA-9910786761003321 |
| Boca Raton : , : CRC Press, , [2015] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Nanotechnology and drug delivery / / editor, Professor Dr. Jose L. Arias, Department of Pharmacy and Pharmaceutical Technology Faculty of Pharmacy University of Granada Campus Universitario de Cartuja s/n, 18071 Granada, Spain
| Nanotechnology and drug delivery / / editor, Professor Dr. Jose L. Arias, Department of Pharmacy and Pharmaceutical Technology Faculty of Pharmacy University of Granada Campus Universitario de Cartuja s/n, 18071 Granada, Spain |
| Pubbl/distr/stampa | Boca Raton : , : CRC Press, , [2015] |
| Descrizione fisica | 1 online resource (378 p.) |
| Disciplina |
620.1/18
620.118 |
| Soggetto topico |
Drug delivery systems
Nanoparticles Drugs - Design Nanotechnology |
| ISBN |
0-429-07353-4
1-4665-9948-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Preface to The Book Series; Preface to Volume 1; Contents; CHAPTER 1: Key Aspects in Nanotechnology and Drug Delivery; CHAPTER 2: Drug Delivery and Release from Polymeric Nanomaterials; CHAPTER 3: Nano-Sized Polymeric Drug Carrier Systems; CHAPTER 4: Reversible Cross-Linked Polymeric Nanoplatform in Drug Delivery; CHAPTER 5: Cyclodextrins in Drug Delivery; CHAPTER 6: Drug Delivery Systems Based on Tyrosine-derived Nanospheres (TyroSpheresTM); CHAPTER 7: Carbon Nanotubes for Drug Delivery Applications; CHAPTER 8: Metallic Nanoparticulate Drug Delivery Systems
CHAPTER 9: Porous Silica Nanoparticles for Drug Delivery and Controlled ReleaseCHAPTER 10: Iron Oxides in Drug Delivery; CHAPTER 11: Nanoengineered Magnetic Field-Induced Targeted Drug Delivery System with Stimuli-Responsive Release; Color Plate Section; Back Cover |
| Record Nr. | UNINA-9910821872203321 |
| Boca Raton : , : CRC Press, , [2015] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Natural Product Based Drug Discovery Against Human Parasites : Opportunities and Challenges / / edited by Archana Singh, Brijesh Rathi, Anita K. Verma, Indrakant K. Singh
| Natural Product Based Drug Discovery Against Human Parasites : Opportunities and Challenges / / edited by Archana Singh, Brijesh Rathi, Anita K. Verma, Indrakant K. Singh |
| Autore | Singh Archana |
| Edizione | [1st ed. 2023.] |
| Pubbl/distr/stampa | Singapore : , : Springer Nature Singapore : , : Imprint : Springer, , 2023 |
| Descrizione fisica | 1 online resource (602 pages) |
| Disciplina | 616.96 |
| Altri autori (Persone) |
RathiBrijesh
VermaAnita K SinghIndrakant K |
| Soggetto topico |
Parasitology
Medical microbiology Pharmacology Drugs - Design Medical Microbiology Structure-Based Drug Design |
| ISBN | 981-19-9605-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Chapter 1. Recent advances on the discovery of plants derived bioactive scaffolds/extracts against parasitic diseases -- Chapter 2. Applications of Computational Methods in Natural Products based Drug Discovery -- Chapter 3. Natural Product-Based Drug Designing for treatment of Human parasitic diseases -- Chapter 4. Secondary Metabolites of Plant Origin in Parasitic manifestations -- Chapter 5. Exploring marine biodiversity as alternative resources for treatment of Human Parasitic Diseases -- Chapter 6. Marine Bioprospecting for the Treatment of Human Parasitic Diseases -- Chapter 7. Microorganisms-Derived Biochemicals: Potential Drugs for Human Parasitic Diseases -- Chapter 8. Plant-Based Vaccines against Human Parasitic Diseases -- Chapter 9. Nanotechnology: its usages in drug delivery for the treatment of Human Parasitic Diseases -- Chapter 10. Therapeutic Potential Of Benzopyrones Against Antiparasitic Diseases -- Chapter 11. Antimicrobial peptides (AMPs): current state and future prospects for the treatment of human parasitic diseases -- Chapter 12. Pathway To Register Natural Product-Derived Therapeutics -- Chapter 13. Recent Advances in the Treatment of Parasitic Diseases: Current Status and Future -- Chapter 14. Strategies and challenges for developing plant-based therapeutics against Protozoans -- Chapter 15. Recent approaches to combat toxoplasma gondii with plant-derived alternatives -- Chapter 16. Target-based rational improvement strategies and pitfalls in Leishmania drug discovery -- Chapter 17. Versatile Structurally Diverse Natural Products and Their Semisynthetic Analogs as Potential Anti-leishmanial Drugs -- Chapter 18. Promising compounds of plant origin and their synthetic analogs against Trypanosomes -- Chapter 19. Pathogenesis and Immune Response inT. cruzi infection: Quest for Natural compound-based drugs -- Chapter 20. Limitations of current drugs and prospects of plant-based compounds and their constructed analogues as therapeutics for treatment of malaria -- Chapter 21. An Analytical Approach to Progression in Malaria Therapeutics -- Chapter 22. Malaria Drug Discovery: How to tackle the problem of Drug Resistance -- Chapter 23. Approaches to drug discovery against Ascariasis: Opportunity and challenges in plant-based products -- Chapter 24. The Potential of Plant Secondary Metabolites as Drugs or Leads Against Helminths -- Chapter 25. Drug Resistance in Helminth parasites: Role of plant based natural therapeutics -- Chapter 26. Schistosomiasis: current and future strategies to develop novel therapeutics. |
| Record Nr. | UNINA-9910766882803321 |
|
Singh Archana
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| Singapore : , : Springer Nature Singapore : , : Imprint : Springer, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Nature reviews Drug discovery
| Nature reviews Drug discovery |
| Pubbl/distr/stampa | England, : Nature Pub. Group, 2002- |
| Soggetto topico |
Drugs - Research
Drugs - Design Pharmaceutical chemistry Pharmaceutical Preparations Pharmacology |
| Soggetto genere / forma |
Review
Periodicals. |
| Soggetto non controllato | Pharmacy, Therapeutics, & Pharmacology |
| ISSN | 1474-1784 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Drug discovery |
| Record Nr. | UNINA-9910134075403321 |
| England, : Nature Pub. Group, 2002- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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New developments in medicinal chemistry / / Marta P. Ortega and Irene C. Gil, editors
| New developments in medicinal chemistry / / Marta P. Ortega and Irene C. Gil, editors |
| Pubbl/distr/stampa | New York : , : Nova Science Publishers, , 2009 |
| Descrizione fisica | 1 online resource (290 pages) |
| Disciplina | 615/.19 |
| Altri autori (Persone) |
OrtegaMarta P
GilIrene C |
| Soggetto topico |
Pharmaceutical chemistry
Drugs - Design |
| ISBN | 1-61728-546-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Folate biosynthesis : reappraisal of old and novel targets in the search for new antimicrobials / James Swarbrick ... [et al.] -- Studies on anti-cancer agents : phenolic compounds and their pharmacological activity / Maria Dolors Pujol and Isabel Sánchez -- Cytotoxic anticancer drugs from medicinal plants / Anh-Tho Nguyen and Pierre Duez -- Emerging applications of quantum dots in medicinal chemistry and drug development / Ian D. Tomlinson, Michael R. Warnement and Sandra J. Rosenthal -- Medicinal chemistry of copper and vanadium bioactive compounds / Susana B. Etcheverry and Patricia A.M. Williams -- Antimalarial peroxides : from artemisinin to synthetic peroxides / Jernej Iskra -- Chemical ecology and medicinal chemistry of marine NF-kB inhibitors / F. Folmer ... [et al.] -- Layered double hydroxides and their intercalation compounds in photo-chemistry and in medicinal chemistry / Umberto Costantino and Morena Nocchetti. |
| Record Nr. | UNINA-9910785290203321 |
| New York : , : Nova Science Publishers, , 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
New developments in medicinal chemistry / / Marta P. Ortega and Irene C. Gil, editors
| New developments in medicinal chemistry / / Marta P. Ortega and Irene C. Gil, editors |
| Pubbl/distr/stampa | New York : , : Nova Science Publishers, , 2009 |
| Descrizione fisica | 1 online resource (290 pages) |
| Disciplina | 615/.19 |
| Altri autori (Persone) |
OrtegaMarta P
GilIrene C |
| Soggetto topico |
Pharmaceutical chemistry
Drugs - Design |
| ISBN | 1-61728-546-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Folate biosynthesis : reappraisal of old and novel targets in the search for new antimicrobials / James Swarbrick ... [et al.] -- Studies on anti-cancer agents : phenolic compounds and their pharmacological activity / Maria Dolors Pujol and Isabel Sánchez -- Cytotoxic anticancer drugs from medicinal plants / Anh-Tho Nguyen and Pierre Duez -- Emerging applications of quantum dots in medicinal chemistry and drug development / Ian D. Tomlinson, Michael R. Warnement and Sandra J. Rosenthal -- Medicinal chemistry of copper and vanadium bioactive compounds / Susana B. Etcheverry and Patricia A.M. Williams -- Antimalarial peroxides : from artemisinin to synthetic peroxides / Jernej Iskra -- Chemical ecology and medicinal chemistry of marine NF-kB inhibitors / F. Folmer ... [et al.] -- Layered double hydroxides and their intercalation compounds in photo-chemistry and in medicinal chemistry / Umberto Costantino and Morena Nocchetti. |
| Record Nr. | UNINA-9910827243803321 |
| New York : , : Nova Science Publishers, , 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
-
Drugs - Design
(283)
- Pharmaceutical chemistry (86)
- Drug development (61)
- Drug Design (35)
- Drug delivery systems (16)