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Carbon Nanotubes : Polymer Nanocomposites / / edited by Siva Yellampalli
| Carbon Nanotubes : Polymer Nanocomposites / / edited by Siva Yellampalli |
| Pubbl/distr/stampa | Rijeka : , : IntechOpen, , 2011 |
| Descrizione fisica | 1 online resource (ix, 412 pages) : illustrations |
| Disciplina | 620.115 |
| Soggetto topico |
Chemistry, Organic
Carbon nanotubes |
| ISBN | 953-51-4458-8 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Carbon nanotubes |
| Record Nr. | UNINA-9910138254703321 |
| Rijeka : , : IntechOpen, , 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski
| Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (665 p.) |
| Disciplina | 547 |
| Altri autori (Persone) |
HaleyMichael
TykwinskiR. R (Rik R.) |
| Soggetto topico |
Carbon compounds
Chemistry, Organic |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-85431-6
9786610854318 3-527-60799-4 3-527-60724-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Carbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction
2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ́,4 ́-di(4 ́ ́-dodecylphenyl)-2 ́,5 ́-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] |
| Record Nr. | UNINA-9910144321703321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski
| Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (665 p.) |
| Disciplina | 547 |
| Altri autori (Persone) |
HaleyMichael
TykwinskiR. R (Rik R.) |
| Soggetto topico |
Carbon compounds
Chemistry, Organic |
| ISBN |
1-280-85431-6
9786610854318 3-527-60799-4 3-527-60724-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Carbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction
2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ́,4 ́-di(4 ́ ́-dodecylphenyl)-2 ́,5 ́-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] |
| Record Nr. | UNINA-9910830795503321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-rich compounds : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski
| Carbon-rich compounds : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (665 p.) |
| Disciplina | 547 |
| Altri autori (Persone) |
HaleyMichael
TykwinskiR. R (Rik R.) |
| Soggetto topico |
Carbon compounds
Chemistry, Organic |
| ISBN |
1-280-85431-6
9786610854318 3-527-60799-4 3-527-60724-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Carbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction
2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ́,4 ́-di(4 ́ ́-dodecylphenyl)-2 ́,5 ́-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] |
| Record Nr. | UNINA-9910841200803321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carboxylic Acid : Key Role in Life Sciences / / Gabriel Lucian Radu, Georgiana Ileana Badea, editors
| Carboxylic Acid : Key Role in Life Sciences / / Gabriel Lucian Radu, Georgiana Ileana Badea, editors |
| Pubbl/distr/stampa | London : , : IntechOpen, , [2018] |
| Descrizione fisica | 1 online resource (94 pages) : illustrations |
| Disciplina | 547 |
| Soggetto topico | Chemistry, Organic |
| ISBN |
1-83881-309-8
1-78923-279-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910317813203321 |
| London : , : IntechOpen, , [2018] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carotenoids : structure and function in the human body / / edited by Muhammad Zia-Ul-Haq, Saikat Dewanjee, Muhammad Riaz
| Carotenoids : structure and function in the human body / / edited by Muhammad Zia-Ul-Haq, Saikat Dewanjee, Muhammad Riaz |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2021] |
| Descrizione fisica | 1 online resource (862 pages) |
| Disciplina | 664 |
| Soggetto topico |
Food science
Chemistry, Organic Nutrition |
| ISBN | 3-030-46459-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910485141403321 |
| Cham, Switzerland : , : Springer, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction
| Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction |
| Autore | Roberts Stanley M |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2003 |
| Descrizione fisica | 1 online resource (245 p.) |
| Disciplina |
660.634
660/.28443 |
| Altri autori (Persone) | PoignantGeraldine |
| Collana | Catalysts For Fine Chemicals Synthesis |
| Soggetto topico |
Catalysts
Chemistry, Organic Enzymes Hydrolysis Organic compounds Oxidation-reduction reaction Synthesis Biomedical Engineering Health & Biological Sciences |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-27032-2
9786610270323 0-470-36296-0 0-470-85579-7 0-470-85580-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds
4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 9 Asymmetric Reduction of Ketones Using Organometallic Catalysts |
| Record Nr. | UNINA-9910143508003321 |
Roberts Stanley M
|
||
| Hoboken, : Wiley, 2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction
| Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction |
| Autore | Roberts Stanley M |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2003 |
| Descrizione fisica | 1 online resource (245 p.) |
| Disciplina |
660.634
660/.28443 |
| Altri autori (Persone) | PoignantGeraldine |
| Collana | Catalysts For Fine Chemicals Synthesis |
| Soggetto topico |
Catalysts
Chemistry, Organic Enzymes Hydrolysis Organic compounds Oxidation-reduction reaction Synthesis Biomedical Engineering Health & Biological Sciences |
| ISBN |
1-280-27032-2
9786610270323 0-470-36296-0 0-470-85579-7 0-470-85580-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds
4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 9 Asymmetric Reduction of Ketones Using Organometallic Catalysts |
| Record Nr. | UNISA-996218171503316 |
|
Roberts Stanley M
|
||
| Hoboken, : Wiley, 2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction
| Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction |
| Autore | Roberts Stanley M |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2003 |
| Descrizione fisica | 1 online resource (245 p.) |
| Disciplina |
660.634
660/.28443 |
| Altri autori (Persone) | PoignantGeraldine |
| Collana | Catalysts For Fine Chemicals Synthesis |
| Soggetto topico |
Catalysts
Chemistry, Organic Enzymes Hydrolysis Organic compounds Oxidation-reduction reaction Synthesis Biomedical Engineering Health & Biological Sciences |
| ISBN |
1-280-27032-2
9786610270323 0-470-36296-0 0-470-85579-7 0-470-85580-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds
4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 9 Asymmetric Reduction of Ketones Using Organometallic Catalysts |
| Record Nr. | UNINA-9910831084903321 |
|
Roberts Stanley M
|
||
| Hoboken, : Wiley, 2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction
| Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction |
| Autore | Roberts Stanley M |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2003 |
| Descrizione fisica | 1 online resource (245 p.) |
| Disciplina |
660.634
660/.28443 |
| Altri autori (Persone) | PoignantGeraldine |
| Collana | Catalysts For Fine Chemicals Synthesis |
| Soggetto topico |
Catalysts
Chemistry, Organic Enzymes Hydrolysis Organic compounds Oxidation-reduction reaction Synthesis Biomedical Engineering Health & Biological Sciences |
| ISBN |
1-280-27032-2
9786610270323 0-470-36296-0 0-470-85579-7 0-470-85580-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds
4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 9 Asymmetric Reduction of Ketones Using Organometallic Catalysts |
| Record Nr. | UNINA-9910841318903321 |
|
Roberts Stanley M
|
||
| Hoboken, : Wiley, 2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
-
Chemistry, Organic
(690)
- Chemistry (99)
- Organic compounds - Synthesis (73)
- Organic reaction mechanisms (69)
- Organic Chemistry (55)