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Arene chemistry : reaction mechanisms and methods for aromatic compounds / / edited by Jacques Mortier
| Arene chemistry : reaction mechanisms and methods for aromatic compounds / / edited by Jacques Mortier |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (990 p.) |
| Disciplina | 547/.61 |
| Soggetto topico |
Aromatic compounds
Chemistry, Organic |
| ISBN |
1-118-75498-0
1-118-75495-6 1-118-75488-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
TITLE PAGE ; COPYRIGHT PAGE ; CONTENTS; LIST OF CONTRIBUTORS; PREFACE; Part I Electrophilic Aromatic Substitution ; CHAPTER 1 ELECTROPHILIC AROMATIC SUBSTITUTION: MECHANISM ; 1.1 INTRODUCTION; 1.2 GENERAL ASPECTS; 1.3 ELECTROPHILES; 1.4 ARENE NUCLEOPHILES; 1.5 π-COMPLEX INTERMEDIATES ; 1.6 σ-COMPLEX OR WHELAND INTERMEDIATES ; 1.7 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 2 FRIEDEL-CRAFTS ALKYLATION OF ARENES IN TOTAL SYNTHESIS ; 2.1 INTRODUCTION; 2.2 TOTAL SYNTHESIS INVOLVING INTERMOLECULAR FC ALKYLATIONS; 2.2.1 Synthesis of Coenzyme Q10
2.2.2 Total Synthesis of (±)-Brasiliquinone B 2.2.3 Synthesis of (2212;)-Podophyllotoxin ; 2.2.4 Synthesis of Puupehenol and Related Compounds; 2.2.5 Synthesis of (2212;)-Talaumidin ; 2.2.6 Total Synthesis of (±)-Schefferine ; 2.3 TOTAL SYNTHESIS INVOLVING INTRAMOLECULAR FC ALKYLATIONS; 2.3.1 C-C Bond Formation Leading to Homocyclic Rings ; 2.3.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.3.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.4 TOTAL SYNTHESIS THROUGH TANDEM AND CASCADE PROCESSES INVOLVING FC REACTIONS 2.4.1 C-C Bond Formation Leading to Homocyclic Rings 2.4.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.4.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.5 TOTAL SYNTHESIS INVOLVING ipso-FC REACTIONS ; 2.5.1 Synthesis of (S)-(2212;)-Xylopinine ; 2.5.2 Synthesis of Garcibracteatone; 2.6 SUMMARY AND OUTLOOK; 2.7 ACKNOWLEDGMENT; ABBREVIATIONS ; REFERENCES; CHAPTER 3 CATALYTIC FRIEDEL-CRAFTS ACYLATION REACTIONS ; 3.1 INTRODUCTION AND HISTORICAL BACKGROUND; 3.2 CATALYTIC HOMOGENEOUS ACYLATIONS; 3.2.1 Metal Halides 3.2.2 Perfluoroalkanoic Acids, Perfluorosulfonic Acids, and Their (Metal) Derivatives 3.2.3 Miscellaneous; 3.3 CATALYTIC HETEROGENEOUS ACYLATIONS; 3.3.1 Zeolites; 3.3.2 Clays; 3.3.3 Metal Oxides; 3.3.4 Acid-Treated Metal Oxides ; 3.3.5 Heteropoly Acids (HPAs); 3.3.6 Nafion; 3.3.7 Miscellaneous; 3.4 DIRECT PHENOL ACYLATION; 3.5 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 4 THE USE OF QUANTUM CHEMISTRY FOR MECHANISTIC ANALYSES OF SEAr REACTIONS ; 4.1 INTRODUCTION; 4.1.1 Historical Overview of Early Quantum Chemistry Work 4.1.2 Current Mechanistic Understanding Based on Kinetic and Spectroscopic Studies 4.2 THE SEAr MECHANISM: QUANTUM CHEMICAL CHARACTERIZATION IN GAS PHASE AND SOLUTION; 4.2.1 Nitration and Nitrosation; 4.2.2 Halogenation; 4.2.3 Sulfonation; 4.2.4 Friedel-Crafts Alkylations and Acylations; 4.3 PREDICTION OF RELATIVE REACTIVITY AND REGIOSELECTIVITY BASED ON QUANTUM CHEMICAL DESCRIPTORS; 4.4 QUANTUM CHEMICAL REACTIVITY PREDICTION BASED ON MODELING OF TRANSITION STATES AND INTERMEDIATES; 4.4.1 Transition State Modeling; 4.4.2 The Reaction Intermediate or Sigma-Complex Approach 4.5 SUMMARY AND CONCLUSIONS |
| Record Nr. | UNINA-9910827921703321 |
| Hoboken, New Jersey : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
ARKIVOC : free online journal of organic chemistry
| ARKIVOC : free online journal of organic chemistry |
| Pubbl/distr/stampa | [Place of publication not identified], : Arkat-USA, [2000]- |
| Disciplina | 547 |
| Soggetto topico | Chemistry, Organic |
| Soggetto genere / forma | Periodicals. |
| ISSN | 1551-7012 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti |
Free online journal of organic chemistry
Archive for organic chemistry ARKIVOC journal |
| Record Nr. | UNINA-9910146932703321 |
| [Place of publication not identified], : Arkat-USA, [2000]- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
ARKIVOC : free online journal of organic chemistry
| ARKIVOC : free online journal of organic chemistry |
| Pubbl/distr/stampa | [Place of publication not identified], : Arkat-USA, [2000]- |
| Disciplina | 547 |
| Soggetto topico | Chemistry, Organic |
| Soggetto genere / forma | Periodicals. |
| ISSN | 1551-7012 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti |
Free online journal of organic chemistry
Archive for organic chemistry ARKIVOC journal |
| Record Nr. | UNISA-996215926103316 |
| [Place of publication not identified], : Arkat-USA, [2000]- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
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Arrow-pushing in organic chemistry : an easy approach to understanding reaction mechanisms / / Daniel E. Levy
| Arrow-pushing in organic chemistry : an easy approach to understanding reaction mechanisms / / Daniel E. Levy |
| Autore | Levy D. E (Daniel E.) |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2017 |
| Descrizione fisica | 1 online resource (600 pages) |
| Disciplina | 547.2 |
| Soggetto topico |
Chemistry, Organic
Reaction mechanisms (Chemistry) |
| ISBN | 1-118-99120-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Introduction -- Free radicals -- Acids -- Bases and nucleophiles -- SN2 substitution reactions -- SN1 substitution reactions -- Elimination reactions -- Addition reactions -- Carbenes -- Pericyclic reactions -- Moving forward. |
| Record Nr. | UNINA-9910165038703321 |
Levy D. E (Daniel E.)
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| Hoboken, New Jersey : , : Wiley, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asian journal of organic chemistry
| Asian journal of organic chemistry |
| Pubbl/distr/stampa | Weinheim : , : Wiley-VCH, , [2012]- |
| Descrizione fisica | 1 online resource |
| Disciplina | 547.005 |
| Soggetto topico |
Chemistry, Organic
Organic compounds - Synthesis Chimie organique Composés organiques - Synthèse Organic Chemistry Phenomena |
| Soggetto genere / forma |
periodicals.
Periodicals. Périodiques. Periodical |
| Soggetto non controllato |
organische scheikunde
organic chemistry Organic Chemistry Organische chemie |
| ISSN | 2193-5815 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti |
AsianJOC
Asian j. org. chem |
| Record Nr. | UNISA-996206138903316 |
| Weinheim : , : Wiley-VCH, , [2012]- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Asian journal of organic chemistry
| Asian journal of organic chemistry |
| Pubbl/distr/stampa | Weinheim : , : Wiley-VCH, , [2012]- |
| Descrizione fisica | 1 online resource |
| Disciplina | 547.005 |
| Soggetto topico |
Chemistry, Organic
Organic compounds - Synthesis Chimie organique Composés organiques - Synthèse Organic Chemistry Phenomena |
| Soggetto genere / forma |
periodicals.
Periodicals. Périodiques. Periodical |
| Soggetto non controllato |
organische scheikunde
organic chemistry Organic Chemistry Organische chemie |
| ISSN | 2193-5815 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti |
AsianJOC
Asian j. org. chem |
| Record Nr. | UNINA-9910227297703321 |
| Weinheim : , : Wiley-VCH, , [2012]- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Aspects of organic chemistry / Gerhard Quinkert, Ernst Egert, Christian Griesinger ; [translated by Andrew Beard]
| Aspects of organic chemistry / Gerhard Quinkert, Ernst Egert, Christian Griesinger ; [translated by Andrew Beard] |
| Autore | Quinkert, Gerhard |
| Pubbl/distr/stampa | Basel : Verlag Helvetica Chimica Acta ; Weinheim ; New York : VCH, c1996 |
| Descrizione fisica | xvii, 489 p. : ill. ; 29 cm |
| Disciplina | 547 |
| Altri autori (Persone) |
Egert, Ernstauthor
Griesinger, Christianauthor |
| Soggetto topico | Chemistry, Organic |
| ISBN | 3906390152 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003423799707536 |
|
Quinkert, Gerhard
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| Basel : Verlag Helvetica Chimica Acta ; Weinheim ; New York : VCH, c1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Aspects of Polyurethanes / / edited by Faris Yilmaz
| Aspects of Polyurethanes / / edited by Faris Yilmaz |
| Pubbl/distr/stampa | Rijeka, Croatia : , : IntechOpen, , 2017 |
| Descrizione fisica | 1 online resource (222 pages) : illustrations |
| Disciplina | 547 |
| Soggetto topico | Chemistry, Organic |
| ISBN |
953-51-4644-0
953-51-3546-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910317846903321 |
| Rijeka, Croatia : , : IntechOpen, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Atmospheric degradation of organic substances [[electronic resource] ] : data for persistence and long-range transport potential / / Walter Klöpffer and Burkhard O. Wagner
| Atmospheric degradation of organic substances [[electronic resource] ] : data for persistence and long-range transport potential / / Walter Klöpffer and Burkhard O. Wagner |
| Autore | Klöpffer Walter <1938-> |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (261 p.) |
| Disciplina | 628.52 |
| Altri autori (Persone) | WagnerBurkhard O |
| Soggetto topico |
Organic compounds - Biodegradation
Chemistry, Organic |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-23920-8
9786611239206 3-527-61163-0 3-527-61162-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Atmospheric Degradation of Organic Substances; Foreword; Preface; Contents; Chapter 1 Significance of Photo-degradation in Environmental Risk Assessment; 1 Introduction; 2 Persistence and Long-range Transport Potential in Chemicals Regulation; 3 Multimedia Models as Tools to Estimate Persistence and Long-range Transport Potential; 4 Data Requirements for Multimedia Models; 5 Estimation of the Rate Constant of Organic Substances with Hydroxyl Radicals; 6 Research Requirements for Photo-degradation of Semi-volatile Substances; 7 Conclusions; References
Chapter 2 Abiotic Degradation in the Atmosphere1 Introduction; 2 Photo-degradation in the Homogenous Gas Phase of the Troposphere; 2.1 Indirect Photochemical Reactions; 2.1.1 The Reaction with OH-Radicals; 2.1.1.1 Sources and Sinks of the OH-Radical; 2.1.1.2 Reactions of OH with Organic Compounds; 2.1.2 The Reaction with NO(3)-Radicals; 2.1.2.1 Sources and Sinks of the NO(3)-Radical; 2.1.2.2 Reactions of NO(3) with Organic Compounds; 2.1.3 The Reaction with Ozone; 2.1.3.1 Sources and Sinks of O(3) in the Troposphere; 2.1.3.2 Reactions of O(3) with Organic Compounds 2.2 Direct Photochemical Reactions2.2.1 Quantum Efficiency; 2.2.2 Examples of Photochemical Reactions in the Gas Phase; 3 Heterogeneous Degradation; 3.1 Degradation on Solid Surfaces; 3.1.1 Introduction; 3.1.2 Degradation on Fly Ash and Soot; 3.1.3 Degradation on Artificial Aerosols; 3.2 Degradation in Droplets; 3.2.1 Direct Photochemical Transformation; 3.2.2 Reactive Trace Compounds in Cloud, Fog and Rainwater; 3.2.3 Reactions of Organic Molecules; 3.2.4 Summary; 4 Experimental; 4.1 Indirect Photochemical Degradation; 4.1.1 Bimolecular Reaction with OH 4.1.1.1 Direct Methods for Measuring k(OH)4.1.1.2 Indirect Methods for the Measurement of k(OH); 4.1.2 Bimolecular Reaction with NO(3); 4.1.2.1 Introduction; 4.1.2.2 Absolute Measurement; 4.1.2.3 Relative Measurements; 4.1.3 Bimolecular Reaction with Ozone; 4.2 Direct Photo-transformation; 4.2.1 Determination of the Quantum Efficiency in the Gas Phase; 4.2.1.1 Gas Cuvette and Monochromatic Radiation; 4.2.1.2 Smog-chamber Method; 4.2.2 Outlook; 4.3 Degradation in the Adsorbed State; 4.3.1 Introduction; 4.3.2 Aerosol Chambers; 4.3.3 Alternative Measurements of k(OH,ads) 5 Additional Information Necessary for Calculating Lifetimes5.1 Atmospheric Lifetimes; 5.2 Indirect Photochemical Degradation; 5.2.1 Average OH Concentration in the Troposphere; 5.2.2 Average NO(3) Concentration in the Troposphere; 5.2.3 Average O(3) Concentration in the Troposphere; 5.3 Direct Photochemical Degradation; 5.3.1 Introduction; 5.3.2 Absorption Spectrum; 5.3.3 Spectral Photon Irradiance; 5.3.4 Final Comments on Direct and Indirect Photochemical Transformation; References; Chapter 3 Table of Reaction Rate Constants of Photo-Degradation Processes; 1 Content of the Table 2 Explanation of the Column Headings |
| Record Nr. | UNINA-9910143971703321 |
|
Klöpffer Walter <1938->
|
||
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Atmospheric degradation of organic substances [[electronic resource] ] : data for persistence and long-range transport potential / / Walter Klöpffer and Burkhard O. Wagner
| Atmospheric degradation of organic substances [[electronic resource] ] : data for persistence and long-range transport potential / / Walter Klöpffer and Burkhard O. Wagner |
| Autore | Klöpffer Walter <1938-> |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (261 p.) |
| Disciplina | 628.52 |
| Altri autori (Persone) | WagnerBurkhard O |
| Soggetto topico |
Organic compounds - Biodegradation
Chemistry, Organic |
| ISBN |
1-281-23920-8
9786611239206 3-527-61163-0 3-527-61162-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Atmospheric Degradation of Organic Substances; Foreword; Preface; Contents; Chapter 1 Significance of Photo-degradation in Environmental Risk Assessment; 1 Introduction; 2 Persistence and Long-range Transport Potential in Chemicals Regulation; 3 Multimedia Models as Tools to Estimate Persistence and Long-range Transport Potential; 4 Data Requirements for Multimedia Models; 5 Estimation of the Rate Constant of Organic Substances with Hydroxyl Radicals; 6 Research Requirements for Photo-degradation of Semi-volatile Substances; 7 Conclusions; References
Chapter 2 Abiotic Degradation in the Atmosphere1 Introduction; 2 Photo-degradation in the Homogenous Gas Phase of the Troposphere; 2.1 Indirect Photochemical Reactions; 2.1.1 The Reaction with OH-Radicals; 2.1.1.1 Sources and Sinks of the OH-Radical; 2.1.1.2 Reactions of OH with Organic Compounds; 2.1.2 The Reaction with NO(3)-Radicals; 2.1.2.1 Sources and Sinks of the NO(3)-Radical; 2.1.2.2 Reactions of NO(3) with Organic Compounds; 2.1.3 The Reaction with Ozone; 2.1.3.1 Sources and Sinks of O(3) in the Troposphere; 2.1.3.2 Reactions of O(3) with Organic Compounds 2.2 Direct Photochemical Reactions2.2.1 Quantum Efficiency; 2.2.2 Examples of Photochemical Reactions in the Gas Phase; 3 Heterogeneous Degradation; 3.1 Degradation on Solid Surfaces; 3.1.1 Introduction; 3.1.2 Degradation on Fly Ash and Soot; 3.1.3 Degradation on Artificial Aerosols; 3.2 Degradation in Droplets; 3.2.1 Direct Photochemical Transformation; 3.2.2 Reactive Trace Compounds in Cloud, Fog and Rainwater; 3.2.3 Reactions of Organic Molecules; 3.2.4 Summary; 4 Experimental; 4.1 Indirect Photochemical Degradation; 4.1.1 Bimolecular Reaction with OH 4.1.1.1 Direct Methods for Measuring k(OH)4.1.1.2 Indirect Methods for the Measurement of k(OH); 4.1.2 Bimolecular Reaction with NO(3); 4.1.2.1 Introduction; 4.1.2.2 Absolute Measurement; 4.1.2.3 Relative Measurements; 4.1.3 Bimolecular Reaction with Ozone; 4.2 Direct Photo-transformation; 4.2.1 Determination of the Quantum Efficiency in the Gas Phase; 4.2.1.1 Gas Cuvette and Monochromatic Radiation; 4.2.1.2 Smog-chamber Method; 4.2.2 Outlook; 4.3 Degradation in the Adsorbed State; 4.3.1 Introduction; 4.3.2 Aerosol Chambers; 4.3.3 Alternative Measurements of k(OH,ads) 5 Additional Information Necessary for Calculating Lifetimes5.1 Atmospheric Lifetimes; 5.2 Indirect Photochemical Degradation; 5.2.1 Average OH Concentration in the Troposphere; 5.2.2 Average NO(3) Concentration in the Troposphere; 5.2.3 Average O(3) Concentration in the Troposphere; 5.3 Direct Photochemical Degradation; 5.3.1 Introduction; 5.3.2 Absorption Spectrum; 5.3.3 Spectral Photon Irradiance; 5.3.4 Final Comments on Direct and Indirect Photochemical Transformation; References; Chapter 3 Table of Reaction Rate Constants of Photo-Degradation Processes; 1 Content of the Table 2 Explanation of the Column Headings |
| Record Nr. | UNINA-9910830092703321 |
|
Klöpffer Walter <1938->
|
||
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
-
Chemistry, Organic
(690)
- Chemistry (99)
- Organic compounds - Synthesis (73)
- Organic reaction mechanisms (69)
- Organic Chemistry (55)