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Biblioteca

MARC Lista (tabellare)
Chemistry in alternative reaction media [[electronic resource] /] / Dave J. Adams, Paul J. Dyson, and Stewart J. Tavener
Chemistry in alternative reaction media [[electronic resource] /] / Dave J. Adams, Paul J. Dyson, and Stewart J. Tavener
Autore Adams Dave J
Pubbl/distr/stampa Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Descrizione fisica 1 online resource (269 p.)
Disciplina 541.39
Altri autori (Persone) DysonPaul J
TavenerStewart J
Soggetto topico Solvents
Solvation
Chemical reactions
Chemical kinetics
Soggetto genere / forma Electronic books.
ISBN 0-470-86966-6
9786610238927
0-470-49123-X
0-471-49848-3
1-280-23892-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Chemistry In Alternative Reaction Media; CONTENTS; Preface; Abbreviations and Acronyms; 1 Chemistry in Alternative Reaction Media; 1.1 Economic and Political Considerations; 1.2 Why Do Things Dissolve?; 1.3 Solvent Properties and Solvent Classification; 1.3.1 Density; 1.3.2 Mass Transport; 1.3.3 Boiling Point, Melting Point and Volatility; 1.3.4 Solvents as Heat-Transfer Media; 1.3.5 Cohesive Pressure, Internal Pressure, and Solubility Parameter; 1.4 Solvent Polarity; 1.4.1 Dipole Moment and Dispersive Forces; 1.4.2 Dielectric Constant; 1.4.3 Electron Pair Donor and Acceptor Numbers
1.4.4 Empirical Polarity Scales1.4.5 E(N)(T) and E(T)(30) Parameters; 1.4.6 Kamlet-Taft Parameters; 1.4.7 Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents; 1.5 The Effect of Solvent Polarity on Chemical Systems; 1.5.1 The Effect of Solvent Polarity on Chemical Reactions; 1.5.2 The Effect of Solvent Polarity on Equilibria; 1.6 What is Required from Alternative Solvent Strategies?; References; 2 Multiphasic Solvent Systems; 2.1 An Introduction to Multiphasic Chemistry; 2.1.1 The Traditional Biphasic Approach; 2.1.2 Temperature Dependent Solvent Systems
2.1.3 Single- to Two-Phase Systems2.1.4 Multiphasic Systems; 2.2 Solvent Combinations; 2.2.1 Water; 2.2.2 Fluorous Solvents; 2.2.3 Ionic Liquids; 2.2.4 Supercritical Fluids and Other Solvent Combinations; 2.3 Benefits and Problems Associated with Multiphasic Systems; 2.3.1 Partially Miscible Liquids; 2.4 Kinetics of Homogeneous Reactions; 2.4.1 Rate is Independent of Stoichiometry; 2.4.2 Rate is Determined by the Probability of Reactants Meeting; 2.4.3 Rate is Measured by the Concentration of the Reagents; 2.4.4 Catalysed Systems; 2.5 Kinetics of Biphasic Reactions
2.5.1 The Concentration of Reactants in Each Phase is Affected by Diffusion2.5.2 The Concentration of the Reactants and Products in the Reacting Phase is Determined by Their Partition Coefficients; 2.5.3 The Partition Coefficients of the Reactants and Products May Alter the Position of the Equilibrium; 2.5.4 Effect of Diffusion on Rate; 2.5.5 Determining the Rate of a Reaction in a Biphasic System; 2.6 Conclusions; References; 3 Reactions in Fluorous Media; 3.1 Introduction; 3.2 Properties of Perfluorinated Solvents; 3.3 Designing Molecules for Fluorous Compatibility
3.4 Probing the Effect of Perfluoroalkylation on Ligand Properties3.5 Partition Coefficients; 3.6 Liquid-Liquid Extractions; 3.7 Solid Separations; 3.8 Conclusions; References; 4 Ionic Liquids; 4.1 Introduction; 4.1.1 The Cations and Anions; 4.1.2 Synthesis of Ionic Liquids; 4.2 Physical Properties of Ionic Liquids; 4.3 Benefits and Problems Associated with Using Ionic Liquids in Synthesis; 4.4 Catalyst Design; 4.5 Conclusions; References; 5 Reactions in Water; 5.1 The Structure and Properties of Water; 5.1.1 The Structure of Water; 5.1.2 Near-Critical Water; 5.1.3 The Hydrophobic Effect
5.1.4 The Salt Effect
Record Nr. UNINA-9910132371303321
Adams Dave J  
Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Chemistry in alternative reaction media [[electronic resource] /] / Dave J. Adams, Paul J. Dyson, and Stewart J. Tavener
Chemistry in alternative reaction media [[electronic resource] /] / Dave J. Adams, Paul J. Dyson, and Stewart J. Tavener
Autore Adams Dave J
Pubbl/distr/stampa Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Descrizione fisica 1 online resource (269 p.)
Disciplina 541.39
Altri autori (Persone) DysonPaul J
TavenerStewart J
Soggetto topico Solvents
Solvation
Chemical reactions
Chemical kinetics
ISBN 0-470-86966-6
9786610238927
0-470-49123-X
0-471-49848-3
1-280-23892-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Chemistry In Alternative Reaction Media; CONTENTS; Preface; Abbreviations and Acronyms; 1 Chemistry in Alternative Reaction Media; 1.1 Economic and Political Considerations; 1.2 Why Do Things Dissolve?; 1.3 Solvent Properties and Solvent Classification; 1.3.1 Density; 1.3.2 Mass Transport; 1.3.3 Boiling Point, Melting Point and Volatility; 1.3.4 Solvents as Heat-Transfer Media; 1.3.5 Cohesive Pressure, Internal Pressure, and Solubility Parameter; 1.4 Solvent Polarity; 1.4.1 Dipole Moment and Dispersive Forces; 1.4.2 Dielectric Constant; 1.4.3 Electron Pair Donor and Acceptor Numbers
1.4.4 Empirical Polarity Scales1.4.5 E(N)(T) and E(T)(30) Parameters; 1.4.6 Kamlet-Taft Parameters; 1.4.7 Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents; 1.5 The Effect of Solvent Polarity on Chemical Systems; 1.5.1 The Effect of Solvent Polarity on Chemical Reactions; 1.5.2 The Effect of Solvent Polarity on Equilibria; 1.6 What is Required from Alternative Solvent Strategies?; References; 2 Multiphasic Solvent Systems; 2.1 An Introduction to Multiphasic Chemistry; 2.1.1 The Traditional Biphasic Approach; 2.1.2 Temperature Dependent Solvent Systems
2.1.3 Single- to Two-Phase Systems2.1.4 Multiphasic Systems; 2.2 Solvent Combinations; 2.2.1 Water; 2.2.2 Fluorous Solvents; 2.2.3 Ionic Liquids; 2.2.4 Supercritical Fluids and Other Solvent Combinations; 2.3 Benefits and Problems Associated with Multiphasic Systems; 2.3.1 Partially Miscible Liquids; 2.4 Kinetics of Homogeneous Reactions; 2.4.1 Rate is Independent of Stoichiometry; 2.4.2 Rate is Determined by the Probability of Reactants Meeting; 2.4.3 Rate is Measured by the Concentration of the Reagents; 2.4.4 Catalysed Systems; 2.5 Kinetics of Biphasic Reactions
2.5.1 The Concentration of Reactants in Each Phase is Affected by Diffusion2.5.2 The Concentration of the Reactants and Products in the Reacting Phase is Determined by Their Partition Coefficients; 2.5.3 The Partition Coefficients of the Reactants and Products May Alter the Position of the Equilibrium; 2.5.4 Effect of Diffusion on Rate; 2.5.5 Determining the Rate of a Reaction in a Biphasic System; 2.6 Conclusions; References; 3 Reactions in Fluorous Media; 3.1 Introduction; 3.2 Properties of Perfluorinated Solvents; 3.3 Designing Molecules for Fluorous Compatibility
3.4 Probing the Effect of Perfluoroalkylation on Ligand Properties3.5 Partition Coefficients; 3.6 Liquid-Liquid Extractions; 3.7 Solid Separations; 3.8 Conclusions; References; 4 Ionic Liquids; 4.1 Introduction; 4.1.1 The Cations and Anions; 4.1.2 Synthesis of Ionic Liquids; 4.2 Physical Properties of Ionic Liquids; 4.3 Benefits and Problems Associated with Using Ionic Liquids in Synthesis; 4.4 Catalyst Design; 4.5 Conclusions; References; 5 Reactions in Water; 5.1 The Structure and Properties of Water; 5.1.1 The Structure of Water; 5.1.2 Near-Critical Water; 5.1.3 The Hydrophobic Effect
5.1.4 The Salt Effect
Record Nr. UNINA-9910830067603321
Adams Dave J  
Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Chemistry in alternative reaction media [[electronic resource] /] / Dave J. Adams, Paul J. Dyson, and Stewart J. Tavener
Chemistry in alternative reaction media [[electronic resource] /] / Dave J. Adams, Paul J. Dyson, and Stewart J. Tavener
Autore Adams Dave J
Pubbl/distr/stampa Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Descrizione fisica 1 online resource (269 p.)
Disciplina 541.39
Altri autori (Persone) DysonPaul J
TavenerStewart J
Soggetto topico Solvents
Solvation
Chemical reactions
Chemical kinetics
ISBN 0-470-86966-6
9786610238927
0-470-49123-X
0-471-49848-3
1-280-23892-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Chemistry In Alternative Reaction Media; CONTENTS; Preface; Abbreviations and Acronyms; 1 Chemistry in Alternative Reaction Media; 1.1 Economic and Political Considerations; 1.2 Why Do Things Dissolve?; 1.3 Solvent Properties and Solvent Classification; 1.3.1 Density; 1.3.2 Mass Transport; 1.3.3 Boiling Point, Melting Point and Volatility; 1.3.4 Solvents as Heat-Transfer Media; 1.3.5 Cohesive Pressure, Internal Pressure, and Solubility Parameter; 1.4 Solvent Polarity; 1.4.1 Dipole Moment and Dispersive Forces; 1.4.2 Dielectric Constant; 1.4.3 Electron Pair Donor and Acceptor Numbers
1.4.4 Empirical Polarity Scales1.4.5 E(N)(T) and E(T)(30) Parameters; 1.4.6 Kamlet-Taft Parameters; 1.4.7 Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents; 1.5 The Effect of Solvent Polarity on Chemical Systems; 1.5.1 The Effect of Solvent Polarity on Chemical Reactions; 1.5.2 The Effect of Solvent Polarity on Equilibria; 1.6 What is Required from Alternative Solvent Strategies?; References; 2 Multiphasic Solvent Systems; 2.1 An Introduction to Multiphasic Chemistry; 2.1.1 The Traditional Biphasic Approach; 2.1.2 Temperature Dependent Solvent Systems
2.1.3 Single- to Two-Phase Systems2.1.4 Multiphasic Systems; 2.2 Solvent Combinations; 2.2.1 Water; 2.2.2 Fluorous Solvents; 2.2.3 Ionic Liquids; 2.2.4 Supercritical Fluids and Other Solvent Combinations; 2.3 Benefits and Problems Associated with Multiphasic Systems; 2.3.1 Partially Miscible Liquids; 2.4 Kinetics of Homogeneous Reactions; 2.4.1 Rate is Independent of Stoichiometry; 2.4.2 Rate is Determined by the Probability of Reactants Meeting; 2.4.3 Rate is Measured by the Concentration of the Reagents; 2.4.4 Catalysed Systems; 2.5 Kinetics of Biphasic Reactions
2.5.1 The Concentration of Reactants in Each Phase is Affected by Diffusion2.5.2 The Concentration of the Reactants and Products in the Reacting Phase is Determined by Their Partition Coefficients; 2.5.3 The Partition Coefficients of the Reactants and Products May Alter the Position of the Equilibrium; 2.5.4 Effect of Diffusion on Rate; 2.5.5 Determining the Rate of a Reaction in a Biphasic System; 2.6 Conclusions; References; 3 Reactions in Fluorous Media; 3.1 Introduction; 3.2 Properties of Perfluorinated Solvents; 3.3 Designing Molecules for Fluorous Compatibility
3.4 Probing the Effect of Perfluoroalkylation on Ligand Properties3.5 Partition Coefficients; 3.6 Liquid-Liquid Extractions; 3.7 Solid Separations; 3.8 Conclusions; References; 4 Ionic Liquids; 4.1 Introduction; 4.1.1 The Cations and Anions; 4.1.2 Synthesis of Ionic Liquids; 4.2 Physical Properties of Ionic Liquids; 4.3 Benefits and Problems Associated with Using Ionic Liquids in Synthesis; 4.4 Catalyst Design; 4.5 Conclusions; References; 5 Reactions in Water; 5.1 The Structure and Properties of Water; 5.1.1 The Structure of Water; 5.1.2 Near-Critical Water; 5.1.3 The Hydrophobic Effect
5.1.4 The Salt Effect
Record Nr. UNINA-9910840693203321
Adams Dave J  
Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Cinetica chimica moderna / di Henry Eyring and Edward M. Eyring ; [traduzione di Luisa Rossi]
Cinetica chimica moderna / di Henry Eyring and Edward M. Eyring ; [traduzione di Luisa Rossi]
Autore Eyring, Henry
Pubbl/distr/stampa Milano : Progresso tecnico editoriale, 1965
Descrizione fisica 117 p. : ill. ; 19 cm
Disciplina 541.3
Altri autori (Persone) Eyring, Edward M.
Rossi, Luisa
Collana Argomenti di chimica moderna
Soggetto topico Chemical kinetics
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISALENTO-991003058309707536
Eyring, Henry  
Milano : Progresso tecnico editoriale, 1965
Materiale a stampa
Lo trovi qui: Univ. del Salento
Opac: Controlla la disponibilità qui
Cinétique enzymatique [[electronic resource] /] / Athel Cornish-Bowden, Marc Jamin, Valdur Saks
Cinétique enzymatique [[electronic resource] /] / Athel Cornish-Bowden, Marc Jamin, Valdur Saks
Autore Cornish-Bowden Athel
Pubbl/distr/stampa [Les Ulis], : EDP Sciences, 2005
Descrizione fisica 1 online resource (465 p.)
Disciplina 572.744
Altri autori (Persone) JaminMarc
SaksV. A
Collana Collection Grenoble sciences
Soggetto topico Enzyme kinetics
Chemical kinetics
ISBN 1-280-96200-3
9786610962006
1-4237-4477-2
2-7598-0116-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione fre
Nota di contenuto PRÉFACE; 1 – PRINCIPES DE BASE DE LA CINÉTIQUE CHIMIQUE; 2 – LA THERMODYNAMIQUE ET LA THÉORIE DES VITESSES ABSOLUES; 3 – INTRODUCTION À LA CINÉTIQUE ENZYMATIQUE RÉACTIONS À UN SUBSTRAT ET UN PRODUIT; 4 – ASPECTS PRATIQUES DES ÉTUDES CINÉTIQUES; 5 – INHIBITION ET ACTIVATION DES ENZYMES; 6 – RÉACTIONS À PLUSIEURS SUBSTRATS; 7 – UTILISATION D'ISOTOPES POUR L'ÉTUDE DES MÉCANISMES ENZYMATIQUES; 8 – EFFETS DE L'ENVIRONNEMENT SUR LES ENZYMES; 9 – CONTRÔLE DE L'ACTIVITÉ ENZYMATIQUE; 10 – CINÉTIQUES DES SYSTÈMES MULTI-ENZYMATIQUES; 11 – LES RÉACTIONS RAPIDES; 12 – ESTIMATION DES CONSTANTES CINÉTIQUES
SOLUTIONS DES PROBLÈMES ET COMMENTAIRESRÉFÉRENCES; INDEX; TABLE DES MATIÈRES;
Record Nr. UNINA-9910784295003321
Cornish-Bowden Athel  
[Les Ulis], : EDP Sciences, 2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Cinétique enzymatique / / Athel Cornish-Bowden, Marc Jamin, Valdur Saks
Cinétique enzymatique / / Athel Cornish-Bowden, Marc Jamin, Valdur Saks
Autore Cornish-Bowden Athel
Pubbl/distr/stampa [Les Ulis], : EDP Sciences, 2005
Descrizione fisica 1 online resource (465 p.)
Disciplina 572.744
Altri autori (Persone) JaminMarc
SaksV. A
Collana Collection Grenoble sciences
Soggetto topico Enzyme kinetics
Chemical kinetics
ISBN 1-280-96200-3
9786610962006
1-4237-4477-2
2-7598-0116-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione fre
Nota di contenuto PRÉFACE; 1 – PRINCIPES DE BASE DE LA CINÉTIQUE CHIMIQUE; 2 – LA THERMODYNAMIQUE ET LA THÉORIE DES VITESSES ABSOLUES; 3 – INTRODUCTION À LA CINÉTIQUE ENZYMATIQUE RÉACTIONS À UN SUBSTRAT ET UN PRODUIT; 4 – ASPECTS PRATIQUES DES ÉTUDES CINÉTIQUES; 5 – INHIBITION ET ACTIVATION DES ENZYMES; 6 – RÉACTIONS À PLUSIEURS SUBSTRATS; 7 – UTILISATION D'ISOTOPES POUR L'ÉTUDE DES MÉCANISMES ENZYMATIQUES; 8 – EFFETS DE L'ENVIRONNEMENT SUR LES ENZYMES; 9 – CONTRÔLE DE L'ACTIVITÉ ENZYMATIQUE; 10 – CINÉTIQUES DES SYSTÈMES MULTI-ENZYMATIQUES; 11 – LES RÉACTIONS RAPIDES; 12 – ESTIMATION DES CONSTANTES CINÉTIQUES
SOLUTIONS DES PROBLÈMES ET COMMENTAIRESRÉFÉRENCES; INDEX; TABLE DES MATIÈRES;
Record Nr. UNINA-9910810780203321
Cornish-Bowden Athel  
[Les Ulis], : EDP Sciences, 2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Cinétique et dynamique des réactions chimiques / / Mehran Mostafavi
Cinétique et dynamique des réactions chimiques / / Mehran Mostafavi
Autore Mostafavi Mehran
Pubbl/distr/stampa [Les Ulis, France] : , : edp sciences, , 2015
Descrizione fisica 1 online resource (373 p.)
Disciplina 541.394
Collana QuinteSciences
Soggetto topico Chemical kinetics
Molecular dynamics
ISBN 2-7598-1812-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione fre
Nota di contenuto Sommaire; Avant-propos; Remerciements; Chapitre 1. Réactions, temps, et températureen cinétique homogène; 1.1 Introduction; 1.2 Réactions élémentaires et réactions globales; 1.3 Vitesse des réactions; 1.4 Avancement et degré d'avancement de la réaction; 1.5 Facteurs influençant la vitesse d'une réaction; 1.6 Ordre d'une réaction; 1.7 Loi cinétique des vitesses; 1.8 Influence de la température sur la vitesse de réaction; 1.9 Exercices; 1.10 Références; Chapitre 2. Cinétique des réactions multi-étapes; 2.1 Introduction
2.2 Expression de la vitesse d'évolution d'un composé qui intervient dans plusieurs réactions2.3 Réactions consécutives; 2.4 Réactions compétitives; 2.5 Réactions parallèles; 2.6 Cinétique des équilibres; 2.7 Réactions en chaîne; 2.8 Exercices; 2.9 Références; Chapitre 3. Méthodes et techniques expérimentales en cinétique et dynamique chimique; 3.1 Introduction; 3.2 Méthodes et techniques en régime stationnaire; 3.3 Mélange rapide des réactifs (Flux stoppé ou Stopped flow); 3.4 Méthodes de relaxation; 3.5 Méthodes et techniques impulsionnelles résolues en temps
3.6 Techniques impulsionnelles d'observation résolues dans le temps3.7 Absorption et émission transitoire; 3.8 Autres méthodes de détection rapide; 3.9 Exercice; 3.10 Références; Chapitre 4. Théorie des collisions en phase gazeuse; 4.1 Introduction; 4.2 Modèle des collisions entre sphères dures; 4.3 Section efficace et paramètre d'impact; 4.4 Définition de la constante cinétique bimoléculaire; 4.5 Équations du mouvement d'un système à deux particules en collision; 4.6 Potentiel d'interaction et calcul de la section efficace de réaction; 4.7 Potentiels modèles; 4.8 Au-delà des cas simples
4.9 ExercicesChapitre 5. Théorie de l'état de transition; 5.1 Introduction; 5.2 Surfaces de potentiel; 5.3 Approche thermodynamique; 5.4 Lien entre les théories des collisions et du complexe activé; 5.5 Conclusion; 5.6 Exercices; Chapitre 6. Réactions unimoléculaires en phase gazeuse; 6.1 Introduction; 6.2 Modèle de Lindemann; 6.3 Modification du modèle de Lindemann; 6.4 Théorie R.R.K. (Rice, Ramsperger, Kessel); 6.5 Vers la théorie R.R.K.M. (Rice, Ramsperger, Kessel, Marcus); 6.6 Exercices; Chapitre 7. Diffusion et réaction élémentaire en solution; 7.1 Introduction; 7.2 Diffusion en solution
7.3 Diffusion et réaction chimique7.4 Détermination de la constante de vitesse entre deux espèces neutres ou chargées; 7.5 Critique du modèle de Smoluchowski : l'étape d'activation; 7.6 Réactions limitées par l'activation kact < kdiff; 7.7 Influence de la force ionique pour les réactions de macromolécules chargées; 7.8 Exercices; Chapitre 8. Initiation à la cinétique des processus photophysiques et photochimiques; 8.1 Introduction; 8.2 Lois élémentaires et principes de la photochimie; 8.3 Processus photophysiques; 8.4 Processus photochimiques; 8.5 Exercices
Chapitre 9. Initiation aux processus induits par les rayonnements ionisants
Record Nr. UNINA-9910797133503321
Mostafavi Mehran  
[Les Ulis, France] : , : edp sciences, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Cinétique et dynamique des réactions chimiques / / Mehran Mostafavi
Cinétique et dynamique des réactions chimiques / / Mehran Mostafavi
Autore Mostafavi Mehran
Pubbl/distr/stampa [Les Ulis, France] : , : edp sciences, , 2015
Descrizione fisica 1 online resource (373 p.)
Disciplina 541.394
Collana QuinteSciences
Soggetto topico Chemical kinetics
Molecular dynamics
ISBN 2-7598-1812-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione fre
Nota di contenuto Sommaire; Avant-propos; Remerciements; Chapitre 1. Réactions, temps, et températureen cinétique homogène; 1.1 Introduction; 1.2 Réactions élémentaires et réactions globales; 1.3 Vitesse des réactions; 1.4 Avancement et degré d'avancement de la réaction; 1.5 Facteurs influençant la vitesse d'une réaction; 1.6 Ordre d'une réaction; 1.7 Loi cinétique des vitesses; 1.8 Influence de la température sur la vitesse de réaction; 1.9 Exercices; 1.10 Références; Chapitre 2. Cinétique des réactions multi-étapes; 2.1 Introduction
2.2 Expression de la vitesse d'évolution d'un composé qui intervient dans plusieurs réactions2.3 Réactions consécutives; 2.4 Réactions compétitives; 2.5 Réactions parallèles; 2.6 Cinétique des équilibres; 2.7 Réactions en chaîne; 2.8 Exercices; 2.9 Références; Chapitre 3. Méthodes et techniques expérimentales en cinétique et dynamique chimique; 3.1 Introduction; 3.2 Méthodes et techniques en régime stationnaire; 3.3 Mélange rapide des réactifs (Flux stoppé ou Stopped flow); 3.4 Méthodes de relaxation; 3.5 Méthodes et techniques impulsionnelles résolues en temps
3.6 Techniques impulsionnelles d'observation résolues dans le temps3.7 Absorption et émission transitoire; 3.8 Autres méthodes de détection rapide; 3.9 Exercice; 3.10 Références; Chapitre 4. Théorie des collisions en phase gazeuse; 4.1 Introduction; 4.2 Modèle des collisions entre sphères dures; 4.3 Section efficace et paramètre d'impact; 4.4 Définition de la constante cinétique bimoléculaire; 4.5 Équations du mouvement d'un système à deux particules en collision; 4.6 Potentiel d'interaction et calcul de la section efficace de réaction; 4.7 Potentiels modèles; 4.8 Au-delà des cas simples
4.9 ExercicesChapitre 5. Théorie de l'état de transition; 5.1 Introduction; 5.2 Surfaces de potentiel; 5.3 Approche thermodynamique; 5.4 Lien entre les théories des collisions et du complexe activé; 5.5 Conclusion; 5.6 Exercices; Chapitre 6. Réactions unimoléculaires en phase gazeuse; 6.1 Introduction; 6.2 Modèle de Lindemann; 6.3 Modification du modèle de Lindemann; 6.4 Théorie R.R.K. (Rice, Ramsperger, Kessel); 6.5 Vers la théorie R.R.K.M. (Rice, Ramsperger, Kessel, Marcus); 6.6 Exercices; Chapitre 7. Diffusion et réaction élémentaire en solution; 7.1 Introduction; 7.2 Diffusion en solution
7.3 Diffusion et réaction chimique7.4 Détermination de la constante de vitesse entre deux espèces neutres ou chargées; 7.5 Critique du modèle de Smoluchowski : l'étape d'activation; 7.6 Réactions limitées par l'activation kact < kdiff; 7.7 Influence de la force ionique pour les réactions de macromolécules chargées; 7.8 Exercices; Chapitre 8. Initiation à la cinétique des processus photophysiques et photochimiques; 8.1 Introduction; 8.2 Lois élémentaires et principes de la photochimie; 8.3 Processus photophysiques; 8.4 Processus photochimiques; 8.5 Exercices
Chapitre 9. Initiation aux processus induits par les rayonnements ionisants
Record Nr. UNINA-9910809862103321
Mostafavi Mehran  
[Les Ulis, France] : , : edp sciences, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Cleaner combustion : developing detailed chemical kinetic models / / Frederique Battin-Leclerc, John M. Simmie, Edward Blurock, editors
Cleaner combustion : developing detailed chemical kinetic models / / Frederique Battin-Leclerc, John M. Simmie, Edward Blurock, editors
Edizione [1st ed. 2013.]
Pubbl/distr/stampa London : , : Springer, , 2013
Descrizione fisica 1 online resource (xiii, 658 pages) : illustrations (some color)
Disciplina 621.042
Collana Green Energy and Technology
Soggetto topico Fossil fuels - Combustion
Chemical kinetics
ISBN 1-4471-5307-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto 1.Introduction,- PART I -- 2.Modeling combustion with detailed kinetic mechanisms -- 3.Automatic generation of detailed mechanisms -- 4.Specificities related to detailed kinetic models for the combustion of oxygenated fuel components -- 5.Multistep kinetic model of biomass pyrolysis -- PART II -- 6.Speciation in shock tubes -- 7.Rapid compression machines -- 8.Jet-stirred reactors -- 9.Tubular flow reactors -- 10.Flame studies of oxygenated hydrocarbons -- PART III -- 11.Formation and characterization of polyaromatic hydrocarbons -- 12.Laser diagnostics for selective and quantitative measurement of PAHs and soot -- 13.Characterization of soot -- 14.An Advanced Multi-Sectional Method for Particulate Matter Modeling in Flames -- 15.Modelling soot formation: model of particle formation -- PART IV -- 16.Investigation and improvement of reaction mechanisms using sensitivity analysis and optimization -- 17.Mechanism reduction to skeletal form and species lumping -- 18.Time Scale Splitting Based Mechanism Reduction -- 19.Storage of chemical kinetic information -- PART V -- 20.Calculation of molecular thermochemical data and their availability in databases -- 21.Statistical rate theory in combustion: An operational approach -- 22.Primary products and branching ratios for combustion multi-channel bimolecular reactions from crossed molecular beam studies -- 23.Kinetic studies of elementary chemical steps with relevance in combustion and environmental chemistry -- 24.Shock-tube studies of combustion-relevant elementary chemical steps and sub-Mechanisms.
Record Nr. UNINA-9910437781203321
London : , : Springer, , 2013
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Compilation of chemical kinetic data for combustion chemistry [[electronic resource] /] / Francis Westley, John T. Herron, and R.J. Cvetanović
Compilation of chemical kinetic data for combustion chemistry [[electronic resource] /] / Francis Westley, John T. Herron, and R.J. Cvetanović
Autore Westley Francis
Pubbl/distr/stampa Gaithersburg, MD., : U.S. Dept. of Commerce, National Bureau of Standards
Descrizione fisica 1 online resource (2 volumes)
Altri autori (Persone) HerronJohn Thomas <1931->
CvetanovićRatimir J
Collana NSRDS-NBS
Soggetto topico Combustion
Chemical kinetics
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto pt. 1. Non-aromatic C, H, O, N, and S containing compounds (1971-1982) -- pt. 2. Non-aromatic C, H, O, N and S containing compounds (1983).
Record Nr. UNINA-9910697863803321
Westley Francis  
Gaithersburg, MD., : U.S. Dept. of Commerce, National Bureau of Standards
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui