Autore	Buchachenko A. L (Anatolii Leonidovich)
Pubbl/distr/stampa	New York, : Nova Science Publishers, c2009
Descrizione fisica	1 online resource (159 p.)
Disciplina	541/.38
Soggetto topico	Free radical reactions Nuclear spin Chemical kinetics Isotopes
ISBN	1-60876-794-9
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Record Nr.	UNINA-9910779522503321

Autore	Buchachenko A. L (Anatolii Leonidovich)
Edizione	[1st ed.]
Pubbl/distr/stampa	New York, : Nova Science Publishers, c2009
Descrizione fisica	1 online resource (159 p.)
Disciplina	541/.38
Soggetto topico	Free radical reactions Nuclear spin Chemical kinetics Isotopes
ISBN	1-60876-794-9
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Intro -- MAGNETIC ISOTOPE EFFECT IN CHEMISTRY AND BIOCHEMISTRY -- MAGNETIC ISOTOPE EFFECT IN CHEMISTRY AND BIOCHEMISTRY -- CONTENTS -- PREFACE -- INTRODUCTION -- Chapter 1 ENERGY AND ANGULAR MOMENTUM AS THE REACTION CONTROLLING FACTORS -- 1.1. ENERGY -- 1.2. ANGULAR MOMENTUM -- 1.2.1. Rotational Angular Momentum -- 1.2.2. Electron Orbital Momentum -- 1.2.3. Electron Angular Momentum: Spin States and Spin Multiplicity -- 1.2.4. Nuclear Angular Momentum and Nuclear Spin States -- Chapter 2 SPIN CONTROL OF CHEMICAL REACTIONS -- 2.1. SPIN STATES AND CHEMICAL REACTIVITY -- 2.2. MAGNETIC INTERACTIONS AND MAGNETIC EFFECTS -- Chapter 3 MAGNETIC ISOTOPE EFFECT (MIE) -- 3.1. HOW TO DISCRIMINATE CLASSICAL AND MAGNETIC ISOTOPE EFFECTS -- 3.2. MIE: HOW IT FUNCTIONS -- 3.3. MIE AS A TEST OF REACTION MECHANISM -- 3.4. NUCLEAR SPIN POLARIZATION -- 3.5. MIE AND ISOTOPE TECHNOLOGY -- 3.6. MIE: THE ROAD OF DISCOVERIES -- Chapter 4 KINETICS OF ISOTOPE FRACTIONATION -- 4.1. MEASUREMENT OF ISOTOPE COMPOSITION -- 4.2. ANALYSIS OF THE KINETIC SCHEMES -- 4.3. ABSOLUTE MEASURE OF ISOTOPE SEPARATION -- 4.4. DYNAMIC CHARACTERISTICS OF SPIN SELECTIVE NANOREACTOR -- 4.5. IS THERE A LIMIT IN MIE INDUCED ISOTOPE FRACTIONATION? -- Chapter 5 PHYSICS OF THE MIE -- 5.1. SPIN-SELECTIVE NANOREACTOR: HOW IT FUNCTIONS? -- 5.2. SPIN DYNAMICS -- 5.3. MOLECULAR DYNAMICS -- 5.4. CHEMICAL DYNAMICS -- 5.5. GENERALIZED SPIN DYNAMICS -- Chapter 6 MIE FOR DEUTERIUM-HYDROGEN DYAD -- Chapter 7 13C MIE: CONTROLLING FACTORS -- 7.1. SPIN PROHIBITION: HOW IT IS RIGOROUS -- 7.2. HYPERFINE COUPLING AND CHEMICAL REACTIVITY -- 7.3. MIE AS A FUNCTION OF THE MAGNETIC FIELD -- 7.4. VISCOSITY, LIFETIME OF RADICALS AND A SIZE OF MICROREACTORS -- 7.5. SPIN MULTIPLICITY AND COMPETITION OF RADICAL AND NON-RADICAL REACTION CHANNELS -- 7.6. MIE AS A FUNCTION OF MOLECULAR ENERGY. Chapter 8 OXYGEN MIE -- 8.1. FRACTIONATION OF ISOTOPES IN CHAIN REACTIONS OF MOLECULAR OXYGEN -- 8.2. ADDITION OF MOLECULAR OXYGEN TO RADICALS -- 8.3. INTERACTION OF PEROXY RADICALS (CHAIN TERMINATION REACTION) -- 8.4. TEMPERATURE AND VISCOSITY AS CONTROLLING FACTORS OF CHEMICAL SPIN SELECTIVITY -- 8.5. NONCHAIN PROCESSES: ENDOPEROXIDES - SYNTHESIS AND DECOMPOSITION -- 8.6. GEOCHEMICAL ANOMALIES OF 17О -- Chapter 9 SILICON MIE -- 9.1. PHOTOLYSIS OF PHENYLSILYLKETONE -- 9.2. PHOTOLYSIS OF BENZYLSILYLKETONE -- 9.3. SPIN MULTIPLICITY AND THE SIGN OF MIE -- Chapter 10 MIE FOR SULFUR, GERMANIUM AND TIN NUCLEI -- 10.1. SULFUR -- 10.2. GERMANIUM -- 10.3. TIN -- Chapter 11 URANIUM MIE -- 11.1. SPIN-SELECTIVE REACTIONS OF URANYL -- 11.2. URANIUM NANOREACTOR -- 11.2.1. Proton CIDNP -- 11.2.2. Magnetic Field Effect -- 11.3. FRACTIONATION OF URANIUM ISOTOPES -- Chapter 12 MERCURY MIE -- 12.1. MIE IN PHOTOCHEMICAL REACTIONS -- 12.2. MERCURY MIE IN ENZYMATIC PHOSPHORYLATION BY CREATINE KINASE -- Chapter 13 MAGNESIUM ISOTOPE EFFECTS -- 13.1. CLASSICAL ISOTOPE EFFECTS -- 13.2. MAGNETIC ISOTOPE EFFECTS IN ENZYMATIC PHOSPHORYLATION -- 13.2.1. Materials and Experimental Techniques -- 13.2.2. Experimental Detection of Magnesium Isotope Effects -- 13.2.3. Enzymatic Phosphorylation as a Spin-Selective Reaction -- 13.2.4. Quantitative Measure of Magnesium MIE -- 13.2.5. ATP Hydrolysis: No Isotope Effect -- 13.2.6. Magnetic Field Dependence of the Phosphorylation -- 13.2.7. Magnesium MIE Is a Key to Mechanochemistry of Enzymes as the Molecular Machines -- Chapter 14 MICROWAVE EFFECTS -- 14.1. MICROWAVE MIE -- 14.2. Biological Microwave Effects -- 14.2.1. Resonant Microwave Fields -- 14.2.2. Non-Resonant Low Frequency Fields -- ACKNOWLEDGEMENTS -- REFERENCES -- INDEX.
Record Nr.	UNINA-9910824161103321

Edizione	[14th ed.]
Pubbl/distr/stampa	River Edge, N.J. ; ; Hong Kong, : World Scientific, c2004
Descrizione fisica	1 online resource (539 p.)
Disciplina	541/.394
Altri autori (Persone)	YangXueming <1964-> LiuKopin
Collana	Advanced series in physical chemistry
Soggetto topico	Chemical kinetics Reactivity (Chemistry)
Soggetto genere / forma	Electronic books.
ISBN	1-281-87698-4 9786611876982 981-256-542-6
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Introduction; Preface; CONTENTS; 1. Doppler-Selected Time-of-Flight Technique: A Versatile Three-Dimensional Velocity Mapping Approach Shih-Huang Lee and Kopin Liu; 2. The Effect of Reactive Resonance on Collision Observables Sheng Der Chao and Rex T. Skodje; 3. State-to-State Dynamics of Elementary Chemical Reactions Using Rydberg H-Atom Translational Spectorscopy Xueming Yang; 4. Multimass Ion Imaging - A New Experimental Method and Its Application in the Photodissociation of Small Aromatic Molecules Cheng-Liang Huang, Yuan T. Lee and Chi-Kung Ni 5. Reactions of Neutral Transition Metal Atoms with Small Molecules in the Gas Phase Jonathan J. Schroden and H. Floyd Davis 6. Photodissociation Dynamics of Ozone in the Hartley Band Paul L. Houston; 7. Crossed Molecular Beam Reactive Scattering: Towards Universal Product Detection by Soft Electron-Impact Ionization Piergiorgio Casavecchia, Giovanni Capozza and Enrico Segoloni; 8. Interactions of Vibrationally-Excited Molecules at Surfaces: A Probe for Electronically Nonadiabatic Effects in Heterogeneous Chemistry Alec M. Wodtke 9. First Principles Quantum Dynamical Study of Four-Atom Reactions Dong H. Zhang, Minghui Yang, Soo-Y. Lee and Michael A. Collins 10. Photodissociation Dynamics of Free Radicals Jingsong Zhang; Index
Record Nr.	UNINA-9910449884803321

Autore	Yang Xueming
Pubbl/distr/stampa	Singapore, : World Scientific Publishing Company, 2004
Descrizione fisica	1 online resource (539 p.)
Disciplina	541.39 541.394
Altri autori (Persone)	LiuKopin
Collana	Advanced series in physical chemistry
Soggetto topico	Chemical kinetics
Soggetto genere / forma	Electronic books.
ISBN	1-281-87718-2 9786611877187 981-256-580-9
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Introduction; Preface; CONTENTS; 1. Doppler-Selected Time-of-Flight Technique: A Versatile Three-Dimensional Velocity Mapping Approach Shih-Huang Lee and Kopin Liu; 2. The Effect of Reactive Resonance on Collision Observables Sheng Der Chao and Rex T. Skodje; 3. State-to-State Dynamics of Elementary Chemical Reactions Using Rydberg H-Atom Translational Spectroscopy Xueming Yang; 4. Multimass Ion Imaging - A New Experimental Method and Its Application in the Photodissociation of Small Aromatic Molecules Cheng-Liang Huang, Yuan T. Lee and Chi-Kung Ni 5. Reactions of Neutral Transition Metal Atoms with Small Molecules in the Gas Phase Jonathan J. Schroden and H. Floyd Davis6. Photodissociation Dynamics of Ozone in the Hartley Band Paul L. Houston; 7. Crossed Molecular Beam Reactive Scattering: Towards Universal Product Detection by Soft Electron-Impact Ionization Piergiorgio Casavecchia, Giovanni Capozza and Enrico Segoloni; 8. Interactions of Vibrationally-Excited Molecules at Surfaces: A Probe for Electronically Nonadiabatic Effects in Heterogeneous Chemistry Alec M. Wodtke 9. First Principles Quantum Dynamical Study of Four-Atom Reactions Dong H. Zhang, Minghui Yang, Soo-Y. Lee and Michael A. Collins10. Photodissociation Dynamics of Free Radicals Jingsong Zhang; Index
Record Nr.	UNINA-9910450223703321

Autore	Lawley K. P
Pubbl/distr/stampa	London ; ; New York, : Wiley, 1975
Descrizione fisica	1 online resource (552 p.)
Disciplina	541.305 541/.08
Collana	Advances in chemical physics
Soggetto topico	Excited state chemistry Chemical kinetics
Soggetto genere / forma	Electronic books.
ISBN	1-282-34752-7 9786612347528 0-470-14382-7 0-470-14415-7
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	ADVANCES IN CHEMICAL PHYSICS; CONTENTS; INTRODUCTION: NEW DIRECTIONS IN MOLECULAR BEAMS; QUANTUM THEORY OF REACTIVE MOLECULAR COLLISIONS; CLASSICAL S-MATRIX IN MOLECULAR COLLISIONS; POTENTIAL ENERGY SURFACES FOR CHEMICAL REACTION; SCATTERING OF POSITIVE IONS BY MOLECULE; REACTIVE SCATTERING; ELASTIC SCATTERING; SCATTERING FROM ORIENTED MOLECULES; ELECTRONIC EXCITATION IN COLLISIONS BETWEEN NEUTRALS; CHARGE TRANSFER BETWEEN NEUTRALS AT HYPERTHERMAL ENERGIES; SUBJECT INDEX
Record Nr.	UNINA-9910144263603321