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Liquid Polymorphism : Advances in Chemical Physics . Volume 152
| Liquid Polymorphism : Advances in Chemical Physics . Volume 152 |
| Autore | Stanley H. E |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2013 |
| Descrizione fisica | 1 online resource (654 p.) |
| Disciplina |
541.2
541.3 |
| Collana | Advances in Chemical Physics, v. 152 |
| Soggetto topico |
Chemistry, Physical and theoretical
Electron Spectroscopy Polymorphism (Crystallography) Liquids Chemical & Materials Engineering Engineering & Applied Sciences Materials Science |
| ISBN |
1-118-54037-9
1-118-54035-2 1-299-44917-4 1-118-54036-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Liquid Polymorphism: Advances In Chemical Physics; CONTRIBUTORS TO VOLUME 152; FOREWORD; PREFACE; PREFACE TO THE SERIES; CONTENTS; Electron Spin Resonance Studies of Supercooled Water; I. Introduction; II. Outline of ESR Spectroscopy; A. Spin Probes; B. Rigid-Limit and Motional Narrowing of the Lineshape; C. Accessible Range of the Rotational Dynamics; III. ESR Spectroscopy of Spin Probes: Basic Theoretical Introduction; A. Spin Hamiltonian; B. Lineshape Analysis; 1. No Tumbling: Powder Lineshape; 2. Tumbling: Motional Narrowing of the ESR Lineshape
IV. ESR Studies of Liquid Water and Aqueous Solutions: A ReviewV. ESR Studies of Confined Water in Polycrystalline Ice; A. Water Confinement in Polycrystalline Ice; B. Location of Paramagnetic Solutes in Water-Ice Mixtures; C. Rotational Dynamics of TEMPOL in Interstitial Water of Polycrystalline Ice; 1. Spin Probe Mobility Above 130K; 2. Dynamical Heterogeneities; 3. Temperature Dependence of the Spin Probe Reorientation; 4. Breakdown of the Debye-Stokes-Einstein Law; 5. Spin Probe Sensing of the Water Static Heterogeneities; 6. Missing Evidence of Additional Impurities in Interstitial Water VI. SummaryReferences; Pressure-Driven Liquid-Liquid Transformations and Corresponding Bizarre Viscosity Behavior; I. Introduction; II. Methods; III. Results and Discussions; A. Se; B. AsS; C. As2S3; D. B2O3; IV. Conclusions; References; The Stability Limit and Other Open Questions on Water at Negative Pressure; I. Introduction; II. What is Negative Pressure?; III. The Phase Diagram of Water; IV. Experimental Methods to Generate Tension; A. Acoustic Cavitation; B. Metastable Vapor-Liquid Equilibrium; C. Berthelot Tube; D. Centrifuge Method; V. Limit(s) of Metastability A. Comparison Between the Different MethodsB. Origin of the Discrepancy in the Limits of Metastability; C. Remaining Issues with Inclusions; D. Path-Dependent Nucleation; VI. Other Topics in the Study of Liquids Under Tension; A. Equation of State of Water at Negative Pressure; B. Other Properties of Liquid at Negative Pressure; VII. Perspectives; References; Water-Like Anomalies of Core-Softened Fluids: Dependenceon the Trajectories in (PρT ) Space; I. Introduction; II. System and Methods; III. Results and Discussion; A. Diffusion Anomaly; B. Density Anomaly; C. Structural Anomaly IV. Rosenfeld ScalingV. Conclusions; References; High-Frequency Dynamics of Liquids Through a Liquid-Liquid Transition: The Case of CS; I. Introduction; II. The Case of Liquid Cesium; III. The Experiment; IV. Results; V. Discussion; VI. Conclusions; References; The Liquid-Liquid Phase Transition, Anomalous Properties, and Glass Behavior of Polymorphic Liquids; I. Introduction; II. Polymorphic Liquids: Phase Diagram, Anomalous Properties, and Glass Behavior; A. Liquid-Liquid Phase Transition; B. Supercritical Region: Anomalous Properties; C. Glass Polymorphism III. Computer Simulation Models of Polymorphic Liquids |
| Record Nr. | UNINA-9910139027103321 |
Stanley H. E
|
||
| Hoboken, : Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Liquid Polymorphism : Advances in Chemical Physics . Volume 152
| Liquid Polymorphism : Advances in Chemical Physics . Volume 152 |
| Autore | Stanley H. E |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2013 |
| Descrizione fisica | 1 online resource (654 p.) |
| Disciplina |
541.2
541.3 |
| Collana | Advances in Chemical Physics, v. 152 |
| Soggetto topico |
Chemistry, Physical and theoretical
Electron Spectroscopy Polymorphism (Crystallography) Liquids Chemical & Materials Engineering Engineering & Applied Sciences Materials Science |
| ISBN |
1-118-54037-9
1-118-54035-2 1-299-44917-4 1-118-54036-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Liquid Polymorphism: Advances In Chemical Physics; CONTRIBUTORS TO VOLUME 152; FOREWORD; PREFACE; PREFACE TO THE SERIES; CONTENTS; Electron Spin Resonance Studies of Supercooled Water; I. Introduction; II. Outline of ESR Spectroscopy; A. Spin Probes; B. Rigid-Limit and Motional Narrowing of the Lineshape; C. Accessible Range of the Rotational Dynamics; III. ESR Spectroscopy of Spin Probes: Basic Theoretical Introduction; A. Spin Hamiltonian; B. Lineshape Analysis; 1. No Tumbling: Powder Lineshape; 2. Tumbling: Motional Narrowing of the ESR Lineshape
IV. ESR Studies of Liquid Water and Aqueous Solutions: A ReviewV. ESR Studies of Confined Water in Polycrystalline Ice; A. Water Confinement in Polycrystalline Ice; B. Location of Paramagnetic Solutes in Water-Ice Mixtures; C. Rotational Dynamics of TEMPOL in Interstitial Water of Polycrystalline Ice; 1. Spin Probe Mobility Above 130K; 2. Dynamical Heterogeneities; 3. Temperature Dependence of the Spin Probe Reorientation; 4. Breakdown of the Debye-Stokes-Einstein Law; 5. Spin Probe Sensing of the Water Static Heterogeneities; 6. Missing Evidence of Additional Impurities in Interstitial Water VI. SummaryReferences; Pressure-Driven Liquid-Liquid Transformations and Corresponding Bizarre Viscosity Behavior; I. Introduction; II. Methods; III. Results and Discussions; A. Se; B. AsS; C. As2S3; D. B2O3; IV. Conclusions; References; The Stability Limit and Other Open Questions on Water at Negative Pressure; I. Introduction; II. What is Negative Pressure?; III. The Phase Diagram of Water; IV. Experimental Methods to Generate Tension; A. Acoustic Cavitation; B. Metastable Vapor-Liquid Equilibrium; C. Berthelot Tube; D. Centrifuge Method; V. Limit(s) of Metastability A. Comparison Between the Different MethodsB. Origin of the Discrepancy in the Limits of Metastability; C. Remaining Issues with Inclusions; D. Path-Dependent Nucleation; VI. Other Topics in the Study of Liquids Under Tension; A. Equation of State of Water at Negative Pressure; B. Other Properties of Liquid at Negative Pressure; VII. Perspectives; References; Water-Like Anomalies of Core-Softened Fluids: Dependenceon the Trajectories in (PρT ) Space; I. Introduction; II. System and Methods; III. Results and Discussion; A. Diffusion Anomaly; B. Density Anomaly; C. Structural Anomaly IV. Rosenfeld ScalingV. Conclusions; References; High-Frequency Dynamics of Liquids Through a Liquid-Liquid Transition: The Case of CS; I. Introduction; II. The Case of Liquid Cesium; III. The Experiment; IV. Results; V. Discussion; VI. Conclusions; References; The Liquid-Liquid Phase Transition, Anomalous Properties, and Glass Behavior of Polymorphic Liquids; I. Introduction; II. Polymorphic Liquids: Phase Diagram, Anomalous Properties, and Glass Behavior; A. Liquid-Liquid Phase Transition; B. Supercritical Region: Anomalous Properties; C. Glass Polymorphism III. Computer Simulation Models of Polymorphic Liquids |
| Record Nr. | UNINA-9910818054503321 |
|
Stanley H. E
|
||
| Hoboken, : Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
