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Multimetallic catalysts in organic synthesis [[electronic resource] /] / edited by Masakatsu Shibasaki and Yoshinori Yamamoto
| Multimetallic catalysts in organic synthesis [[electronic resource] /] / edited by Masakatsu Shibasaki and Yoshinori Yamamoto |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (313 p.) |
| Disciplina |
547.1395
547.2 |
| Altri autori (Persone) |
ShibasakiMasakatsu
YamamotoY (Yoshinori) |
| Soggetto topico |
Organic compounds - Synthesis
Metal catalysts |
| ISBN |
1-280-51967-3
9786610519675 3-527-60355-7 3-527-60432-4 |
| Classificazione |
35.52
35.17 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Multimetallic Catalysts in Organic Synthesis; Contents; Preface; List of Contributors; 1 Organic Synthesis with Bimetallic Systems; 1.1 Introduction; 1.2 Reactions Promoted by a Combination of Catalytic and Stoichiometric Amounts of Metals; 1.2.1 Transition Metal-Catalyzed Cross-Coupling Reactions; 1.2.2 The Wacker Reaction; 1.2.3 The Heck Reaction; 1.2.4 Reactions Involving π-Allylpalladium Intermediates; 1.2.4.1 Electrophilic Reactions; 1.2.4.2 Nucleophilic Reactions; 1.2.5 Nickel-Catalyzed Three-Component Coupling Reaction; 1.2.6 The Nozaki-Hiyama-Kishi Reaction
1.3 Reactions Promoted by a Combination of Catalytic Amounts of Two Metals1.3.1 Transition Metal Catalyzed Cross-Coupling Reactions; 1.3.1.1 The Stille Reaction; 1.3.1.2 The Hiyama Reaction; 1.3.1.3 The Sonogashira Reaction; 1.3.2 The Wacker Reaction; 1.3.3 Reactions Involving π-Allylpalladium Intermediates; 1.3.4 Transition Metal Catalyzed Cyclization Reactions; 1.3.4.1 [3+2] Cycloaddition Reactions; 1.3.4.2 Intramolecular [n+2] Cyclization Reactions; 1.3.4.3 Intermolecular [n+2+2] Cyclotrimerization Reactions; 1.3.4.4 [2+2+1] Cycloaddition Reactions; The Pauson-Khand Reaction 1.3.4.5 Cycloisomerization Reactions1.3.4.6 Indole-Forming Reaction; 1.3.4.7 Furan- and Pyrrole-Forming Reactions; 1.3.5 Reactions Involving Nucleophilic Addition of Carbonyl Compounds; 1.3.5.1 The Aldol Reaction; 1.3.5.2 Alkynylation Reactions; 1.3.5.3 Conjugate Addition Reactions; 1.3.6 Miscellaneous Reactions; 1.3.6.1 Transition Metal Catalyzed Reactions; 1.3.6.2 Lewis Acid Catalyzed Reactions; 1.3.6.3 Sequential Reactions; References; 2 Zinc Polymetallic Asymmetric Catalysis; 2.1 Introduction; 2.2 Asymmetric Alternating Copolymerization with Dimeric Zn Complexes 2.3 Direct Catalytic Asymmetric Aldol Reaction with Zn Polymetallic Catalysts2.3.1 Introduction; 2.3.2 Direct Catalytic Asymmetric Aldol Reaction with Methyl Ketones; 2.3.3 Direct Catalytic Asymmetric Aldol Reaction with α-Hydroxy Ketones; 2.4 Direct Catalytic Asymmetric Mannich-Type Reactions; 2.5 Direct Catalytic Asymmetric Michael Reaction; 2.6 Nitroaldol (Henry) Reaction; 2.7 Conclusions; References; 3 Group 13-Alkali Metal Heterobimetallic Asymmetric Catalysis; 3.1 Introduction; 3.2 Catalytic Asymmetric Michael Reaction of Stabilized Carbon Nucleophiles 3.2.1 Development of ALB - The First Example of a Group 13-Alkali Metal Heterobimetallic Asymmetric Catalyst3.2.2 Development of the Second-Generation Heterobimetallic Catalysts - Self-Assembly of Heterobimetallic Catalysts and Reactive Nucleophiles; 3.3 Catalytic Asymmetric Ring-Opening Reaction of meso-Epoxides; 3.3.1 Ring-Opening Reaction with Thiols; 3.3.2 Ring-Opening Reaction with Phenolic Oxygen - Development of a Novel Linked-BINOL Complex; 3.4 Catalytic Asymmetric Mannich Reactions; 3.4.1 Direct Catalytic Asymmetric Mannich-Type Reaction of Unmodified Ketones 3.4.2 Enantio- and Diastereoselective Catalytic Nitro-Mannich Reactions |
| Record Nr. | UNINA-9910831021903321 |
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Multimetallic catalysts in organic synthesis [[electronic resource] /] / edited by Masakatsu Shibasaki and Yoshinori Yamamoto
| Multimetallic catalysts in organic synthesis [[electronic resource] /] / edited by Masakatsu Shibasaki and Yoshinori Yamamoto |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (313 p.) |
| Disciplina |
547.1395
547.2 |
| Altri autori (Persone) |
ShibasakiMasakatsu
YamamotoY (Yoshinori) |
| Soggetto topico |
Organic compounds - Synthesis
Metal catalysts |
| ISBN |
1-280-51967-3
9786610519675 3-527-60355-7 3-527-60432-4 |
| Classificazione |
35.52
35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Multimetallic Catalysts in Organic Synthesis; Contents; Preface; List of Contributors; 1 Organic Synthesis with Bimetallic Systems; 1.1 Introduction; 1.2 Reactions Promoted by a Combination of Catalytic and Stoichiometric Amounts of Metals; 1.2.1 Transition Metal-Catalyzed Cross-Coupling Reactions; 1.2.2 The Wacker Reaction; 1.2.3 The Heck Reaction; 1.2.4 Reactions Involving π-Allylpalladium Intermediates; 1.2.4.1 Electrophilic Reactions; 1.2.4.2 Nucleophilic Reactions; 1.2.5 Nickel-Catalyzed Three-Component Coupling Reaction; 1.2.6 The Nozaki-Hiyama-Kishi Reaction
1.3 Reactions Promoted by a Combination of Catalytic Amounts of Two Metals1.3.1 Transition Metal Catalyzed Cross-Coupling Reactions; 1.3.1.1 The Stille Reaction; 1.3.1.2 The Hiyama Reaction; 1.3.1.3 The Sonogashira Reaction; 1.3.2 The Wacker Reaction; 1.3.3 Reactions Involving π-Allylpalladium Intermediates; 1.3.4 Transition Metal Catalyzed Cyclization Reactions; 1.3.4.1 [3+2] Cycloaddition Reactions; 1.3.4.2 Intramolecular [n+2] Cyclization Reactions; 1.3.4.3 Intermolecular [n+2+2] Cyclotrimerization Reactions; 1.3.4.4 [2+2+1] Cycloaddition Reactions; The Pauson-Khand Reaction 1.3.4.5 Cycloisomerization Reactions1.3.4.6 Indole-Forming Reaction; 1.3.4.7 Furan- and Pyrrole-Forming Reactions; 1.3.5 Reactions Involving Nucleophilic Addition of Carbonyl Compounds; 1.3.5.1 The Aldol Reaction; 1.3.5.2 Alkynylation Reactions; 1.3.5.3 Conjugate Addition Reactions; 1.3.6 Miscellaneous Reactions; 1.3.6.1 Transition Metal Catalyzed Reactions; 1.3.6.2 Lewis Acid Catalyzed Reactions; 1.3.6.3 Sequential Reactions; References; 2 Zinc Polymetallic Asymmetric Catalysis; 2.1 Introduction; 2.2 Asymmetric Alternating Copolymerization with Dimeric Zn Complexes 2.3 Direct Catalytic Asymmetric Aldol Reaction with Zn Polymetallic Catalysts2.3.1 Introduction; 2.3.2 Direct Catalytic Asymmetric Aldol Reaction with Methyl Ketones; 2.3.3 Direct Catalytic Asymmetric Aldol Reaction with α-Hydroxy Ketones; 2.4 Direct Catalytic Asymmetric Mannich-Type Reactions; 2.5 Direct Catalytic Asymmetric Michael Reaction; 2.6 Nitroaldol (Henry) Reaction; 2.7 Conclusions; References; 3 Group 13-Alkali Metal Heterobimetallic Asymmetric Catalysis; 3.1 Introduction; 3.2 Catalytic Asymmetric Michael Reaction of Stabilized Carbon Nucleophiles 3.2.1 Development of ALB - The First Example of a Group 13-Alkali Metal Heterobimetallic Asymmetric Catalyst3.2.2 Development of the Second-Generation Heterobimetallic Catalysts - Self-Assembly of Heterobimetallic Catalysts and Reactive Nucleophiles; 3.3 Catalytic Asymmetric Ring-Opening Reaction of meso-Epoxides; 3.3.1 Ring-Opening Reaction with Thiols; 3.3.2 Ring-Opening Reaction with Phenolic Oxygen - Development of a Novel Linked-BINOL Complex; 3.4 Catalytic Asymmetric Mannich Reactions; 3.4.1 Direct Catalytic Asymmetric Mannich-Type Reaction of Unmodified Ketones 3.4.2 Enantio- and Diastereoselective Catalytic Nitro-Mannich Reactions |
| Record Nr. | UNINA-9910841131503321 |
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
N-Heterocyclic carbenes in synthesis [[electronic resource] /] / edited by Steven P. Nolan
| N-Heterocyclic carbenes in synthesis [[electronic resource] /] / edited by Steven P. Nolan |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (322 p.) |
| Disciplina | 547.59 |
| Altri autori (Persone) | NolanSteven P |
| Soggetto topico |
Carbenes (Methylene compounds) - Synthesis
Heterocyclic compounds - Synthesis |
| ISBN |
1-280-72290-8
9786610722907 3-527-60945-8 3-527-60940-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
N-Heterocyclic Carbenes in Synthesis; Contents; Preface; List of Contributors; 1 N-Heterocyclic Carbene-Ruthenium Complexes in Olefin Metathesis; 1.1 Introduction; 1.2 N-Heterocyclic Carbene-Ruthenium Complexes; 1.2.1 Introduction of N-Heterocyclic Carbenes; 1.3 Second-generation NHC-Ru Catalysts; 1.3.1 Variations on the NHC Group; 1.3.2 Variation on the Benzylidene Group; 1.3.3 Phosphine-free NHC-Ruthenium Complexes; 1.3.4 Variation of the Anionic Ligands; 1.3.5 14-Electron NHC-Ruthenium Complexes; 1.4 Enantioselective Ruthenium Olefin Catalysts; 1.4.1 Grubbs II Analogues
1.4.2 Phosphine-free Chiral NHC-Ruthenium Complexes1.4.2.1 First-generation Catalysts; 1.4.2.2 Second-generation Chiral Ru Complexes; 1.5 Solid Supported NHC-Ru Complexes; 1.5.1 Immobilization via the NHC Ligand; 1.5.2 Attachment Through the Anionic Ligand; 1.5.3 Attachment Through the Alkylidene Moiety; 1.5.4 Homogenous Catalysts; 1.5.5 Ionic Liquids; 1.6 Conclusion and Outlook; References; 2 Ruthenium N-Heterocyclic Carbene Complexes in Organic Transformations (Excluding Metathesis); 2.1 Introduction; 2.2 Hydrogenation and Hydrosilylation Reactions; 2.3 Isomerization; 2.4 Other Reactivity 2.5 Tandem Reactions [29]2.5.1 Metathesis and Hydrogenation; 2.5.2 Metathesis and Isomerization; 2.5.3 Tandem Reactions not Involving Metathesis; 2.6 Conclusions; References; 3 Cross-coupling Reactions Catalyzed by Palladium N-Heterocyclic Carbene Complexes; 3.1 Introduction; 3.2 Palladium(0) NHC Complexes; 3.3 Palladium(ii) N-Heterocyclic Carbene Complexes; 3.4 Palladium/NHC Complexes as Catalysts; 3.4.1 C-N Bond-forming Reactions: the Hartwig-Buchwald Reaction; 3.4.2 C-C Bond-forming Reactions: α-Arylation of Ketones 3.4.3 Suzuki-Miyaura Cross-coupling of Aryl Chlorides with Arylboronic Acids3.4.4 C-H Bond-forming Reactions: Dehalogenation of Aryl Halides; 3.4.5 C-C Bond-forming Reactions: Hydroarylation of Alkynes; 3.5 Conclusion; References; 4 Pd-NHC Complexes as Catalysts in Telomerization and Aryl Amination Reactions; 4.1 Introduction; 4.2 Telomerization; 4.2.1 Definition and Background; 4.2.1.1 Commercial Viability of the Telomerization Reaction; 4.2.2 Catalyst Design: Ligand Selection; 4.2.3 Mechanism of the Pd-catalyzed Telomerization of Buta-1,3-diene with Methanol 4.2.4 Pd-(NHC) Complexes as Telomerization Catalysts4.2.5 Telomerization in Imidazolium-based Ionic Liquids; 4.3 Buchwald-Hartwig Amination Reactions Catalyzed by Pd(NHC) Complexes; 4.3.1 Introduction; 4.3.2 Mechanism of Aryl Amination; 4.3.3 Palladium-NHC Systems as Catalysts for Aryl Amination; 4.3.3.1 Application of Preformed Pd(0/ii)(NHC) Complexes; 4.3.3.2 In situ Pd Imidazolium Catalyst Systems; 4.4 Conclusions; References; 5 Metal-mediated and -catalyzed Oxidations Using N-Heterocyclic Carbene Ligands; 5.1 Introduction; 5.2 Metal-NHC-mediated Activation of Molecular Oxygen; 5.2.1 Co 5.2.2 Ni |
| Record Nr. | UNINA-9910144305903321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
N-Heterocyclic carbenes in synthesis [[electronic resource] /] / edited by Steven P. Nolan
| N-Heterocyclic carbenes in synthesis [[electronic resource] /] / edited by Steven P. Nolan |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (322 p.) |
| Disciplina | 547.59 |
| Altri autori (Persone) | NolanSteven P |
| Soggetto topico |
Carbenes (Methylene compounds) - Synthesis
Heterocyclic compounds - Synthesis |
| ISBN |
1-280-72290-8
9786610722907 3-527-60945-8 3-527-60940-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
N-Heterocyclic Carbenes in Synthesis; Contents; Preface; List of Contributors; 1 N-Heterocyclic Carbene-Ruthenium Complexes in Olefin Metathesis; 1.1 Introduction; 1.2 N-Heterocyclic Carbene-Ruthenium Complexes; 1.2.1 Introduction of N-Heterocyclic Carbenes; 1.3 Second-generation NHC-Ru Catalysts; 1.3.1 Variations on the NHC Group; 1.3.2 Variation on the Benzylidene Group; 1.3.3 Phosphine-free NHC-Ruthenium Complexes; 1.3.4 Variation of the Anionic Ligands; 1.3.5 14-Electron NHC-Ruthenium Complexes; 1.4 Enantioselective Ruthenium Olefin Catalysts; 1.4.1 Grubbs II Analogues
1.4.2 Phosphine-free Chiral NHC-Ruthenium Complexes1.4.2.1 First-generation Catalysts; 1.4.2.2 Second-generation Chiral Ru Complexes; 1.5 Solid Supported NHC-Ru Complexes; 1.5.1 Immobilization via the NHC Ligand; 1.5.2 Attachment Through the Anionic Ligand; 1.5.3 Attachment Through the Alkylidene Moiety; 1.5.4 Homogenous Catalysts; 1.5.5 Ionic Liquids; 1.6 Conclusion and Outlook; References; 2 Ruthenium N-Heterocyclic Carbene Complexes in Organic Transformations (Excluding Metathesis); 2.1 Introduction; 2.2 Hydrogenation and Hydrosilylation Reactions; 2.3 Isomerization; 2.4 Other Reactivity 2.5 Tandem Reactions [29]2.5.1 Metathesis and Hydrogenation; 2.5.2 Metathesis and Isomerization; 2.5.3 Tandem Reactions not Involving Metathesis; 2.6 Conclusions; References; 3 Cross-coupling Reactions Catalyzed by Palladium N-Heterocyclic Carbene Complexes; 3.1 Introduction; 3.2 Palladium(0) NHC Complexes; 3.3 Palladium(ii) N-Heterocyclic Carbene Complexes; 3.4 Palladium/NHC Complexes as Catalysts; 3.4.1 C-N Bond-forming Reactions: the Hartwig-Buchwald Reaction; 3.4.2 C-C Bond-forming Reactions: α-Arylation of Ketones 3.4.3 Suzuki-Miyaura Cross-coupling of Aryl Chlorides with Arylboronic Acids3.4.4 C-H Bond-forming Reactions: Dehalogenation of Aryl Halides; 3.4.5 C-C Bond-forming Reactions: Hydroarylation of Alkynes; 3.5 Conclusion; References; 4 Pd-NHC Complexes as Catalysts in Telomerization and Aryl Amination Reactions; 4.1 Introduction; 4.2 Telomerization; 4.2.1 Definition and Background; 4.2.1.1 Commercial Viability of the Telomerization Reaction; 4.2.2 Catalyst Design: Ligand Selection; 4.2.3 Mechanism of the Pd-catalyzed Telomerization of Buta-1,3-diene with Methanol 4.2.4 Pd-(NHC) Complexes as Telomerization Catalysts4.2.5 Telomerization in Imidazolium-based Ionic Liquids; 4.3 Buchwald-Hartwig Amination Reactions Catalyzed by Pd(NHC) Complexes; 4.3.1 Introduction; 4.3.2 Mechanism of Aryl Amination; 4.3.3 Palladium-NHC Systems as Catalysts for Aryl Amination; 4.3.3.1 Application of Preformed Pd(0/ii)(NHC) Complexes; 4.3.3.2 In situ Pd Imidazolium Catalyst Systems; 4.4 Conclusions; References; 5 Metal-mediated and -catalyzed Oxidations Using N-Heterocyclic Carbene Ligands; 5.1 Introduction; 5.2 Metal-NHC-mediated Activation of Molecular Oxygen; 5.2.1 Co 5.2.2 Ni |
| Record Nr. | UNINA-9910830830503321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
N-Heterocyclic carbenes in synthesis [[electronic resource] /] / edited by Steven P. Nolan
| N-Heterocyclic carbenes in synthesis [[electronic resource] /] / edited by Steven P. Nolan |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (322 p.) |
| Disciplina | 547.59 |
| Altri autori (Persone) | NolanSteven P |
| Soggetto topico |
Carbenes (Methylene compounds) - Synthesis
Heterocyclic compounds - Synthesis |
| ISBN |
1-280-72290-8
9786610722907 3-527-60945-8 3-527-60940-7 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
N-Heterocyclic Carbenes in Synthesis; Contents; Preface; List of Contributors; 1 N-Heterocyclic Carbene-Ruthenium Complexes in Olefin Metathesis; 1.1 Introduction; 1.2 N-Heterocyclic Carbene-Ruthenium Complexes; 1.2.1 Introduction of N-Heterocyclic Carbenes; 1.3 Second-generation NHC-Ru Catalysts; 1.3.1 Variations on the NHC Group; 1.3.2 Variation on the Benzylidene Group; 1.3.3 Phosphine-free NHC-Ruthenium Complexes; 1.3.4 Variation of the Anionic Ligands; 1.3.5 14-Electron NHC-Ruthenium Complexes; 1.4 Enantioselective Ruthenium Olefin Catalysts; 1.4.1 Grubbs II Analogues
1.4.2 Phosphine-free Chiral NHC-Ruthenium Complexes1.4.2.1 First-generation Catalysts; 1.4.2.2 Second-generation Chiral Ru Complexes; 1.5 Solid Supported NHC-Ru Complexes; 1.5.1 Immobilization via the NHC Ligand; 1.5.2 Attachment Through the Anionic Ligand; 1.5.3 Attachment Through the Alkylidene Moiety; 1.5.4 Homogenous Catalysts; 1.5.5 Ionic Liquids; 1.6 Conclusion and Outlook; References; 2 Ruthenium N-Heterocyclic Carbene Complexes in Organic Transformations (Excluding Metathesis); 2.1 Introduction; 2.2 Hydrogenation and Hydrosilylation Reactions; 2.3 Isomerization; 2.4 Other Reactivity 2.5 Tandem Reactions [29]2.5.1 Metathesis and Hydrogenation; 2.5.2 Metathesis and Isomerization; 2.5.3 Tandem Reactions not Involving Metathesis; 2.6 Conclusions; References; 3 Cross-coupling Reactions Catalyzed by Palladium N-Heterocyclic Carbene Complexes; 3.1 Introduction; 3.2 Palladium(0) NHC Complexes; 3.3 Palladium(ii) N-Heterocyclic Carbene Complexes; 3.4 Palladium/NHC Complexes as Catalysts; 3.4.1 C-N Bond-forming Reactions: the Hartwig-Buchwald Reaction; 3.4.2 C-C Bond-forming Reactions: α-Arylation of Ketones 3.4.3 Suzuki-Miyaura Cross-coupling of Aryl Chlorides with Arylboronic Acids3.4.4 C-H Bond-forming Reactions: Dehalogenation of Aryl Halides; 3.4.5 C-C Bond-forming Reactions: Hydroarylation of Alkynes; 3.5 Conclusion; References; 4 Pd-NHC Complexes as Catalysts in Telomerization and Aryl Amination Reactions; 4.1 Introduction; 4.2 Telomerization; 4.2.1 Definition and Background; 4.2.1.1 Commercial Viability of the Telomerization Reaction; 4.2.2 Catalyst Design: Ligand Selection; 4.2.3 Mechanism of the Pd-catalyzed Telomerization of Buta-1,3-diene with Methanol 4.2.4 Pd-(NHC) Complexes as Telomerization Catalysts4.2.5 Telomerization in Imidazolium-based Ionic Liquids; 4.3 Buchwald-Hartwig Amination Reactions Catalyzed by Pd(NHC) Complexes; 4.3.1 Introduction; 4.3.2 Mechanism of Aryl Amination; 4.3.3 Palladium-NHC Systems as Catalysts for Aryl Amination; 4.3.3.1 Application of Preformed Pd(0/ii)(NHC) Complexes; 4.3.3.2 In situ Pd Imidazolium Catalyst Systems; 4.4 Conclusions; References; 5 Metal-mediated and -catalyzed Oxidations Using N-Heterocyclic Carbene Ligands; 5.1 Introduction; 5.2 Metal-NHC-mediated Activation of Molecular Oxygen; 5.2.1 Co 5.2.2 Ni |
| Record Nr. | UNINA-9910841493003321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNINA-9910145417103321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNISA-996203979703316 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNINA-9910830256103321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNINA-9910841876403321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
