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Business and technology of the global polyethylene industry : an in-depth look at the history, technology, catalysts, and modern commercial manufacture of polyethylene and its products / / Thomas E. Nowlin
Business and technology of the global polyethylene industry : an in-depth look at the history, technology, catalysts, and modern commercial manufacture of polyethylene and its products / / Thomas E. Nowlin
Autore Nowlin Thomas E.
Pubbl/distr/stampa Hoboken, New Jersey ; ; Salem, Massachusetts : , : Wiley : , : Scrivener Publishing, , 2014
Descrizione fisica 1 online resource (428 p.)
Disciplina 668.4234
Soggetto topico Polyethylene
Soggetto genere / forma Electronic books.
ISBN 1-118-94603-0
1-118-94599-9
1-118-94600-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Title Page; Copyright Page; Contents; Preface; 1. Global Polyethylene Business Overview; 1.1 Introduction; 1.2 The Business of Polyethylene; 1.3 Cyclical Nature of the Polyethylene Business; 1.3.1 Global Feedstock Cost Variations; 1.3.2 Change in Middle East Feedstock Cost Advantage; 1.3.2.1. 2012 Capital Requirements for an Integrated Ethylene/Polyethylene Facility; 1.4 Early History of Ethylene and Polyethylene Manufacturing; 1.4.1 Discovery of Polyethylene; 1.4.1.1 Branched High-Pressure Polyethylene; 1.4.1.2 Linear Polyethylene
1.4.2 Linear Low-Pressure Polyethylene - High-Density Polyethylene1.4.3 Manufacture of HDPE (1955-1975); 1.4.3.1 Phillips Catalyst Produced HDPE with Higher Product Demand; 1.4.3.2 Phillips Catalyst Manufacturing Advantages; 1.4.3.3 Second Generation Ziegler Catalysts; 1.4.4 Single-Site Ethylene Polymerization Catalysts; 1.4.5 Status of the Polyethylene Industry as of 2010; 1.4.6 Global Demand for Polyethylene in 2010; 1.4.7 Polyethylene Product Lifecycle; 1.4.7.1 North American Polyethylene Market; 1.4.8 Comparison of Other Global Polyethylene Markets with the North American Market
1.4.9 Growth of the Global Consumer Class1.4.9.1 Quantitative Forecast for the Growth of the Global Middle Class; 1.4.10 Global Economic Freedom; 1.4.11 Future Economic Growth in India and China; 1.4.12 Long-Term Global Polyethylene Capacity Expansion (2010-2050); 1.4.12.1 Location of New Ethylene/Polyethylene Capacity (2010-2050); 1.4.13 Ethylene Feedstock Costs; 1.4.13.1 Manufacture of Ethylene; 1.4.13.2 Crude Oil and Natural Gas Prices; 1.4.14 Impact of the Shale Natural Gas Revolution on Global Polyethylene Business; 1.4.15 Natural Gas Liquids; 1.4.15.1 North American Natural Gas Supply
1.4.15.2 Globalization of Natural Gas1.4.15.3 Status of Ethylene Costs as of 2010 and Future Trends; 1.4.15.4 Additional Feedstock for Ethylene Production; 1.4.15.5 U.S. Ethylene Forecast by Burns & McDonnell (2013); 1.4.15.6 Ethylene Based on New Feedstock; 1.4.15.7 Methane/Methanol as Feedstock for Ethylene; 1.4.15.8 Biomass as Feedstock; 1.4.15.9 Governmental Policy and Regulation; 1.4.16 Environmental Factors; 1.4.16.1 Polyethylene Recycling - Waste-to-Energy; 1.4.16.2 Biodegradation; 1.4.17 Biobased Ethylene; References
2. Titanium-Based Ziegler Catalysts for the Production of Polyethylene2.1 Introduction; 2.2 Titanium-Based Catalyst Developments; 2.2.1 Historical Developments; 2.2.2 The Role of Professor G. Natta; 2.2.3 Historical Controversy - Isotactic Polypropylene with Cr-Based Catalyst; 2.3 Titanium-Based Catalysts for the Manufacture of Polyethylene; 2.3.1 First Generation Ziegler Catalysts for the Manufacture of Polyethylene; 2.3.2 Types of Metal Alkyls Investigated; 2.3.3 Soluble Titanium-Based Complexes for Ethylene Polymerization (1955-1960); 2.3.4 Mechanism of Polymerization
2.4 Second Generation Ziegler Catalyst for the Manufacture of Polyethylene
Record Nr. UNINA-9910132166503321
Nowlin Thomas E.  
Hoboken, New Jersey ; ; Salem, Massachusetts : , : Wiley : , : Scrivener Publishing, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Business and technology of the global polyethylene industry : an in-depth look at the history, technology, catalysts, and modern commercial manufacture of polyethylene and its products / / Thomas E. Nowlin
Business and technology of the global polyethylene industry : an in-depth look at the history, technology, catalysts, and modern commercial manufacture of polyethylene and its products / / Thomas E. Nowlin
Autore Nowlin Thomas E.
Pubbl/distr/stampa Hoboken, New Jersey ; ; Salem, Massachusetts : , : Wiley : , : Scrivener Publishing, , 2014
Descrizione fisica 1 online resource (428 p.)
Disciplina 668.4234
Soggetto topico Polyethylene
ISBN 1-118-94603-0
1-118-94599-9
1-118-94600-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Title Page; Copyright Page; Contents; Preface; 1. Global Polyethylene Business Overview; 1.1 Introduction; 1.2 The Business of Polyethylene; 1.3 Cyclical Nature of the Polyethylene Business; 1.3.1 Global Feedstock Cost Variations; 1.3.2 Change in Middle East Feedstock Cost Advantage; 1.3.2.1. 2012 Capital Requirements for an Integrated Ethylene/Polyethylene Facility; 1.4 Early History of Ethylene and Polyethylene Manufacturing; 1.4.1 Discovery of Polyethylene; 1.4.1.1 Branched High-Pressure Polyethylene; 1.4.1.2 Linear Polyethylene
1.4.2 Linear Low-Pressure Polyethylene - High-Density Polyethylene1.4.3 Manufacture of HDPE (1955-1975); 1.4.3.1 Phillips Catalyst Produced HDPE with Higher Product Demand; 1.4.3.2 Phillips Catalyst Manufacturing Advantages; 1.4.3.3 Second Generation Ziegler Catalysts; 1.4.4 Single-Site Ethylene Polymerization Catalysts; 1.4.5 Status of the Polyethylene Industry as of 2010; 1.4.6 Global Demand for Polyethylene in 2010; 1.4.7 Polyethylene Product Lifecycle; 1.4.7.1 North American Polyethylene Market; 1.4.8 Comparison of Other Global Polyethylene Markets with the North American Market
1.4.9 Growth of the Global Consumer Class1.4.9.1 Quantitative Forecast for the Growth of the Global Middle Class; 1.4.10 Global Economic Freedom; 1.4.11 Future Economic Growth in India and China; 1.4.12 Long-Term Global Polyethylene Capacity Expansion (2010-2050); 1.4.12.1 Location of New Ethylene/Polyethylene Capacity (2010-2050); 1.4.13 Ethylene Feedstock Costs; 1.4.13.1 Manufacture of Ethylene; 1.4.13.2 Crude Oil and Natural Gas Prices; 1.4.14 Impact of the Shale Natural Gas Revolution on Global Polyethylene Business; 1.4.15 Natural Gas Liquids; 1.4.15.1 North American Natural Gas Supply
1.4.15.2 Globalization of Natural Gas1.4.15.3 Status of Ethylene Costs as of 2010 and Future Trends; 1.4.15.4 Additional Feedstock for Ethylene Production; 1.4.15.5 U.S. Ethylene Forecast by Burns & McDonnell (2013); 1.4.15.6 Ethylene Based on New Feedstock; 1.4.15.7 Methane/Methanol as Feedstock for Ethylene; 1.4.15.8 Biomass as Feedstock; 1.4.15.9 Governmental Policy and Regulation; 1.4.16 Environmental Factors; 1.4.16.1 Polyethylene Recycling - Waste-to-Energy; 1.4.16.2 Biodegradation; 1.4.17 Biobased Ethylene; References
2. Titanium-Based Ziegler Catalysts for the Production of Polyethylene2.1 Introduction; 2.2 Titanium-Based Catalyst Developments; 2.2.1 Historical Developments; 2.2.2 The Role of Professor G. Natta; 2.2.3 Historical Controversy - Isotactic Polypropylene with Cr-Based Catalyst; 2.3 Titanium-Based Catalysts for the Manufacture of Polyethylene; 2.3.1 First Generation Ziegler Catalysts for the Manufacture of Polyethylene; 2.3.2 Types of Metal Alkyls Investigated; 2.3.3 Soluble Titanium-Based Complexes for Ethylene Polymerization (1955-1960); 2.3.4 Mechanism of Polymerization
2.4 Second Generation Ziegler Catalyst for the Manufacture of Polyethylene
Record Nr. UNINA-9910830994303321
Nowlin Thomas E.  
Hoboken, New Jersey ; ; Salem, Massachusetts : , : Wiley : , : Scrivener Publishing, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Crosslinkable polyethylene : manufacture, properties, recycling, and applications / / Jince Thomas, Sabu Thomas, Zakiah Ahmad, editors
Crosslinkable polyethylene : manufacture, properties, recycling, and applications / / Jince Thomas, Sabu Thomas, Zakiah Ahmad, editors
Edizione [1st ed. 2021.]
Pubbl/distr/stampa Singapore : , : Springer, , [2021]
Descrizione fisica 1 online resource (X, 412 p. 228 illus., 116 illus. in color.)
Disciplina 668.4234
Collana Materials horizons
Soggetto topico Polyethylene
ISBN 981-16-0514-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Chapter 1: Cross linked Polyethylene- State of Art and New Challenges -- Chapter 2: Historical and Theoretical aspects of Cross linked Polyethylene (XLPE) -- Chapter 3: Manufacturing process and their significance -- Chapter 4: General awareness to XLPE manufactures -- Chapter 5: Physio- Chemical properties of XLPE -- Chapter 6: Morphology, Structure, property applications of XLPE -- Chapter 7: XLPE: Crosslinking techniques and recycling process -- Chapter 8: Ageing and Degradation Studies in XLPE -- Chapter 9: Flame retardant aspects of XLPE -- Chpater 10: Structural design and performance of XLPE cable for insulation -- Chapter 11: Failure mechanisms in XLPE cables -- Chapter 12: Innovative characterization techniques in Cross linked Polyethylene (XLPE) -- Chapter 13: Industrial and commercial importance of XLPE -- Chapter 14: Scope and future aspects of XLPE.
Record Nr. UNINA-9910484651603321
Singapore : , : Springer, , [2021]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of engineering and specialty thermoplastics . Volume 1 Polyolefins and styrenics / / Johannes Karl Fink
Handbook of engineering and specialty thermoplastics . Volume 1 Polyolefins and styrenics / / Johannes Karl Fink
Autore Fink Johannes Karl
Edizione [1st ed.]
Pubbl/distr/stampa Hoboken : , : Wiley, , [2010]
Descrizione fisica 1 online resource (401 p.)
Disciplina 668.423
668.4234
Collana Wiley-Scrivener
Soggetto topico Polyolefins
Polystyrene
Thermoplastics
ISBN 1-118-02928-3
1-282-65407-1
9786612654077
1-61344-194-0
0-470-88171-2
0-470-88185-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Engineering and Speciality Thermoplastics; Preface; Contents; 1 Metathesis Polymers; 2 Cyclic Olefin Copolymers; 3 Ultra High Molecular Weight Poly(ethylene); 4 Poly(methyl)pentene; 5 Ionomers; 6 Poly(isobutylene); 7 Ethylene Vinyl Acetate Copolymers; 8 Acrylonitrile-Butadiene-Styrene Polymers; 9 High Impact Poly(styrene); 10 Styrene/Acrylonitrile Polymers; 11 Methyl methacrylate/Butadiene/Styrene Polymers; 12 Acrylonitrile/Styrene/Acrylate Polymers; Index
Record Nr. UNINA-9910140558503321
Fink Johannes Karl  
Hoboken : , : Wiley, , [2010]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of engineering and specialty thermoplastics . Volume 1 Polyolefins and styrenics / / Johannes Karl Fink
Handbook of engineering and specialty thermoplastics . Volume 1 Polyolefins and styrenics / / Johannes Karl Fink
Autore Fink Johannes Karl
Edizione [1st ed.]
Pubbl/distr/stampa Hoboken : , : Wiley, , [2010]
Descrizione fisica 1 online resource (401 p.)
Disciplina 668.423
668.4234
Collana Wiley-Scrivener
Soggetto topico Polyolefins
Polystyrene
Thermoplastics
ISBN 1-118-02928-3
1-282-65407-1
9786612654077
1-61344-194-0
0-470-88171-2
0-470-88185-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Engineering and Speciality Thermoplastics; Preface; Contents; 1 Metathesis Polymers; 2 Cyclic Olefin Copolymers; 3 Ultra High Molecular Weight Poly(ethylene); 4 Poly(methyl)pentene; 5 Ionomers; 6 Poly(isobutylene); 7 Ethylene Vinyl Acetate Copolymers; 8 Acrylonitrile-Butadiene-Styrene Polymers; 9 High Impact Poly(styrene); 10 Styrene/Acrylonitrile Polymers; 11 Methyl methacrylate/Butadiene/Styrene Polymers; 12 Acrylonitrile/Styrene/Acrylate Polymers; Index
Record Nr. UNINA-9910827524503321
Fink Johannes Karl  
Hoboken : , : Wiley, , [2010]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of engineering and specialty thermoplastics . Vol. 3 Polyethers and polyesters [[electronic resource] /] / Sabu Thomas and Visakh P.M
Handbook of engineering and specialty thermoplastics . Vol. 3 Polyethers and polyesters [[electronic resource] /] / Sabu Thomas and Visakh P.M
Autore Thomas Sabu
Pubbl/distr/stampa Hoboken N.J., : Wiley, 2011
Descrizione fisica 1 online resource (564 p.)
Disciplina 668.423
668.4234
Altri autori (Persone) P. MVisakh
Collana Wiley-Scrivener
Soggetto topico Polyethers
Polyesters
ISBN 1-283-17700-5
9786613177001
1-118-10472-2
1-118-10473-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Engineering and Specialty Thermoplastics: Polyethers and Polyesters; Contents; List of Contributors; 1. Engineering and Specialty Thermoplastics: Polyethers and Polyesters; 1.1 Introduction; 1.2 Polyesters Synthesis; 1.3 Polyethers; 1.3.1 Aromatic Polyethers; 1.4 Individual Polyethers and Polyesters and Their Application; 1.4.1 Poly (Phenylene Oxide); 1.4.2 Polyether Ether Ketone; 1.4.3 Poly(Ethylene Terephthalate); 1.4.4 Poly(Butylene Terephthalate); 1.4.5 Polyesters Containing Cyclohexanedimethanol Units; 1.4.6. Liquid Crystal Polyesters; 1.4.7 Polylactide
1.4.8 Thermoplastic Copolyester Elastomers (TPEEs)1.4.9 Polycarbonate (PC); 1.5 New Challenges and Opportunities; References; 2. Poly(phenylene oxide); 2.1 Introduction and History; 2.2 Monomer; 2.3 Polymerization and Mechanism; 2.4 Properties; 2.5 Compounding and Special Additives; 2.6 Processing; 2.7 Applications; 2.8 Environmental Impact and Recycling; 2.9 Recent Developments in Poly Phenylene Oxide Based Blends and Composites and Their Applications; References; 3. Polyether Ether Ketone; 3.1 Introduction and History; 3.2 Polymerization and Fabrication; 3.3 Properties
3.3.1 Solution Properties3.3.2 Thermal Properties; 3.3.2.1 Melting and Crystallization; 3.3.2.2 Crystallization Kinetics; 3.3.2.3 Spherulites; 3.3.2.4 Decomposition; 3.3.3 Mechanical Properties; 3.3.3.1 Tensile Properties; 3.3.3.2 Fracture Toughness; 3.3.3.3 Tensile Creep; 3.3.3.4 Compressive Properties; 3.3.3.5 Taylor Impact; 3.3.3.6 Tribological Behavior; 3.4 Chemical Properties; 3.5 Environmental Resistance; 3.6 Compounding and Special Additives; 3.7 Processing; 3.8 Applications; 3.9 Environmental Impact and Recycling
3.10 Recent Developments in PEEK Based Blends and Composites and Their ApplicationsReferences; 4. Poly(ethylene terephthalate); 4.1 Introduction and History; 4.2 Polymerization and Fabrication; 4.2.1 First Step: Prepolymerization; 4.2.2 Second Step: Polycondensation; 4.2.3 Solid-State Polymerization; 4.3 Solid-State Properties; 4.3.1 Mechanical Properties; 4.3.2 Thermal Properties; 4.3.3 Gas Barrier Properties; 4.3.4 Other Physical Properties; 4.4 Chemical Stability; 4.4.1 Solubility and Chemical Resistance of PET; 4.4.2 Hydrolytic Degradation of PET; 4.4.2 Thermal Degradation of PET
4.4.3 Thermo-oxidative Degradation of PET4.5 Compounding and Special Additives; 4.6 Processing; 4.6.1 Extrusion; 4.6.2 Injection Molding; 4.6.3 Blow Molding; 4.7 Applications; 4.7.1 PET Fibers; 4.7.2 PET Films; 4.7.3 PET Bottles; 4.8 Environmental Impact and Recycling; 4.8.1 Generality about PET Recycling; 4.8.2 Chemical Recycling of PET; 4.8.2.1 Methanolysis; 4.8.2.2 Glycolysis; 4.8.2.3 Hydrolysis; 4.8.2.4 Others methods; 4.8.3 Mechanical Recycling; 4.8.4 Recent Developments in PET Recycling
4.9 Recent Developments in Poly(ethylene terephthalate) Based Blends and Composites and Their Applications
Record Nr. UNINA-9910139642603321
Thomas Sabu  
Hoboken N.J., : Wiley, 2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of engineering and specialty thermoplastics . Vol. 3 Polyethers and polyesters [[electronic resource] /] / Sabu Thomas and Visakh P.M
Handbook of engineering and specialty thermoplastics . Vol. 3 Polyethers and polyesters [[electronic resource] /] / Sabu Thomas and Visakh P.M
Autore Thomas Sabu
Pubbl/distr/stampa Hoboken N.J., : Wiley, 2011
Descrizione fisica 1 online resource (564 p.)
Disciplina 668.423
668.4234
Altri autori (Persone) P. MVisakh
Collana Wiley-Scrivener
Soggetto topico Polyethers
Polyesters
ISBN 1-283-17700-5
9786613177001
1-118-10472-2
1-118-10473-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Engineering and Specialty Thermoplastics: Polyethers and Polyesters; Contents; List of Contributors; 1. Engineering and Specialty Thermoplastics: Polyethers and Polyesters; 1.1 Introduction; 1.2 Polyesters Synthesis; 1.3 Polyethers; 1.3.1 Aromatic Polyethers; 1.4 Individual Polyethers and Polyesters and Their Application; 1.4.1 Poly (Phenylene Oxide); 1.4.2 Polyether Ether Ketone; 1.4.3 Poly(Ethylene Terephthalate); 1.4.4 Poly(Butylene Terephthalate); 1.4.5 Polyesters Containing Cyclohexanedimethanol Units; 1.4.6. Liquid Crystal Polyesters; 1.4.7 Polylactide
1.4.8 Thermoplastic Copolyester Elastomers (TPEEs)1.4.9 Polycarbonate (PC); 1.5 New Challenges and Opportunities; References; 2. Poly(phenylene oxide); 2.1 Introduction and History; 2.2 Monomer; 2.3 Polymerization and Mechanism; 2.4 Properties; 2.5 Compounding and Special Additives; 2.6 Processing; 2.7 Applications; 2.8 Environmental Impact and Recycling; 2.9 Recent Developments in Poly Phenylene Oxide Based Blends and Composites and Their Applications; References; 3. Polyether Ether Ketone; 3.1 Introduction and History; 3.2 Polymerization and Fabrication; 3.3 Properties
3.3.1 Solution Properties3.3.2 Thermal Properties; 3.3.2.1 Melting and Crystallization; 3.3.2.2 Crystallization Kinetics; 3.3.2.3 Spherulites; 3.3.2.4 Decomposition; 3.3.3 Mechanical Properties; 3.3.3.1 Tensile Properties; 3.3.3.2 Fracture Toughness; 3.3.3.3 Tensile Creep; 3.3.3.4 Compressive Properties; 3.3.3.5 Taylor Impact; 3.3.3.6 Tribological Behavior; 3.4 Chemical Properties; 3.5 Environmental Resistance; 3.6 Compounding and Special Additives; 3.7 Processing; 3.8 Applications; 3.9 Environmental Impact and Recycling
3.10 Recent Developments in PEEK Based Blends and Composites and Their ApplicationsReferences; 4. Poly(ethylene terephthalate); 4.1 Introduction and History; 4.2 Polymerization and Fabrication; 4.2.1 First Step: Prepolymerization; 4.2.2 Second Step: Polycondensation; 4.2.3 Solid-State Polymerization; 4.3 Solid-State Properties; 4.3.1 Mechanical Properties; 4.3.2 Thermal Properties; 4.3.3 Gas Barrier Properties; 4.3.4 Other Physical Properties; 4.4 Chemical Stability; 4.4.1 Solubility and Chemical Resistance of PET; 4.4.2 Hydrolytic Degradation of PET; 4.4.2 Thermal Degradation of PET
4.4.3 Thermo-oxidative Degradation of PET4.5 Compounding and Special Additives; 4.6 Processing; 4.6.1 Extrusion; 4.6.2 Injection Molding; 4.6.3 Blow Molding; 4.7 Applications; 4.7.1 PET Fibers; 4.7.2 PET Films; 4.7.3 PET Bottles; 4.8 Environmental Impact and Recycling; 4.8.1 Generality about PET Recycling; 4.8.2 Chemical Recycling of PET; 4.8.2.1 Methanolysis; 4.8.2.2 Glycolysis; 4.8.2.3 Hydrolysis; 4.8.2.4 Others methods; 4.8.3 Mechanical Recycling; 4.8.4 Recent Developments in PET Recycling
4.9 Recent Developments in Poly(ethylene terephthalate) Based Blends and Composites and Their Applications
Record Nr. UNINA-9910822808403321
Thomas Sabu  
Hoboken N.J., : Wiley, 2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Integrated Process Modeling, Advanced Control and Data Analytics for Optimizing Polyolefin Manufacturing / / Y. A. Liu and Niket Sharma
Integrated Process Modeling, Advanced Control and Data Analytics for Optimizing Polyolefin Manufacturing / / Y. A. Liu and Niket Sharma
Autore Liu Y. A.
Edizione [First edition.]
Pubbl/distr/stampa Weinheim, Germany : , : WILEY-VCH GmbH, , [2023]
Descrizione fisica 1 online resource (865 pages)
Disciplina 668.4234
Soggetto topico Polyolefins
ISBN 3-527-84383-3
3-527-84381-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Volume 1 -- Title Page -- Copyright -- Contents -- Foreword -- Preface -- Acknowledgment -- Copyright Notice -- About the Authors -- About the Companion Website -- Chapter 1 Introduction to Integrated Process Modeling, Advanced Control, and Data Analytics in Optimizing Polyolefin Manufacturing -- 1.1 Segment‐Based Modeling of Polymerization Processes: Component Characterization and Polymer Attributes -- 1.1.1 Component Types in Polymer Process Modeling -- 1.1.2 Concept of Moments and Some Basic Polymer Attributes -- 1.1.3 Stream Initialization and Basic Polymer Attributes -- 1.2 Workshop 1.1: Finding the Resulting Stream Attributes After Mixing Two Copolymer Streams -- 1.2.1 Objective -- 1.2.2 Problem Statement -- 1.2.3 Process Flowsheet -- 1.2.4 Unit System, Components, and Characterization of Copolymers -- 1.2.5 Property Method and Property Parameters for Components -- 1.2.6 Specifications of Streams and Blocks -- 1.3 Workshop 1.2: A Simplified Simulation Model for a Slurry HDPE Process and the Workflow for Developing a Polymer Process Simulation Model -- 1.3.1 Objective -- 1.3.2 Step 1: Problem Setup -- 1.3.3 Step 2: Component Specifications -- 1.3.4 Step 3: Property Method -- 1.3.5 Step 4: Property Parameters - Obtaining Values from Databanks and Estimating Missing Parameters -- 1.3.6 Step 5: Verification of the Accuracy of the Selected Property Method by Comparing Predicted Pure‐Component Property Values with Report Experimental Data -- 1.3.7 Step 6: Regress Component Liquid Density Data and Binary Vapor-Liquid Equilibrium (TPXY) Data to Estimate Missing Pure‐component and Binary Interaction Parameters of Selected Property Method and Verify Predicted VLE Results with Experimental Data -- 1.3.8 Step 7: Develop Correlations for Polymer Product Quality Indices, Such as Density and Melt Index (Melt Flow Rate) Based on Plant Data.
1.3.9 Step 8: Define the Polymerization Reactions and Enter the Initial Reaction Rate Constants -- 1.3.10 Step 9: Draw the Open‐Loop Process Flowsheet and Enter the Inputs for Streams and Blocks -- 1.3.11 Step 10: Run the Initial Open‐loop Process Simulation and Check if the Simulation Results Are Reasonable -- 1.3.12 Step 11: Close the Recycled Loops, Finalize a Converged Closed‐loop Steady‐state Simulation Model, and Investigate Applications to Improving Process Operations and Identifying Operating Conditions for New Product Design -- 1.3.13 Step 12: Convert the Steady‐state Simulation Model in Aspen Plus to a Dynamic Simulation Model in Aspen Plus Dynamics -- Add Appropriate Controllers -- and Investigate Process Operability, Control, and Grade Changes -- 1.4 Industrial and Potential Applications of Integrated Process Modeling, Advanced Control, and Data Analytics to Optimizing Polyolefin Manufacturing -- 1.4.1 Industrial and Potential Applications of Process Modeling to Optimizing Polyolefin Manufacturing -- 1.4.2 Industrial and Potential Applications of Advanced Process Control to Optimizing Polyolefin Manufacturing -- 1.4.3 Industrial and Potential Applications of Data Analytics to Optimizing Polyolefin Manufacturing -- 1.4.4 Hybrid Modeling: Integrated Applications of Process Modeling, Advanced Control, and Data Analytics to Optimizing Polyolefin Manufacturing -- References -- Chapter 2 Selection of Property Methods and Estimation of Physical Properties for Polymer Process Modeling -- 2.1 Property Methods and Thermophysical Parameter Requirements for Process Simulation -- 2.2 Polymer Activity Coefficient Models (ACM): Polymer Nonrandom Two‐liquid (POLYNRTL) Model -- 2.2.1 Vapor-Liquid Equilibrium for an Ideal Vapor Phase and a Nonideal Liquid Phase.
2.2.2 General Vapor-Liquid Equilibrium Relationships Based on Fugacity Coefficient and Liquid‐phase Activity Coefficient -- 2.2.3 Segment‐based Mole Fraction Versus Species‐based Mole Fraction -- 2.2.4 POLYNRTL: Polymer Nonrandom Two‐liquid Activity Coefficient Model -- 2.2.5 Concept of Henry Components for Vapor-Liquid Equilibrium for a Vapor Phase and a Nonideal Liquid Phase Involving Supercritical Components -- 2.3 Workshop 2.1. Estimating POLYNRTL Binary Parameters Using UNIFAC -- 2.3.1 Objective -- 2.3.2 Estimating POLYNRTL Binary Parameters Using UNIFAC for Polystyrene Manufacturing -- 2.4 Prediction of Polymer Physical Properties by Van Krevelen Functional Group Method -- 2.5 Workshop 2.2. Estimating the Physical Properties of a Copolymer Using the Van Krevelen Group Contribution Method -- 2.5.1 Objective -- 2.5.2 Draw the Process Flowsheet and Specify the Unit Set and Global Options -- 2.5.3 Define Components, Segments, and Polymer and Characterize Their Structures -- 2.5.4 Choosing Property Method and Entering or Estimating Property Parameters -- 2.5.5 Specifications of Feed Stream and Flash Block -- 2.5.6 Creating Property Sets -- 2.5.7 Defining Property Analysis Run to Create Property Tables -- 2.6 Polymer Sanchez-Lacombe Equation of State (POLYSL) -- 2.7 Workshop 2.3. Estimating Property Parameters Using Data Regression Tool -- 2.7.1 Objective -- 2.7.2 Defining a DRS Run -- 2.7.3 Specifying a Unit Set and Global Options -- 2.7.4 Defining Components, Segments, Oligomers, and Polymer -- 2.7.5 Choose Property Method and Enter Known Property Parameters from Aspen Enterprise Databanks -- 2.7.6 Enter Experimental Data for Data Regression, Run the Regression, and Examine the Results -- 2.7.7 Specifying a Regression Run and the Parameters to be Regressed -- 2.7.8 Running the Regression Case and Examining the Results.
2.8 Polymer Perturbed‐chain Statistical Fluid Theory (POLYPCSF) Equation of State -- 2.9 Workshop 2.4. Regression of Property Parameters for POLYPCSF EOS -- 2.9.1 Objective and Data Sources -- 2.9.2 Regression of Pure Component Parameters for POLYPCSF EOS -- 2.10 Correlation of Polymer Product Quality Indices and Structure-Property Correlations -- 2.10.1 Polyolefin Product Quality Indices -- 2.10.2 Empirical Correlations of Polymer Product Quality Targets -- 2.10.3 Estimation of Apparent Newtonian Viscosity from MI‐MWW Measurement -- References -- Chapter 3 Reactor Modeling, Convergence Tips, and Data‐Fit Tool -- 3.1 Kinetic or Rate‐Based Reactors -- 3.2 Continuous Stirred‐Tank Reactor Model (RCSTR) -- 3.2.1 RCSTR Configurations -- 3.2.2 RCSTR Specifications -- 3.3 Plug‐Flow Reactor Model (RPLUG) -- 3.3.1 RPLUG Configurations -- 3.3.2 RPLUG Specifications -- 3.4 Batch Reactor Model (RBATCH) -- 3.4.1 RBATCH Configuration -- 3.4.2 RBATCH Specifications -- 3.5 Representation of Nonideal Reactors -- 3.6 RCSTR Convergence -- 3.6.1 Initialization -- 3.6.2 Scaling Factors -- 3.6.3 Residence Time Loop -- 3.6.4 Energy Balance Loop -- 3.6.5 Mass Balance Loop -- 3.6.6 Flash Loop -- 3.6.7 Recommendation for RCSTR Mass Balance Algorithm for Polyolefin Process Simulation -- 3.7 RPLUG/RBATCH Model Convergence -- 3.8 Data Fit (Simulation Data Regression) -- 3.9 Workshop 3.1: Data Fit of Kinetic Parameters for Styrene Polymerization Using Concentration Profile Data -- 3.9.1 Objective -- 3.9.2 A Simplified Kinetic Model for Styrene Polymerization -- 3.9.3 Datasets -- 3.9.4 Simulation Data Regression (Data Fit) -- 3.10 Workshop 3.2: Data Fit of Kinetic Parameters for Styrene Polymerization Using Point Data -- 3.10.1 Objective -- 3.10.2 Dataset -- 3.10.3 Simulation Data Regression (Data Fit) -- References -- Chapter 4 Free Radical Polymerizations: LDPE and EVA.
4.1 Polymers by Free Radical Polymerization -- 4.2 Kinetics of Free Radical Polymerization -- 4.2.1 Initiator and Its Decomposition‐Rate Parameters -- 4.2.2 Chain Initiation Reactions -- 4.2.3 Chain Propagation Reactions -- 4.2.4 Chain Transfer Reactions -- 4.2.5 Termination Reactions -- 4.2.6 Autoacceleration, Trommsdorff Effect, or Gel Effect -- 4.2.7 Other Free Radical Polymerization Reactions -- 4.3 Thermodynamic Methods and Property Parameter Requirements -- 4.4 Workshop 4.1: Simulation of an Autoclave High‐pressure LDPE Process -- 4.4.1 Objectives -- 4.4.2 Process Flowsheet and Simulation Representation -- 4.4.3 Unit System, Components, and Characterization of Polymer -- 4.4.4 Thermodynamic Methods and Property Parameters for Components, Segment, and Polymer -- 4.4.5 PCES (Physical Constant Estimation System) for Estimating Missing‐Property Parameters -- 4.4.6 Defining Free Radical Polymerization Reactions for LDPE -- 4.4.7 Specifications of Inlet Process Streams and Unit Operation and Reactor Blocks -- 4.4.8 Methodology for Improving Simulation Convergence and for Kinetic Parameter Estimation -- 4.4.9 Base‐Case Simulation Results -- 4.4.10 Model Applications -- 4.4.11 Separation Section -- 4.5 Workshop 4.2: Simulation of Tubular Reactors for HP LDPE Process -- 4.5.1 Objectives -- 4.5.2 Process Flowsheet and Simulation Representation -- 4.5.3 Unit System, Components, and Characterization of Polymer -- 4.5.4 Thermodynamic Method and Property Parameters for Components -- 4.5.5 PCES (Physical Constant Estimation System) for Estimating Missing‐Property Parameters -- 4.5.6 Free Radical Polymerization Reactions for LDPE -- 4.5.7 Specifications of Inlet Process Streams and Unit Operation and Reactor Blocks -- 4.5.8 User FORTRAN Subroutine for Heat Transfer Calculations for the LDPE Reactor.
4.5.9 Base‐Case Simulation Targets and Kinetic Parameter Estimation.
Record Nr. UNINA-9910830887803321
Liu Y. A.  
Weinheim, Germany : , : WILEY-VCH GmbH, , [2023]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Introduction to industrial polyethylene [[electronic resource] ] : properties, catalysts, processes / / Dennis B. Malpass
Introduction to industrial polyethylene [[electronic resource] ] : properties, catalysts, processes / / Dennis B. Malpass
Autore Malpass Dennis B
Pubbl/distr/stampa Salem, MA, : Scrivener
Descrizione fisica 1 online resource (156 p.)
Disciplina 668.4234
Collana Wiley-Scrivener
Soggetto topico Polyethylene - Industrial applications
Thermoplastics - Industrial applications
ISBN 1-282-70811-2
9786612708114
1-118-03179-2
1-61344-182-7
0-470-90046-6
0-470-90045-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Introduction to Industrial Polyethylene; Contents; Preface; List of Tables; List of Figures; Chapter 1 Introduction to Polymers of Ethylene; Chapter 2 Free Radical Polymerization of Ethylene; Chapter 3 Ziegler-Natta Catalysts; Chapter 4 Metal Alkyls in Polyethylene Catalyst Systems; Chapter 5 Chromium Catalysts; Chapter 6 Single Site Catalysts; Chapter 7 An Overview of Industrial Polyethylene Processes; Chapter 8 Downstream Aspects of Polyethylene; Glossary; Trade Name Index; Index
Record Nr. UNINA-9910140829203321
Malpass Dennis B  
Salem, MA, : Scrivener
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Introduction to industrial polyethylene [[electronic resource] ] : properties, catalysts, processes / / Dennis B. Malpass
Introduction to industrial polyethylene [[electronic resource] ] : properties, catalysts, processes / / Dennis B. Malpass
Autore Malpass Dennis B
Pubbl/distr/stampa Salem, MA, : Scrivener
Descrizione fisica 1 online resource (156 p.)
Disciplina 668.4234
Collana Wiley-Scrivener
Soggetto topico Polyethylene - Industrial applications
Thermoplastics - Industrial applications
ISBN 1-282-70811-2
9786612708114
1-118-03179-2
1-61344-182-7
0-470-90046-6
0-470-90045-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Introduction to Industrial Polyethylene; Contents; Preface; List of Tables; List of Figures; Chapter 1 Introduction to Polymers of Ethylene; Chapter 2 Free Radical Polymerization of Ethylene; Chapter 3 Ziegler-Natta Catalysts; Chapter 4 Metal Alkyls in Polyethylene Catalyst Systems; Chapter 5 Chromium Catalysts; Chapter 6 Single Site Catalysts; Chapter 7 An Overview of Industrial Polyethylene Processes; Chapter 8 Downstream Aspects of Polyethylene; Glossary; Trade Name Index; Index
Record Nr. UNINA-9910824298903321
Malpass Dennis B  
Salem, MA, : Scrivener
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui