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Fundamentals of industrial catalytic processes [[electronic resource] /] / Calvin H. Bartholomew, Robert J. Farrauto
Fundamentals of industrial catalytic processes [[electronic resource] /] / Calvin H. Bartholomew, Robert J. Farrauto
Autore Bartholomew Calvin H
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2006
Descrizione fisica 1 online resource (1001 p.)
Disciplina 660.2995
660/.2995
Altri autori (Persone) FarrautoRobert J. <1941->
Soggetto topico Catalysis
Catalysts - Industrial applications
ISBN 9780471730064
1-118-20973-7
1-282-78363-7
9786612783630
0-471-73007-6
0-471-73006-8
Classificazione 58.14
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Fundamentals of Industrial Catalytic Processes; CONTENTS; Preface; Acknowledgments; Nomenclature; Part One: Introduction and Fundamentals; 1 Catalysis: Introduction and Fundamental Catalytic Phenomena; 2 Catalyst Materials, Properties and Preparation; 3 Catalyst Characterization and Selection; 4 Reactors, Reactor Design, and Activity Testing; 5 Catalyst Deactivation: Causes, Mechanisms, and Treatment; Part Two: Industrial Practice; 6 Hydrogen Production and Synthesis Gas Reactions; 7 Hydrogenation and Dehydrogenation of Organic Compounds
8 Catalytic Oxidations of Inorganic and Organic Compounds9 Petroleum Refining and Processing; 10 Environmental Catalysis: Mobile Sources; 11 Environmental Catalysis: Stationary Sources; 12 Homogeneous, Enzyme, And Polymerization Catalysis; 13 Hydrogen Production and Fuel Cells: Catalyst Technology; Glossary; Index
Record Nr. UNISA-996218416303316
Bartholomew Calvin H  
Hoboken, N.J., : Wiley, c2006
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
Fundamentals of industrial catalytic processes [[electronic resource] /] / Calvin H. Bartholomew, Robert J. Farrauto
Fundamentals of industrial catalytic processes [[electronic resource] /] / Calvin H. Bartholomew, Robert J. Farrauto
Autore Bartholomew Calvin H
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2006
Descrizione fisica 1 online resource (1001 p.)
Disciplina 660.2995
660/.2995
Altri autori (Persone) FarrautoRobert J. <1941->
Soggetto topico Catalysis
Catalysts - Industrial applications
ISBN 9780471730064
1-118-20973-7
1-282-78363-7
9786612783630
0-471-73007-6
0-471-73006-8
Classificazione 58.14
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Fundamentals of Industrial Catalytic Processes; CONTENTS; Preface; Acknowledgments; Nomenclature; Part One: Introduction and Fundamentals; 1 Catalysis: Introduction and Fundamental Catalytic Phenomena; 2 Catalyst Materials, Properties and Preparation; 3 Catalyst Characterization and Selection; 4 Reactors, Reactor Design, and Activity Testing; 5 Catalyst Deactivation: Causes, Mechanisms, and Treatment; Part Two: Industrial Practice; 6 Hydrogen Production and Synthesis Gas Reactions; 7 Hydrogenation and Dehydrogenation of Organic Compounds
8 Catalytic Oxidations of Inorganic and Organic Compounds9 Petroleum Refining and Processing; 10 Environmental Catalysis: Mobile Sources; 11 Environmental Catalysis: Stationary Sources; 12 Homogeneous, Enzyme, And Polymerization Catalysis; 13 Hydrogen Production and Fuel Cells: Catalyst Technology; Glossary; Index
Record Nr. UNINA-9910830759103321
Bartholomew Calvin H  
Hoboken, N.J., : Wiley, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fundamentals of industrial catalytic processes [[electronic resource] /] / Calvin H. Bartholomew, Robert J. Farrauto
Fundamentals of industrial catalytic processes [[electronic resource] /] / Calvin H. Bartholomew, Robert J. Farrauto
Autore Bartholomew Calvin H
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2006
Descrizione fisica 1 online resource (1001 p.)
Disciplina 660.2995
660/.2995
Altri autori (Persone) FarrautoRobert J. <1941->
Soggetto topico Catalysis
Catalysts - Industrial applications
ISBN 9780471730064
1-118-20973-7
1-282-78363-7
9786612783630
0-471-73007-6
0-471-73006-8
Classificazione 58.14
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Fundamentals of Industrial Catalytic Processes; CONTENTS; Preface; Acknowledgments; Nomenclature; Part One: Introduction and Fundamentals; 1 Catalysis: Introduction and Fundamental Catalytic Phenomena; 2 Catalyst Materials, Properties and Preparation; 3 Catalyst Characterization and Selection; 4 Reactors, Reactor Design, and Activity Testing; 5 Catalyst Deactivation: Causes, Mechanisms, and Treatment; Part Two: Industrial Practice; 6 Hydrogen Production and Synthesis Gas Reactions; 7 Hydrogenation and Dehydrogenation of Organic Compounds
8 Catalytic Oxidations of Inorganic and Organic Compounds9 Petroleum Refining and Processing; 10 Environmental Catalysis: Mobile Sources; 11 Environmental Catalysis: Stationary Sources; 12 Homogeneous, Enzyme, And Polymerization Catalysis; 13 Hydrogen Production and Fuel Cells: Catalyst Technology; Glossary; Index
Record Nr. UNINA-9910877565803321
Bartholomew Calvin H  
Hoboken, N.J., : Wiley, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Homogeneous catalysis : mechanisms and industrial applications / / Sumit Bhaduri, Doble Mukesh
Homogeneous catalysis : mechanisms and industrial applications / / Sumit Bhaduri, Doble Mukesh
Autore Bhaduri Sumit <1948->
Edizione [Second edition.]
Pubbl/distr/stampa Hoboken, New Jersey : , : Wiley, , 2014
Descrizione fisica 1 online resource (291 p.)
Disciplina 660/.2995
Soggetto topico Catalysis
Catalysis - Industrial applications
ISBN 1-118-87251-7
1-118-87236-3
1-118-87247-9
Classificazione SCI013040SCI013050TEC009010
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Homogeneous Catalysis: Mechanisms and Industrial Applications; Copyright; Contents; Preface; Chapter 1 Chemical Industry and Homogeneous Catalysis; 1.1 Feedstocks, Fuels, and Catalysts; 1.2 Crude Oil to Gasoline and Basic Building Blocks by Heterogeneous Catalysts; 1.2.1 Cracking Reactions; 1.2.2 Hydrodesulfurization Reactions; 1.3 Basic Building Blocks to Downstream Products by Homogeneous Catalysis; 1.4 Comparison among Different Types of Catalysis; 1.5 Catalyst Recovery; 1.6 Environmental Issues; 1.6.1 Background; 1.6.2 Biofuel, Ethanol, and Glycerol; 1.6.3 Biodegradable Plastics
1.6.4 Hydrogen and Carbon DioxideProblems; Bibliography; Books; Articles; Chapter 2 Basic Chemical Concepts; 2.1 Ligands; 2.1.1 Types of Ligands; 2.1.2 Donor and Acceptor Properties of Ligands; 2.1.3 CO, R2C=CR2, other π-acids, and H- as Ligands; 2.1.4 Phosphines and Related Ligands; 2.1.5 Alkyl, Aryl, Alkylidene, and Related Ligands; 2.1.6 Cyclopentadienyl, Allyl, and Related Ligands; 2.1.7 Chiral Ligands; 2.2 Metals; 2.2.1 Oxidation State; 2.2.2 Electron Counting; 2.2.3 Coordinative Unsaturation; 2.2.4 Lanthanides and Actinides; 2.3 Important Reaction Types
2.3.1 Oxidative Addition and Reductive Elimination2.3.2 Insertion and Elimination Reactions; 2.3.3 Metallacycle Formation; 2.3.4 Attack on a Coordinated Ligand; 2.3.5 Activation of Alkanes; 2.3.6 Activation of Dinitrogen; 2.3.7 Activation of Dioxygen (O2); Problems; Bibliography; Books; Articles; Chapter 3 Methods of Investigation; 3.1 Catalytic Cycle and Intermediates; 3.2 Spectroscopic Studies; 3.2.1 In Situ Spectroscopy; 3.2.2 Infrared Spectroscopy; 3.2.3 NMR Spectroscopy; 3.2.4 Advanced NMR Spectroscopy; 3.2.5 Other Spectroscopic Methods; 3.3 Kinetic Studies; 3.4 Model Compounds
3.5 Computational Methods3.6 Asymmetric Catalysis; Problems; Bibliography; Books; Articles; Chapter 4 Carbonylation and Related Reactions; 4.1 Introduction; 4.2 Carbonylation and Manufacture of Acetic Acid; 4.2.1 Cobalt Process; 4.2.2 Rhodium Cycle; 4.2.3 Iridium Process; 4.2.4 Mechanistic Studies and Differences; 4.3 Carbonylation of Other Alcohols; 4.4 Carbonylation of Methyl Acetate; 4.5 Carbonylation of Alkynes; 4.6 Other Carbonylation and Hydrocarboxylation Reactions; 4.7 C1 Chemistry; 4.7.1 Water Gas Shift Reaction; 4.7.2 Fischer-Tropsch Reactions; 4.7.3 Utilization of CO2
4.7.4 Polycarbonates from CO24.8 Engineering Aspects; Problems; Bibliography; Articles; Patents; Chapter 5 Hydrogenation and Other Hydrogen-Based Catalytic Reactions; 5.1 Hydrogenation; 5.1.1 Mechanisms and Catalytic Cycles; 5.1.2 Asymmetric Hydrogenation; 5.2 Hydroformylation; 5.2.1 Ligands and Selectivity; 5.2.2 Mechanistic Studies; 5.2.3 Water-Soluble Phosphines and Catalyst Recovery; 5.2.4 Other Methods for Catalyst Recovery; 5.3 Other Hydroformylation Reactions; 5.4 Asymmetric Hydroformylation; 5.5 Hydrosilylation; 5.6 Hydrocyanation; 5.6.1 Catalysts and Mechanistic Studies
5.6.2 Asymmetric Hydrocyanation
Record Nr. UNINA-9910132170703321
Bhaduri Sumit <1948->  
Hoboken, New Jersey : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Homogeneous catalysis : mechanisms and industrial applications / / Sumit Bhaduri, Doble Mukesh
Homogeneous catalysis : mechanisms and industrial applications / / Sumit Bhaduri, Doble Mukesh
Autore Bhaduri Sumit <1948->
Edizione [Second edition.]
Pubbl/distr/stampa Hoboken, New Jersey : , : Wiley, , 2014
Descrizione fisica 1 online resource (291 p.)
Disciplina 660/.2995
Soggetto topico Catalysis
Catalysis - Industrial applications
ISBN 1-118-87251-7
1-118-87236-3
1-118-87247-9
Classificazione SCI013040SCI013050TEC009010
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Homogeneous Catalysis: Mechanisms and Industrial Applications; Copyright; Contents; Preface; Chapter 1 Chemical Industry and Homogeneous Catalysis; 1.1 Feedstocks, Fuels, and Catalysts; 1.2 Crude Oil to Gasoline and Basic Building Blocks by Heterogeneous Catalysts; 1.2.1 Cracking Reactions; 1.2.2 Hydrodesulfurization Reactions; 1.3 Basic Building Blocks to Downstream Products by Homogeneous Catalysis; 1.4 Comparison among Different Types of Catalysis; 1.5 Catalyst Recovery; 1.6 Environmental Issues; 1.6.1 Background; 1.6.2 Biofuel, Ethanol, and Glycerol; 1.6.3 Biodegradable Plastics
1.6.4 Hydrogen and Carbon DioxideProblems; Bibliography; Books; Articles; Chapter 2 Basic Chemical Concepts; 2.1 Ligands; 2.1.1 Types of Ligands; 2.1.2 Donor and Acceptor Properties of Ligands; 2.1.3 CO, R2C=CR2, other π-acids, and H- as Ligands; 2.1.4 Phosphines and Related Ligands; 2.1.5 Alkyl, Aryl, Alkylidene, and Related Ligands; 2.1.6 Cyclopentadienyl, Allyl, and Related Ligands; 2.1.7 Chiral Ligands; 2.2 Metals; 2.2.1 Oxidation State; 2.2.2 Electron Counting; 2.2.3 Coordinative Unsaturation; 2.2.4 Lanthanides and Actinides; 2.3 Important Reaction Types
2.3.1 Oxidative Addition and Reductive Elimination2.3.2 Insertion and Elimination Reactions; 2.3.3 Metallacycle Formation; 2.3.4 Attack on a Coordinated Ligand; 2.3.5 Activation of Alkanes; 2.3.6 Activation of Dinitrogen; 2.3.7 Activation of Dioxygen (O2); Problems; Bibliography; Books; Articles; Chapter 3 Methods of Investigation; 3.1 Catalytic Cycle and Intermediates; 3.2 Spectroscopic Studies; 3.2.1 In Situ Spectroscopy; 3.2.2 Infrared Spectroscopy; 3.2.3 NMR Spectroscopy; 3.2.4 Advanced NMR Spectroscopy; 3.2.5 Other Spectroscopic Methods; 3.3 Kinetic Studies; 3.4 Model Compounds
3.5 Computational Methods3.6 Asymmetric Catalysis; Problems; Bibliography; Books; Articles; Chapter 4 Carbonylation and Related Reactions; 4.1 Introduction; 4.2 Carbonylation and Manufacture of Acetic Acid; 4.2.1 Cobalt Process; 4.2.2 Rhodium Cycle; 4.2.3 Iridium Process; 4.2.4 Mechanistic Studies and Differences; 4.3 Carbonylation of Other Alcohols; 4.4 Carbonylation of Methyl Acetate; 4.5 Carbonylation of Alkynes; 4.6 Other Carbonylation and Hydrocarboxylation Reactions; 4.7 C1 Chemistry; 4.7.1 Water Gas Shift Reaction; 4.7.2 Fischer-Tropsch Reactions; 4.7.3 Utilization of CO2
4.7.4 Polycarbonates from CO24.8 Engineering Aspects; Problems; Bibliography; Articles; Patents; Chapter 5 Hydrogenation and Other Hydrogen-Based Catalytic Reactions; 5.1 Hydrogenation; 5.1.1 Mechanisms and Catalytic Cycles; 5.1.2 Asymmetric Hydrogenation; 5.2 Hydroformylation; 5.2.1 Ligands and Selectivity; 5.2.2 Mechanistic Studies; 5.2.3 Water-Soluble Phosphines and Catalyst Recovery; 5.2.4 Other Methods for Catalyst Recovery; 5.3 Other Hydroformylation Reactions; 5.4 Asymmetric Hydroformylation; 5.5 Hydrosilylation; 5.6 Hydrocyanation; 5.6.1 Catalysts and Mechanistic Studies
5.6.2 Asymmetric Hydrocyanation
Record Nr. UNINA-9910820316103321
Bhaduri Sumit <1948->  
Hoboken, New Jersey : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Homogeneous catalysts [[electronic resource] ] : activity, stability, deactivation / / Piet W.N.M. van Leeuwen and John C. Chadwick
Homogeneous catalysts [[electronic resource] ] : activity, stability, deactivation / / Piet W.N.M. van Leeuwen and John C. Chadwick
Autore Leeuwen P. W. N. M. van (Piet W. N. M.)
Pubbl/distr/stampa Weinheim, Germany, : Wiley -VCH, c2011
Descrizione fisica 1 online resource (420 p.)
Disciplina 541.395
660.2995
660/.2995
Altri autori (Persone) ChadwickJohn C
Soggetto topico Catalysts
Alkenes
ISBN 3-527-63600-5
1-283-14092-6
9786613140920
3-527-63599-8
3-527-63601-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Homogeneous Catalysts: Activity - Stability - Deactivation; Contents; Preface; 1 Elementary Steps; 1.1 Introduction; 1.2 Metal Deposition; 1.2.1 Ligand Loss; 1.2.2 Loss of H+, Reductive Elimination of HX; 1.2.3 Reductive Elimination of C-, N-, O-Donor Fragments; 1.2.4 Metallic Nanoparticles; 1.3 Ligand Decomposition by Oxidation; 1.3.1 General; 1.3.2 Oxidation; 1.3.2.1 Catalysis Using O2; 1.3.2.2 Catalysis Using Hydroperoxides; 1.4 Phosphines; 1.4.1 Introduction; 1.4.2 Oxidation of Phosphines; 1.4.3 Oxidative Addition of a P-C Bond to a Low-Valent Metal
1.4.4 Nucleophilic Attack at Phosphorus1.4.5 Aryl Exchange Via Phosphonium Intermediates; 1.4.6 Aryl Exchange Via Metallophosphoranes; 1.5 Phosphites; 1.6 Imines and Pyridines; 1.7 Carbenes; 1.7.1 Introduction to NHCs as Ligands; 1.7.2 Reductive Elimination of NHCs; 1.7.3 Carbene Decomposition in Metathesis Catalysts; 1.8 Reactions of Metal-Carbon and Metal-Hydride Bonds; 1.8.1 Reactions with Protic Reagents; 1.8.2 Reactions of Zirconium and Titanium Alkyl Catalysts; 1.9 Reactions Blocking the Active Sites; 1.9.1 Polar Impurities; 1.9.2 Dimer Formation; 1.9.3 Ligand Metallation; References
2 Early Transition Metal Catalysts for Olefin Polymerization2.1 Ziegler-Natta Catalysts; 2.1.1 Introduction; 2.1.2 Effect of Catalyst Poisons; 2.1.3 TiCl3 Catalysts; 2.1.4 MgCl2-supported Catalysts; 2.1.4.1 MgCl2/TiCl4/Ethyl Benzoate Catalysts; 2.1.4.2 MgCl2/TiCl4/Diester Catalysts; 2.1.4.3 MgCl2/TiCl4/Diether Catalysts; 2.1.5 Ethene Polymerization; 2.2 Metallocenes; 2.2.1 Introduction; 2.2.2 Metallocene/MAO Systems; 2.2.3 Metallocene/Borate Systems; 2.3 Other Single-Center Catalysts; 2.3.1 Constrained Geometry and Half-Sandwich Complexes; 2.3.2 Octahedral Complexes
2.3.3 Diamide and Other Complexes2.4 Vanadium-Based Catalysts; 2.5 Chromium-Based Catalysts; 2.6 Conclusions; References; 3 Late Transition Metal Catalysts for Olefin Polymerization; 3.1 Nickel- and Palladium-based Catalysts; 3.1.1 Diimine Complexes; 3.1.2 Neutral Nickel(II) Complexes; 3.1.3 Other Nickel(II) and Palladium(II) Complexes; 3.2 Iron- and Cobalt-based Catalysts; 3.2.1 Bis(imino)Pyridyl Complexes; 3.3 Conclusions; References; 4 Effects of Immobilization of Catalysts for Olefin Polymerization; 4.1 Introduction; 4.2 Metallocenes and Related Complexes
4.2.1 Immobilized MAO/Metallocene Systems4.2.2 Immobilized Borane and Borate Activators; 4.2.3 Superacidic Supports; 4.2.4 MgCl2-Supported Systems; 4.3 Other Titanium and Zirconium Complexes; 4.3.1 Constrained Geometry Complexes; 4.3.2 Octahedral Complexes; 4.4 Vanadium Complexes; 4.5 Chromium Complexes; 4.6 Nickel Complexes; 4.7 Iron Complexes; 4.8 Conclusions; References; 5 Dormant Species in Transition Metal-Catalyzed Olefin Polymerization; 5.1 Introduction; 5.2 Ziegler-Natta Catalysts; 5.2.1 Ethene Polymerization; 5.2.2 Propene Polymerization
5.3 Metallocenes and Related Early Transition Metal Catalysts
Record Nr. UNINA-9910137856303321
Leeuwen P. W. N. M. van (Piet W. N. M.)  
Weinheim, Germany, : Wiley -VCH, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Homogeneous catalysts [[electronic resource] ] : activity, stability, deactivation / / Piet W.N.M. van Leeuwen and John C. Chadwick
Homogeneous catalysts [[electronic resource] ] : activity, stability, deactivation / / Piet W.N.M. van Leeuwen and John C. Chadwick
Autore Leeuwen P. W. N. M. van (Piet W. N. M.)
Pubbl/distr/stampa Weinheim, Germany, : Wiley -VCH, c2011
Descrizione fisica 1 online resource (420 p.)
Disciplina 541.395
660.2995
660/.2995
Altri autori (Persone) ChadwickJohn C
Soggetto topico Catalysts
Alkenes
ISBN 3-527-63600-5
1-283-14092-6
9786613140920
3-527-63599-8
3-527-63601-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Homogeneous Catalysts: Activity - Stability - Deactivation; Contents; Preface; 1 Elementary Steps; 1.1 Introduction; 1.2 Metal Deposition; 1.2.1 Ligand Loss; 1.2.2 Loss of H+, Reductive Elimination of HX; 1.2.3 Reductive Elimination of C-, N-, O-Donor Fragments; 1.2.4 Metallic Nanoparticles; 1.3 Ligand Decomposition by Oxidation; 1.3.1 General; 1.3.2 Oxidation; 1.3.2.1 Catalysis Using O2; 1.3.2.2 Catalysis Using Hydroperoxides; 1.4 Phosphines; 1.4.1 Introduction; 1.4.2 Oxidation of Phosphines; 1.4.3 Oxidative Addition of a P-C Bond to a Low-Valent Metal
1.4.4 Nucleophilic Attack at Phosphorus1.4.5 Aryl Exchange Via Phosphonium Intermediates; 1.4.6 Aryl Exchange Via Metallophosphoranes; 1.5 Phosphites; 1.6 Imines and Pyridines; 1.7 Carbenes; 1.7.1 Introduction to NHCs as Ligands; 1.7.2 Reductive Elimination of NHCs; 1.7.3 Carbene Decomposition in Metathesis Catalysts; 1.8 Reactions of Metal-Carbon and Metal-Hydride Bonds; 1.8.1 Reactions with Protic Reagents; 1.8.2 Reactions of Zirconium and Titanium Alkyl Catalysts; 1.9 Reactions Blocking the Active Sites; 1.9.1 Polar Impurities; 1.9.2 Dimer Formation; 1.9.3 Ligand Metallation; References
2 Early Transition Metal Catalysts for Olefin Polymerization2.1 Ziegler-Natta Catalysts; 2.1.1 Introduction; 2.1.2 Effect of Catalyst Poisons; 2.1.3 TiCl3 Catalysts; 2.1.4 MgCl2-supported Catalysts; 2.1.4.1 MgCl2/TiCl4/Ethyl Benzoate Catalysts; 2.1.4.2 MgCl2/TiCl4/Diester Catalysts; 2.1.4.3 MgCl2/TiCl4/Diether Catalysts; 2.1.5 Ethene Polymerization; 2.2 Metallocenes; 2.2.1 Introduction; 2.2.2 Metallocene/MAO Systems; 2.2.3 Metallocene/Borate Systems; 2.3 Other Single-Center Catalysts; 2.3.1 Constrained Geometry and Half-Sandwich Complexes; 2.3.2 Octahedral Complexes
2.3.3 Diamide and Other Complexes2.4 Vanadium-Based Catalysts; 2.5 Chromium-Based Catalysts; 2.6 Conclusions; References; 3 Late Transition Metal Catalysts for Olefin Polymerization; 3.1 Nickel- and Palladium-based Catalysts; 3.1.1 Diimine Complexes; 3.1.2 Neutral Nickel(II) Complexes; 3.1.3 Other Nickel(II) and Palladium(II) Complexes; 3.2 Iron- and Cobalt-based Catalysts; 3.2.1 Bis(imino)Pyridyl Complexes; 3.3 Conclusions; References; 4 Effects of Immobilization of Catalysts for Olefin Polymerization; 4.1 Introduction; 4.2 Metallocenes and Related Complexes
4.2.1 Immobilized MAO/Metallocene Systems4.2.2 Immobilized Borane and Borate Activators; 4.2.3 Superacidic Supports; 4.2.4 MgCl2-Supported Systems; 4.3 Other Titanium and Zirconium Complexes; 4.3.1 Constrained Geometry Complexes; 4.3.2 Octahedral Complexes; 4.4 Vanadium Complexes; 4.5 Chromium Complexes; 4.6 Nickel Complexes; 4.7 Iron Complexes; 4.8 Conclusions; References; 5 Dormant Species in Transition Metal-Catalyzed Olefin Polymerization; 5.1 Introduction; 5.2 Ziegler-Natta Catalysts; 5.2.1 Ethene Polymerization; 5.2.2 Propene Polymerization
5.3 Metallocenes and Related Early Transition Metal Catalysts
Record Nr. UNINA-9910830680303321
Leeuwen P. W. N. M. van (Piet W. N. M.)  
Weinheim, Germany, : Wiley -VCH, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Homogeneous catalysts : activity, stability, deactivation / / Piet W.N.M. van Leeuwen and John C. Chadwick
Homogeneous catalysts : activity, stability, deactivation / / Piet W.N.M. van Leeuwen and John C. Chadwick
Autore Leeuwen P. W. N. M. van (Piet W. N. M.)
Pubbl/distr/stampa Weinheim, Germany, : Wiley -VCH, c2011
Descrizione fisica 1 online resource (420 p.)
Disciplina 541.395
660.2995
660/.2995
Altri autori (Persone) ChadwickJohn C
Soggetto topico Catalysts
Alkenes
ISBN 3-527-63600-5
1-283-14092-6
9786613140920
3-527-63599-8
3-527-63601-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Homogeneous Catalysts: Activity - Stability - Deactivation; Contents; Preface; 1 Elementary Steps; 1.1 Introduction; 1.2 Metal Deposition; 1.2.1 Ligand Loss; 1.2.2 Loss of H+, Reductive Elimination of HX; 1.2.3 Reductive Elimination of C-, N-, O-Donor Fragments; 1.2.4 Metallic Nanoparticles; 1.3 Ligand Decomposition by Oxidation; 1.3.1 General; 1.3.2 Oxidation; 1.3.2.1 Catalysis Using O2; 1.3.2.2 Catalysis Using Hydroperoxides; 1.4 Phosphines; 1.4.1 Introduction; 1.4.2 Oxidation of Phosphines; 1.4.3 Oxidative Addition of a P-C Bond to a Low-Valent Metal
1.4.4 Nucleophilic Attack at Phosphorus1.4.5 Aryl Exchange Via Phosphonium Intermediates; 1.4.6 Aryl Exchange Via Metallophosphoranes; 1.5 Phosphites; 1.6 Imines and Pyridines; 1.7 Carbenes; 1.7.1 Introduction to NHCs as Ligands; 1.7.2 Reductive Elimination of NHCs; 1.7.3 Carbene Decomposition in Metathesis Catalysts; 1.8 Reactions of Metal-Carbon and Metal-Hydride Bonds; 1.8.1 Reactions with Protic Reagents; 1.8.2 Reactions of Zirconium and Titanium Alkyl Catalysts; 1.9 Reactions Blocking the Active Sites; 1.9.1 Polar Impurities; 1.9.2 Dimer Formation; 1.9.3 Ligand Metallation; References
2 Early Transition Metal Catalysts for Olefin Polymerization2.1 Ziegler-Natta Catalysts; 2.1.1 Introduction; 2.1.2 Effect of Catalyst Poisons; 2.1.3 TiCl3 Catalysts; 2.1.4 MgCl2-supported Catalysts; 2.1.4.1 MgCl2/TiCl4/Ethyl Benzoate Catalysts; 2.1.4.2 MgCl2/TiCl4/Diester Catalysts; 2.1.4.3 MgCl2/TiCl4/Diether Catalysts; 2.1.5 Ethene Polymerization; 2.2 Metallocenes; 2.2.1 Introduction; 2.2.2 Metallocene/MAO Systems; 2.2.3 Metallocene/Borate Systems; 2.3 Other Single-Center Catalysts; 2.3.1 Constrained Geometry and Half-Sandwich Complexes; 2.3.2 Octahedral Complexes
2.3.3 Diamide and Other Complexes2.4 Vanadium-Based Catalysts; 2.5 Chromium-Based Catalysts; 2.6 Conclusions; References; 3 Late Transition Metal Catalysts for Olefin Polymerization; 3.1 Nickel- and Palladium-based Catalysts; 3.1.1 Diimine Complexes; 3.1.2 Neutral Nickel(II) Complexes; 3.1.3 Other Nickel(II) and Palladium(II) Complexes; 3.2 Iron- and Cobalt-based Catalysts; 3.2.1 Bis(imino)Pyridyl Complexes; 3.3 Conclusions; References; 4 Effects of Immobilization of Catalysts for Olefin Polymerization; 4.1 Introduction; 4.2 Metallocenes and Related Complexes
4.2.1 Immobilized MAO/Metallocene Systems4.2.2 Immobilized Borane and Borate Activators; 4.2.3 Superacidic Supports; 4.2.4 MgCl2-Supported Systems; 4.3 Other Titanium and Zirconium Complexes; 4.3.1 Constrained Geometry Complexes; 4.3.2 Octahedral Complexes; 4.4 Vanadium Complexes; 4.5 Chromium Complexes; 4.6 Nickel Complexes; 4.7 Iron Complexes; 4.8 Conclusions; References; 5 Dormant Species in Transition Metal-Catalyzed Olefin Polymerization; 5.1 Introduction; 5.2 Ziegler-Natta Catalysts; 5.2.1 Ethene Polymerization; 5.2.2 Propene Polymerization
5.3 Metallocenes and Related Early Transition Metal Catalysts
Record Nr. UNINA-9910877482503321
Leeuwen P. W. N. M. van (Piet W. N. M.)  
Weinheim, Germany, : Wiley -VCH, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Industrial catalysis and separations : innovations for process intensification / / edited by K. V. Raghavan, PhD, and B. M. Reddy, PhD
Industrial catalysis and separations : innovations for process intensification / / edited by K. V. Raghavan, PhD, and B. M. Reddy, PhD
Edizione [First edition.]
Pubbl/distr/stampa Waretown, NJ : , : Apple Academic Press, Inc.
Descrizione fisica 1 online resource (503 p.)
Disciplina 660/.2995
Soggetto topico Catalysis - Industrial applications
Green chemistry
Chemical processes
ISBN 0-429-17028-9
1-5231-0713-8
1-926895-96-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto FRONT COVER; ABOUT THE EDITORS; CONTENTS; LIST OF CONTRIBUTORS; LIST OF ABBREVIATIONS; LIST OF SYMBOLS; PREFACE; INTRODUCTION; PART I - SCIENTIFIC APPROACHES TO PROCESS INTENSIFICATION; CHAPTER 1 - CHEMICAL PROCESS INTENSIFICATION: AN ENGINEERING OVERVIEW; CHAPTER 2 - MICROENVIRONMENT MANAGEMENT IN HETEROGENEOUS CATALYSIS; PART II - INTENSIFICATION OF SEPARATION PROCESSES; CHAPTER 3 - METAL ORGANIC FRAMEWORKS-SYNTHESIS AND APPLICATIONS; CHAPTER 4 - MEMBRANE FACILITATED DEFLUORIDATION OF WATER: PROCESS INTENSIFICATION AND SCALE UP; PART III - CARBON DIOXIDE FACILITATED CHEMICAL TRANSFORMATIONS
CHAPTER 5 - CATALYTIC CONVERSION OF CO2 INTO FUELS AND CHEMICALS: A GREEN CCU OPTIONCHAPTER 6 - SUPERCRITICAL CO2 IN ORGANIC SYNTHESIS; PART IV - INTENSIFICATION OF ORGANIC SYNTHESES; CHAPTER 7 - AMMOXIDATION OF HETERO AROMATIC COMPOUNDS TO THE CORRESPONDING NITRILES; CHAPTER 8 - CRACKING AND OXIDATIVE DEHYDROGENATION OF ETHANE TO ETHYLENE: PROCESS AND INTENSIFICATION OPTIONS; CHAPTER 9 - CATALYTIC ORGANIC SYNTHESIS: A NEW PARADIGM IN INDUSTRIAL PROCESS INTENSIFICATION; CHAPTER 10 - MICROWAVE ASSISTED SYNTHESIS: A VERSATILE TOOL FOR PROCESS INTENSIFICATION
CHAPTER 11 - CATALYTIC PROCESSES FOR FLUOROCHEMICALS: SUSTAINABLE ALTERNATIVESCHAPTER 12 - BASE CATALYZED TRANSESTERIFICATION FOR BIODIESEL: NOVEL CATALYST OPTIONS; BACK COVER
Record Nr. UNINA-9910787846503321
Waretown, NJ : , : Apple Academic Press, Inc.
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Industrial catalysis and separations : innovations for process intensification / / edited by K. V. Raghavan, PhD, and B. M. Reddy, PhD
Industrial catalysis and separations : innovations for process intensification / / edited by K. V. Raghavan, PhD, and B. M. Reddy, PhD
Edizione [First edition.]
Pubbl/distr/stampa Waretown, NJ : , : Apple Academic Press, Inc.
Descrizione fisica 1 online resource (503 p.)
Disciplina 660/.2995
Soggetto topico Catalysis - Industrial applications
Green chemistry
Chemical processes
ISBN 0-429-17028-9
1-5231-0713-8
1-926895-96-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto FRONT COVER; ABOUT THE EDITORS; CONTENTS; LIST OF CONTRIBUTORS; LIST OF ABBREVIATIONS; LIST OF SYMBOLS; PREFACE; INTRODUCTION; PART I - SCIENTIFIC APPROACHES TO PROCESS INTENSIFICATION; CHAPTER 1 - CHEMICAL PROCESS INTENSIFICATION: AN ENGINEERING OVERVIEW; CHAPTER 2 - MICROENVIRONMENT MANAGEMENT IN HETEROGENEOUS CATALYSIS; PART II - INTENSIFICATION OF SEPARATION PROCESSES; CHAPTER 3 - METAL ORGANIC FRAMEWORKS-SYNTHESIS AND APPLICATIONS; CHAPTER 4 - MEMBRANE FACILITATED DEFLUORIDATION OF WATER: PROCESS INTENSIFICATION AND SCALE UP; PART III - CARBON DIOXIDE FACILITATED CHEMICAL TRANSFORMATIONS
CHAPTER 5 - CATALYTIC CONVERSION OF CO2 INTO FUELS AND CHEMICALS: A GREEN CCU OPTIONCHAPTER 6 - SUPERCRITICAL CO2 IN ORGANIC SYNTHESIS; PART IV - INTENSIFICATION OF ORGANIC SYNTHESES; CHAPTER 7 - AMMOXIDATION OF HETERO AROMATIC COMPOUNDS TO THE CORRESPONDING NITRILES; CHAPTER 8 - CRACKING AND OXIDATIVE DEHYDROGENATION OF ETHANE TO ETHYLENE: PROCESS AND INTENSIFICATION OPTIONS; CHAPTER 9 - CATALYTIC ORGANIC SYNTHESIS: A NEW PARADIGM IN INDUSTRIAL PROCESS INTENSIFICATION; CHAPTER 10 - MICROWAVE ASSISTED SYNTHESIS: A VERSATILE TOOL FOR PROCESS INTENSIFICATION
CHAPTER 11 - CATALYTIC PROCESSES FOR FLUOROCHEMICALS: SUSTAINABLE ALTERNATIVESCHAPTER 12 - BASE CATALYZED TRANSESTERIFICATION FOR BIODIESEL: NOVEL CATALYST OPTIONS; BACK COVER
Record Nr. UNINA-9910800184103321
Waretown, NJ : , : Apple Academic Press, Inc.
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui