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Fundamentals of polymerization [[electronic resource] /] / Broja M. Mandal
Fundamentals of polymerization [[electronic resource] /] / Broja M. Mandal
Autore Mandal Broja Mohan
Pubbl/distr/stampa Singapore ; ; London, : World Scientific, c2013
Descrizione fisica 1 online resource (468 p.)
Disciplina 547.28
Soggetto topico Polymerization
Chemical reactions
Soggetto genere / forma Electronic books.
ISBN 1-283-89995-7
981-4322-85-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface; Contents; List of Abbreviations; Chapter 1. Introduction; 1.1 Nomenclature; 1.2 Structural and Repeating (or Repeat) Units; 1.3 Classification; 1.3.1 Condensation and addition polymers and polymerizations; 1.3.2 Step-growth and chain-growth polymers and polymerizations; 1.4 Functionality; 1.5 Designed Branched Polymers; 1.5.1 Star polymers; 1.5.2 Hyperbranched polymers; 1.5.3 Dendrimers; 1.6 Physical State; 1.7 Structure-Property Relationship; 1.7.1 Nonconjugated polymers; Rubbers; Fibers and plastics; 1.7.1.1 Stereoregularity in vinyl polymers
1.7.1.2 Regioregularity in vinyl polymers1.7.2 Conjugated polymers; 1.8 Thermodynamics of Polymerization; 1.9 Polymerizability of Internal Olefins; 1.10 Molecular Weights and Molecular Weight Distributions; References; Problems; Chapter 2. Step Polymerization; 2.1 Principle of Equal Reactivity of Functional Groups and Kinetics of Polymerization; 2.2 Ring vs. Chain Formation; 2.3 Intermolecular Interchange Reactions; 2.4 Degree of Polymerization; 2.4.1 Carothers equation; 2.4.1.1 Bifunctional polycondensation; 2.4.1.2 Control of degree of polymerization
2.4.1.2.1 Polymerization of nonequivalent monomer mixtures2.4.1.2.2 Departure from Carothers equation in interfacial polycondensation; 2.5 Molecular Weight Distribution; 2.5.1 Molecular weight distribution in bifunctional polycondensation; 2.5.2 Average degree of polymerization for most probable distribution; 2.6 Prediction of Gel Point in Polyfunctional Polycondensation; 2.6.1 Prediction based on Carothers equation; 2.6.2 Prediction based on statistical method of Flory; 2.6.2.1 Gel-forming range of monomer proportions; 2.6.2.1.1 Polycondensation of Af and B-B monomers
2.6.2.1.2 Polymerization of a ternary mixture of A-A, B-B, and A3 monomers2.7 Thermosetting Resins; 2.7.1 Phenolic resins; 2.7.2 Amino resins; 2.7.3 Unsaturated polyesters and alkyd resins; 2.7.4 Polyurethanes and polyureas; 2.7.5 Epoxy resins; 2.7.6 Polysiloxanes; 2.7.7 Aliphatic polysulfides; 2.8 Engineering Plastics; 2.8.1 Polyamides; 2.8.1.1 Aliphatic polyamides; 2.8.1.2 Aromatic polyamides; 2.8.2 Polyesters; 2.8.2.1 Aliphatic-aromatic polyesters; 2.8.2.2 Aromatic polyesters; 2.8.3 Polycarbonates; 2.8.4 Poly(phenylene oxide)s; 2.9 High Performance Polymers
2.9.1 Liquid crystalline polymers (LCPs)2.9.2 Poly(p-phenylene sulfide); 2.9.3 Poly(arylene ether)s; 2.9.4 Polyimides; 2.9.4.1 Thermoplastic polyimides; Polyetherimides and Polyamide imides; 2.9.4.2 Thermosetting polyimides; 2.9.5 Polybenzimidazoles; 2.9.6 Polybenzoxazoles and polybenzothiazoles; 2.10 Nonconventional Step Polymerization; References; Problems; Chapter 3. Radical Polymerization; 3.1 General Features; 3.1.1 Monomer types; 3.1.2 Reactivity of monomers and radicals; 3.2 Kinetics of Homogeneous Radical Polymerization; 3.3 Reaction Orders in Initiator and Monomer; 3.4 Initiators
3.4.1 Thermal initiators
Record Nr. UNINA-9910463960003321
Mandal Broja Mohan  
Singapore ; ; London, : World Scientific, c2013
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fundamentals of polymerization [[electronic resource] /] / Broja M. Mandal
Fundamentals of polymerization [[electronic resource] /] / Broja M. Mandal
Autore Mandal Broja Mohan
Pubbl/distr/stampa Singapore ; ; London, : World Scientific, c2013
Descrizione fisica 1 online resource (468 p.)
Disciplina 547.28
Soggetto topico Polymerization
Chemical reactions
ISBN 1-283-89995-7
981-4322-85-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface; Contents; List of Abbreviations; Chapter 1. Introduction; 1.1 Nomenclature; 1.2 Structural and Repeating (or Repeat) Units; 1.3 Classification; 1.3.1 Condensation and addition polymers and polymerizations; 1.3.2 Step-growth and chain-growth polymers and polymerizations; 1.4 Functionality; 1.5 Designed Branched Polymers; 1.5.1 Star polymers; 1.5.2 Hyperbranched polymers; 1.5.3 Dendrimers; 1.6 Physical State; 1.7 Structure-Property Relationship; 1.7.1 Nonconjugated polymers; Rubbers; Fibers and plastics; 1.7.1.1 Stereoregularity in vinyl polymers
1.7.1.2 Regioregularity in vinyl polymers1.7.2 Conjugated polymers; 1.8 Thermodynamics of Polymerization; 1.9 Polymerizability of Internal Olefins; 1.10 Molecular Weights and Molecular Weight Distributions; References; Problems; Chapter 2. Step Polymerization; 2.1 Principle of Equal Reactivity of Functional Groups and Kinetics of Polymerization; 2.2 Ring vs. Chain Formation; 2.3 Intermolecular Interchange Reactions; 2.4 Degree of Polymerization; 2.4.1 Carothers equation; 2.4.1.1 Bifunctional polycondensation; 2.4.1.2 Control of degree of polymerization
2.4.1.2.1 Polymerization of nonequivalent monomer mixtures2.4.1.2.2 Departure from Carothers equation in interfacial polycondensation; 2.5 Molecular Weight Distribution; 2.5.1 Molecular weight distribution in bifunctional polycondensation; 2.5.2 Average degree of polymerization for most probable distribution; 2.6 Prediction of Gel Point in Polyfunctional Polycondensation; 2.6.1 Prediction based on Carothers equation; 2.6.2 Prediction based on statistical method of Flory; 2.6.2.1 Gel-forming range of monomer proportions; 2.6.2.1.1 Polycondensation of Af and B-B monomers
2.6.2.1.2 Polymerization of a ternary mixture of A-A, B-B, and A3 monomers2.7 Thermosetting Resins; 2.7.1 Phenolic resins; 2.7.2 Amino resins; 2.7.3 Unsaturated polyesters and alkyd resins; 2.7.4 Polyurethanes and polyureas; 2.7.5 Epoxy resins; 2.7.6 Polysiloxanes; 2.7.7 Aliphatic polysulfides; 2.8 Engineering Plastics; 2.8.1 Polyamides; 2.8.1.1 Aliphatic polyamides; 2.8.1.2 Aromatic polyamides; 2.8.2 Polyesters; 2.8.2.1 Aliphatic-aromatic polyesters; 2.8.2.2 Aromatic polyesters; 2.8.3 Polycarbonates; 2.8.4 Poly(phenylene oxide)s; 2.9 High Performance Polymers
2.9.1 Liquid crystalline polymers (LCPs)2.9.2 Poly(p-phenylene sulfide); 2.9.3 Poly(arylene ether)s; 2.9.4 Polyimides; 2.9.4.1 Thermoplastic polyimides; Polyetherimides and Polyamide imides; 2.9.4.2 Thermosetting polyimides; 2.9.5 Polybenzimidazoles; 2.9.6 Polybenzoxazoles and polybenzothiazoles; 2.10 Nonconventional Step Polymerization; References; Problems; Chapter 3. Radical Polymerization; 3.1 General Features; 3.1.1 Monomer types; 3.1.2 Reactivity of monomers and radicals; 3.2 Kinetics of Homogeneous Radical Polymerization; 3.3 Reaction Orders in Initiator and Monomer; 3.4 Initiators
3.4.1 Thermal initiators
Record Nr. UNINA-9910788622203321
Mandal Broja Mohan  
Singapore ; ; London, : World Scientific, c2013
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fundamentals of polymerization [[electronic resource] /] / Broja M. Mandal
Fundamentals of polymerization [[electronic resource] /] / Broja M. Mandal
Autore Mandal Broja Mohan
Pubbl/distr/stampa Singapore ; ; London, : World Scientific, c2013
Descrizione fisica 1 online resource (468 p.)
Disciplina 547.28
Soggetto topico Polymerization
Chemical reactions
ISBN 1-283-89995-7
981-4322-85-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface; Contents; List of Abbreviations; Chapter 1. Introduction; 1.1 Nomenclature; 1.2 Structural and Repeating (or Repeat) Units; 1.3 Classification; 1.3.1 Condensation and addition polymers and polymerizations; 1.3.2 Step-growth and chain-growth polymers and polymerizations; 1.4 Functionality; 1.5 Designed Branched Polymers; 1.5.1 Star polymers; 1.5.2 Hyperbranched polymers; 1.5.3 Dendrimers; 1.6 Physical State; 1.7 Structure-Property Relationship; 1.7.1 Nonconjugated polymers; Rubbers; Fibers and plastics; 1.7.1.1 Stereoregularity in vinyl polymers
1.7.1.2 Regioregularity in vinyl polymers1.7.2 Conjugated polymers; 1.8 Thermodynamics of Polymerization; 1.9 Polymerizability of Internal Olefins; 1.10 Molecular Weights and Molecular Weight Distributions; References; Problems; Chapter 2. Step Polymerization; 2.1 Principle of Equal Reactivity of Functional Groups and Kinetics of Polymerization; 2.2 Ring vs. Chain Formation; 2.3 Intermolecular Interchange Reactions; 2.4 Degree of Polymerization; 2.4.1 Carothers equation; 2.4.1.1 Bifunctional polycondensation; 2.4.1.2 Control of degree of polymerization
2.4.1.2.1 Polymerization of nonequivalent monomer mixtures2.4.1.2.2 Departure from Carothers equation in interfacial polycondensation; 2.5 Molecular Weight Distribution; 2.5.1 Molecular weight distribution in bifunctional polycondensation; 2.5.2 Average degree of polymerization for most probable distribution; 2.6 Prediction of Gel Point in Polyfunctional Polycondensation; 2.6.1 Prediction based on Carothers equation; 2.6.2 Prediction based on statistical method of Flory; 2.6.2.1 Gel-forming range of monomer proportions; 2.6.2.1.1 Polycondensation of Af and B-B monomers
2.6.2.1.2 Polymerization of a ternary mixture of A-A, B-B, and A3 monomers2.7 Thermosetting Resins; 2.7.1 Phenolic resins; 2.7.2 Amino resins; 2.7.3 Unsaturated polyesters and alkyd resins; 2.7.4 Polyurethanes and polyureas; 2.7.5 Epoxy resins; 2.7.6 Polysiloxanes; 2.7.7 Aliphatic polysulfides; 2.8 Engineering Plastics; 2.8.1 Polyamides; 2.8.1.1 Aliphatic polyamides; 2.8.1.2 Aromatic polyamides; 2.8.2 Polyesters; 2.8.2.1 Aliphatic-aromatic polyesters; 2.8.2.2 Aromatic polyesters; 2.8.3 Polycarbonates; 2.8.4 Poly(phenylene oxide)s; 2.9 High Performance Polymers
2.9.1 Liquid crystalline polymers (LCPs)2.9.2 Poly(p-phenylene sulfide); 2.9.3 Poly(arylene ether)s; 2.9.4 Polyimides; 2.9.4.1 Thermoplastic polyimides; Polyetherimides and Polyamide imides; 2.9.4.2 Thermosetting polyimides; 2.9.5 Polybenzimidazoles; 2.9.6 Polybenzoxazoles and polybenzothiazoles; 2.10 Nonconventional Step Polymerization; References; Problems; Chapter 3. Radical Polymerization; 3.1 General Features; 3.1.1 Monomer types; 3.1.2 Reactivity of monomers and radicals; 3.2 Kinetics of Homogeneous Radical Polymerization; 3.3 Reaction Orders in Initiator and Monomer; 3.4 Initiators
3.4.1 Thermal initiators
Record Nr. UNINA-9910817001903321
Mandal Broja Mohan  
Singapore ; ; London, : World Scientific, c2013
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of Polymer Reaction Engineering
Handbook of Polymer Reaction Engineering
Autore Meyer Thierry
Pubbl/distr/stampa [Place of publication not identified], : John Wiley & Sons Incorporated, 2005
Descrizione fisica 1 online resource (1000 pages)
Disciplina 547.28
Soggetto topico Polymerization
ISBN 3-527-61987-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto INTRODUCTION TO POLYMER REACTION ENGINEERING, AN INTEGRATED APPROACH.POLYMER CHARACTERIZATION.POLYMER THERMODYNAMICS.POLYCONDENSATION.FREE RADICAL POLYMERIZATION: HOMOGENEOUS.FREE RADICAL POLYMERIZATION: SUSPENSION.Emulsion Polymerization.Ionic Polymerization.COORDINATION POLYMERIZATION.Numerical Methods.SCALE-UP.SAFETY IN POLYMERIZATION PROCESSES.Measurement and control of polymerization reactors.POLYMER PROPERTIES.POLYMER MECHANICAL PROPERTIES.POLYMER STABILIZATION AND DEGRADATION.Modification Processes.Thermosets.Fibers.Removable.Novel polymers and Developement.Recent Developments in Polymer Processes.
Record Nr. UNINA-9910830382403321
Meyer Thierry  
[Place of publication not identified], : John Wiley & Sons Incorporated, 2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of Polymer Reaction Engineering
Handbook of Polymer Reaction Engineering
Autore Meyer Thierry
Pubbl/distr/stampa [Place of publication not identified], : John Wiley & Sons Incorporated, 2005
Descrizione fisica 1 online resource (1000 pages)
Disciplina 547.28
Soggetto topico Polymerization
ISBN 3-527-61987-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto INTRODUCTION TO POLYMER REACTION ENGINEERING, AN INTEGRATED APPROACH.POLYMER CHARACTERIZATION.POLYMER THERMODYNAMICS.POLYCONDENSATION.FREE RADICAL POLYMERIZATION: HOMOGENEOUS.FREE RADICAL POLYMERIZATION: SUSPENSION.Emulsion Polymerization.Ionic Polymerization.COORDINATION POLYMERIZATION.Numerical Methods.SCALE-UP.SAFETY IN POLYMERIZATION PROCESSES.Measurement and control of polymerization reactors.POLYMER PROPERTIES.POLYMER MECHANICAL PROPERTIES.POLYMER STABILIZATION AND DEGRADATION.Modification Processes.Thermosets.Fibers.Removable.Novel polymers and Developement.Recent Developments in Polymer Processes.
Record Nr. UNINA-9910840519203321
Meyer Thierry  
[Place of publication not identified], : John Wiley & Sons Incorporated, 2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of radical polymerization / / Krzysztof Matyjaszewski, Thomas P. Davis
Handbook of radical polymerization / / Krzysztof Matyjaszewski, Thomas P. Davis
Autore Matyjaszewski K (Krzysztof)
Pubbl/distr/stampa Hoboken, New Jersey : , : Wiley-Interscience, , 2002
Descrizione fisica 1 online resource (934 p.)
Disciplina 547.28
547/.28
Soggetto topico Polymerization
Free radical reactions
ISBN 1-280-36694-X
9786610366941
0-470-35609-X
0-471-46157-1
0-471-22045-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto HANDBOOK OF RADICAL POLYMERIZATION; CONTENTS; Introduction; Contributors; 1 Theory of Radical Reactions; 2 Small Radical Chemistry; 3 General Chemistry of Radical Polymerization; 4 The Kinetics of Free Radical Polymerization; 5 Copolymerization Kinetics; 6 Heterogeneous Systems; 7 Industrial Applications and Processes; 8 General Concepts and History of Living Radical Polymerization; 9 Kinetics of Living Radical Polymerization; 10 Nitroxide Mediated Living Radical Polymerization; 11 Fundamentals of Atom Transfer Radical Polymerization
12 Control of Free Radical Polymerization by Chain Transfer Methods13 Control of Stereochemistry of Polymers in Radical Polymerization; 14 Macromolecular Engineering by Controlled Radical Polymerization; 15 Experimental Procedures and Techniques for Radical Polymerization; 16 Future Outlook and Perspectives; Index
Record Nr. UNINA-9910143177603321
Matyjaszewski K (Krzysztof)  
Hoboken, New Jersey : , : Wiley-Interscience, , 2002
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of radical polymerization / / Krzysztof Matyjaszewski, Thomas P. Davis
Handbook of radical polymerization / / Krzysztof Matyjaszewski, Thomas P. Davis
Autore Matyjaszewski K (Krzysztof)
Pubbl/distr/stampa Hoboken, New Jersey : , : Wiley-Interscience, , 2002
Descrizione fisica 1 online resource (934 p.)
Disciplina 547.28
547/.28
Soggetto topico Polymerization
Free radical reactions
ISBN 1-280-36694-X
9786610366941
0-470-35609-X
0-471-46157-1
0-471-22045-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto HANDBOOK OF RADICAL POLYMERIZATION; CONTENTS; Introduction; Contributors; 1 Theory of Radical Reactions; 2 Small Radical Chemistry; 3 General Chemistry of Radical Polymerization; 4 The Kinetics of Free Radical Polymerization; 5 Copolymerization Kinetics; 6 Heterogeneous Systems; 7 Industrial Applications and Processes; 8 General Concepts and History of Living Radical Polymerization; 9 Kinetics of Living Radical Polymerization; 10 Nitroxide Mediated Living Radical Polymerization; 11 Fundamentals of Atom Transfer Radical Polymerization
12 Control of Free Radical Polymerization by Chain Transfer Methods13 Control of Stereochemistry of Polymers in Radical Polymerization; 14 Macromolecular Engineering by Controlled Radical Polymerization; 15 Experimental Procedures and Techniques for Radical Polymerization; 16 Future Outlook and Perspectives; Index
Record Nr. UNINA-9910830496403321
Matyjaszewski K (Krzysztof)  
Hoboken, New Jersey : , : Wiley-Interscience, , 2002
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of RAFT polymerization [[electronic resource] /] / edited by Christopher Barner-Kowollik
Handbook of RAFT polymerization [[electronic resource] /] / edited by Christopher Barner-Kowollik
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2008
Descrizione fisica 1 online resource (557 p.)
Disciplina 547.28
547/.28
Altri autori (Persone) Barner-KowollikChristopher
Soggetto topico Addition polymerization
Polymerization
ISBN 1-281-94700-8
9786611947002
3-527-62275-6
3-527-62276-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of RAFT Polymerization; Contents; List of Contributors; 1 Introduction; 2 Quantum-Chemical Studies of RAFT Polymerization: Methodology, Structure-Reactivity Correlations and Kinetic Implications; 2.1 Introduction; 2.2 Methodology; 2.3 Computational Modeling of RAFT Kinetics; 2.4 Structure-Reactivity Studies; 2.5 Abbreviations; 3 The Mechanism and Kinetics of the RAFT Process: Overview, Rates, Stabilities, Side Reactions, Product Spectrum and Outstanding Challenges; 3.1 History; 3.2 Preequilibrium Kinetics and Mechanism; 3.3 Main Equilibrium Kinetics and Mechanism
3.4 Mechanisms for Rate Retardation/Inhibition - Outstanding Questions3.5 RAFT Copolymerization: Block and Statistical Copolymers; 3.6 The Kinetics and Mechanism of Star and Graft Polymer Formation Processes; 3.7 Mechanism and Kinetics as a Guide for the Synthetic Polymer Chemist; 4 The RAFT Process as a Kinetic Tool: Accessing Fundamental Parameters of Free Radical Polymerization; 4.1 Introduction; 4.2 Chain-Length-Dependent Termination: A Brief Overview; 4.3 RAFT Chemistry as a Tool for Elucidating the Chain Length Dependence of k(t); 4.4 Chain-Length-Dependent Propagation Rate Coefficients
5 The Radical Chemistry of Thiocarbonylthio Compounds: An Overview5.1 Historical Overview and Early Chemistry; 5.2 The Barton-McCombie Deoxygenation; 5.3 A Minor Mechanistic Controversy; 5.4 A New Degenerative Radical Process; 5.5 Synthetic Routes to Thiocarbonylthio Derivatives; 5.6 Some Synthetic Applications of the Degenerative Radical Transfer to Small Molecules; 5.7 Applications to Controlled Radical Polymerizations; 5.8 Concluding Remarks; 6 RAFT Polymerization in Bulk Monomer or in (Organic) Solution; 6.1 Introduction; 6.2 RAFT Agents; 6.3 RAFT Polymerization
6.4 RAFT Polymerization Conditions6.5 Abbreviations; 7 RAFT Polymerization in Homogeneous Aqueous Media: Initiation Systems, RAFT Agent Stability, Monomers and Polymer Structures; 7.1 Introduction; 7.2 Initiation Systems; 7.3 RAFT Agent Stability; 7.4 Suitable Monomers; 7.5 Examples of Experimental Procedures; 8 RAFT-Mediated Polymerization in Heterogeneous Systems; 8.1 Introduction; 8.2 Effect of C(tr,RAFT) on M(n) and PDI in Homogeneous Systems; 8.3 Raft in Heterogeneous Systems; 8.4 Conclusion; 9 Complex Architecture Design via the RAFT Process: Scope, Strengths and Limitations
9.1 Complex Polymer Architectures9.2 Block Copolymers; 9.3 Star Polymers via RAFT Polymerization; 9.4 Comb Polymers; 9.5 Other Complex Architectures; 9.6 Conclusions; 10 Macromolecular Design by Interchange of Xanthates: Background, Design, Scope and Applications; 10.1 Introduction; 10.2 History of MADIX Polymerization; 10.3 Mechanism of MADIX Polymerization; 10.4 Kinetics of MADIX Polymerization; 10.5 Choice of MADIX Agents; 10.6 Synthesis of MADIX Agents; 10.7 Experimental Conditions in MADIX; 10.8 Monomers Polymerizable by MADIX; 10.9 MADIX Polymerization in Waterborne Dispersed Media
10.10 Macromolecular Engineering by MADIX
Record Nr. UNINA-9910144095003321
Weinheim, : Wiley-VCH, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of RAFT polymerization [[electronic resource] /] / edited by Christopher Barner-Kowollik
Handbook of RAFT polymerization [[electronic resource] /] / edited by Christopher Barner-Kowollik
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2008
Descrizione fisica 1 online resource (557 p.)
Disciplina 547.28
547/.28
Altri autori (Persone) Barner-KowollikChristopher
Soggetto topico Addition polymerization
Polymerization
ISBN 1-281-94700-8
9786611947002
3-527-62275-6
3-527-62276-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of RAFT Polymerization; Contents; List of Contributors; 1 Introduction; 2 Quantum-Chemical Studies of RAFT Polymerization: Methodology, Structure-Reactivity Correlations and Kinetic Implications; 2.1 Introduction; 2.2 Methodology; 2.3 Computational Modeling of RAFT Kinetics; 2.4 Structure-Reactivity Studies; 2.5 Abbreviations; 3 The Mechanism and Kinetics of the RAFT Process: Overview, Rates, Stabilities, Side Reactions, Product Spectrum and Outstanding Challenges; 3.1 History; 3.2 Preequilibrium Kinetics and Mechanism; 3.3 Main Equilibrium Kinetics and Mechanism
3.4 Mechanisms for Rate Retardation/Inhibition - Outstanding Questions3.5 RAFT Copolymerization: Block and Statistical Copolymers; 3.6 The Kinetics and Mechanism of Star and Graft Polymer Formation Processes; 3.7 Mechanism and Kinetics as a Guide for the Synthetic Polymer Chemist; 4 The RAFT Process as a Kinetic Tool: Accessing Fundamental Parameters of Free Radical Polymerization; 4.1 Introduction; 4.2 Chain-Length-Dependent Termination: A Brief Overview; 4.3 RAFT Chemistry as a Tool for Elucidating the Chain Length Dependence of k(t); 4.4 Chain-Length-Dependent Propagation Rate Coefficients
5 The Radical Chemistry of Thiocarbonylthio Compounds: An Overview5.1 Historical Overview and Early Chemistry; 5.2 The Barton-McCombie Deoxygenation; 5.3 A Minor Mechanistic Controversy; 5.4 A New Degenerative Radical Process; 5.5 Synthetic Routes to Thiocarbonylthio Derivatives; 5.6 Some Synthetic Applications of the Degenerative Radical Transfer to Small Molecules; 5.7 Applications to Controlled Radical Polymerizations; 5.8 Concluding Remarks; 6 RAFT Polymerization in Bulk Monomer or in (Organic) Solution; 6.1 Introduction; 6.2 RAFT Agents; 6.3 RAFT Polymerization
6.4 RAFT Polymerization Conditions6.5 Abbreviations; 7 RAFT Polymerization in Homogeneous Aqueous Media: Initiation Systems, RAFT Agent Stability, Monomers and Polymer Structures; 7.1 Introduction; 7.2 Initiation Systems; 7.3 RAFT Agent Stability; 7.4 Suitable Monomers; 7.5 Examples of Experimental Procedures; 8 RAFT-Mediated Polymerization in Heterogeneous Systems; 8.1 Introduction; 8.2 Effect of C(tr,RAFT) on M(n) and PDI in Homogeneous Systems; 8.3 Raft in Heterogeneous Systems; 8.4 Conclusion; 9 Complex Architecture Design via the RAFT Process: Scope, Strengths and Limitations
9.1 Complex Polymer Architectures9.2 Block Copolymers; 9.3 Star Polymers via RAFT Polymerization; 9.4 Comb Polymers; 9.5 Other Complex Architectures; 9.6 Conclusions; 10 Macromolecular Design by Interchange of Xanthates: Background, Design, Scope and Applications; 10.1 Introduction; 10.2 History of MADIX Polymerization; 10.3 Mechanism of MADIX Polymerization; 10.4 Kinetics of MADIX Polymerization; 10.5 Choice of MADIX Agents; 10.6 Synthesis of MADIX Agents; 10.7 Experimental Conditions in MADIX; 10.8 Monomers Polymerizable by MADIX; 10.9 MADIX Polymerization in Waterborne Dispersed Media
10.10 Macromolecular Engineering by MADIX
Record Nr. UNINA-9910829925303321
Weinheim, : Wiley-VCH, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of RAFT polymerization [[electronic resource] /] / edited by Christopher Barner-Kowollik
Handbook of RAFT polymerization [[electronic resource] /] / edited by Christopher Barner-Kowollik
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2008
Descrizione fisica 1 online resource (557 p.)
Disciplina 547.28
547/.28
Altri autori (Persone) Barner-KowollikChristopher
Soggetto topico Addition polymerization
Polymerization
ISBN 1-281-94700-8
9786611947002
3-527-62275-6
3-527-62276-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of RAFT Polymerization; Contents; List of Contributors; 1 Introduction; 2 Quantum-Chemical Studies of RAFT Polymerization: Methodology, Structure-Reactivity Correlations and Kinetic Implications; 2.1 Introduction; 2.2 Methodology; 2.3 Computational Modeling of RAFT Kinetics; 2.4 Structure-Reactivity Studies; 2.5 Abbreviations; 3 The Mechanism and Kinetics of the RAFT Process: Overview, Rates, Stabilities, Side Reactions, Product Spectrum and Outstanding Challenges; 3.1 History; 3.2 Preequilibrium Kinetics and Mechanism; 3.3 Main Equilibrium Kinetics and Mechanism
3.4 Mechanisms for Rate Retardation/Inhibition - Outstanding Questions3.5 RAFT Copolymerization: Block and Statistical Copolymers; 3.6 The Kinetics and Mechanism of Star and Graft Polymer Formation Processes; 3.7 Mechanism and Kinetics as a Guide for the Synthetic Polymer Chemist; 4 The RAFT Process as a Kinetic Tool: Accessing Fundamental Parameters of Free Radical Polymerization; 4.1 Introduction; 4.2 Chain-Length-Dependent Termination: A Brief Overview; 4.3 RAFT Chemistry as a Tool for Elucidating the Chain Length Dependence of k(t); 4.4 Chain-Length-Dependent Propagation Rate Coefficients
5 The Radical Chemistry of Thiocarbonylthio Compounds: An Overview5.1 Historical Overview and Early Chemistry; 5.2 The Barton-McCombie Deoxygenation; 5.3 A Minor Mechanistic Controversy; 5.4 A New Degenerative Radical Process; 5.5 Synthetic Routes to Thiocarbonylthio Derivatives; 5.6 Some Synthetic Applications of the Degenerative Radical Transfer to Small Molecules; 5.7 Applications to Controlled Radical Polymerizations; 5.8 Concluding Remarks; 6 RAFT Polymerization in Bulk Monomer or in (Organic) Solution; 6.1 Introduction; 6.2 RAFT Agents; 6.3 RAFT Polymerization
6.4 RAFT Polymerization Conditions6.5 Abbreviations; 7 RAFT Polymerization in Homogeneous Aqueous Media: Initiation Systems, RAFT Agent Stability, Monomers and Polymer Structures; 7.1 Introduction; 7.2 Initiation Systems; 7.3 RAFT Agent Stability; 7.4 Suitable Monomers; 7.5 Examples of Experimental Procedures; 8 RAFT-Mediated Polymerization in Heterogeneous Systems; 8.1 Introduction; 8.2 Effect of C(tr,RAFT) on M(n) and PDI in Homogeneous Systems; 8.3 Raft in Heterogeneous Systems; 8.4 Conclusion; 9 Complex Architecture Design via the RAFT Process: Scope, Strengths and Limitations
9.1 Complex Polymer Architectures9.2 Block Copolymers; 9.3 Star Polymers via RAFT Polymerization; 9.4 Comb Polymers; 9.5 Other Complex Architectures; 9.6 Conclusions; 10 Macromolecular Design by Interchange of Xanthates: Background, Design, Scope and Applications; 10.1 Introduction; 10.2 History of MADIX Polymerization; 10.3 Mechanism of MADIX Polymerization; 10.4 Kinetics of MADIX Polymerization; 10.5 Choice of MADIX Agents; 10.6 Synthesis of MADIX Agents; 10.7 Experimental Conditions in MADIX; 10.8 Monomers Polymerizable by MADIX; 10.9 MADIX Polymerization in Waterborne Dispersed Media
10.10 Macromolecular Engineering by MADIX
Record Nr. UNINA-9910841526003321
Weinheim, : Wiley-VCH, c2008
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